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    Adhesives based on polyvinyl ether copolymers
    1.
    发明授权
    Adhesives based on polyvinyl ether copolymers 失效
    基于聚乙烯醚共聚物的粘合剂

    公开(公告)号：US5486586A

    公开(公告)日：1996-01-23

    申请号：US440119

    申请日：1995-05-12

    申请人： Hubertus Kroener ,  Eberhard Schupp ,  Eckehardt Wistuba ,  Oral Aydin ,  Elmar Schwarzenbach ,  Klaus Schnell

    发明人： Hubertus Kroener ,  Eberhard Schupp ,  Eckehardt Wistuba ,  Oral Aydin ,  Elmar Schwarzenbach ,  Klaus Schnell

    IPC分类号： C08F16/26 ,  C08F16/14 ,  C08F16/16 ,  C08F16/28 ,  C08F16/30 ,  C08F216/18 ,  C09J129/00 ,  C09J129/10 ,  C08F16/12

    CPC分类号： C09J129/10

    摘要： Adhesives containing polyvinyl ether copolymers having a weight average molecular weight of >10,000, comprisea) from 0 to 95% by weight of vinyl ethers of the formula IH.sub.2 C.dbd.CH--O--Rb) from 5 to 100% by weight of hydrophilic vinyl ethers of the formula IIH.sub.2 C.dbd.CH--O--R.sup.1andc) from 0 to 30% by weight of further monomers,where R is C.sub.1 -C.sub.20 -alkyl and R.sup.1 is an aliphatic or cycloaliphatic radical which may be substituted by hydroxyl groups or interrupted by nonadjacent groups --Y--, Y is oxygen, sulfur or a group NR.sup.2 or N.sup.+ R.sup.2 R.sup.3 X.sup.-, R.sup.2 and R.sup.3 independently of one another are each hydrogen or C.sub.1 -C.sub.4 -alkyl and X.sup.- is a counter-anion, and the molar ratio of carbon atoms to the sum of groups Y and hydroxyl groups in the aliphatic or cycloaliphatic radical is from 1.01:1 to 6.5:1.

    摘要翻译： 包含重均分子量> 10,000的聚乙烯醚共聚物的粘合剂包含a）0至95重量％的式I的乙烯基醚H 2 C = CH-OR b）5至100重量％的亲水乙烯基醚 的式IIH 2 C = CH-O-R 1和c）0至30重量％的另外的单体，其中R是C 1 -C 20 - 烷基，R 1是可以被羟基取代或被中断的脂族或脂环族基团 通过不相邻的基团-Y-，Y是氧，硫或基团NR2或N + R2R3X-，R2和R3彼此独立地各自是氢或C1-C4-烷基，X是抗衡阴离子， 脂肪族或脂环族基团中碳原子与基团Y和羟基之和的比例为1.01:1至6.5:1。

    Thickeners for aqueous dispersions
    2.
    发明授权
    Thickeners for aqueous dispersions 失效
    增稠剂用于水性分散体

    公开(公告)号：US06803405B1

    公开(公告)日：2004-10-12

    申请号：US10088521

    申请日：2002-03-29

    申请人： Klaus Schnell ,  Michael Kerber ,  Eberhard Schupp ,  Eckehardt Wistuba

    发明人： Klaus Schnell ,  Michael Kerber ,  Eberhard Schupp ,  Eckehardt Wistuba

    IPC分类号： C08L3104

    CPC分类号： C08F226/10 ,  C08F218/08

    摘要： The invention relates to the aqueous preparation of a polymer. Said preparation contains a copolymer consisting of a) 30 to 79.5 wt. % N-vinylpyrrolidone, b) 20 to 69.5 wt. % vinylacetate, c) 0.5 to 25 wt % of a monovinyl ester of a C4 to C20 monocarboxylic acid and d) 0 to 40 wt. % of an additional, copolymerisable, ethylenically unsaturated compound.

    摘要翻译： 本发明涉及聚合物的水性制剂。 所述制备物包含由以下组分组成的共聚物：a）30〜79.5重量％ ％N-乙烯基吡咯烷酮，b）20〜69.5重量％ ％乙酸乙烯酯，c）0.5〜25重量％的C4〜C20一元羧酸的单乙烯基酯，以及d）0〜40重量％ ％的另外的可共聚的烯属不饱和化合物。

    Low molecular weight polymers of acrylic esters
    3.
    发明授权
    Low molecular weight polymers of acrylic esters 失效
    丙烯酸酯的低分子量聚合物

    公开(公告)号：US4983760A

    公开(公告)日：1991-01-08

    申请号：US461744

    申请日：1990-01-08

    申请人： Georg Bobar ,  Klaus Schnell ,  Gerd Schroeder ,  Eckehardt Wistuba

    发明人： Georg Bobar ,  Klaus Schnell ,  Gerd Schroeder ,  Eckehardt Wistuba

    IPC分类号： C08F2/00 ,  C08F2/04 ,  C08F2/06 ,  C08F2/38 ,  C08F20/00 ,  C08F20/12 ,  C08L33/08 ,  C09D7/12 ,  C09J11/08

    CPC分类号： C08F20/12

    摘要： Low molecular weight polymers of acrylic esters which are suitable for use as external plasticizers in coated compositions on a synthetic resin basis are obtainable by subjecting(a) from 80 to 100% by weight of at least one acrylic ester of C.sub.1 -C.sub.8 -alkanol (monomer I) and(b) 0 to 20% by weight of one or more other copolymerizable monomers (monomer II)to a free radical polymerization in a solution in isopropanol in a pressure vessel at 130.degree.-140.degree. C. by introducing first from 70 to 95% by weight of a solvent and adding the remainder of the polymerization batch continuously over 3-7 hours in separate portions of which one contains the monomers and, after the polymerization has ended, distilling off the solvent under reduced pressure, the weight proportion of solvent being 5-15% by weight based on the monomers, the weight proportion of initiator being 0.5-3% by weight based on the monomers, and the half-life of the initiator at the polymerization temperature being from 10 seconds to 3 hours.

    摘要翻译： 通过使（a）80-100重量％的至少一种C 1 -C 8 - 链烷醇的丙烯酸酯（例如，丙烯酸酯） 单体I）和（b）0〜20重量％的一种或多种其它可共聚单体（单体II）与在130-140℃的压力容器中的异丙醇溶液中的自由基聚合反应，首先从 70至95重量％的溶剂，并在3-7小时内连续加入其余的聚合批料，其中单体含有单体，聚合结束后，在减压下蒸除溶剂，重量 基于单体，溶剂的比例为5-15重量％，引发剂的重量比例基于单体为0.5-3重量％，引发剂在聚合温度下的半衰期为10秒至 3小时。

    Methods of producing water-soluble, non-turbid copolymers of at least one water-soluble N-vinyllactam and at least one hydrophobic comonomer
    5.
    发明授权
    Methods of producing water-soluble, non-turbid copolymers of at least one water-soluble N-vinyllactam and at least one hydrophobic comonomer 有权
    制备至少一种水溶性N-乙烯基内酰胺和至少一种疏水性共聚单体的水溶性，非混浊共聚物的方法

    公开(公告)号：US07629425B2

    公开(公告)日：2009-12-08

    申请号：US11947223

    申请日：2007-11-29

    申请人： Rainer Dobrawa ,  Ralf Widmaier ,  Klaus Schnell ,  Karl-Hermann Strube ,  Jürgen Nieberle ,  Reinhold Dieing ,  Bernd de Potzolli ,  Andreas Gruber ,  Ulrich Filges ,  Martin Meister ,  Josef Neutzner ,  Wolfgang Bouquet ,  Eberhard Schupp

    发明人： Rainer Dobrawa ,  Ralf Widmaier ,  Klaus Schnell ,  Karl-Hermann Strube ,  Jürgen Nieberle ,  Reinhold Dieing ,  Bernd de Potzolli ,  Andreas Gruber ,  Ulrich Filges ,  Martin Meister ,  Josef Neutzner ,  Wolfgang Bouquet ,  Eberhard Schupp

    IPC分类号： C08F26/10

    CPC分类号： C08F2/06

    摘要： Methods of producing vinyllactam copolymers which include: providing at least one water-soluble N-vinyllactam; providing at least one hydrophobic comonomer; and subjecting the at least one water-soluble N-vinyllactam and the at least one hydrophobic comonomer to free-radical polymerization in an organic solvent in the presence of an initiator, under a combination of process measures selected from the group consisting of A and B; wherein: (A) comprises (i) polymerization under reflux, and at least two of (ii), (iii), (iv), (v), (vi), and (vii), wherein (ii) comprises an addition of at least 5 mol % of N-vinyllactam to the polymerization mixture if at least 70 mol % of the total amount of hydrophobic monomer used have completely reacted, (iii) comprises return of condensate formed in the reflux from below to the polymerization mixture, (iv) comprises introduction of the initiator in the form of a solution in an organic solvent from below into the polymerization mixture, (v) comprises addition of N-vinyllactam to the reflux, (vi) comprises distilling off a portion of the organic solvent and continuing the polymerization following conversion of 70 to 99% by weight of the N-vinyllactam used, and (vii) comprises introduction of at least one monomer from below into the polymerization mixture; and wherein (B) comprises (viii) polymerization under a superatmospheric pressure such that vaporization of the polymerization components is avoided, and at least one of (i), (ii), (iii), (iv), (v), (vi), and (vii), with the proviso that a combination of (viii) with any of (i), (iii) or (v) is carried out sequentially.

    摘要翻译： 制备乙烯基内酰胺共聚物的方法包括：提供至少一种水溶性N-乙烯基内酰胺; 提供至少一种疏水性共聚单体; 以及在引发剂存在下，使所述至少一种水溶性N-乙烯基内酰胺和所述至少一种疏水性共聚单体在有机溶剂中进行自由基聚合，所述方法选自A和B ; 其中：（A）包括（i）在回流下聚合，和（ii），（iii），（iv），（v），（vi）和（vii）中的至少两个，其中（ii） 的至少5摩尔％的N-乙烯基内酰胺加入到聚合混合物中，如果使用的疏水性单体总量的至少70摩尔％已经完全反应，（iii）包括将从回流中形成的缩合物返回到聚合混合物中， （iv）包括将引发剂以有机溶剂形式从有机溶剂中引入聚合混合物中，（v）包括向回流物中加入N-乙烯基内酰胺，（vi）包括蒸馏除去一部分有机溶剂 并且在所使用的N-乙烯基内酰胺的70至99重量％的转化后继续聚合，和（vii）包括将下述至少一种单体引入聚合混合物中; （ⅰ），（ⅱ），（ⅲ），（ⅳ），（ⅴ），（Ⅴ），（Ⅴ），（Ⅳ），（Ⅳ）， vi）和（vii），条件是（viii）与（i），（iii）或（v）中任何一个的组合依次进行。

    METHODS OF PRODUCING WATER-SOLUBLE, NON-TURBID COPOLYMERS OF AT LEAST ONE WATER-SOLUBLE N-VINYLLACTAM AND AT LEAST ONE HYDROPHOBIC COMONOMER
    9.
    发明申请
    METHODS OF PRODUCING WATER-SOLUBLE, NON-TURBID COPOLYMERS OF AT LEAST ONE WATER-SOLUBLE N-VINYLLACTAM AND AT LEAST ONE HYDROPHOBIC COMONOMER 有权
    生产水溶性方法，至少一种水溶性N-乙烯基甲酰胺和至少一种疏水性共聚物的非涡轮共聚物

    公开(公告)号：US20080125554A1

    公开(公告)日：2008-05-29

    申请号：US11947223

    申请日：2007-11-29

    申请人： Rainer Dobrawa ,  Ralf Widmaier ,  Klaus Schnell ,  Karl-Hermann Strube ,  Jurgen Nieberle ,  Reinhold Dieing ,  Bernd de Potzolli ,  Andreas Gruber ,  Ulrich Filges ,  Martin Meister ,  Josef Neutzner ,  Wolfgang Bouquet ,  Eberhard Schupp

    发明人： Rainer Dobrawa ,  Ralf Widmaier ,  Klaus Schnell ,  Karl-Hermann Strube ,  Jurgen Nieberle ,  Reinhold Dieing ,  Bernd de Potzolli ,  Andreas Gruber ,  Ulrich Filges ,  Martin Meister ,  Josef Neutzner ,  Wolfgang Bouquet ,  Eberhard Schupp

    IPC分类号： C08F4/36

    CPC分类号： C08F2/06

    摘要： Methods of producing vinyllactam copolymers which include: providing at least one water-soluble N-vinyllactam; providing at least one hydrophobic comonomer; and subjecting the at least one water-soluble N-vinyllactam and the at least one hydrophobic comonomer to free-radical polymerization in an organic solvent in the presence of an initiator, under a combination of process measures selected from the group consisting of A and B; wherein:(A) comprises (i) polymerization under reflux, and at least two of (ii), (iii), (iv), (v), (vi), and (vii), wherein (ii) comprises an addition of at least 5 mol % of N-vinyllactam to the polymerization mixture if at least 70 mol % of the total amount of hydrophobic monomer used have completely reacted, (iii) comprises return of condensate formed in the reflux from below to the polymerization mixture, (iv) comprises introduction of the initiator in the form of a solution in an organic solvent from below into the polymerization mixture, (v) comprises addition of N-vinyllactam to the reflux, (vi) comprises distilling off a portion of the organic solvent and continuing the polymerization following conversion of 70 to 99% by weight of the N-vinyllactam used, and (vii) comprises introduction of at least one monomer from below into the polymerization mixture; and wherein(B) comprises (viii) polymerization under a superatmospheric pressure such that vaporization of the polymerization components is avoided, and at least one of (i), (ii), (iii), (iv), (v), (vi), and (vii), with the proviso that a combination of (viii) with any of (i), (iii) or (v) is carried out sequentially.

    摘要翻译： 制备乙烯基内酰胺共聚物的方法包括：提供至少一种水溶性N-乙烯基内酰胺; 提供至少一种疏水性共聚单体; 以及在引发剂存在下，使所述至少一种水溶性N-乙烯基内酰胺和所述至少一种疏水性共聚单体在有机溶剂中进行自由基聚合，所述方法选自A和B ; 其中：（A）包括（i）在回流下聚合，和（ii），（iii），（iv），（v），（vi）和（vii）中的至少两个，其中（ii） 的至少5摩尔％的N-乙烯基内酰胺加入到聚合混合物中，如果使用的疏水性单体总量的至少70摩尔％已经完全反应，（iii）包括将从回流中形成的缩合物返回到聚合混合物中， （iv）包括将引发剂以有机溶剂形式从有机溶剂中引入聚合混合物中，（v）包括向回流物中加入N-乙烯基内酰胺，（vi）包括蒸馏除去一部分有机溶剂 并且在所使用的N-乙烯基内酰胺的70至99重量％的转化后继续聚合，和（vii）包括将下述至少一种单体引入聚合混合物中; （ⅰ），（ⅱ），（ⅲ），（ⅳ），（ⅴ），（Ⅴ），（Ⅴ），（Ⅳ），（Ⅳ）， vi）和（vii），条件是（viii）与（i），（iii）或（v）中任何一个的组合依次进行。