摘要:
The present invention relates to a proton-conducting polymer membrane which comprises polyazoles and is coated with a catalyst layer and is obtainable by a process comprising the steps A) preparation of a mixture comprising polyphosphoric acid, at least one polyazole (polymer A) and/or one or more compounds which are suitable for forming polyazoles under the action of heat according to step B), B) heating of the mixture obtainable according to step A) under inert gas to temperatures of up to 400° C., C) application of a layer using the mixture obtained according to step A) and/or B) to a support, D) treatment of the membrane formed in step C) until it is self-supporting, E) application of at least one catalyst-containing coating to the membrane formed in step C) and/or in step D).
摘要:
The present invention relates to a membrane electrode unit comprising a polymer membrane doped with a mineral acid as well as two electrodes, characterized in that the polymer membrane comprises at least one polymer with at least one nitrogen atom and at least one electrode comprises a catalyst which is formed from at least one precious metal and at least one metal less precious according to the electrochemical series.
摘要:
The present invention relates to a membrane electrode unit comprising a polymer membrane doped with a mineral acid as well as two electrodes, characterized in that the polymer membrane comprises at least one polymer with at least one nitrogen atom and at least one electrode comprises a catalyst which is formed from at least one precious metal and at least one metal less precious according to the electrochemical series.
摘要:
The invention concerns a process for applying catalytically active material to a polymer diaphragm for low-temperature fuel cells. In accordance with the invention a non-polar solvent, catalytically active material and a polymer solution are processed to form a paste. The paste is applied to the diaphragm in layer form, in particular by screen printing. Then the paste is dried and pressed to the diaphragm with the application of heat. Swelling of the diaphragm is avoided by virtue of the presence of non-polar solvents. It is therefore possible to produce the desired product with a few processing steps. Material losses are minimized by the provision of the screen printing procedure. Overall therefore the process is simple and inexpensive.
摘要:
The present invention relates to a proton-conducting polymer membrane which comprises polyazoles and is coated with a catalyst layer and is obtainable by a process comprising the steps A) preparation of a mixture comprising polyphosphoric acid, at least one polyazole (polymer A) and/or one or more compounds which are suitable for forming polyazoles under the action of heat according to step B), B) heating of the mixture obtainable according to step A) under inert gas to temperatures of up to 400° C., C) application of a layer using the mixture obtained according to step A) and/or B) to a support, D) treatment of the membrane formed in step C) until it is self-supporting, E) application of at least one catalyst-containing coating to the membrane formed in step C) and/or in step D).
摘要:
The present invention relates to a proton-conducting polymer membrane coated with a catalyst layer, said polymer membrane comprising polymers which comprise phosphonic acid groups and are obtainable by polymerizing monomers comprising phosphonic acid groups, characterized in that the catalyst layer comprises ionomers which comprise phosphonic acid groups and are obtainable by polymerizing monomers comprising phosphonic acid groups.