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1.发明授权公开(公告)号：US06878409B2
公开(公告)日：2005-04-12
申请号：US10773257
申请日：2004-02-09
申请人： Hoon Sik Kim , Yong Soo Kang , Byung Gwon Lee , Hyun Joo Lee , Jae Hee Ryu
发明人： Hoon Sik Kim , Yong Soo Kang , Byung Gwon Lee , Hyun Joo Lee , Jae Hee Ryu
CPC分类号： C10G31/11 , B01D53/228 , B01D69/142 , C07C7/144 , C07C11/02
摘要： The present invention relates to polymer membranes for separating olefins from paraffins which have the similar molecular size and close boiling point. More particularly, it relates to a silver salt-containing facilitated transport membrane for olefin separation, and also a method for producing the same. An object of the present invention is to provide a silver salt-containing facilitated transport membrane for olefin separation having improved stability, and also a method for preparing the same, which exhibits no deterioration in membrane performance even when operated for an extended period of time. The facilitated transport membrane for olefin/paraffin separation of the present invention comprises a polymer, a silver salt, and a phthalate compound represented by the following formula (1) wherein R denotes an alkyl group of 2 to 8 carbon atoms or a phenyl group.
摘要翻译： 本发明涉及用于从具有相似分子大小和接近沸点的石蜡中分离烯烃的聚合物膜。 更具体地说，本发明涉及一种用于烯烃分离的含银盐的促进输送膜，以及它们的制造方法。 本发明的目的是提供一种具有改进的稳定性的含银盐的促进烯烃分离的输送膜以及其制备方法，即使长时间操作也不会降低膜性能。 本发明的促进烯烃/石蜡分离的输送膜包括由下式（1）表示的聚合物，银盐和邻苯二甲酸酯化合物，其中R表示2至8个碳原子的烷基或苯基。
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2.发明授权公开(公告)号：US09136034B2
公开(公告)日：2015-09-15
申请号：US13394523
申请日：2010-08-25
申请人： Moo-Seok Lee , Yong-Cheol Shin , Jae Hee Ryu , Na Young Kim , Kyoung-Ju Kim , Chul Ki Kim , Yong Hwan Lee , Yun Kyung Kang
发明人： Moo-Seok Lee , Yong-Cheol Shin , Jae Hee Ryu , Na Young Kim , Kyoung-Ju Kim , Chul Ki Kim , Yong Hwan Lee , Yun Kyung Kang
CPC分类号： H01B1/122 , C08J5/2275 , C08J2339/06 , C08J2381/02 , H01M8/0293 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/106 , H01M8/1062 , H01M2300/0088 , Y02E60/521
摘要： The present disclosure relates to a polymer electrolyte membrane having a construction wherein an ionomer is charged in pores of a nanoweb having a high melting point, being insoluble in an organic solvent and having excellent pore characteristics, under optimum conditions. Therefore, an overall thickness of the electrolyte membrane may be reduced, thereby attaining advantages such as decrease in ohmic loss, reduction of material costs, excellent heat resistance, low thickness expansion rate which in turn prevents proton conductivity from being deteriorated over a long term. The polymer electrolyte membrane of the present invention comprises a porous nanoweb having a melting point of 300□ or more and being insoluble in an organic solvent of NMP, DMF, DMA, or DMSO at room temperature; and an ionomer which is charged in pores of the porous nanoweb and contains a hydrocarbon material soluble in the organic solvent at room temperature.
摘要翻译： 本公开内容涉及一种具有这样一种结构的聚合物电解质膜，其中在最佳条件下，将离聚物加入具有高熔点的纳米纤维网的孔中，不溶于有机溶剂并具有优异的孔特性。 因此，可以降低电解质膜的整体厚度，从而获得诸如欧姆损耗降低，材料成本降低，耐热性优异，低厚度膨胀率的优点，从而防止质子传导性长期劣化。 本发明的高分子电解质膜包含在室温下熔点为300□以上且不溶于NMP，DMF，DMA或DMSO的有机溶剂的多孔纳米纤维网; 和离子交联聚合物，其装入多孔纳米纤维网的孔中，并含有在室温下可溶于有机溶剂的烃类物质。
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3.发明申请公开(公告)号：US20120231355A1
公开(公告)日：2012-09-13
申请号：US13394523
申请日：2010-08-25
申请人： Moo-Seok Lee , Yong-Cheol Shin , Jae Hee Ryu , Na Young Kim , Kyoung-Ju Kim , Chul Ki Kim , Yong-Hwan Lee , Yun Kyung Kang
发明人： Moo-Seok Lee , Yong-Cheol Shin , Jae Hee Ryu , Na Young Kim , Kyoung-Ju Kim , Chul Ki Kim , Yong-Hwan Lee , Yun Kyung Kang
CPC分类号： H01B1/122 , C08J5/2275 , C08J2339/06 , C08J2381/02 , H01M8/0293 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/106 , H01M8/1062 , H01M2300/0088 , Y02E60/521
摘要： The present disclosure relates to a polymer electrolyte membrane having a construction wherein an ionomer is charged in pores of a nanoweb having a high melting point, being insoluble in an organic solvent and having excellent pore characteristics, under optimum conditions. Therefore, an overall thickness of the electrolyte membrane may be reduced, thereby attaining advantages such as decrease in ohmic loss, reduction of material costs, excellent heat resistance, low thickness expansion rate which in turn prevents proton conductivity from being deteriorated over a long term. The polymer electrolyte membrane of the present invention comprises a porous nanoweb having a melting point of 300□ or more and being insoluble in an organic solvent of NMP, DMF, DMA, or DMSO at room temperature; and an ionomer which is charged in pores of the porous nanoweb and contains a hydrocarbon material soluble in the organic solvent at room temperature.
摘要翻译： 本公开内容涉及一种具有这样一种结构的聚合物电解质膜，其中在最佳条件下，将离聚物加入具有高熔点的纳米纤维网的孔中，不溶于有机溶剂并具有优异的孔特性。 因此，可以降低电解质膜的整体厚度，从而获得诸如欧姆损耗降低，材料成本降低，耐热性优异，低厚度膨胀率的优点，从而防止质子传导性长期劣化。 本发明的高分子电解质膜包含在室温下熔点为300□以上且不溶于NMP，DMF，DMA或DMSO的有机溶剂的多孔纳米纤维网; 和离子交联聚合物，其装入多孔纳米纤维网的孔中，并含有在室温下可溶于有机溶剂的烃类物质。
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公开(公告)号：US20110049026A1
公开(公告)日：2011-03-03
申请号：US12638155
申请日：2009-12-15
申请人： Jae Hee RYU , Yong-Cheol Shin , Moo-Seok Lee
发明人： Jae Hee RYU , Yong-Cheol Shin , Moo-Seok Lee
CPC分类号： C02F1/444 , B01D63/024 , B01D63/043 , B01D71/26 , B01D71/68 , B01D2319/00 , B01D2319/06 , B01D2325/36 , B01D2325/38
摘要： A hollow fiber membrane module with good ventilativity is disclosed, which is capable of reducing a time period for completely filling a water space of housing with water introduced through a water inlet by quickly replacing the air in the water space with the water thereby improving the efficiency of water flow.
摘要翻译： 公开了一种具有良好透气性的中空纤维膜组件，其能够通过用水快速地更换水空间中的空气来缩短通过入水口引入的水完全填充壳体的水空间的时间，从而提高效率 的水流。
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公开(公告)号：US20080199619A1
公开(公告)日：2008-08-21
申请号：US12063070
申请日：2006-08-08
申请人： Jae Hee Ryu , Sung Hak Choi , Kwang Jin Lee
发明人： Jae Hee Ryu , Sung Hak Choi , Kwang Jin Lee
IPC分类号： B05D3/10
CPC分类号： C08J5/2275 , C08J2300/202
摘要： The present invention provides a method of manufacturing an aromatic polyamide composite membrane comprising: coating an aqueous solution containing polyfunctional aromatic amine to a porous polymer substrate; and reacting the coated substrate with an organic solution containing polyfunctional aromatic acyl halide to lead to interfacial condensation polymerization between the polyfunctional aromatic amine and the polyfunctional aromatic acyl halide so that the reaction product resulting from the interfacial condensation polymerization is coated on the surface of the substrate, characterized in that either of the aqueous solution containing polyfunctional aromatic amine or the organic solution containing polyfunctional aromatic acyl halide has dendritic polymer as one of polyfunctional compounds added thereto. The resulting aromatic polyamide composite membrane which includes dendrimer as polyfunctional compound, exhibits high salt rejection rate and water flux.
摘要翻译： 本发明提供了一种制备芳族聚酰胺复合膜的方法，包括：将多官能芳族胺的水溶液涂布到多孔聚合物基材上; 并使涂覆的基材与含有多官能芳族酰卤的有机溶液反应，导致多官能芳族胺和多官能芳族酰卤之间的界面缩聚，从而将界面缩聚产生的反应产物涂覆在基材表面上 其特征在于，含有多官能芳香族胺的水溶液或含有多官能芳香族酰卤的有机溶液中的任一种都具有树枝状聚合物作为添加多官能化合物之一。 得到的芳香族聚酰胺复合膜，其包含作为多官能化合物的树枝状大分子，显示出高的脱盐率和水通量。
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6.发明授权公开(公告)号：US06706771B2
公开(公告)日：2004-03-16
申请号：US10194303
申请日：2002-07-15
申请人： Hoon Sik Kim , Yong Soo Kang , Byung Gwon Lee , Hyun Joo Lee , Jae Hee Ryu
发明人： Hoon Sik Kim , Yong Soo Kang , Byung Gwon Lee , Hyun Joo Lee , Jae Hee Ryu
IPC分类号： C08J520
CPC分类号： C10G31/11 , B01D53/228 , B01D69/142 , C07C7/144 , C07C11/02
摘要： The present invention relates to polymer membranes for separating olefins from paraffins which have the similar molecular size and close boiling point. More particularly, it relates to a silver salt-containing facilitated transport membrane for olefin separation, and also a method for producing the same. An object of the present invention is to provide a silver salt-containing facilitated transport membrane for olefin separation having improved stability, and also a method for preparing the same, which exhibits no deterioration in membrane performance even when operated for an extended period of time. The facilitated transport membrane for olefin/paraffin separation of the present invention comprises a polymer, a silver salt, and a phthalate compound represented by the following formula (1) wherein R denotes an alkyl group of 2 to 8 carbon atoms or a phenyl group.
摘要翻译： 本发明涉及用于从具有相似分子大小和接近沸点的石蜡中分离烯烃的聚合物膜。 更具体地说，本发明涉及一种用于烯烃分离的含银盐的促进输送膜，以及它们的制造方法。 本发明的目的是提供一种具有改进的稳定性的含银盐的促进烯烃分离的输送膜以及其制备方法，即使长时间操作也不会降低膜性能。 本发明的促进烯烃/石蜡分离的输送膜包括由下式（1）表示的聚合物，银盐和邻苯二甲酸酯化合物，其中R表示2至8个碳原子的烷基或苯基。
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公开(公告)号：US09034189B2
公开(公告)日：2015-05-19
申请号：US14114840
申请日：2012-06-21
申请人： Jae Hee Ryu , Yong-Cheol Shin , Kwang-Jin Lee , Moo-Seok Lee
发明人： Jae Hee Ryu , Yong-Cheol Shin , Kwang-Jin Lee , Moo-Seok Lee
IPC分类号： B01D63/04 , B01D69/08 , B01D69/12 , B01D71/68 , B01D71/34 , B01D71/48 , B01D63/02 , B01D69/10
CPC分类号： B01D63/04 , B01D63/021 , B01D63/027 , B01D69/08 , B01D69/10 , B01D69/12 , B01D71/34 , B01D71/48 , B01D71/68 , B01D2313/23 , B01D2325/40
摘要： Disclosed is a pressurized hollow fiber membrane module that exhibits improved durability without deterioration in packing density and permeation flux. The pressurized hollow fiber membrane module includes a composite hollow fiber membrane comprising a tubular braid woven by yarns and a polymer film on the outer surface of the tubular braid. At least one of the yarns comprises a small-fineness filament and a medium-fineness filament. The small-fineness filament comprises first monofilaments having a fineness of 0.01 to 0.4 denier, the medium-fineness filament comprises second monofilaments having a fineness higher than 0.4 and lower than 3, and a ratio of thickness of the tubular braid to outer diameter thereof is 15 to 35%.
摘要翻译： 公开了一种加压中空纤维膜组件，其具有改善的耐久性，而不会降低填充密度和渗透通量。 加压中空纤维膜组件包括复合中空纤维膜，其包括由纱线编织的管状编织物和在管状编织物的外表面上的聚合物膜。 至少一根纱线包括细细丝和中细丝。 小细丝包括细度为0.01至0.4旦尼尔的第一单丝，中细丝包括细度高于0.4且低于3的第二单丝，并且管状编织物的厚度与外径之比为 15到35％。
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