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    SILICIDE COMPOSITIONS CONTAINING ALKALI METALS AND METHODS OF MAKING THE SAME
    1.
    发明申请
    SILICIDE COMPOSITIONS CONTAINING ALKALI METALS AND METHODS OF MAKING THE SAME 有权
    含有碱金属的硅氧烷组合物及其制备方法

    公开(公告)号：US20120201734A1

    公开(公告)日：2012-08-09

    申请号：US13445557

    申请日：2012-04-12

    申请人： Michael LEFENFELD ,  James L. DYE

    发明人： Michael LEFENFELD ,  James L. DYE

    IPC分类号： C01B33/06 ,  B08B7/00 ,  F24J1/00 ,  C01B3/06

    CPC分类号： C11D7/04 ,  C01B3/06 ,  C01B3/08 ,  C01B33/06 ,  C11D17/042 ,  F24V30/00 ,  Y02E60/364

    摘要： The invention relates to a method of making alkali metal silicide compositions, and the compositions resulting from the method, comprising mixing an alkali metal with silicon and heating the resulting mixture to a temperature below about 475° C. The resulting compositions do not react with dry O2. Also, the invention relates to sodium silicide compositions having a powder X-ray diffraction pattern comprising at least three peaks with 2Theta angles selected from about 18.2, 28.5, 29.5, 33.7, 41.2, 47.4, and 56.2 and a solid state 23Na MAS NMR spectra peak at about 18 ppm. Moreover, the invention relates to methods of removing a volatile or flammable substance in a controlled manner. Furthermore, the alkali metal silicide compositions of the invention react with water to produce hydrogen gas.

    摘要翻译： 本发明涉及一种制备碱金属硅化物组合物的方法和由该方法得到的组合物，其包括将碱金属与硅混合并将所得混合物加热至低于约475℃的温度。所得组合物不与干 O2。 此外，本发明涉及具有粉末X射线衍射图的硅化钠组合物，其包含至少三个具有选自约18.2,28.5,29.5,33.7,41.2,47.4和56.2的2θ角的峰和固态23Na MAS NMR光谱 峰值约为18ppm。 此外，本发明涉及以受控方式除去挥发性或易燃物质的方法。 此外，本发明的碱金属硅化物组合物与水反应产生氢气。

    Lithium-porous metal oxide compositions and lithium reagent-porous metal compositions
    2.
    发明授权
    Lithium-porous metal oxide compositions and lithium reagent-porous metal compositions 有权
    锂多孔金属氧化物组合物和锂试剂多孔金属组合物

    公开(公告)号：US08197707B2

    公开(公告)日：2012-06-12

    申请号：US11852820

    申请日：2007-09-10

    申请人： Michael Lefenfeld ,  James L. Dye ,  Partha Nandi ,  James Jackson

    发明人： Michael Lefenfeld ,  James L. Dye ,  Partha Nandi ,  James Jackson

    IPC分类号： H01M4/58 ,  B05D5/12

    CPC分类号： C07F1/02 ,  C01C1/026 ,  C01D15/00 ,  C01P2002/86 ,  C01P2002/87 ,  C01P2002/89 ,  C01P2006/16 ,  Y02P20/52

    摘要： The invention relates to lithium metal/porous metal oxide compositions. These lithium metal compositions are prepared by mixing liquid lithium metal with a porous metal oxide in an inert atmosphere under exothermic conditions sufficient to absorb the liquid lithium metal into the porous metal oxide pores. The lithium metal/porous metal oxide compositions of the invention are preferably loaded with lithium metal up to about 40% by weight, with about 20% to 40% by weight being the most preferred loading. The invention also relates to lithium reagent-porous metal oxide compositions having RLi absorbed into a porous oxide. The preparation and use of these compositions are also described.

    摘要翻译： 本发明涉及锂金属/多孔金属氧化物组合物。 这些锂金属组合物通过在惰性气氛中将液态锂金属与多孔金属氧化物混合，在足以将液态锂金属吸收到多孔金属氧化物孔中的放热条件下来制备。 本发明的锂金属/多孔金属氧化物组合物优选负载高达约40重量％的锂金属，其中最优选的负载量为约20重量％至40重量％。 本发明还涉及具有吸收到多孔氧化物中的RLi的锂试剂多孔金属氧化物组合物。 还描述了这些组合物的制备和用途。

    LITHIUM-POROUS METAL OXIDE COMPOSITIONS AND LITHIUM REAGENT-POROUS METAL COMPOSITIONS
    3.
    发明申请
    LITHIUM-POROUS METAL OXIDE COMPOSITIONS AND LITHIUM REAGENT-POROUS METAL COMPOSITIONS 审中-公开
    锂金属氧化物组合物和锂试剂多孔金属组合物

    公开(公告)号：US20120235084A1

    公开(公告)日：2012-09-20

    申请号：US13469299

    申请日：2012-05-11

    申请人： Michael LEFENFELD ,  James L. DYE ,  Partha NANDI ,  James JACKSON

    发明人： Michael LEFENFELD ,  James L. DYE ,  Partha NANDI ,  James JACKSON

    IPC分类号： C09K3/00

    CPC分类号： C07F1/02 ,  C01C1/026 ,  C01D15/00 ,  C01P2002/86 ,  C01P2002/87 ,  C01P2002/89 ,  C01P2006/16 ,  Y02P20/52

    摘要： The invention relates to lithium metal/porous metal oxide compositions. These lithium metal compositions are prepared by mixing liquid lithium metal with a porous metal oxide in an inert atmosphere under exothermic conditions sufficient to absorb the liquid lithium metal into the porous metal oxide pores. The lithium metal/porous metal oxide compositions of the invention are preferably loaded with lithium metal up to about 40% by weight, with about 20% to 40% by weight being the most preferred loading. The invention also relates to lithium reagent-porous metal oxide compositions having RLi absorbed into a porous oxide. In formula RLi, R is an alkyl group, an alkenyl group, an alkynyl group, an aryl group, an alkaryl group, or an NR1R2 group; R1 is an alkyl group, an alkenyl group, an alkynyl group, an aryl group, an alkaryl group; and R2 is hydrogen, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, and an alkaryl group. The preparation and use of these compositions are also described.

    摘要翻译： 本发明涉及锂金属/多孔金属氧化物组合物。 这些锂金属组合物通过在惰性气氛中将液态锂金属与多孔金属氧化物混合，在足以将液态锂金属吸收到多孔金属氧化物孔中的放热条件下来制备。 本发明的锂金属/多孔金属氧化物组合物优选负载高达约40重量％的锂金属，其中最优选的负载量为约20重量％至40重量％。 本发明还涉及具有吸收到多孔氧化物中的RLi的锂试剂多孔金属氧化物组合物。 在式RLi中，R是烷基，烯基，炔基，芳基，烷芳基或NR1R2基团; R1是烷基，烯基，炔基，芳基，烷芳基; R2是氢，烷基，烯基，炔基，芳基和烷芳基。 还描述了这些组合物的制备和用途。

    Method for deprotecting aryl or alkyl sulfonamides of primary or secondary amines
    4.
    发明授权
    Method for deprotecting aryl or alkyl sulfonamides of primary or secondary amines 有权
    伯胺或仲胺芳基或烷基磺酰胺脱保护方法

    公开(公告)号：US08263808B2

    公开(公告)日：2012-09-11

    申请号：US12300409

    申请日：2007-02-13

    申请人： Michael Lefenfeld ,  James L. Dye ,  Partha Nandi ,  James Jackson

    发明人： Michael Lefenfeld ,  James L. Dye ,  Partha Nandi ,  James Jackson

    IPC分类号： C07C209/00

    CPC分类号： C07D211/96 ,  C07C209/62 ,  C07C213/08 ,  C07C2601/14 ,  Y02P20/55 ,  C07C211/35 ,  C07C211/40 ,  C07C211/45 ,  C07C217/08

    摘要： The invention relates to a method for removing an alkyl sulfonyl or aryl sulfonyl protecting group from a primary or secondary amine by contacting an alkyl sulfonamide or an aryl sulfonamide with a Stage 0 or Stage I alkali metal-silica gel material in the presence of a solid proton source under conditions sufficient to form the corresponding amine. The invention also relates to a method for removing an alkyl sulfonyl or aryl sulfonyl protecting group from a primary or secondary amine by a) reacting an alkyl sulfonamide or an aryl sulfonamide with a Stage 0 or Stage I alkali metal-silica gel material, and b) subsequently reacting the reaction product from step a) with an electrophile or a proton source. Preferred Stage 0 or Stage I alkali metal-silica gel materials include Na, K2Na, and Na2K.

    摘要翻译： 本发明涉及通过在固体存在下使烷基磺酰胺或芳基磺酰胺与阶段0或阶段I碱金属 - 硅胶材料接触来从伯胺或仲胺除去烷基磺酰基或芳基磺酰基保护基的方法 质子源在足以形成相应胺的条件下。 本发明还涉及通过以下步骤从伯胺或仲胺除去烷基磺酰基或芳基磺酰基保护基的方法：a）使烷基磺酰胺或芳基磺酰胺与阶段0或阶段I碱金属 - 硅胶材料反应，b ）随后使来自步骤a）的反应产物与亲电试剂或质子源反应。 优选的阶段0或阶段I碱金属 - 硅胶材料包括Na，K 2 Na和Na 2 K。

    SILICIDE COMPOSITIONS CONTAINING ALKALI METALS AND METHODS OF MAKING THE SAME
    6.
    发明申请
    SILICIDE COMPOSITIONS CONTAINING ALKALI METALS AND METHODS OF MAKING THE SAME 有权
    含有碱金属的硅氧烷组合物及其制备方法

    公开(公告)号：US20100316917A1

    公开(公告)日：2010-12-16

    申请号：US12854510

    申请日：2010-08-11

    申请人： Michael LEFENFELD ,  James L. DYE

    发明人： Michael LEFENFELD ,  James L. DYE

    IPC分类号： H01M8/06 ,  C01B33/06 ,  C01B3/04 ,  C02F1/68

    CPC分类号： C11D7/04 ,  C01B3/06 ,  C01B3/08 ,  C01B33/06 ,  C11D17/042 ,  F24V30/00 ,  Y02E60/364

    摘要： The invention relates to a method of making alkali metal silicide compositions, and the compositions resulting from the method, comprising mixing an alkali metal with silicon and heating the resulting mixture to a temperature below about 475° C. The resulting compositions do not react with dry O2. Also, the invention relates to sodium silicide compositions having a powder X-ray diffraction pattern comprising at least three peaks with 2Theta angles selected from about 18.2, 28.5, 29.5, 33.7, 41.2, 47.4, and 56.2 and a solid state 23Na MAS NMR spectra peak at about 18 ppm. Moreover, the invention relates to methods of removing a volatile or flammable substance in a controlled manner. Furthermore, the alkali metal silicide compositions of the invention react with water to produce hydrogen gas.

    摘要翻译： 本发明涉及一种制备碱金属硅化物组合物的方法和由该方法得到的组合物，其包括将碱金属与硅混合并将所得混合物加热至低于约475℃的温度。所得组合物不与干 O2。 此外，本发明涉及具有粉末X射线衍射图的硅化钠组合物，其包含至少三个具有选自约18.2,28.5,29.5,33.7,41.2,47.4和56.2的2θ角的峰和固态23Na MAS NMR光谱 峰值约为18ppm。 此外，本发明涉及以受控方式除去挥发性或易燃物质的方法。 此外，本发明的碱金属硅化物组合物与水反应产生氢气。

    METHOD FOR DEPROTECTING ARYL OR ALKYL SULFONAMIDES OF PRIMARY OR SECONDARY AMINES
    7.
    发明申请
    METHOD FOR DEPROTECTING ARYL OR ALKYL SULFONAMIDES OF PRIMARY OR SECONDARY AMINES 有权
    用于去除主要或次要氨基的亚芳基或亚氨基磺酰胺的方法

    公开(公告)号：US20090306391A1

    公开(公告)日：2009-12-10

    申请号：US12300409

    申请日：2007-02-13

    申请人： Michael Lefenfeld ,  James L. Dye ,  Partha Nandi ,  James Jackson

    发明人： Michael Lefenfeld ,  James L. Dye ,  Partha Nandi ,  James Jackson

    IPC分类号： C07D211/12 ,  C07C209/68 ,  C07C213/08

    CPC分类号： C07D211/96 ,  C07C209/62 ,  C07C213/08 ,  C07C2601/14 ,  Y02P20/55 ,  C07C211/35 ,  C07C211/40 ,  C07C211/45 ,  C07C217/08

    摘要： The invention relates to a method for removing an alkyl sulfonyl or aryl sulfonyl protecting group from a primary or secondary amine by contacting an alkyl sulfonamide or an aryl sulfonamide with a Stage 0 or Stage I alkali metal-silica gel material in the presence of a solid proton source under conditions sufficient to form the corresponding amine. The invention also relates to a method for removing an alkyl sulfonyl or aryl sulfonyl protecting group from a primary or secondary amine by a) reacting an alkyl sulfonamide or an aryl sulfonamide with a Stage 0 or Stage I alkali metal-silica gel material, and b) subsequently reacting the reaction product from step a) with an electrophile or a proton source. Preferred Stage 0 or Stage I alkali metal-silica gel materials include Na, K2Na, and Na2K.

    摘要翻译： 本发明涉及通过在固体存在下使烷基磺酰胺或芳基磺酰胺与阶段0或阶段I碱金属 - 硅胶材料接触来从伯胺或仲胺除去烷基磺酰基或芳基磺酰基保护基的方法 质子源在足以形成相应胺的条件下。 本发明还涉及通过以下步骤从伯胺或仲胺除去烷基磺酰基或芳基磺酰基保护基的方法：a）使烷基磺酰胺或芳基磺酰胺与阶段0或阶段I碱金属 - 硅胶材料反应，b ）随后使来自步骤a）的反应产物与亲电试剂或质子源反应。 优选的阶段0或阶段I碱金属 - 硅胶材料包括Na，K 2 Na和Na 2 K。

    Titanium oxide and alumina alkali metal compositions
    8.
    发明授权
    Titanium oxide and alumina alkali metal compositions 有权
    氧化钛和氧化铝碱金属组合物

    公开(公告)号：US07560606B2

    公开(公告)日：2009-07-14

    申请号：US11839684

    申请日：2007-08-16

    申请人： Michael Lefenfeld ,  James L. Dye

    发明人： Michael Lefenfeld ,  James L. Dye

    IPC分类号： C01B3/08 ,  C01F7/02 ,  C01G23/04 ,  C07C15/18 ,  C07C15/28

    CPC分类号： C01G23/00 ,  B01J21/04 ,  B01J21/063 ,  B01J23/04 ,  B01J35/1061 ,  B01J35/1066 ,  B01J37/0081 ,  B01J37/0201 ,  B01J37/023 ,  B01J37/08 ,  C01B3/042 ,  C01B3/065 ,  C01B3/08 ,  C01P2006/16 ,  C07C1/26 ,  C07C2/861 ,  C07C5/324 ,  C07C17/23 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2523/04 ,  Y02E60/362 ,  Y02E60/364 ,  C07C15/18 ,  C07C15/20

    摘要： The invention relates to Group 1 metal/porous metal oxide compositions comprising porous metal oxide selected from porous titanium oxide and porous alumina and an alkali metal or an alkali metal alloy. The compositions of the inventions are described as Stage 0 and I materials. These materials differ in their preparation and chemical reactivity. Each successive stage may be prepared directly using the methods described below or from an earlier stage material. Stage 0 materials may, for example, be prepared using liquid alloys of Na and K which are rapidly absorbed by porous metal oxide under isothermal conditions, preferably at or just above room temperature, to form loose black powders that retain much of the reducing ability of the parent metals. When the low melting Group 1 metals are absorbed into the porous metal oxide at about 150° C., an exothermic reaction produces Stage I material, loose black powders that are stable in dry air. Further heating forms higher stage materials of unknown composition. It is believed that Stage I higher materials represent reductions of the porous metal oxide after absorption of the Group 1 metal. Preferred Group 1 metal/porous metal oxide compositions of the invention are those containing sodium, potassium, or sodium-potassium alloys with sodium and sodium-potassium alloys being most preferred. Each stage of the Group 1 metal/porous metal oxide composition of the invention may be used as a reducing agent reacting with a number of reducible organic materials in the same manner known for alkali metals and their alloys.

    摘要翻译： 本发明涉及包含选自多孔氧化钛和多孔氧化铝的多孔金属氧化物和碱金属或碱金属合金的第1族金属/多孔金属氧化物组合物。 本发明的组合物被描述为阶段0和I材料。 这些材料的制备和化学反应性不同。 可以使用下述方法或从较早阶段的材料直接制备每个连续阶段。 阶段0材料可以例如使用Na和K的液体合金制备，其在等温条件下优选在或刚好高于室温下被多孔金属氧化物快速吸收，形成松散的黑色粉末，其保留大量的还原能力 母体金属。 当低熔点的第1族金属在约150℃下被吸收到多孔金属氧化物中时，放热反应产生阶段I材料，在干燥空气中稳定的松散的黑色粉末。 进一步加热形成未知组成的较高级材料。 据信，第一阶段较高的材料表示吸收第1族金属后多孔金属氧化物的减少。 优选的本发明的第1族金属/多孔金属氧化物组合物是含有钠，钾或钠 - 钾合金的那些，其中钠和钠 - 钾合金是最优选的。 本发明的第1族金属/多孔金属氧化物组合物的每个阶段可以以与碱金属及其合金已知的相同方式用作与许多可还原的有机材料反应的还原剂。

    Alloy of AuZn AuCu or ZnCu
    9.
    发明授权
    Alloy of AuZn AuCu or ZnCu 失效
    AuZn AuCu或ZnCu合金

    公开(公告)号：US06350408B1

    公开(公告)日：2002-02-26

    申请号：US08692310

    申请日：1996-08-05

    申请人： James L. Dye ,  Ahmed S. Ellaboudy ,  Kuo-Lih Tsai

    发明人： James L. Dye ,  Ahmed S. Ellaboudy ,  Kuo-Lih Tsai

    IPC分类号： C22C3000

    CPC分类号： B82Y30/00 ,  B22F1/0018 ,  B22F1/025 ,  B22F9/24 ,  C21B15/006 ,  C22C5/00

    摘要： A process for producing finely divided 20 to 500 angstrom metal particles, metals with oxide coatings or metal oxides using an alkalide or electride in a non-reactive solvent is described. The process produces various forms of the metal depending upon the oxidizability of the metal initially produced by the process. The process is useful for producing catalysts, alloys, colloidal solutions, semi-conductors and the like.

    摘要翻译： 描述了在非反应性溶剂中生产细分20至500埃的金属颗粒，具有氧化物涂层或金属氧化物的金属的方法，该方法使用碱处理或碱处理。 该方法根据最初由该方法生产的金属的氧化性，产生各种形式的金属。 该方法可用于生产催化剂，合金，胶体溶液，半导体等。