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1.发明授权New sulfured compounds, their preparation and their use as additives for lubricating oils 失效新型硫化物，它们的制备及其作为润滑油添加剂的用途
公开(公告)号：US5415794A
公开(公告)日：1995-05-16
申请号：US240588
申请日：1994-05-10
IPC分类号： C07C321/14 , C07C321/18 , C10M135/22
CPC分类号： C07C321/14 , C07C321/18 , C10M135/22 , C10M2219/082 , C10M2221/043
摘要： Novel sulfurized compounds, their preparation and use. The compounds are based on the general formula{[R-S.sub.x --(CH.sub.2).sub.n --].sub.z CH.sub.3-z --(CH.sub.2).sub.p --}.sub.2 S.sub.y,in which R is a monovalent hydrocarbon radical having 1 to 30 carbon atoms, optionally functionalized; x is a number equal to or greater than 1; z is an integer equal to 1 or 2; when z=1, n is an integer from 0 to 3 and p is an integer from 0 to 3, with n+p being an integer from 0 to 3; when z=2, n is an integer from 1 to 3 and p is an integer from 0 to 3; and y is a number equal to or greater than 1, at least one of the numbers x and y being strictly greater than 1. The sulphurized compounds can be used as extreme pressure or wear prevention additives in lubricating oils, in particular in oils for gear systems and those used in working metal.
摘要翻译： 新型硫化化合物，其制备和用途。 化合物基于通式{[R-Sx-（CH2）n-] zCH3-z-（CH2）p-} 2Sy，其中R是具有1至30个碳原子的一价烃基，任选官能化; x是等于或大于1的数字; z是等于1或2的整数; 当z = 1时，n为0〜3的整数，p为0〜3的整数，n + p为0〜3的整数。 当z = 2时，n为1〜3的整数，p为0〜3的整数。 并且y是等于或大于1的数字，数字x和y中的至少一个严格大于1.硫化化合物可用作润滑油中的极压或耐磨性添加剂，特别是用于齿轮的油 系统和用于工作金属的系统。
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公开(公告)号：US5663401A
公开(公告)日：1997-09-02
申请号：US369484
申请日：1995-01-06
CPC分类号： C08F30/02 , C07F9/1651
摘要： Compounds represented by the formulae (I) and (II) in which:R.sup.1 =H or CH.sub.3 ;X=O or S;R.sup.2 =C.sub.1-12 straight-chain or branched alkylene groups, monocyclic or polycyclic cycloalkylene and heterocycloalkylene groups, alkylarylene and arylalkylene groups;R.sup.6 =H or C.sub.1-12 alkyl and aryl radicals;R.sup.3 =C.sub.1-20 alkyl and aryl radicals, --(CH.sub.2).sub.p SR.sup.4 groups where p=integer from 2 to 12 and R.sup.4 =C.sub.1-20 alkyl, and ##STR1## where q is an integer from 2 to 12 and R.sup.5 =H or CH.sub.3. ##STR2##
摘要翻译： 由式（I）和（II）表示的化合物，其中：R 1 = H或CH 3; X = O或S; R2 = C1-12直链或支链亚烷基，单环或多环亚环烷基和杂环亚烷基，烷基亚芳基和芳基亚烷基; R6 = H或C1-12烷基和芳基; R3 = C1-20烷基和芳基， - （CH2）pSR4基团，其中p = 2至12的整数，R4 = C1-20烷基，和其中q是2至12的整数，R5 = H或 CH3。 （I）
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3.发明授权Process for the preparation of phosphosulfide compounds useful as oil lubricants 失效制备可用作油润滑剂的磷硫化合物的方法
公开(公告)号：US5463132A
公开(公告)日：1995-10-31
申请号：US186077
申请日：1994-01-25
IPC分类号： C07F9/09 , C07F9/141 , C07F9/165 , C07F9/173 , C10M137/02 , C10M137/10 , C10M137/14 , C10N10/04 , C10N30/06 , C10N30/10 , C10N40/04 , C07C319/14
CPC分类号： C10M137/14 , C07F9/091 , C07F9/1411 , C07F9/1651 , C10M137/02 , C10M137/105
摘要： Useful as additive for lubricating oils are novel phosphosulphur compounds in accordance with the general formula (I):(((R.sup.1 --S.sub.x --O.sub.y --A--).sub.r B.sub.v).sub.p P(X)--Y.sub.i --).sub.q Z.sub.min which e.g. R.sup.1 represents an alkyl or alkenyl group, A represents the group --(CH.sub.2).sub.n --O--, B represents the group --P(S)--S--CH.sub.2 --(CH.sub.3)--O--, X represents an oxygen atom or a sulphur atom, Y represents an oxygen atom, a sulphur atom or an oxygen or sulphur-containing hydrocarbon chain, Z represents a hydrogen, chlorine or sulphur atom, a polysulphide chain, a metal or an alkyl or alkenyl group, x=1,2 or 3, y=0, 1 or 2, v is 0 or 1, r is 1 (if v=0) or r=2 (if v=1), p=2 or 3, t=0 or 1, m=0,1 or 2, q=the valency of Z if Z is a metal or q=1 or 2 and n is an integer from 1 to 30.
摘要翻译： 可用作润滑油的添加剂是根据通式（I）：（（（R1-Sx-Oy-A-）rBv）pP（X）-Yi-）qZm的新型磷硫化合物，其中例如 R1表示烷基或烯基，A表示 - （CH2）nO-基团，B表示基团-P（S）-S-CH2-（CH3）-O-，X表示氧原子或硫原子， Y表示氧原子，硫原子或含氧或含硫烃链，Z表示氢，氯或硫原子，多硫化物链，金属或烷基或烯基，x = 1,2或3， y = 0,1或2，v为0或1，r为1（如果v = 0）或r = 2（如果v = 1），p = 2或3，t = 0或1，m = 1或2，如果Z是金属或q = 1或2，且n是1至30的整数，q = Z的化合价。
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4.发明授权(Thio) (meth) acrylate monomers, intermediate compounds for the synthesis of these monomers, polymerizable compositions and polymers obtained, and their optical and ophthalmic uses 失效（Thio）（甲基）丙烯酸酯单体，用于合成这些单体的中间体化合物，可聚合组合物和获得的聚合物，以及它们的光学和眼科用途公开(公告)号：US06472488B2
公开(公告)日：2002-10-29
申请号：US09957597
申请日：2001-09-20
申请人： Florence Caye , Michèle Sindt , Daniel Paquer , Dorothée Jury , Michel Schneider , Jean-Luc Mieloszynski
发明人： Florence Caye , Michèle Sindt , Daniel Paquer , Dorothée Jury , Michel Schneider , Jean-Luc Mieloszynski
IPC分类号： C08F12802
CPC分类号： C08F20/38 , C07D339/00 , C07D339/04 , C07D339/08 , C07D341/00 , G02B1/041 , C08L33/14
摘要： Polymerizable compositions from novel monomers that correspond to the formula: in which: Z represents H or CH3 and X represents O or S, and Y is a 5- to 8-membered heterocycle consisting of hydrogen, carbon and sulphur atoms and at least two endocyclic sulphur atoms.
摘要翻译： 新型单体可与下式对应的可聚合组合物：其中：Z代表H或CH3，X代表O或S，Y是由氢，碳和硫原子组成的5至8元杂环和至少两个内环硫 原子
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5.发明授权(Meth) acrylic compounds, process for their preparation and their application to the synthesis of new polymers 失效（甲基）丙烯酸酯化合物，其制备方法及其在合成新聚合物中的应用
公开(公告)号：US5587499A
公开(公告)日：1996-12-24
申请号：US439141
申请日：1995-05-11
IPC分类号： C07C69/54 , C07C69/675 , C07C317/44 , C07C323/52 , C07C323/54 , C08F20/26 , C08F20/38 , C08F120/28 , C08F120/38 , C08F128/02 , C07C53/126 , C07C69/02 , C07C327/20
CPC分类号： C07C69/675 , C07C317/44 , C07C323/52 , C08F120/38 , C08F128/02
摘要： These compounds are denoted by the following formula (I): ##STR1## in which: Z denotes H or a linear or branched alkyl radical,X denotes O or S,each of A and B independently denotes an alkylene radical, it being possible for this radical to be substituted,R denotes H or an alkali metal, or else a linear or branched alkyl radical,x has the value of 0 or 1, andy has the value of 0, 1 or 2,the radical A not existing if x and y are both equal to 0, X being incapable of denoting O when R=alkyl and when R=H with x=y=0, and B being incapable of denoting optionally substituted methylene when X=S, x=y=0 and R=alkyl.According to the invention, different simple and efficient processes are proposed for preparing these new compounds, which can be applied to the preparation of new polymers and copolymers.
摘要翻译： 这些化合物由下式（I）表示：其中：Z表示H或直链或支链烷基，X表示O或S，A和B各自独立地表示亚烷基，它 可以将该基团取代，R表示H或碱金属，或者是直链或支链烷基，x的值为0或1，y的值为0,1或2，基团A 如果x和y都等于0，X不能表示O，当x = y = 0时R = H，当X = S时，B不能表示任意取代的亚甲基，x = y = 0，R =烷基。 根据本发明，提出了用于制备这些新化合物的不同简单有效的方法，其可以用于制备新的聚合物和共聚物。
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6.发明授权(Meth)acrylic compounds, process for their preparation and their application to the synthesis of new polymers 失效（甲基）丙烯酸酯化合物，其制备方法及其在合成新聚合物中的应用
公开(公告)号：US5457172A
公开(公告)日：1995-10-10
申请号：US18594
申请日：1993-02-17
IPC分类号： C07C69/54 , C07C69/675 , C07C317/44 , C07C323/52 , C07C323/54 , C08F20/26 , C08F20/38 , C08F120/28 , C08F120/38 , C08F128/02 , C07C327/20 , C07C69/34
CPC分类号： C07C69/675 , C07C317/44 , C07C323/52 , C08F120/38 , C08F128/02
摘要： These compounds are denoted by the following formula (I): ##STR1## in which: Z denotes H or a linear or branched alkyl radical,X denotes O or S,each of A and B independently denotes an alkylene radical, it being possible for this radical to be substituted,R denotes H or an alkali metal, or else a linear or branched alkyl radical,x has the value of 0 or 1, andy has the value of 0, 1 or 2,the radical A not existing if x and y are both equal to 0, X being incapable of denoting O when R=alkyl and when R=H with x=y=0, and B being incapable of denoting optionally substituted methylene when X=S, x=y=0 and R=alkyl.According to the invention, different simple and efficient processes are proposed for preparing these new compounds, which can be applied to the preparation of new polymers and copolymers.
摘要翻译： 这些化合物由下式（I）表示：其中：Z表示H或直链或支链烷基，X表示O或S，A和B各自独立地表示亚烷基，它 可以将该基团取代，R表示H或碱金属，或者是直链或支链烷基，x的值为0或1，y的值为0,1或2，基团A 如果x和y都等于0，X不能表示O，当x = y = 0时R = H，当X = S时，B不能表示任意取代的亚甲基，x = y = 0，R =烷基。 根据本发明，提出了用于制备这些新化合物的不同简单有效的方法，其可以用于制备新的聚合物和共聚物。
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7.发明授权(Poly) sulfurized carboxylic compounds, their preparation and their use as petroleum additives for lubricating oils 失效（聚）硫化羧酸化合物，它们的制备及其作为润滑油的石油添加剂的用途
公开(公告)号：US5284592A
公开(公告)日：1994-02-08
申请号：US872196
申请日：1992-04-22
IPC分类号： C10M135/26 , C07C319/20 , C07C323/12 , C10M135/24 , C10N30/06
CPC分类号： C10M135/24 , C07C323/12 , C10M2219/084
摘要： Novel (poly)sulfurized carboxylic compounds, their preparation, and their use as additives to lubricating oils are disclosed. Such novel carboxylic compounds are more particularly esters of the general formula:[R.sup.3 --OC(O)--].sub.q R.sup.2 {--C(O)O--(CH.sub.2).sub.m --CH.sub.3-z [--(CH.sub.2).sub.n --S.sub.x --R.sup.1 ].sub.z }.sub.p (1)wherein R.sup.1 is a saturated or unsaturated monovalent aliphatic radical with 1 to 30 carbon atoms; the number x is equal to or greater than 1; z equals 1 or 2; when z equals 1, n is an integer from 0 to 5 and m an integer from 0 to 0.5, with m+n an integer from 1 to 10; when z equals 2, n is an integer from 1 to 5 and m an integer from 0 to 5, with m+n an integer from 1 to 10; R.sup.2 is a hydrocarbon radical with 1 to 31 carbon atoms and a valency of p+q; R.sup.3 is a hydrogen atom or an aliphatic radical with 1 to 30 carbon atoms; p is an integer from 1 to 4; and q is an integer from 0 to 3, with p+q being an integer from 1 to 4. They are obtained by esterifying carboxylic acid R.sup.2 (--COOH).sub.p+q with a (poly)sulfurized monoalcohol:[R.sup.1 --S.sub.x --(CH.sub.2).sub.n --].sub.z CH.sub.3-z --(CH.sub.2).sub.m --OHand possibly an alcohol R.sup.3 OH. They are used as anti-wear and extreme pressure additives in lubricating oils.
摘要翻译： 公开了新型（多）硫化羧酸化合物，它们的制备及其作为润滑油添加剂的用途。 这样的新型羧酸化合物更特别是以下通式的酯：（R3-OC（O） - ）qR2（-C（O）O-（CH2）m-CH3-z（ - （CH2）n-Sx-R1） z）p（1）其中R1是具有1至30个碳原子的饱和或不饱和的一价脂族基; 数x等于或大于1; z等于1或2; 当z为1时，n为0〜5的整数，m为0〜0.5的整数，m + n为1〜10的整数。 当z为2时，n为1〜5的整数，m为0〜5的整数，m + n为1〜10的整数。 R2是具有1至31个碳原子并且p + q的化合价的烃基; R3是氢原子或具有1至30个碳原子的脂族基团; p是1至4的整数; 并且q为0〜3的整数，p + q为1〜4的整数。它们是通过用（多）硫化一元醇将羧酸R2（-COOH）p + q酯化得到的：（R1-Sx- （CH 2）n - ）z CH 3 -Z-（CH 2）m -OH以及可能的醇R 3 OH。 它们用作润滑油中的抗磨和极压添加剂。
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8.发明授权(Thio) (meth) acrylate monomers, intermediate compounds for the synthesis of these monomers, polymerisable compositions and polymers obtained, and their optical and ophthalmic uses 失效（Thio）（甲基）丙烯酸酯单体，用于合成这些单体的中间体化合物，可聚合组合物和获得的聚合物，以及它们的光学和眼科用途公开(公告)号：US06307062B1
公开(公告)日：2001-10-23
申请号：US09171219
申请日：1998-10-13
申请人： Florence Caye , Michèle Sindt , Daniel Paquer , Dorothée Jury , Michel Schneider , Jean-Luc Mieloszynski
发明人： Florence Caye , Michèle Sindt , Daniel Paquer , Dorothée Jury , Michel Schneider , Jean-Luc Mieloszynski
IPC分类号： C07D32710
CPC分类号： C08F20/38 , C07D339/00 , C07D339/04 , C07D339/08 , C07D341/00 , G02B1/041 , C08L33/14
摘要： The novel monomers correspond to the formula: in which: Z represents H or CH3 and X represents O or S, and Y is a 5- to 8-membered heterocycle consisting of hydrogen, carbon and sulphur atoms and at least two endocyclic sulphur atoms.
摘要翻译： 新单体对应于下式：其中：Z表示H或CH 3，X表示O或S，Y是由氢，碳和硫原子和至少两个内环硫原子组成的5至8元杂环。
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公开(公告)号：US5412138A
公开(公告)日：1995-05-02
申请号：US993724
申请日：1992-12-14
IPC分类号： C07F9/09 , C07F9/165 , C08F230/02 , C07F9/113 , C07F9/173
CPC分类号： C08F230/02 , C07F9/091 , C07F9/1651
摘要： These acrylic and methacrylic compounds are chosen from those of the formula: ##STR1## in which R.sup.1 is H or CH.sub.3 ; A is (CH.sub.2).sub.n or n is an integer from 2 to 12 or --(CH.sub.2 CH.sub.2 O).sub.d --CH.sub.2 CH.sub.2 --, d is an integer from 1 to 20; X is S or O; Y is S or O, under the condition that X is S and Y is O when A is --(CH.sub.2 CH.sub.2 O).sub.d --CH.sub.2 CH.sub.2 --; R is C.sub.1 --C.sub.20 alkyl or --(CH.sub.2).sub.p SR.sup.3 where p is an integer from 3 to 12 and R.sup.3 is C.sub.1 -C.sub.20 -alkyl; m is an integer from 1 to 3; and Z is H, R.sup.2 QH, or R.sup.2 is C.sub.2 -C.sub.12 -alkyl and Q is O or S, and the atoms of the metals from Groups IA, IIA, IIIA, IB, IIB, VIB, VIIB and VIII of the Periodic Table, on condition that Z is H or R.sup.2 OH when m is 1 and m is the valence of Z when Z is a metal.
摘要翻译： 这些丙烯酸和甲基丙烯酸酯化合物选自下式的那些：其中R 1是H或CH 3;（II）其中R 1是H或CH 3; A是（CH 2）n或n是2至12的整数或 - （CH 2 CH 2 O）d -CH 2 CH 2 - ，d是1至20的整数; X是S或O; 在A为 - （CH 2 CH 2 O）d-CH 2 CH 2的情况下，X为S且Y为O时，Y为S或O。 R是C1-C20烷基或 - （CH2）pSR3，其中p是3-12的整数，R3是C1-C20-烷基; m为1〜3的整数; Z为H，R2QH或R2为C2-C12-烷基且Q为O或S，元素周期表IA，IIA，IIIA，IB，IIB，VIB，VIIB和VIII族金属的原子， 当m为1时Z为H或R2OH，当Z为金属时，m为Z的化合价。
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10.发明授权
公开(公告)号：US5399733A
公开(公告)日：1995-03-21
申请号：US29288
申请日：1993-03-08
CPC分类号： C08F30/02 , C07F9/1651
摘要： Compounds represented by the formulae (I) and (II) in which:R.sup.1 =H or CH.sub.3 ;X=O or S;R.sup.2 =C.sub.1-12 straight-chain or branched alkylene groups, monocyclic or polycyclic cycloalkylene and heterocycloalkylene groups, alkylarylene and arylalkylene groups;R.sup.6 =H or C.sub.1-12 alkyl and aryl radicals;R.sup.3 =C.sub.1-20 alkyl and aryl radicals, --CH.sub.2).sub.p SR.sup.4 groups where p=integer from 2 to 12 and R.sup.4 =C.sub.1-20 alkyl, and ##STR1## where q is an integer from 2 to 12 and R.sup.5 =H or CH.sub.3. ##STR2##
摘要翻译： 由式（I）和（II）表示的化合物，其中：R 1 = H或CH 3; X = O或S; R2 = C1-12直链或支链亚烷基，单环或多环亚环烷基和杂环亚烷基，烷基亚芳基和芳基亚烷基; R6 = H或C 1-12烷基和芳基; R 3 = C 1-20烷基和芳基，-CH 2）pSR 4基团，其中p = 2至12的整数和R 4 = C 1-20烷基，和其中q是2至12的整数，并且R 5 = H或CH 3 。 （I）
（II）
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