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    Olefin polysulfide compositions of high sulfur content and very low chlorine content, their manufacture and use as additives for lubricants
    1.
    发明授权
    Olefin polysulfide compositions of high sulfur content and very low chlorine content, their manufacture and use as additives for lubricants 失效
    含硫量高，氯含量非常低的烯烃多硫化物组合物，其制造和用作润滑剂的添加剂

    公开(公告)号：US5286395A

    公开(公告)日：1994-02-15

    申请号：US883793

    申请日：1992-05-14

    申请人： Maurice Born ,  Lucienne Briquet ,  Guy Parc

    发明人： Maurice Born ,  Lucienne Briquet ,  Guy Parc

    IPC分类号： C07G99/00 ,  C10M135/04

    CPC分类号： C10M135/04 ,  C07G17/004 ,  C10M2219/022 ,  C10N2240/02 ,  C10N2240/401

    摘要： Olefin polysulfide compositions of high sulfur content and of very low chlorine content are obtained by a process comprising the steps of: (1) reacting sulfur mono- and/or dichloride with at least one aliphatic monoolefin of 2-12 carbon atoms, to form an addition product or "adduct", (2) reacting hydrogen sulfide with an alkali hydroxide or ammonium hydroxide dissolved in at least one substantially anhydrous C.sub.1 -C.sub.4 aliphatic monoalcohol, with optional addition of elemental sulfur, (3) contacting said "adduct" together with at least one monohalogenated hydrocarbon compound, with the alcoholic solution obtained at the end of step (2), (4) heating the resultant mixture from step (3), removing the monoalcohol, while adding water, and (5) after settling and removal of the aqueous phase, recovering the organic phase formed at least in major part of the desired olefin polysulfide composition. These compositions, of sulfur content up to 65% by weight and of chlorine content generally lower than about 0.1% by weight, are used in particular as additives for improving the extreme-pressure properties of lubricants.

    摘要翻译： 通过包括以下步骤的方法获得高硫含量和非常低氯含量的烯烃多硫化物组合物：（1）使单 - 和/或二氯化物与至少一种2-12个碳原子的脂族单烯烃反应，形成 加成产物或“加合物”，（2）使硫化氢与溶于至少一种基本上无水的C 1 -C 4脂族一元醇中的碱金属氢氧化物或氢氧化铵反应，任选加入元素硫，（3）使所述“加合物”与 至少一种一卤化烃化合物与步骤（2）结束时得到的醇溶液，（4）加热步骤（3）的所得混合物，同时加入水，除去一元醇，和（5）沉淀和除去后 的水相，回收至少大部分所需的烯烃多硫化物组合物形成的有机相。 这些硫含量高达65重量％，氯含量通常低于约0.1重量％的组合物特别用作改善润滑剂的极压性能的添加剂。

    Copolymer compositions usable as additives for lubricating oils
    2.
    发明授权
    Copolymer compositions usable as additives for lubricating oils 失效
    用作润滑油添加剂的共聚物组合物

    公开(公告)号：US4756843A

    公开(公告)日：1988-07-12

    申请号：US927981

    申请日：1986-11-07

    申请人： Jacques Jarrin ,  Magali Robine ,  Guy Parc ,  Francois Dawans

    发明人： Jacques Jarrin ,  Magali Robine ,  Guy Parc ,  Francois Dawans

    IPC分类号： C10M121/04 ,  C08F212/00 ,  C08F212/08 ,  C08F220/10 ,  C08F220/12 ,  C08F220/18 ,  C08L25/00 ,  C08L25/08 ,  C08L33/04 ,  C08L33/10 ,  C10M119/12 ,  C10M145/14 ,  C10N40/00 ,  C10N40/25 ,  C10N50/10 ,  C10M101/04

    CPC分类号： C10M145/14 ,  C08F220/18 ,  C10M2205/04 ,  C10M2209/084

    摘要： Compositions of copolymers are disclosed containing 10 to 35% by weight of units derived from at least one vinylaromatic monomer, 5 to 15% by weight of units derived from at least one linear or branched alkyl methacrylate with 1 to 4 carbon atoms, 20 to 50% by weight of units derived from at least one linear alkyl methacrylate with 8 to 14 carbon atoms and 15 to 50% by weight of units derived from at least one linear alkyl methacrylate with 16 to 22 carbon atoms. The copolymer compositions have a weight average molecular weight of 100,000 to 400,000 and a polydispersity index in general of less than 5.They are prepared by any free-radical copolymerization method using for example azo or peroxide initiators.These compositions have the advantage of providing a better compromise between the characteristics required of a viscosity additive for lubricating oils.

    摘要翻译： 公开了共聚物的组合物，其含有10至35重量％的衍生自至少一种乙烯基芳族单体的单元，5至15重量％的衍生自至少一个具有1至4个碳原子的直链或支链烷基甲基丙烯酸酯的单元，20至50 由至少一种具有8至14个碳原子的直链烷基甲基丙烯酸酯和15至50重量％衍生自至少一个具有16-22个碳原子的直链烷基甲基丙烯酸酯的单元的单元的重量％。 共聚物组合物的重均分子量为100,000〜400,000，多分散指数通常小于5.它们通过使用例如偶氮或过氧化物引发剂的任何自由基共聚方法制备。 这些组合物具有在润滑油的粘度添加剂所需的特性之间提供更好的折中的优点。

    Lubricating bases for multigrade oils
    4.
    发明授权
    Lubricating bases for multigrade oils 失效
    多级油润滑基础

    公开(公告)号：US4036771A

    公开(公告)日：1977-07-19

    申请号：US610769

    申请日：1975-09-05

    申请人： Jacques Denis ,  Guy Parc

    发明人： Jacques Denis ,  Guy Parc

    IPC分类号： C10M159/12 ,  C08G65/332 ,  C10M105/42 ,  C10M129/78 ,  C10M169/00 ,  C10N30/02 ,  C10N40/20 ,  C10N40/22 ,  C10N40/25 ,  C10M1/24

    CPC分类号： C10M3/00 ,  C08G65/332 ,  C10M2203/06 ,  C10M2205/02 ,  C10M2207/282 ,  C10M2207/283 ,  C10M2207/34 ,  C10M2209/084 ,  C10M2209/109 ,  C10M2209/11 ,  C10M2209/111

    摘要： There are disclosed lubricating compositions consisting of homogeneous mixtures of:a. from 50 to 99% by weight of at least one mineral or synthetic hydrocarbon oil of lubricating viscosity,B. from 1 to 50% by weight of at least one complex ester composition formed as between at least one polycarboxylic acid selected from dimeric and trimeric unsaturated fatty acids, optionally hydrogenated, at least one dihydroxyl compound selected from polyalkylene glycols and diols, and at least one monofunctional compound comprising at least one monocarboxylic acid or at least one monohydroxyl compound selected from monohydric alcohols or monohydric phenols and oxyalkylenated monohydric alcohols or monohydric phenols, with the condition that one at least of the mono- or dihydroxyl compounds comprises a compound with oxyalkylene groups, andC. from 0 to 40% by weight of at least one light ester.These compositions are usable as bases for multigrade oils with the addition of low amounts of viscosity index improvers, or without any addition of such additives.

    摘要翻译： 公开了由以下均匀混合物组成的润滑组合物：

    (Poly) sulfurized carboxylic compounds, their preparation and their use as petroleum additives for lubricating oils
    5.
    发明授权
    (Poly) sulfurized carboxylic compounds, their preparation and their use as petroleum additives for lubricating oils 失效
    （聚）硫化羧酸化合物，它们的制备及其作为润滑油的石油添加剂的用途

    公开(公告)号：US5284592A

    公开(公告)日：1994-02-08

    申请号：US872196

    申请日：1992-04-22

    申请人： Ourida Aberkane ,  Maurice Born ,  Jean-Luc Mieloszynski ,  Daniel Paquer ,  Guy Parc

    发明人： Ourida Aberkane ,  Maurice Born ,  Jean-Luc Mieloszynski ,  Daniel Paquer ,  Guy Parc

    IPC分类号： C10M135/26 ,  C07C319/20 ,  C07C323/12 ,  C10M135/24 ,  C10N30/06

    CPC分类号： C10M135/24 ,  C07C323/12 ,  C10M2219/084

    摘要： Novel (poly)sulfurized carboxylic compounds, their preparation, and their use as additives to lubricating oils are disclosed. Such novel carboxylic compounds are more particularly esters of the general formula:[R.sup.3 --OC(O)--].sub.q R.sup.2 {--C(O)O--(CH.sub.2).sub.m --CH.sub.3-z [--(CH.sub.2).sub.n --S.sub.x --R.sup.1 ].sub.z }.sub.p (1)wherein R.sup.1 is a saturated or unsaturated monovalent aliphatic radical with 1 to 30 carbon atoms; the number x is equal to or greater than 1; z equals 1 or 2; when z equals 1, n is an integer from 0 to 5 and m an integer from 0 to 0.5, with m+n an integer from 1 to 10; when z equals 2, n is an integer from 1 to 5 and m an integer from 0 to 5, with m+n an integer from 1 to 10; R.sup.2 is a hydrocarbon radical with 1 to 31 carbon atoms and a valency of p+q; R.sup.3 is a hydrogen atom or an aliphatic radical with 1 to 30 carbon atoms; p is an integer from 1 to 4; and q is an integer from 0 to 3, with p+q being an integer from 1 to 4. They are obtained by esterifying carboxylic acid R.sup.2 (--COOH).sub.p+q with a (poly)sulfurized monoalcohol:[R.sup.1 --S.sub.x --(CH.sub.2).sub.n --].sub.z CH.sub.3-z --(CH.sub.2).sub.m --OHand possibly an alcohol R.sup.3 OH. They are used as anti-wear and extreme pressure additives in lubricating oils.

    摘要翻译： 公开了新型（多）硫化羧酸化合物，它们的制备及其作为润滑油添加剂的用途。 这样的新型羧酸化合物更特别是以下通式的酯：（R3-OC（O） - ）qR2（-C（O）O-（CH2）m-CH3-z（ - （CH2）n-Sx-R1） z）p（1）其中R1是具有1至30个碳原子的饱和或不饱和的一价脂族基; 数x等于或大于1; z等于1或2; 当z为1时，n为0〜5的整数，m为0〜0.5的整数，m + n为1〜10的整数。 当z为2时，n为1〜5的整数，m为0〜5的整数，m + n为1〜10的整数。 R2是具有1至31个碳原子并且p + q的化合价的烃基; R3是氢原子或具有1至30个碳原子的脂族基团; p是1至4的整数; 并且q为0〜3的整数，p + q为1〜4的整数。它们是通过用（多）硫化一元醇将羧酸R2（-COOH）p + q酯化得到的：（R1-Sx- （CH 2）n - ）z CH 3 -Z-（CH 2）m -OH以及可能的醇R 3 OH。 它们用作润滑油中的抗磨和极压添加剂。

    Polysulphurized olefin compositions, their preparation and their use as additives for lubricants
    6.
    发明授权
    Polysulphurized olefin compositions, their preparation and their use as additives for lubricants 失效
    多硫化烯烃组合物，它们的制备及其作为润滑剂添加剂的用途

    公开(公告)号：US5045221A

    公开(公告)日：1991-09-03

    申请号：US403968

    申请日：1989-09-07

    申请人： Maurice Born ,  Lucienne Briquet ,  Jacques Lallement ,  Guy Parc

    发明人： Maurice Born ,  Lucienne Briquet ,  Jacques Lallement ,  Guy Parc

    IPC分类号： C07C319/14 ,  C07C321/00 ,  C10M135/04 ,  C10N30/06 ,  C10N40/04 ,  C10N40/22

    CPC分类号： C10M135/04

    摘要： Polysulphurized olefin compositions used as additives for gear oils, cutting oils, and as sulphurizing agents in organic media are obtained by a process comprising:a stage (1) in which at least one compound chosen from among sulphur dichloride and monochloride is reacted with at least one aliphatic monpolefin with 2 to 12 carbon atoms, thus forming an adduct;a stage (2) in which sulphurized hydrogen and at least one mercaptan is reacted with ammonium or alkali metal hydroxide dissolved in at least one aliphatic monoalcohol with 1 to 4 carbon atoms, which is substantially anhydrous, so as to give an alcoholic solution;a stage (3) in which contacting takes place between the adduct obtained in stage (1) and the alcoholic solution obtained in stage (2);a stage (4), in which the resulting mixture is heated and then the aliphatic monoalcohol is eliminated by distillation, while adding water in a quantity adequate for maintaining in solution the reagents and the mineral products formed during the reaction; anda stage (5) in which elimination takes place of the aqueous phase and recovery takes place of the organic phase mainly constituted by the polysulphurized olefin composition.

    摘要翻译： 用于齿轮油，切削油和作为有机介质中的硫化剂的添加剂的多硫化烯烃组合物通过以下方法获得，该方法包括：其中至少一种选自二氯化硫和一氯化物的化合物至少与 一种具有2至12个碳原子的脂族单烯烃，从而形成加合物; 使硫化氢和至少一种硫醇与溶解在至少一种具有1-4个碳原子的脂族一元醇中的铵或碱金属氢氧化物反应的阶段（2），其基本上是无水的，以得到醇溶液; 在阶段（1）中获得的加合物和阶段（2）中获得的醇溶液之间发生接触的阶段（3）; 加热得到的混合物，然后通过蒸馏除去脂肪族一元醇的阶段（4），同时加入足以维持溶液中的水，反应物中形成的试剂和矿物产物; 以及主要由多硫化烯烃组合物构成的有机相进行水相脱除发生阶段（5）。

    Process for presulfurizing a hydrocarbon treatment catalyst
    8.
    发明授权
    Process for presulfurizing a hydrocarbon treatment catalyst 失效
    预处理烃处理催化剂的方法

    公开(公告)号：US4983558A

    公开(公告)日：1991-01-08

    申请号：US311503

    申请日：1989-02-16

    申请人： Maurice Born ,  Guy Parc ,  Herve Toulhoat

    发明人： Maurice Born ,  Guy Parc ,  Herve Toulhoat

    IPC分类号： B01J27/051 ,  B01J37/20 ,  C10G11/02

    CPC分类号： B01J37/20

    摘要： The invention relates to a process for treating a new or regenerated catalyst containing a support having as a base at least one metal or metalloid oxide and at least one active metal, comprising treating the catalyst with at least one sulfuration agent dissolved in a solvent.The invention is charcterized in that the sulfuration agent is a polysulfide with the following general formulaR'--S.sub.y --R--S.sub.x --R--S.sub.y).sub.n R'where R is a linear or a branched organic radical comprising from 2 to 12 carbon atoms; R' is an alkyl, alkenyl, arylalkyl or arylalkenyl radical comprising from 1 to 12 carbon atoms, R' possibly comprising at least one heteroatom selected from the group consisting of oxygen, nitrogen, and sulfur; x has a value of from 1 to 4; y has a value of from 1 to 8 and n is such that the average molar mass of the polymer is about 5000.

    摘要翻译： 本发明涉及一种处理含有至少一种金属或准金属氧化物和至少一种活性金属作为碱的载体的新型或再生催化剂的方法，包括用溶解在溶剂中的至少一种硫化剂处理催化剂。 本发明的特征在于硫化剂是具有以下通式R'-Sy-R-Sx -R-Sy）nR'的多硫化物，其中R是包含2至12个碳原子的直链或支链有机基团; R'是包含1至12个碳原子的烷基，烯基，芳基烷基或芳基烯基，R'可以包含至少一个选自氧，氮和硫的杂原子; x的值为1到4; y的值为1〜8，n为聚合物的平均摩尔质量为约5000。