公开(公告)号：US20090062466A1

公开(公告)日：2009-03-05

申请号：US11718256

申请日：2004-11-30

申请人： Jinyong Dong ,  Jiguang Liu ,  Zhichao Han ,  Dujin Wang

发明人： Jinyong Dong ,  Jiguang Liu ,  Zhichao Han ,  Dujin Wang

IPC分类号： C08L23/08 ,  C08L23/12

CPC分类号： C08L23/0807 ,  C08F10/00 ,  C08F210/06 ,  C08F2410/05 ,  C08L23/0815 ,  C08L23/10 ,  C08L23/16 ,  C08L2314/02 ,  C08L2314/06 ,  C08F4/6545 ,  C08F4/65922 ,  C08L2666/06 ,  C08F210/18 ,  C08F236/00 ,  C08F210/16

摘要： The present invention belongs to the field of polyolefin alloy preparation, and particularly relates to a polyolefin composite material in good form with adjustable composition and performances, produced by controlling a composite catalyst composed of Zieglar-Natta catalyst and metallocene catalyst to be catalytic by stage in the olefin polymerization reaction. This material is composed of propylene polymer and ethylene copolymer which is obtained by copolymerizing ethylene with alpha olefin or diolefin, wherein: the molar content of alpha olefin or diolefin in the ethylene copolymer is 0%˜60%, and the ethylene copolymer is 3˜80% by weight of the polyolefin composite material; the polyolefin composite material is in particle form, and the ethylene copolymer has a molecular weight distribution of 1˜6 and a glass transition temperature of −80˜0° C.; and the ethylene copolymer produced in the reaction is dispersed homogeneously in the propylene polymer particles to form the polyolefin composite material.

摘要翻译： 本发明属于聚烯烃合金制备领域，特别涉及一种具有可调组合物和性能的良好形式的聚烯烃复合材料，其通过控制由齐格列塔 - 纳塔催化剂和茂金属催化剂组成的复合催化剂在催化阶段 烯烃聚合反应。 该材料由丙烯聚合物和乙烯共聚物组成，其通过乙烯与α-烯烃或二烯烃共聚获得，其中：乙烯共聚物中α-烯烃或二烯烃的摩尔含量为0％〜60％，乙烯共聚物为3〜 80重量％的聚烯烃复合材料; 聚烯烃复合材料为颗粒形式，乙烯共聚物的分子量分布为1〜6，玻璃化转变温度为-80〜0℃。 并且在反应中制备的乙烯共聚物均匀地分散在丙烯聚合物颗粒中以形成聚烯烃复合材料。

公开(公告)号：US06265493B1

公开(公告)日：2001-07-24

申请号：US09573737

申请日：2000-05-18

申请人： Tze-Chiang Chung ,  Jinyong Dong

发明人： Tze-Chiang Chung ,  Jinyong Dong

IPC分类号： C08F25506

CPC分类号： C08F290/042 ,  C08F4/65912 ,  C08F4/6592 ,  C08F4/65925 ,  C08F10/00 ,  C08F210/00 ,  C08F210/02 ,  C08F210/06 ,  C08F210/16 ,  C08F210/18 ,  C08F212/36 ,  C08F255/02 ,  Y02P20/582 ,  C08F4/6543 ,  C08F4/65927 ,  C08F212/08 ,  C08F236/20 ,  C08F2500/03 ,  C08F2500/06 ,  C08F2500/25 ,  C08F210/14

摘要： The invention relates to a process for preparing polyolefin graft copolymers (II) from linear and well defined polyolefin copolymers (I) containing divinylbenzene comonomer units, wherein R, in formulas I and II, is a C1 to C10 linear or branched alkyl group or a C6 to C10 substituted or unsubstituted aromatic group; and wherein G and G′, independantly, are selected from —H, —OH, epoxy, —NH2, —COOH, anhydride, —Cl, —Br, —M, —COOM (M=metal, e.g., Li, Na, K and Ca) or a polymer chain having the molecular weight of at least about 500, which can be derived from both step and chain polymerization reactions. G and G′ can be selected singly or in a combination of two or more thereof. In the graft copolymer composition, the combined alpha-olefin mole .% (x+y) is from about 50 to 99.9 mole %. Preferably, x+y is from 85 to 99.9 mole %, and most preferably x+y is from 95 to 99.9 mole %. The sum of x, y, m and n is 100%, and n is at least 0.05%. The molecular weight of backbone polymer chain has a number average molecular weight (Mn) of at least about 1,000, and preferably at least about 10,000.

摘要翻译： 本发明涉及由含二乙烯基苯共聚单体单元的直链且明确定义的聚烯烃共聚物（I）制备聚烯烃接枝共聚物（II）的方法，其中式I和II中的R 1为C 1至C 10直链或支链烷基或 C6〜C10取代或未取代的芳基; 并且其中G和G'独立地选自-H，-OH，环氧基，-NH 2，-COOH，酸酐，-Cl，-Br，-M，-COOM（M =金属，例如Li，Na， K和Ca）或分子量为至少约500的聚合物链，其可以衍生自步进和链式聚合反应。 G和G'可以单独选择或以其两种或更多种的组合来选择。 在接枝共聚物组合物中，组合的α-烯烃摩尔％（x + y）为约50至99.9摩尔％。 优选地，x + y为85〜99.9摩尔％，最优选为x + y为95〜99.9摩尔％。 x，y，m和n的和为100％，n为至少0.05％。 主链聚合物链的分子量具有至少约1,000，优选至少约10,000的数均分子量（Mn）。

公开(公告)号：US6096849A

公开(公告)日：2000-08-01

申请号：US359345

申请日：1999-07-21

申请人： Tze-Chiang Chung ,  Jinyong Dong

发明人： Tze-Chiang Chung ,  Jinyong Dong

IPC分类号： C08F4/642 ,  C08F4/658 ,  C08F10/00 ,  C08F210/00 ,  C08F210/02 ,  C08F210/06 ,  C08F210/16 ,  C08F210/18 ,  C08F212/36 ,  C08F255/02 ,  C08F290/04 ,  C08F236/20 ,  C08F4/643

CPC分类号： C08F290/042 ,  C08F10/00 ,  C08F210/00 ,  C08F210/02 ,  C08F210/06 ,  C08F210/18 ,  C08F212/36 ,  C08F255/02 ,  C08F210/16 ,  Y02P20/582 ,  Y10S526/943

摘要： The invention relates to linear copolymers containing alpha-olefin and divinylbenzene comonomer units and to a process for preparing the copolymers, the copolymers having a mole ratio of unsaturation/divinylbenzene (TUS/DOU) between 0.8 and 1.1, a molecular weight distribution of less than 4, and a homogeneous composition distribution, and having the structural formula ##STR1## in which R is a linear or branched C.sub.1 to C.sub.10 alkyl group or a phenyl or alkyl-substituted phenyl group, x+y is the mole % of alpha-olefin units in the copolymer, z is the mole % of divinylbenzene units in the copolymer, the sum of x+y is from 50 to 99.9, and the sum of x+y+z is 100. The copolymers are prepared in the presence of a bridged metallocene catalyst having a spacial opening at the metal active site of between 135 and 105.degree. for reacting with only one of the two vinyl groups in the divinylbenzene comonomer, which assures the formation of linear copolymers without detectable branching structure.

摘要翻译： 本发明涉及含有α-烯烃和二乙烯基苯共聚单体单元的线性共聚物以及制备该共聚物的方法，该共聚物的不饱和/二乙烯基苯的摩尔比（TUS / DOU）为0.8-1.1，分子量分布小于 4和均匀的组成分布，并且具有结构式，其中R是直链或支链C1至C10烷基或苯基或烷基取代的苯基，x + y是α-烯烃单元的摩尔％ 共聚物，z是共聚物中二乙烯基苯单元的摩尔％，x + y的总和为50至99.9，x + y + z的总和为100.该共聚物是在桥连茂金属催化剂 在金属活性部位具有135至105度之间的空间开口，仅与二乙烯基苯共聚单体中的两个乙烯基之一反应，这确保形成不具有可检测的支化结构的线型共聚物。

公开(公告)号：US20080312390A1

公开(公告)日：2008-12-18

申请号：US11818480

申请日：2007-06-14

申请人： Jinyong Dong ,  Bochao Zhu ,  Zhichao Han ,  Changjun Zhang ,  Hui Niu ,  Shaoyi Wei ,  Jiguang Liu ,  Peihong Yao ,  Hongying Wang ,  Xiaojun Li ,  Dujin Wang ,  Pingsheng Zhang ,  Yajie Zhu ,  Junji Jia ,  Chunbo Huang

发明人： Jinyong Dong ,  Bochao Zhu ,  Zhichao Han ,  Changjun Zhang ,  Hui Niu ,  Shaoyi Wei ,  Jiguang Liu ,  Peihong Yao ,  Hongying Wang ,  Xiaojun Li ,  Dujin Wang ,  Pingsheng Zhang ,  Yajie Zhu ,  Junji Jia ,  Chunbo Huang

IPC分类号： C08F4/64 ,  C08F2/00 ,  C08F4/68 ,  C08F4/52

CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65927 ,  C08F110/06 ,  C08F210/06 ,  C08F210/16 ,  C08F4/651 ,  C08F4/65904 ,  C08F2/001 ,  C08F2500/12 ,  C08F2500/21 ,  C08F2500/11

摘要： A process for preparing polypropylene compositions having high impact strength at low temperatures is disclosed in which the reaction is catalyzed by Ziegler-Natta/metallocene hybrid catalysts by the in-situ polymerization of one or more olefins of the formula CH2═CHR, in which R is hydrogen or an alkyl, cycloalkyl or aryl group having from 1 to 10 carbon atoms, and more specifically comprises preparing an olefin polymer by Ziegler-Natta catalyst components of the titanium or vanadium/metallocene hybrid catalysts while the metallocene components are inactivated beforehand by catalyst inactivators; and polymerizing one or more olefins in the presence of the above olefin polymer, followed by a reactivation of the metallocene components.

摘要翻译： 公开了一种制备在低温下具有高冲击强度的聚丙烯组合物的方法，其中该反应由齐格勒 - 纳塔/茂金属杂化催化剂通过一种或多种式CH 2 -CHR的烯烃的原位聚合催化，其中R 是氢或具有1至10个碳原子的烷基，环烷基或芳基，更具体地包括通过钛或钒/茂金属杂化催化剂的齐格勒 - 纳塔催化剂组分制备烯烃聚合物，同时通过催化剂预先将茂金属组分灭活 灭活剂 并在上述烯烃聚合物的存在下聚合一种或多种烯烃，接着再活化茂金属组分。