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公开(公告)号：US08217081B2
公开(公告)日：2012-07-10
申请号：US12647661
申请日：2009-12-28
申请人： Joseph M. Antonucci
发明人： Joseph M. Antonucci
CPC分类号： C07C219/08 , A01N33/12 , A01N37/06 , A01N25/10 , A01N2300/00
摘要： A polymerizable biomedical composition includes a quaternary ammonium group bonded at its quaternary sites to respective groups R1, R2, R3, and R4. R1 and R2 each include a vinyl moiety such that the composition is at least bi-functional with respect to polymerization.
摘要翻译： 可聚合的生物医学组合物包括在其四元位上键合到各自基团R 1，R 2，R 3和R 4的季铵基团。 R1和R2各自包括乙烯基部分，使得组合物在聚合方面至少是双功能的。
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公开(公告)号：US06177534B1
公开(公告)日：2001-01-23
申请号：US09213892
申请日：1998-12-17
IPC分类号： C08G7714
CPC分类号： A61K6/0023 , A61K6/0017 , C08F230/08 , C09J4/00 , C08L83/12 , C08L51/085
摘要： A silylated resin suitable for use as an adhesive binder for composites and in sealant and adhesive dental applications is represented by the general formula (I): in which: R1 is an aliphatic, cycloaliphatic, aryl, hydrocarbon, or fluorocarbon group; R2 is the same as R1 or a different aliphatic, cycloaliphatic, aryl, hydrocarbon, or fluorocarbon group; M2 is the same as M1 or a different functional or nonfunctional group selected from the group consisting of: n is 1-3; x is 1-20; and y is 1-20; which comprises the reaction product of the exchange reaction of a hydroxylated, aminated, or carboxylated acrylic resin represented by the general formula (II): in which: R4 is an aliphatic, cycloaliphatic, aryl, hydrocarbon, or fluorocarbon group with one or more protic functional groups selected from the group consisting of: OH, N—H, and CO2H R5 is H or CH3; and R6 is H or CH3; with a trialkoxyorganosilane or triacyloxyorganosilane represented by the general formula (III): in which: R7, R8, and R9 each is: R10 is an aliphatic, or aryl group which can optionally be substituted with a group from the group of an acrylic group, a methacrylic group, an epoxy group, and a substituted amino, hydroxyl, or carboxylic acid group such as an ester or an amide.
摘要翻译： 适合用作复合材料和密封剂和粘合剂牙科应用的粘合剂粘合剂的甲硅烷基化树脂由通式（I）表示：其中：R1是脂族，脂环族，芳基，烃基或碳氟化合物基团; R2是 与R1或不同的脂族，脂环族，芳基，碳氢化合物或碳氟化合物基团相同; M2与M1或选自以下的不同的官能团或非官能团基团相同：n为1-3; x为1-20; 其中包括由通式（II）表示的羟基化，胺化或羧化的丙烯酸树脂的交换反应的反应产物：其中：R4是脂族，脂环族，芳基，烃或碳氟化合物 与一个或多个选自以下的质子官能团基团：R5是H或CH3; 和R 6是H或CH 3;具有由通式（III）表示的三烷氧基有机硅烷或三酰氧基有机硅烷：其中：R 7，R 8和R 9各自为：R 10是可以任选地被以下基团取代的脂族或芳基： 丙烯酸基团，甲基丙烯酸基团，环氧基团和取代的氨基，羟基或羧酸基团如酯或酰胺的基团。
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公开(公告)号：US4576882A
公开(公告)日：1986-03-18
申请号：US706811
申请日：1985-02-28
IPC分类号： H01M6/18
CPC分类号： H01M6/181
摘要： A solid polymer electrolyte having(a) a matrix of linear poly(ethylene imine) having the formula (--CH.sub.2H.sub.2 NH--).sub.n ; and(b) a metal salt which is LiI, LiClO.sub.4, NaI, NaBr, KI, CsSCN, AgNO.sub.3, CuCl.sub.2, CoCl.sub.2, or Mg(ClO.sub.4).sub.2, wherein the salt is dissolved in and distributed throughout the poly(ethylene imine) matrix and from more than zero to 0.10 moles of salt are used per mole of monomer repeat unit, --CH.sub.2 CH.sub.2 NH--.
摘要翻译： 一种固体聚合物电解质，其具有（a）具有式（-CH 2 CH 2 NH-）n的直链聚（亚乙基亚胺）基质; 和（b）金属盐，其为LiI，LiClO 4，NaI，NaBr，KI，CsSCN，AgNO 3，CuCl 2，CoCl 2或Mg（ClO 4）2，其中盐溶解并分布在整个聚（亚乙基亚胺） 并且每摩尔单体重复单元-CH 2 CH 2 NH-使用大于0至0.10摩尔的盐。
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公开(公告)号：US20100256242A1
公开(公告)日：2010-10-07
申请号：US12647661
申请日：2009-12-28
申请人： Joseph M. Antonucci
发明人： Joseph M. Antonucci
CPC分类号： C07C219/08 , A01N33/12 , A01N37/06 , A01N25/10 , A01N2300/00
摘要： A polymerizable biomedical composition includes a quaternary ammonium group bonded at its quaternary sites to respective groups R1, R2, R3, and R4. R1 and R2 each include a vinyl moiety such that the composition is at least bi-functional with respect to polymerization.
摘要翻译： 可聚合的生物医学组合物包括在其四元位上键合到各自基团R 1，R 2，R 3和R 4的季铵基团。 R1和R2各自包括乙烯基部分，使得组合物在聚合方面至少是双功能的。
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公开(公告)号：US5756560A
公开(公告)日：1998-05-26
申请号：US562904
申请日：1995-11-27
CPC分类号： A61K6/0029 , A61K6/0052
摘要： An etchant/primer composition is provided which includes (a) a compound having the formula RN(CH.sub.2 YCO.sub.2 M).sub.2 (I) wherein R=R.sup.1 or R.sup.2 ; R.sup.1 =an aromatic group; R.sup.2 =a conjugated aliphatic group; Y=a single bond, CH.sub.2, CHCH.sub.3 or C.dbd.CH.sub.2 ; and each M is independently H, an alkali metal, an alkaline earth metal, aluminum, a transition or redox metal or an alkyl group having 1 to 18 carbon atoms, with the proviso that when both M groups are alkyl groups, the compound corresponding to formula I be capable of being easily hydrolyzed, displaced or exchanged with other reagents present in the etchant/primer composition and (b) a polar solvent system. An etchant/primer/adhesive monomer composition is also provided which includes the etchant/primer composition and an adhesive monomer system. One and two step simplified methods for adhering and for preparing a substrate surface, such as a dental substrate surface, to a polymeric material are also provided. Kits which may be used with these compositions and methods are also provided.
摘要翻译： 提供了一种蚀刻剂/底漆组合物，其包括（a）具有式R N（CH 2 YCO 2 M）2（I）的化合物，其中R = R 1或R 2; R1 =芳族基团; R2 =共轭脂族基团; Y =单键，CH2，CHCH3或C = CH2; 每个M独立地为H，碱金属，碱土金属，铝，过渡金属或氧化还原金属或具有1至18个碳原子的烷基，条件是当两个M基团都是烷基时，对应于 式I能够容易地水解，置换或与存在于蚀刻剂/底漆组合物中的其它试剂交换，和（b）极性溶剂体系。 还提供了包括蚀刻剂/底漆组合物和粘合剂单体体系的蚀刻剂/底漆/粘合剂单体组合物。 还提供了一种和两步简单的方法，用于粘合和制备基材表面，例如牙科基材表面，聚合物材料。 也可以使用与这些组合物和方法一起使用的试剂盒。
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公开(公告)号：US5690840A
公开(公告)日：1997-11-25
申请号：US562903
申请日：1995-11-27
CPC分类号： A61K6/0029 , A61K6/0052
摘要： An etchant primer composition is provided which includes (a) a compound hng the formula RN (CH.sub.2 YCO.sub.2 M).sub.2 (I) wherein R=R.sup.1 or R.sup.2 ; R.sup.1 =an aromatic group; R.sup.2 =a conjugated aliphatic group; Y=a single bond, CH.sub.2, CHCH.sub.3 or C.dbd.CH.sub.2 ; and each M is independently H, an alkali metal, an alkaline earth metal, aluminum, a transition or redox metal or an alkyl group having 1 to 18 carbon atoms, with the proviso that when both M groups are alkyl groups, the compound corresponding to formula I be capable of being easily hydrolyzed, displaced or exchanged with other reagents present in the etchant/primer composition and (b) a polar solvent system. An etchant/primer/adhesive monomer composition is also provided which includes the etchant/primer composition and an adhesive monomer system. One and two step simplified methods for adhering and for preparing a substrate surface, such as a dental substrate surface, to a polymeric material are also provided. Kits which may be used with these compositions and methods are also provided.
摘要翻译： 提供蚀刻剂底漆组合物，其包括（a）具有式R N（CH 2 YCO 2 M）2（I）的化合物，其中R = R 1或R 2; R1 =芳族基团; R2 =共轭脂族基团; Y =单键，CH2，CHCH3或C = CH2; 每个M独立地为H，碱金属，碱土金属，铝，过渡金属或氧化还原金属或具有1至18个碳原子的烷基，条件是当两个M基团都是烷基时，对应于 式I能够容易地水解，置换或与存在于蚀刻剂/底漆组合物中的其它试剂交换，和（b）极性溶剂体系。 还提供了包括蚀刻剂/底漆组合物和粘合剂单体体系的蚀刻剂/底漆/粘合剂单体组合物。 还提供了一种和两步简单的方法，用于粘合和制备基材表面，例如牙科基材表面，聚合物材料。 也可提供可与这些组合物和方法一起使用的试剂盒。
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公开(公告)号：US4616073A
公开(公告)日：1986-10-07
申请号：US639673
申请日：1984-08-09
申请人： Joseph M. Antonucci
发明人： Joseph M. Antonucci
IPC分类号： A61K6/083 , A61C13/08 , C08F214/18
CPC分类号： A61K6/083
摘要： Dental resin systems prepared from polyfunctional or monofunctional highly-fluorinated methacrylate prepolymers are described. Preferred systems comprise (a) a major amount of a polyfluorinated aligomeric polyfunctional methacrylate such as (PFMA), preferably in combination with a diluent monomer such as 1,10-decamethylene dimethacrylate (DMDMA), methyl methacrylate (MMA), neopentyl dimethacrylate (NPDMA), 1,6-hexamethylene dimethacrylate (HMDMA), etc., or mixtures thereof; and (b) a minor amount of a polyfluorinated monofunctional methacrylate (PFMMA), such as 1,1-dihydropentadecafluorooctyl methacrylate (PDFOMA) as a minor or secondary diluent monomer in a non-hydroxylated bis-GMA resin system. The products are generally useful as hydrophobic dental materials, esepcially as composited (with fillers), sealants and cements.
摘要翻译： 描述了由多官能或单官能高度氟化的甲基丙烯酸酯预聚物制备的牙科树脂体系。 优选的体系包括（a）主要量的多氟化聚异氰酸多官能甲基丙烯酸酯如（PFMA），优选与稀释剂单体如1,1-二甲基丙烯酸甲酯（DMDMA），甲基丙烯酸甲酯（MMA），新戊基二甲基丙烯酸酯（NPDMA） ），1,6-己二甲基丙烯酸酯（HMDMA）等，或其混合物; 和（b）少量的多氟化单官能甲基丙烯酸酯（PFMMA），例如在非羟基化双-GMA树脂体系中作为次要或次要稀释剂单体的甲基丙烯酸1,1-二氢十九氟辛酯（PDFOMA）。 这些产品通常用作疏水牙科材料，特别是作为复合材料（含填料），密封剂和水泥。
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公开(公告)号：US5508342A
公开(公告)日：1996-04-16
申请号：US189708
申请日：1994-02-01
CPC分类号： A61L27/12 , A61K6/0067 , A61K6/0085 , A61K6/0088 , A61K6/0091 , A61L27/46 , C08K3/32 , A61F2310/00293
摘要： A mineralizing composition for skeletal tissue comprising a mixture of an saturated monomer system, and a particulate mineralizing agent.
摘要翻译： 一种用于骨骼组织的矿化组合物，其包含不饱和单体体系和微粒化矿化剂的混合物。
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公开(公告)号：US5037473A
公开(公告)日：1991-08-06
申请号：US339802
申请日：1989-04-18
CPC分类号： A61C13/0025 , A61K6/083
摘要： A denture liner composition is provided comprising a methacrylate polymer and/or copolymer in powder form to be wetted by a liquid composition containing dimethacrylate, butyl methacrylate, and long chain methacrylate monomers, the mixture setting upon wetting and being polymerized by visible light and chemical action. A method for using the composition in denture liner formation is also provided.
摘要翻译： 提供了一种义齿衬里组合物，其包含粉末形式的甲基丙烯酸酯聚合物和/或共聚物，以由含有二甲基丙烯酸酯，甲基丙烯酸丁酯和长链甲基丙烯酸酯单体的液体组合物润湿，该混合物在润湿后设定并通过可见光和化学作用聚合 。 还提供了一种在假牙衬垫形成中使用组合物的方法。
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10.发明授权Etchant/primer composition, etchant/primer/adhesive monomer composition, kits and methods using the same for improved bonding to dental structures 有权蚀刻剂/底漆组合物，蚀刻剂/底漆/粘合剂单体组合物，使用它们的试剂盒和方法用于改善与牙科结构的结合公开(公告)号：US06458869B1
公开(公告)日：2002-10-01
申请号：US09537703
申请日：2000-03-30
IPC分类号： A61K724
CPC分类号： A61K6/0029 , A61K6/0023 , A61K6/0052 , A61K6/083 , C08L33/10
摘要： The present invention is directed to an etchant/primer composition, an etchant/primer/adhesive monomer composition, kits using the same and methods using the same for improved bonding to dental structures. The etchant/primer composition comprises a compound having the formula: RN(CH2YCO2M)2 wherein R=R1 or R2; R1=an aromatic group; R2=a conjugated unsaturated aliphatic group; Y=a single bond, CH2, CHCH3 or C═CH2; and each M is independently H, an alkali metal, an alkaline earth metal, aluminum, a transition or redox metal or an alkyl group having 1 to 18 carbon atoms, with the proviso that when both M groups are alkyl groups, said compound is capable of being easily hydrolyzed, displaced, or exchanged with other reagents present in the etchant/primer composition, a polar solvent system, and nitric acid. The etchant/primer/adhesive monomer composition comprises a compound having the formula (I) as noted above, a polar solvent system, an acid selected from the group consisting of nitric acid, hydrochloric acid, citric acid, lactic acid, glycolic acid, formic acid, pyruvic acid and combinations thereof, and adhesive monomer resin, and an initiator. The above-noted compositions are applied to dental structures requiring dental restoration for improved bonding of adhesive resins and polymers to dental structures.
摘要翻译： 本发明涉及一种蚀刻剂/底漆组合物，蚀刻剂/底漆/粘合剂单体组合物，使用该组合物的试剂盒以及使用该蚀刻剂/底漆/粘合剂单体组合物的方法，以改进与牙科结构的结合。 蚀刻剂/底漆组合物包含具有下式的化合物：其中R = R 1或R 2; R 1 =芳族基团; R 2 =共轭不饱和脂族基; Y =单键，CH 2，CHCH 3或C = CH 2; M独立地为H，碱金属，碱土金属，铝，过渡金属或氧化还原金属或具有1至18个碳原子的烷基，条件是当两个M基都是烷基时，所述化合物能够 易于水解，置换或与存在于蚀刻剂/底漆组合物中的其它试剂，极性溶剂体系和硝酸交换。 蚀刻剂/底漆/粘合剂单体组合物包含如上所述的具有式（I）的化合物，极性溶剂体系，选自硝酸，盐酸，柠檬酸，乳酸，乙醇酸，甲酸的酸 酸，丙酮酸及其组合，以及粘合单体树脂和引发剂。 将上述组合物应用于需要牙齿修复的牙科结构，以改善粘合剂树脂和聚合物与牙科结构的粘合。
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