公开(公告)号：US06897255B1

公开(公告)日：2005-05-24

申请号：US09461147

申请日：1999-12-14

申请人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Olan Stanley Fruchey

发明人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Olan Stanley Fruchey

IPC分类号： C08K5/098 ,  C09D11/10 ,  C09D133/06 ,  C08K5/04

CPC分类号： C08K5/098 ,  C09D11/106 ,  C09D133/06 ,  C08L31/02 ,  C08L2666/34

摘要： Novel latex or emulsion compositions containing internally plasticizing and crosslinkable long-chain alkenol ester monomers are disclosed and claimed. Preferred embodiments include latex formed from acrylate or methacrylate esters of long-chain alkenols. A process for the synthesis of the latex composition is also disclosed, which involves (a) esterification of a long-chain alkenol with an ethylenically unsaturated carboxylic acid; (b) polymerization of the ethylenically unsaturated ester in an aqueous phase with at least one other copolymerizable monomer; and (b) blending of so formed polymer with at least one drier and a surfactant to form the novel latex or emulsion compositions. These compositions form films at low minimum film forming temperatures (MFT) ranging from −5 to 10° C. and cure to above ambient glass transition (Tg) polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These compositions are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.

摘要翻译： 公开并要求保护含有内部增塑和可交联的长链烯醇酯单体的新型胶乳或乳液组合物。 优选的实施方案包括由长链烯醇的丙烯酸酯或甲基丙烯酸酯形成的胶乳。 还公开了合成胶乳组合物的方法，其包括（a）长链烯醇与烯属不饱和羧酸的酯化; （b）烯键式不饱和酯在水相中与至少一种其它可共聚单体的聚合; 和（b）将如此形成的聚合物与至少一种干燥剂和表面活性剂混合以形成新的胶乳或乳液组合物。 这些组合物在-5至10℃的低最低成膜温度（MFT）下形成薄膜，并固化至高于环境的玻璃化转变（T g）聚合物，而不使用传统的有机助溶剂 通过挥发性有机化合物（VOCs）排放对环境造成污染。 因此，这些组合物可用于水性涂料，接触和压敏粘合剂和油墨。

公开(公告)号：US6001913A

公开(公告)日：1999-12-14

申请号：US773670

申请日：1996-12-24

申请人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Olan Stanley Fruchey

发明人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Olan Stanley Fruchey

IPC分类号： C08K5/098 ,  C09D11/10 ,  C09D133/06 ,  C08K5/04

CPC分类号： C08K5/098 ,  C09D11/106 ,  C09D133/06

摘要： Novel latex or emulsion compositions containing internally plasticizing and crosslinkable long-chain alkenol ester monomers are disclosed and claimed. Preferred embodiments include latex formed from acrylate or methacrylate esters of long-chain alkenols. A process for the synthesis of the latex composition is also disclosed, which involves (a) esterification of a long-chain alkenol with an ethylenically unsaturated carboxylic acid; (b) polymerization of the ethylenically unsaturated ester in an aqueous phase with at least one other copolymerizable monomer; and (b) blending of so formed polymer with at least one drier and a surfactant to form the novel latex or emulsion compositions. These compositions form films at low minimum film forming temperatures (MFT) ranging from -5 to 10.degree. C. and cure to above ambient glass transition (T.sub.g) polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These compositions are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.

摘要翻译： 公开并要求保护含有内部增塑和可交联的长链烯醇酯单体的新型胶乳或乳液组合物。 优选的实施方案包括由长链烯醇的丙烯酸酯或甲基丙烯酸酯形成的胶乳。 还公开了合成胶乳组合物的方法，其包括（a）长链烯醇与烯属不饱和羧酸的酯化; （b）烯键式不饱和酯在水相中与至少一种其它可共聚单体的聚合; 和（b）将如此形成的聚合物与至少一种干燥剂和表面活性剂混合以形成新的胶乳或乳液组合物。 这些组合物在-5至10℃的低最低成膜温度（MFT）下形成薄膜，并固化至高于环境的玻璃化转变（Tg）聚合物，而不使用通过挥发性有机化合物有助于环境污染的传统有机助溶剂（ 挥发性有机化合物）排放。 因此，这些组合物可用于水性涂料，接触和压敏粘合剂和油墨。

公开(公告)号：US5807922A

公开(公告)日：1998-09-15

申请号：US739850

申请日：1996-10-30

申请人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Rajan Hariharan

发明人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Rajan Hariharan

IPC分类号： C07F7/18 ,  C08K5/16

CPC分类号： C07F7/1868

摘要： Novel organosilane derivatized long-chain compounds containing halosilane and hydroxysilane groups are disclosed and claimed. A process for the syntheses of these novel compositions is also disclosed, which involves simple one-pot hydrosilylation reaction of substituted halosilanes with substituted long-chain olefinic compounds, and subsequent hydrolysis to form surface active silanol derivatives. Preferred embodiments include organosilane derivatives of fatty acids derived from tung oil, high erucic acid rape seed oil, and linseed oil. These compositions feature high surface activity in forming stable organic/water emulsions of various difficultly emulsifiable materials as compared with conventional emulsifying agents. These compositions are useful as reactive-dispersants, defoamers, reactive-surfactants in emulsion polymerization, crosslinkers, film formers, gloss enhancers, anticorrosive additives, adhesion promoters and as general property enhancers in coatings, adhesives and inks. These compositions contribute zero volatile organic components (VOC) to these formulations.

摘要翻译： 公开并要求保护含有卤代硅烷和羟基硅烷基团的新型有机硅烷衍生的长链化合物。 还公开了这些新型组合物的合成方法，其涉及取代的卤代硅烷与取代的长链烯烃化合物的简单的一锅氢硅烷化反应，随后水解形成表面活性硅烷醇衍生物。 优选的实施方案包括衍生自桐油，高芥酸菜籽油和亚麻子油的脂肪酸的有机硅烷衍生物。 与常规乳化剂相比，这些组合物在形成各种难以乳化的材料的稳定的有机/水乳液中具有高的表面活性。 这些组合物可用作乳液聚合中的反应性分散剂，消泡剂，反应性表面活性剂，交联剂，成膜剂，光泽增强剂，防腐添加剂，粘合促进剂以及作为涂料，粘合剂和油墨中的一般性能增强剂。 这些组合物对这些制剂贡献零挥发性有机成分（VOC）。

公开(公告)号：US06174948B1

公开(公告)日：2001-01-16

申请号：US08773668

申请日：1996-12-24

申请人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Olan Stanley Fruchey

发明人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Olan Stanley Fruchey

IPC分类号： C08K504

CPC分类号： C09D133/062 ,  C08L2666/28

摘要： Novel latex or emulsion compositions containing internally plasticizing and crosslinkable monomers derived from traditional semi-drying or non-drying oils are disclosed and claimed. The monomers are ethylenically unsaturated derivatives of long-chain olefinic compounds. Preferred embodiments include latex formed from acrylate or methacrylate esters of fatty alcohols. A process for the synthesis of the latex composition is also disclosed, which involves (a) polymerization of the ethylenically unsaturated derivatives of a long-chain olefinic compound in an aqueous phase with at least one other copolymerizable monomer; and (b) blending of so formed polymer with at least one drier and a surfactant to form the novel latex or emulsion compositions. These compositions form films at low minimum film forming temperatures (MFT) ranging from −5 to 10° C. and cure to above ambient glass transition (Tg) polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These compositions are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.

摘要翻译： 公开并要求保护含有衍生自传统半干燥或非干燥油的内部增塑和可交联单体的新型胶乳或乳液组合物。 单体是长链烯烃化合物的烯属不饱和衍生物。 优选的实施方案包括由脂肪醇的丙烯酸酯或甲基丙烯酸酯形成的胶乳。 还公开了合成胶乳组合物的方法，其包括（a）将水性相中的长链烯烃化合物的烯属不饱和衍生物与至少一种其它可共聚单体聚合; 和（b）将如此形成的聚合物与至少一种干燥剂和表面活性剂混合以形成新的胶乳或乳液组合物。 这些组合物在-5至10℃的低最低成膜温度（MFT）下形成薄膜，并固化至高于环境的玻璃化转变（Tg）聚合物，而不使用通过挥发性有机化合物有助于环境污染的传统有机助溶剂（ 挥发性有机化合物）排放。 因此，这些组合物可用于水性涂料，接触和压敏粘合剂以及油墨。

公开(公告)号：US06700006B2

公开(公告)日：2004-03-02

申请号：US09832266

申请日：2001-04-10

申请人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Rajan Hariharan ,  Zhiyu Wang

发明人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Rajan Hariharan ,  Zhiyu Wang

IPC分类号： C07C5900

CPC分类号： C08F220/18 ,  C07C69/73 ,  C08F218/08 ,  Y10S977/788

摘要： Novel compounds derived from traditional semi- drying and non-drying oils featuring internally plasticizing and crosslinkable properties are disclosed and claimed. Preferred embodiments include acrylate or methacrylate esters of hydroxy long-chain olefinic compounds derived from castor oil or lesquerella oil. A process for the preparation of the novel compounds is also disclosed, which involves esterification reaction of ethylenically unsaturated carboxylic acids or its derivatives with substituted hydroxy long-chain olefinic compounds. These compounds are suitable for forming latices, which form films at low minimum film forming temperatures (MFT) ranging from −5 to 10° C. and cure to above ambient glass transition (Tg) polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These latices are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.

摘要翻译： 公开并要求保护具有内部增塑和交联性能的传统半干燥和非干燥油衍生的新型化合物。 优选的实施方案包括衍生自蓖麻油或莱斯特雷拉油的羟基长链烯烃化合物的丙烯酸酯或甲基丙烯酸酯。 还公开了制备新化合物的方法，其涉及烯键式不饱和羧酸或其衍生物与取代的羟基长链烯烃化合物的酯化反应。 这些化合物适用于形成胶乳，其在低至最低成膜温度（MFT）为-5至10℃下形成薄膜，并固化至高于环境的玻璃化转变（Tg）聚合物，而不使用传统的有机共溶剂，其有助于 通过挥发性有机化合物（VOCs）排放的环境污染。 因此，这些胶乳可用于水性涂料，接触和压敏粘合剂以及油墨。

公开(公告)号：US06599972B2

公开(公告)日：2003-07-29

申请号：US09759305

申请日：2001-01-12

申请人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Olan Stanley Fruchey

发明人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Olan Stanley Fruchey

IPC分类号： C08K504

CPC分类号： C09D133/062 ,  C08L2666/28

摘要： Novel latex or emulsion compositions containing internally plasticizing and crosslinkable monomers derived from traditional semi-drying or non-drying oils are disclosed and claimed. The monomers are ethylenically unsaturated derivatives of long-chain olefinic compounds. Preferred embodiments include latex formed from acrylate or methacrylate esters of fatty alcohols. A process for the synthesis of the latex composition is also disclosed, which involves (a) polymerization of the ethylenically unsaturated derivatives of a long-chain olefinic compound in an aqueous phase with at least one other copolymerizable monomer; and (b) blending of so formed polymer with at least one drier and a surfactant to form the novel latex or emulsion compositions. These compositions form films at low minimum film forming temperatures (MFT) ranging from −5 to 10° C. and cure to above ambient glass transition (Tg) polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These compositions are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.

摘要翻译： 公开并要求保护含有衍生自传统半干燥或非干燥油的内部增塑和可交联单体的新型胶乳或乳液组合物。 单体是长链烯烃化合物的烯属不饱和衍生物。 优选的实施方案包括由脂肪醇的丙烯酸酯或甲基丙烯酸酯形成的胶乳。 还公开了合成胶乳组合物的方法，其包括（a）将水性相中的长链烯烃化合物的烯属不饱和衍生物与至少一种其它可共聚单体聚合; 和（b）将如此形成的聚合物与至少一种干燥剂和表面活性剂混合以形成新的胶乳或乳液组合物。 这些组合物在-5至10℃的低最低成膜温度（MFT）下形成薄膜，并固化至高于环境的玻璃化转变（Tg）聚合物，而不使用通过挥发性有机化合物有助于环境污染的传统有机助溶剂（ 挥发性有机化合物）排放。 因此，这些组合物可用于水性涂料，接触和压敏粘合剂和油墨。

公开(公告)号：US06653381B2

公开(公告)日：2003-11-25

申请号：US09832185

申请日：2001-04-10

申请人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Rajan Hariharan ,  Zhiyu Wang

发明人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Rajan Hariharan ,  Zhiyu Wang

IPC分类号： C08K509

CPC分类号： C08F220/18 ,  C07C69/73 ,  C08F218/08 ,  Y10S977/788

摘要： Novel compounds derived from traditional semi- drying and non-drying oils featuring internally plasticizing and crosslinkable properties are disclosed and claimed. Preferred embodiments include acrylate or methacrylate esters of hydroxy long-chain olefinic compounds derived from castor oil or lesquerella oil. A process for the preparation of the novel compounds is also disclosed, which involves esterification reaction of ethylenically unsaturated carboxylic acids or its derivatives with substituted hydroxy long-chain olefinic compounds. These compounds are suitable for forming latices, which form films at low minimum film forming temperatures (MFT) ranging from −5 to 10 ° C. and cure to above ambient glass transition (Tg polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These latices are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.

摘要翻译： 公开并要求保护具有内部增塑和交联性能的传统半干燥和非干燥油衍生的新型化合物。 优选的实施方案包括衍生自蓖麻油或莱斯特雷拉油的羟基长链烯烃化合物的丙烯酸酯或甲基丙烯酸酯。 还公开了制备新化合物的方法，其涉及烯键式不饱和羧酸或其衍生物与取代的羟基长链烯烃化合物的酯化反应。 这些化合物适用于形成胶乳，其在低至最低成膜温度（MFT）为-5至10℃下形成薄膜，并固化至高于环境的玻璃化转变温度（Tg聚合物，而不使用有助于环境的传统有机助溶剂 因此，通过挥发性有机化合物（VOCs）排放污染，因此这些胶乳可用于水性涂料，接触和压敏粘合剂以及油墨。

公开(公告)号：US06624223B1

公开(公告)日：2003-09-23

申请号：US09460946

申请日：1999-12-14

申请人： Shelby Freland Thames ,  Zhiyu Wang ,  Elizabeth H. Brister ,  Rajan Hariharan ,  Corey L. King ,  Kamlesh Gopichand Panjnani

发明人： Shelby Freland Thames ,  Zhiyu Wang ,  Elizabeth H. Brister ,  Rajan Hariharan ,  Corey L. King ,  Kamlesh Gopichand Panjnani

IPC分类号： C08K5098

CPC分类号： C08F242/00 ,  C07C69/732 ,  C08F20/28 ,  C08F283/01 ,  C08F289/00 ,  C09D11/06 ,  C09D11/106 ,  C09D133/00 ,  C09D135/00 ,  C09D135/06

摘要： Novel latex or emulsion compositions containing internally plasticizing and crosslinkable monomers derived from traditional semi-drying or non-drying oils are disclosed and claimed. The monomers are ethylenically unsaturated esters of long-chain olefinic compounds. Preferred embodiments include latex formed from acrylate or methacrylate esters of hydroxy fatty acid esters derived from castor oil or lesquerella oil. A process for the synthesis of the latex composition is also disclosed, which involves (a) an esterification reaction of ethylenically unsaturated carboxylic acid or its derivatives with a substituted hydroxy long-chain olefinic compound; (b) subsequent polymerization of the so formed ethylenically unsaturated ester of a long-chain olefinic compound in an aqueous phase with at least one other copolymerizable monomer; and (c) blending so formed polymer with at least one drier and a surfactant to form the novel latex or emulsion compositions. These compositions form films at low minimum film forming temperatures (MFT) ranging from −5 to 10° C. and cure to above ambient glass transition (Tg) polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These compositions are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.

摘要翻译： 公开并要求保护含有衍生自传统半干燥或非干燥油的内部增塑和可交联单体的新型胶乳或乳液组合物。 单体是长链烯烃化合物的烯属不饱和酯。 优选的实施方案包括由衍生自蓖麻油或莱斯特雷拉油的羟基脂肪酸酯的丙烯酸酯或甲基丙烯酸酯形成的胶乳。 还公开了合成胶乳组合物的方法，其包括（a）烯键式不饱和羧酸或其衍生物与取代的羟基长链烯烃化合物的酯化反应; （b）将如此形成的长链烯属化合物的烯键式不饱和酯在水相中与至少一种其它可共聚单体的聚合; 和（c）将如此形成的聚合物与至少一种干燥剂和表面活性剂混合以形成新的胶乳或乳液组合物。 这些组合物在-5至10℃的低最低成膜温度（MFT）下形成薄膜，并固化至高于环境的玻璃化转变（Tg）聚合物，而不使用通过挥发性有机化合物有助于环境污染的传统有机助溶剂（ 挥发性有机化合物）排放。 因此，这些组合物可用于水性涂料，接触和压敏粘合剂和油墨。

公开(公告)号：US06235916B1

公开(公告)日：2001-05-22

申请号：US08773014

申请日：1996-12-24

申请人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Rajan Hariharan ,  Zhiyu Wang

发明人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Rajan Hariharan ,  Zhiyu Wang

IPC分类号： C07C5900

CPC分类号： C08F220/18 ,  C07C69/73 ,  C08F218/08 ,  Y10S977/788

摘要： Novel compounds derived from traditional semi-drying and non-drying oils featuring internally plasticizing and crosslinkable properties are disclosed and claimed. Preferred embodiments include acrylate or methacrylate esters of hydroxy long-chain olefinic compounds derived from castor oil or lesquerella oil. A process for the preparation of the novel compounds is also disclosed, which involves esterification reaction of ethylenically unsaturated carboxylic acids or its derivatives with substituted hydroxy long-chain olefinic compounds. These compounds are suitable for forming latices, which form films at low minimum film forming temperatures (MFT) ranging from −5 to 10° C. and cure to above ambient glass transition (Tg) polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These latices are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.

摘要翻译： 公开并要求保护具有内部增塑和可交联性能的传统半干燥和非干燥油衍生的新型化合物。 优选的实施方案包括衍生自蓖麻油或莱斯特雷拉油的羟基长链烯烃化合物的丙烯酸酯或甲基丙烯酸酯。 还公开了制备新化合物的方法，其涉及烯键式不饱和羧酸或其衍生物与取代的羟基长链烯烃化合物的酯化反应。 这些化合物适用于形成胶乳，其在低至最低成膜温度（MFT）为-5至10℃下形成薄膜，并固化至高于环境的玻璃化转变（Tg）聚合物，而不使用传统的有机共溶剂，其有助于 通过挥发性有机化合物（VOCs）排放的环境污染。 因此，这些胶乳可用于水性涂料，接触和压敏粘合剂以及油墨。

公开(公告)号：US06203720B1

公开(公告)日：2001-03-20

申请号：US08773741

申请日：1996-12-24

申请人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Rajan Hariharan ,  Zhiyu Wang

发明人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Rajan Hariharan ,  Zhiyu Wang

IPC分类号： C09K300

CPC分类号： C09D11/106 ,  C08F242/00 ,  C08F289/00 ,  C09D133/00 ,  C09D135/00 ,  C09D135/06

摘要： Novel latex or emulsion compositions containing internally plasticizing and crosslinkable monomers derived from traditional semi-drying or non-drying oils are disclosed and claimed. The monomers are ethylenically unsaturated esters of long-chain olefinic compounds. Preferred embodiments include latex formed from acrylate or methacrylate esters of hydroxy fatty acid esters derived from castor oil or lesquerella oil. A process for the synthesis of the latex composition is also disclosed, which involves (a) an esterification reaction of ethylenically unsaturated carboxylic acid or its derivatives with a substituted hydroxy long-chain olefinic compound; (b) subsequent polymerization of the so formed ethylenically unsaturated ester of a long-chain olefinic compound in an aqueous phase with at least one other copolymerizable monomer; and (c) blending so formed polymer with at least one drier and a surfactant to form the novel latex or emulsion compositions. These compositions form films at low minimum film forming temperatures (MFT) ranging from −5 to 10° C. and cure to above ambient glass transition (Tg) polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These compositions are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.

摘要翻译： 公开并要求保护含有衍生自传统半干燥或非干燥油的内部增塑和可交联单体的新型胶乳或乳液组合物。 单体是长链烯烃化合物的烯属不饱和酯。 优选的实施方案包括由衍生自蓖麻油或莱斯特雷拉油的羟基脂肪酸酯的丙烯酸酯或甲基丙烯酸酯形成的胶乳。 还公开了合成胶乳组合物的方法，其包括（a）烯键式不饱和羧酸或其衍生物与取代的羟基长链烯烃化合物的酯化反应; （b）将如此形成的长链烯属化合物的烯键式不饱和酯在水相中与至少一种其它可共聚单体的聚合; 和（c）将如此形成的聚合物与至少一种干燥剂和表面活性剂混合以形成新的胶乳或乳液组合物。 这些组合物在-5至10℃的低最低成膜温度（MFT）下形成薄膜，并固化至高于环境的玻璃化转变（Tg）聚合物，而不使用通过挥发性有机化合物有助于环境污染的传统有机助溶剂（ 挥发性有机化合物）排放。 因此，这些组合物可用于水性涂料，接触和压敏粘合剂和油墨。