公开(公告)号：US06700006B2

公开(公告)日：2004-03-02

申请号：US09832266

申请日：2001-04-10

申请人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Rajan Hariharan ,  Zhiyu Wang

发明人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Rajan Hariharan ,  Zhiyu Wang

IPC分类号： C07C5900

CPC分类号： C08F220/18 ,  C07C69/73 ,  C08F218/08 ,  Y10S977/788

摘要： Novel compounds derived from traditional semi- drying and non-drying oils featuring internally plasticizing and crosslinkable properties are disclosed and claimed. Preferred embodiments include acrylate or methacrylate esters of hydroxy long-chain olefinic compounds derived from castor oil or lesquerella oil. A process for the preparation of the novel compounds is also disclosed, which involves esterification reaction of ethylenically unsaturated carboxylic acids or its derivatives with substituted hydroxy long-chain olefinic compounds. These compounds are suitable for forming latices, which form films at low minimum film forming temperatures (MFT) ranging from −5 to 10° C. and cure to above ambient glass transition (Tg) polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These latices are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.

摘要翻译： 公开并要求保护具有内部增塑和交联性能的传统半干燥和非干燥油衍生的新型化合物。 优选的实施方案包括衍生自蓖麻油或莱斯特雷拉油的羟基长链烯烃化合物的丙烯酸酯或甲基丙烯酸酯。 还公开了制备新化合物的方法，其涉及烯键式不饱和羧酸或其衍生物与取代的羟基长链烯烃化合物的酯化反应。 这些化合物适用于形成胶乳，其在低至最低成膜温度（MFT）为-5至10℃下形成薄膜，并固化至高于环境的玻璃化转变（Tg）聚合物，而不使用传统的有机共溶剂，其有助于 通过挥发性有机化合物（VOCs）排放的环境污染。 因此，这些胶乳可用于水性涂料，接触和压敏粘合剂以及油墨。

公开(公告)号：US06653381B2

公开(公告)日：2003-11-25

申请号：US09832185

申请日：2001-04-10

申请人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Rajan Hariharan ,  Zhiyu Wang

发明人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Rajan Hariharan ,  Zhiyu Wang

IPC分类号： C08K509

CPC分类号： C08F220/18 ,  C07C69/73 ,  C08F218/08 ,  Y10S977/788

摘要： Novel compounds derived from traditional semi- drying and non-drying oils featuring internally plasticizing and crosslinkable properties are disclosed and claimed. Preferred embodiments include acrylate or methacrylate esters of hydroxy long-chain olefinic compounds derived from castor oil or lesquerella oil. A process for the preparation of the novel compounds is also disclosed, which involves esterification reaction of ethylenically unsaturated carboxylic acids or its derivatives with substituted hydroxy long-chain olefinic compounds. These compounds are suitable for forming latices, which form films at low minimum film forming temperatures (MFT) ranging from −5 to 10 ° C. and cure to above ambient glass transition (Tg polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These latices are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.

摘要翻译： 公开并要求保护具有内部增塑和交联性能的传统半干燥和非干燥油衍生的新型化合物。 优选的实施方案包括衍生自蓖麻油或莱斯特雷拉油的羟基长链烯烃化合物的丙烯酸酯或甲基丙烯酸酯。 还公开了制备新化合物的方法，其涉及烯键式不饱和羧酸或其衍生物与取代的羟基长链烯烃化合物的酯化反应。 这些化合物适用于形成胶乳，其在低至最低成膜温度（MFT）为-5至10℃下形成薄膜，并固化至高于环境的玻璃化转变温度（Tg聚合物，而不使用有助于环境的传统有机助溶剂 因此，通过挥发性有机化合物（VOCs）排放污染，因此这些胶乳可用于水性涂料，接触和压敏粘合剂以及油墨。

公开(公告)号：US06624223B1

公开(公告)日：2003-09-23

申请号：US09460946

申请日：1999-12-14

申请人： Shelby Freland Thames ,  Zhiyu Wang ,  Elizabeth H. Brister ,  Rajan Hariharan ,  Corey L. King ,  Kamlesh Gopichand Panjnani

发明人： Shelby Freland Thames ,  Zhiyu Wang ,  Elizabeth H. Brister ,  Rajan Hariharan ,  Corey L. King ,  Kamlesh Gopichand Panjnani

IPC分类号： C08K5098

CPC分类号： C08F242/00 ,  C07C69/732 ,  C08F20/28 ,  C08F283/01 ,  C08F289/00 ,  C09D11/06 ,  C09D11/106 ,  C09D133/00 ,  C09D135/00 ,  C09D135/06

摘要： Novel latex or emulsion compositions containing internally plasticizing and crosslinkable monomers derived from traditional semi-drying or non-drying oils are disclosed and claimed. The monomers are ethylenically unsaturated esters of long-chain olefinic compounds. Preferred embodiments include latex formed from acrylate or methacrylate esters of hydroxy fatty acid esters derived from castor oil or lesquerella oil. A process for the synthesis of the latex composition is also disclosed, which involves (a) an esterification reaction of ethylenically unsaturated carboxylic acid or its derivatives with a substituted hydroxy long-chain olefinic compound; (b) subsequent polymerization of the so formed ethylenically unsaturated ester of a long-chain olefinic compound in an aqueous phase with at least one other copolymerizable monomer; and (c) blending so formed polymer with at least one drier and a surfactant to form the novel latex or emulsion compositions. These compositions form films at low minimum film forming temperatures (MFT) ranging from −5 to 10° C. and cure to above ambient glass transition (Tg) polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These compositions are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.

摘要翻译： 公开并要求保护含有衍生自传统半干燥或非干燥油的内部增塑和可交联单体的新型胶乳或乳液组合物。 单体是长链烯烃化合物的烯属不饱和酯。 优选的实施方案包括由衍生自蓖麻油或莱斯特雷拉油的羟基脂肪酸酯的丙烯酸酯或甲基丙烯酸酯形成的胶乳。 还公开了合成胶乳组合物的方法，其包括（a）烯键式不饱和羧酸或其衍生物与取代的羟基长链烯烃化合物的酯化反应; （b）将如此形成的长链烯属化合物的烯键式不饱和酯在水相中与至少一种其它可共聚单体的聚合; 和（c）将如此形成的聚合物与至少一种干燥剂和表面活性剂混合以形成新的胶乳或乳液组合物。 这些组合物在-5至10℃的低最低成膜温度（MFT）下形成薄膜，并固化至高于环境的玻璃化转变（Tg）聚合物，而不使用通过挥发性有机化合物有助于环境污染的传统有机助溶剂（ 挥发性有机化合物）排放。 因此，这些组合物可用于水性涂料，接触和压敏粘合剂和油墨。

公开(公告)号：US06235916B1

公开(公告)日：2001-05-22

申请号：US08773014

申请日：1996-12-24

申请人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Rajan Hariharan ,  Zhiyu Wang

发明人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Rajan Hariharan ,  Zhiyu Wang

IPC分类号： C07C5900

CPC分类号： C08F220/18 ,  C07C69/73 ,  C08F218/08 ,  Y10S977/788

摘要： Novel compounds derived from traditional semi-drying and non-drying oils featuring internally plasticizing and crosslinkable properties are disclosed and claimed. Preferred embodiments include acrylate or methacrylate esters of hydroxy long-chain olefinic compounds derived from castor oil or lesquerella oil. A process for the preparation of the novel compounds is also disclosed, which involves esterification reaction of ethylenically unsaturated carboxylic acids or its derivatives with substituted hydroxy long-chain olefinic compounds. These compounds are suitable for forming latices, which form films at low minimum film forming temperatures (MFT) ranging from −5 to 10° C. and cure to above ambient glass transition (Tg) polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These latices are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.

摘要翻译： 公开并要求保护具有内部增塑和可交联性能的传统半干燥和非干燥油衍生的新型化合物。 优选的实施方案包括衍生自蓖麻油或莱斯特雷拉油的羟基长链烯烃化合物的丙烯酸酯或甲基丙烯酸酯。 还公开了制备新化合物的方法，其涉及烯键式不饱和羧酸或其衍生物与取代的羟基长链烯烃化合物的酯化反应。 这些化合物适用于形成胶乳，其在低至最低成膜温度（MFT）为-5至10℃下形成薄膜，并固化至高于环境的玻璃化转变（Tg）聚合物，而不使用传统的有机共溶剂，其有助于 通过挥发性有机化合物（VOCs）排放的环境污染。 因此，这些胶乳可用于水性涂料，接触和压敏粘合剂以及油墨。

公开(公告)号：US06203720B1

公开(公告)日：2001-03-20

申请号：US08773741

申请日：1996-12-24

申请人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Rajan Hariharan ,  Zhiyu Wang

发明人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Rajan Hariharan ,  Zhiyu Wang

IPC分类号： C09K300

CPC分类号： C09D11/106 ,  C08F242/00 ,  C08F289/00 ,  C09D133/00 ,  C09D135/00 ,  C09D135/06

摘要： Novel latex or emulsion compositions containing internally plasticizing and crosslinkable monomers derived from traditional semi-drying or non-drying oils are disclosed and claimed. The monomers are ethylenically unsaturated esters of long-chain olefinic compounds. Preferred embodiments include latex formed from acrylate or methacrylate esters of hydroxy fatty acid esters derived from castor oil or lesquerella oil. A process for the synthesis of the latex composition is also disclosed, which involves (a) an esterification reaction of ethylenically unsaturated carboxylic acid or its derivatives with a substituted hydroxy long-chain olefinic compound; (b) subsequent polymerization of the so formed ethylenically unsaturated ester of a long-chain olefinic compound in an aqueous phase with at least one other copolymerizable monomer; and (c) blending so formed polymer with at least one drier and a surfactant to form the novel latex or emulsion compositions. These compositions form films at low minimum film forming temperatures (MFT) ranging from −5 to 10° C. and cure to above ambient glass transition (Tg) polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These compositions are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.

摘要翻译： 公开并要求保护含有衍生自传统半干燥或非干燥油的内部增塑和可交联单体的新型胶乳或乳液组合物。 单体是长链烯烃化合物的烯属不饱和酯。 优选的实施方案包括由衍生自蓖麻油或莱斯特雷拉油的羟基脂肪酸酯的丙烯酸酯或甲基丙烯酸酯形成的胶乳。 还公开了合成胶乳组合物的方法，其包括（a）烯键式不饱和羧酸或其衍生物与取代的羟基长链烯烃化合物的酯化反应; （b）将如此形成的长链烯属化合物的烯键式不饱和酯在水相中与至少一种其它可共聚单体的聚合; 和（c）将如此形成的聚合物与至少一种干燥剂和表面活性剂混合以形成新的胶乳或乳液组合物。 这些组合物在-5至10℃的低最低成膜温度（MFT）下形成薄膜，并固化至高于环境的玻璃化转变（Tg）聚合物，而不使用通过挥发性有机化合物有助于环境污染的传统有机助溶剂（ 挥发性有机化合物）排放。 因此，这些组合物可用于水性涂料，接触和压敏粘合剂和油墨。

公开(公告)号：US5807922A

公开(公告)日：1998-09-15

申请号：US739850

申请日：1996-10-30

申请人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Rajan Hariharan

发明人： Shelby Freland Thames ,  Kamlesh Gopichand Panjnani ,  Rajan Hariharan

IPC分类号： C07F7/18 ,  C08K5/16

CPC分类号： C07F7/1868

摘要： Novel organosilane derivatized long-chain compounds containing halosilane and hydroxysilane groups are disclosed and claimed. A process for the syntheses of these novel compositions is also disclosed, which involves simple one-pot hydrosilylation reaction of substituted halosilanes with substituted long-chain olefinic compounds, and subsequent hydrolysis to form surface active silanol derivatives. Preferred embodiments include organosilane derivatives of fatty acids derived from tung oil, high erucic acid rape seed oil, and linseed oil. These compositions feature high surface activity in forming stable organic/water emulsions of various difficultly emulsifiable materials as compared with conventional emulsifying agents. These compositions are useful as reactive-dispersants, defoamers, reactive-surfactants in emulsion polymerization, crosslinkers, film formers, gloss enhancers, anticorrosive additives, adhesion promoters and as general property enhancers in coatings, adhesives and inks. These compositions contribute zero volatile organic components (VOC) to these formulations.

摘要翻译： 公开并要求保护含有卤代硅烷和羟基硅烷基团的新型有机硅烷衍生的长链化合物。 还公开了这些新型组合物的合成方法，其涉及取代的卤代硅烷与取代的长链烯烃化合物的简单的一锅氢硅烷化反应，随后水解形成表面活性硅烷醇衍生物。 优选的实施方案包括衍生自桐油，高芥酸菜籽油和亚麻子油的脂肪酸的有机硅烷衍生物。 与常规乳化剂相比，这些组合物在形成各种难以乳化的材料的稳定的有机/水乳液中具有高的表面活性。 这些组合物可用作乳液聚合中的反应性分散剂，消泡剂，反应性表面活性剂，交联剂，成膜剂，光泽增强剂，防腐添加剂，粘合促进剂以及作为涂料，粘合剂和油墨中的一般性能增强剂。 这些组合物对这些制剂贡献零挥发性有机成分（VOC）。

公开(公告)号：US06291077B1

公开(公告)日：2001-09-18

申请号：US09649002

申请日：2000-08-28

申请人： Rajan Hariharan ,  David A. Hutchings ,  Kenneth A. Bourlier ,  Ellen V. Nagy

发明人： Rajan Hariharan ,  David A. Hutchings ,  Kenneth A. Bourlier ,  Ellen V. Nagy

IPC分类号： B32B2706

CPC分类号： C08G18/4277 ,  C08F283/00 ,  C08F283/02 ,  C08F283/04 ,  C08G61/02 ,  C08G69/44 ,  Y10T428/31786

摘要： A lactone chain-extended polyester polyol of the present invention comprises the reaction product of a lactone and a previously chain-extended phenolic-based hydroxyl compound. The previously chain-extended phenolic-based hydroxyl compound may comprise the reaction product of (i) a lactone or an alkoxylating agent selected from the group consisting of alkylene oxides and alkylene carbonates, and (ii) a phenolic aralkylation polymer comprising the reaction product of a phenolic monomer having at least two free reactive positions; a styrene derivative; and a coupling agent. The previously chain-extended phenolic-based hydroxyl compound also may be chain-extended by reacting with a lactam to produce a lactam chain-extended polyester polyamide. The polyols and polyamides of the present invention provide unique combinations of hard and soft functionalities, which translates into materials exhibiting a unique combination of toughness and hardness. These materials are especially suitable for use in high solids coatings and in the development of resins which can be readily processed into thermoset resins. The materials also may function as compatibilizers for thermoplastics.

摘要翻译： 本发明的内酯链延长聚酯多元醇包括内酯与先前扩链的酚基羟基化合物的反应产物。 先前扩链的酚基羟基化合物可以包含（i）内酯或选自环氧烷烃和碳酸亚烷基酯的烷氧基化剂的反应产物，和（ii）包含以下的反应产物的酚芳烷基化聚合物： 具有至少两个自由反应位置的酚单体; 苯乙烯衍生物; 和偶联剂。 先前的链延长的酚基羟基化合物也可以通过与内酰胺反应来产生内酰胺链延长的聚酯聚酰胺来延伸。 本发明的多元醇和聚酰胺提供硬和软功能的独特组合，其转化为显示韧性和硬度的独特组合的材料。 这些材料特别适用于高固含量涂料和开发可以容易地加工成热固性树脂的树脂。 这些材料也可用作热塑性塑料的增容剂。

公开(公告)号：US5371171A

公开(公告)日：1994-12-06

申请号：US27134

申请日：1993-03-05

申请人： A. G. Pinkus ,  Rajan Hariharan

发明人： A. G. Pinkus ,  Rajan Hariharan

IPC分类号： B32B15/04 ,  B32B17/10 ,  C03C27/04 ,  C03C27/10 ,  C08G63/18 ,  C08G63/40 ,  C08G63/02

CPC分类号： C03C27/10 ,  B32B15/04 ,  B32B17/10779 ,  C03C27/048 ,  C08G63/18 ,  C08G63/40

摘要： A poly(methylene oxalate) polymer [poly(oxy(1,2-dioxo-1,2-ethanediyl)oxymethylene)], a bis(tetrabutylammonium) oxalate salt, methods of synthesis thereof and methods of use. Poly(methylene oxalate) is insoluble in all common organic solvents, does not melt and is resistant to fire. Applications are as a light-weight material for use at high temperatures, e.g. as a structural material in aircraft and space vehicles, as a binder for brake systems, and as an insulator for microelectronic components.

摘要翻译： 聚（亚甲基草酸盐）聚合物[聚（氧基（1,2-二氧代-1,2-乙二基）甲醛）]，双（四丁基铵）草酸盐，其合成方法和使用方法。 聚（亚甲基草酸盐）不溶于所有常见的有机溶剂，不熔化并耐火。 应用是作为在高温下使用的轻质材料，例如。 作为飞机和太空车辆中的结构材料，作为制动系统的粘合剂，以及作为微电子部件的绝缘体。

公开(公告)号：US20100084757A1

公开(公告)日：2010-04-08

申请号：US12567523

申请日：2009-09-25

申请人： Rajan Hariharan ,  James Hurley ,  Senthil Kanagavel ,  Jose Quinones ,  Martin Sobczak ,  Deborah Makita

发明人： Rajan Hariharan ,  James Hurley ,  Senthil Kanagavel ,  Jose Quinones ,  Martin Sobczak ,  Deborah Makita

IPC分类号： H01L23/48 ,  B05D5/12 ,  H01L23/498

CPC分类号： C08K5/09 ,  B23K35/3612 ,  B23K2101/36 ,  C08K3/08 ,  C08K2003/0806 ,  C08K2003/0837 ,  C08K2003/085 ,  H01B1/22 ,  H01L23/04 ,  H01L23/3178 ,  H01L23/4928 ,  H01L23/49883 ,  H01L24/80 ,  H01L2224/03332 ,  H01L2224/03442 ,  H01L2224/80011 ,  H01L2924/0002 ,  H05K7/02 ,  H01L2924/00

摘要： A conductive composition includes a mono-acid hybrid that includes an unprotected, single reactive group. The mono-acid hybrid may include substantially non-reactive groups elsewhere such that the mono-acid hybrid is functional as a chain terminator. Methods and devices using the compositions are also disclosed.

摘要翻译： 导电组合物包括单酸混合物，其包含未被保护的单个反应性基团。 单酸杂化物可以在其他地方包括基本上非反应性基团，使得单酸杂合物作为链终止剂起作用。 还公开了使用该组合物的方法和装置。

公开(公告)号：US20060079050A1

公开(公告)日：2006-04-13

申请号：US11243890

申请日：2005-10-05

申请人： John Cahalen ,  Maria Rzeznik ,  John Schemenaur ,  Rajan Hariharan

发明人： John Cahalen ,  Maria Rzeznik ,  John Schemenaur ,  Rajan Hariharan

IPC分类号： H01L21/8242

CPC分类号： H05K1/162 ,  H01G4/005 ,  H01L28/75 ,  H05K3/384 ,  H05K2201/0355 ,  H05K2201/09509 ,  H05K2203/0723

摘要： Structures including a capacitor dielectric material disposed on the surface of an electrode suitable for use in forming capacitors are disclosed. Methods of forming such structures are also disclosed.

摘要翻译： 公开了包括设置在适合用于形成电容器的电极的表面上的电容器电介质材料的结构。 还公开了形成这种结构的方法。