Carbon nanotube manufacturing method
    2.
    发明授权
    Carbon nanotube manufacturing method 有权
    碳纳米管制造方法

    公开(公告)号:US09527737B2

    公开(公告)日:2016-12-27

    申请号:US14003289

    申请日:2012-03-08

    IPC分类号: C01B31/02 B82Y40/00 B82Y30/00

    摘要: Carbon nanotubes (CNTs) having a desired diameter are selectively produced by reacting a carbon source with a cyclic compound in which multiple aromatic rings are continuously bonded. The reaction is preferably performed by supplying a gaseous carbon source under reduced pressure and heating. The cyclic compound in which multiple aromatic rings are continuously bonded is preferably a cyclic compound in which bivalent aromatic hydrocarbon groups are continuously bonded, or a modified cycloparaphenylene compound in which a cycloparaphenylene compound or at least one phenylene group of the cycloparaphenylene compound is substituted with a condensed cyclic group such as a naphthylene group.

    摘要翻译: 通过使碳源与多个芳环连续键合的环状化合物反应,选择性地制造具有所需直径的碳纳米管(CNT)。 反应优选通过在减压和加热下供给气态碳源进行。 连续键合多个芳香环的环状化合物优选为二价芳香族烃基连续键合的环状化合物,或环状亚苯基化合物或环状亚苯基化合物的至少一个亚苯基被 缩合的环状基团如亚萘基。

    CARBON NANOTUBE MANUFACTURING METHOD
    5.
    发明申请
    CARBON NANOTUBE MANUFACTURING METHOD 有权
    碳纳米管制造方法

    公开(公告)号:US20140030183A1

    公开(公告)日:2014-01-30

    申请号:US14003289

    申请日:2012-03-08

    IPC分类号: C01B31/02

    摘要: Carbon nanotubes (CNTs) having a desired diameter are selectively produced by reacting a carbon source with a cyclic compound in which multiple aromatic rings are continuously bonded. The reaction is preferably performed by supplying a gaseous carbon source under reduced pressure and heating. The cyclic compound in which multiple aromatic rings are continuously bonded is preferably a cyclic compound in which bivalent aromatic hydrocarbon groups are continuously bonded, or a modified cycloparaphenylene compound in which a cycloparaphenylene compound or at least one phenylene group of the cycloparaphenylene compound is substituted with a condensed cyclic group such as a naphthylene group.

    摘要翻译: 通过使碳源与多个芳环连续键合的环状化合物反应,选择性地制造具有所需直径的碳纳米管(CNT)。 反应优选通过在减压和加热下供给气态碳源进行。 连续键合多个芳香环的环状化合物优选为二价芳香族烃基连续键合的环状化合物,或环状亚苯基化合物或环状亚苯基化合物的至少一个亚苯基被 缩合的环状基团如亚萘基。

    METHOD FOR PRODUCING POLYCYCLIC AROMATIC COMPOUND SUBSTITUTED BY ARYL GROUP
    9.
    发明申请
    METHOD FOR PRODUCING POLYCYCLIC AROMATIC COMPOUND SUBSTITUTED BY ARYL GROUP 有权
    用于生产由ARYL GROUP取代的多环芳香化合物的方法

    公开(公告)号:US20140206908A1

    公开(公告)日:2014-07-24

    申请号:US14125119

    申请日:2012-06-08

    IPC分类号: C07C41/30 C07C2/86 C07C17/361

    摘要: PAH is subjected to C—H/C—B coupling using a specific boron compound, a palladium compound, and o-chloranil to produce a compound in which a C—H bond of the PAH is directly arylated regioselectively in a simple manner. When the substrate and the boron compound are appropriately selected, a larger PAH can also be obtained by further performing an annulation reaction after the coupling reaction. Similarly, when PAH is subjected to C—H/C—H cross-coupling using a specific aromatic compound, a palladium compound, and o-chloranil, a compound in which a C—H bond of the PAH is directly arylated regioselectively can be produced in a simple manner. When the substrate and the aromatic compound are appropriately selected in this case, a larger PAH can also be obtained by further performing an annulation reaction after the cross-coupling reaction.

    摘要翻译: 使用特定的硼化合物,钯化合物和邻氯醌对PAH进行C-H / C-B偶联,得到其中PAH的C-H键以简单的方式直接芳基化的化合物。 当适当选择基材和硼化合物时,通过在偶联反应后进一步进行环化反应,也可以获得更大的PAH。 类似地,当使用特定芳族化合物,钯化合物和邻氯醌使PAH进行C-H / C-H交叉偶联时,其中PAH的C-H键直接芳基化的化合物可以是区域选择性的 以简单的方式生产。 当在这种情况下适当选择底物和芳香族化合物时,也可以通过进一步在交联反应后进行环丙烷化反应来获得更大的PAH。