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16 条记录 (耗时 0.016 秒)

    Solvent extraction
    2.
    发明授权
    Solvent extraction 失效
    溶剂萃取

    公开(公告)号：US4544532A

    公开(公告)日：1985-10-01

    申请号：US660592

    申请日：1984-10-15

    申请人： Gary A. Kordosky ,  R. Brantley Sudderth ,  J. Michael Sierakoski ,  Kenneth D. MacKay

    发明人： Gary A. Kordosky ,  R. Brantley Sudderth ,  J. Michael Sierakoski ,  Kenneth D. MacKay

    IPC分类号： C01G3/00 ,  C22B3/26 ,  C22B3/30

    CPC分类号： C22B3/0021 ,  C01G3/003 ,  C22B3/0017 ,  Y02P10/234 ,  Y10S423/14

    摘要： Reagents formulated by admixture of selected hydroxy aryl ketoxime and hydroxy aryl aldoxime extractants provide for efficient recovery of metal values, especially copper values, by solvent extraction processes. Specified kinetic and equilibrium conditions, which would require use of predetermined quantities of kinetic additives if ketoximes alone were employed or predetermined quantities of equilibrium modifiers if aldoximes were employed, are secured through formulation of reagents including both ketoxime and aldoxime extractants with less than the predetermined quantities of kinetic additive or equilibrium modifier. Reagents employed in methods of the invention may include from 0 to about 20 mole percent of a kinetic additive based on ketoxime content and also optionally a modifier of extraction and stripping equilibria in an amount providing a degree of modification of the aldoxime constituent of from about 0.75 to 1.0 and preferably from about 0.90 to 1.0.

    摘要翻译： 通过混合选择的羟基芳基酮肟和羟基芳基醛肟萃取剂配制的试剂通过溶剂萃取方法提供金属值，特别是铜值的有效回收。 规定的动力学和平衡条件，如果使用单一酮肟或需要使用预定量的平衡调节剂，则需要使用预定量的动力学添加剂，通过配制包括酮肟和醛肟萃取剂的试剂，其含量小于预定量 的动力学添加剂或平衡改性剂。 在本发明的方法中使用的试剂可以包括0至约20摩尔％的基于酮肟含量的动力学添加剂，并且还可以任选地提供提取和汽提平衡的改性剂，其量提供约0.75的醛肟组分的一定程度的改性 至1.0，优选约0.90至1.0。

    Solvent extraction
    3.
    发明授权
    Solvent extraction 失效
    溶剂萃取

    公开(公告)号：US4507268A

    公开(公告)日：1985-03-26

    申请号：US592828

    申请日：1984-03-23

    申请人： Gary A. Kordosky ,  Kenneth D. Mackay ,  R. Brantley Sudderth ,  Joseph M. Sierakoski

    发明人： Gary A. Kordosky ,  Kenneth D. Mackay ,  R. Brantley Sudderth ,  Joseph M. Sierakoski

    IPC分类号： C01G3/00 ,  C22B3/26 ,  C22B3/30

    CPC分类号： C01G3/003 ,  C22B3/0017 ,  C22B3/0021 ,  Y02P10/234 ,  Y10S423/14

    摘要： Reagents formulated by admixture of selected hydroxy aryl ketoxime and hydroxyl aryl aldoxime extractants provide for efficient recovery of metal values, especially copper values, by solvent extraction processes. Specified kinetic and equilibrium conditions, which would require use of predetermined quantities of kinetic additives if ketoximes alone were employed or predetermined quantities of equilibrium modifiers if aldoximes were employed, are secured through formulation of reagents including both ketoxime and aldoxime extractants with less than the predetermined quantities of kinetic additive or equilibrium modifier. Reagents employed in methods of the invention may include from 0 to about 20 mole percent of a kinetic additive based on ketoxime content and also optionally a modifier of extraction and stripping equilibria in an amount providing a degree of modification of the aldoxime constituent of from about 0.75 to 1.0 and preferably from about 0.90 to 1.0.

    摘要翻译： 通过混合选择的羟基芳基酮肟和羟基芳基醛肟提取物配制的试剂通过溶剂萃取方法提供有效的金属值，特别是铜值的回收。 规定的动力学和平衡条件，如果使用单一酮肟或需要使用预定量的平衡调节剂，则需要使用预定量的动力学添加剂，通过配制包括酮肟和醛肟萃取剂的试剂，其含量小于预定量 的动力学添加剂或平衡改性剂。 在本发明的方法中使用的试剂可以包括0至约20摩尔％的基于酮肟含量的动力学添加剂，并且还可以任选地提供提取和汽提平衡的改性剂，其量提供约0.75的醛肟组分的一定程度的改性 至1.0，优选约0.90至1.0。

    Extraction of amino an acid from aqueous mixtures thereof
    4.
    发明授权
    Extraction of amino an acid from aqueous mixtures thereof 失效
    从其水性混合物中提取氨基酸

    公开(公告)号：US4886888A

    公开(公告)日：1989-12-12

    申请号：US945735

    申请日：1986-12-22

    申请人： Francis W. Tuominen ,  Ronald R. Swanson ,  Phillip L. Mattison ,  Kenneth D. MacKay ,  Bradley W. Glorvigen

    发明人： Francis W. Tuominen ,  Ronald R. Swanson ,  Phillip L. Mattison ,  Kenneth D. MacKay ,  Bradley W. Glorvigen

    IPC分类号： C07D209/20

    CPC分类号： C07D209/20

    摘要： Amino acids can be purpified and/or concentrated by extracting aqueous mixtures such as fermentation broths by contacting an aqueous mixture containing amino acids with an organic solution containing a water insoluble extractant selected from the group consisting of:1. A quaternary ammonium ion having the formula: ##STR1## where R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are aliphatic, each having from 1 to 22 carbon atoms, and together have a minimum of 25 carbon atoms, and where at least three of the four R groups are at least a C.sub.4.2. A quaternary phosphonium ion having the formula: ##STR2## where R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are as defined above. 3. A tertiary sulfonium ion having the formula: ##STR3## where R.sub.1, R.sub.2 and R.sub.3 each are aliphatic with from 1 to 22 carbon atoms, and together have a minimum of 24 carbons and where at least two of these groups are at least a C.sub.6.4. An organic boride ion having the formula: ##STR4## where R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are as previously defined. 5. An organic sulfonic acid selected from the group consisting of:Organic sulfonic acids having the structural formula: ##STR5## where R.sub.5 and R.sub.6 are aliphatic hydrocarbon groups individually with from about 6 to about 22 carbon atoms, where R.sub.5 and R.sub.6 together contain at least 18 carbon atoms, and where neither R.sub.5 nor R.sub.6 are smaller than a C.sub.6 ; and organic sulfonic acids having the structural formula; ##STR6## where R.sub.7 and R.sub.8 are aliphatic hydrocabon groups containing from about 4 to about 22 carbon atoms, where R.sub.7, R.sub.8, or the sulfonic group may be attached to positions 1-8 on the aromatic rings, and where neither R.sub.7 nor R.sub.8 is smaller than a C.sub.4, and where R.sub.7 and R.sub.8 together have at least 18 carbon atoms.

    摘要翻译： 通过将含有氨基酸的水性混合物与含有水不溶性萃取剂的有机溶液接触，通过萃取含水混合物如发酵液可以纯化和/或浓缩氨基酸。1.一种季铵离子，其具有式 ：其中R 1，R 2，R 3和R 4是脂族的，每个具有1至22个碳原子，并且一起具有最少25个碳原子，并且其中四个R基团中的至少三个至少为C4。 2.具有下式的季鏻离子：其中R 1，R 2，R 3和R 4如上所定义。 3.具有下式的叔锍离子：其中R 1，R 2和R 3各自为具有1至22个碳原子的脂族基，并且一起具有最少24个碳，并且其中至少两个这些基团至少为 C6。 4.具有下式的有机硼化物离子：其中R 1，R 2，R 3和R 4如前所定义。 5.选自以下的有机磺酸：具有以下结构式的有机磺酸：其中R 5和R 6是具有约6至约22个碳原子的脂族烃基，其中R 5和R 6一起含在 至少18个碳原子，其中R5和R6都不小于C6; 和具有结构式的有机磺酸; 其中R 7和R 8是含有约4至约22个碳原子的脂族烃基，其中R 7，R 8或磺酸基可以连接到芳环上的1-8位，并且其中R 7和R 8都不在 小于C4，并且其中R7和R8一起具有至少18个碳原子。

    Sulfonamidophenols, metal complexes thereof, and solutions containing such compounds for use in extraction of metal values
    9.
    发明授权
    Sulfonamidophenols, metal complexes thereof, and solutions containing such compounds for use in extraction of metal values 失效
    磺酰胺苯酚，其金属络合物，以及含有用于提取金属价值的化合物的溶液

    公开(公告)号：US4239699A

    公开(公告)日：1980-12-16

    申请号：US909224

    申请日：1978-05-24

    申请人： Kenneth D. MacKay

    发明人： Kenneth D. MacKay

    IPC分类号： C01G3/00 ,  C01G9/00 ,  C01G53/00 ,  C22B3/34 ,  C07C143/78 ,  B01D11/04 ,  C07C143/79

    CPC分类号： C01G9/003 ,  C01G3/003 ,  C01G53/003 ,  C22B3/0031 ,  Y02P10/234

    摘要： Certain sulfonamidophenols, metal complexes thereof and solutions of said compounds in essentially water-immiscible, liquid hydrocarbon solvents are disclosed. The sulfonamidophenols have the structural formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are as defined in the specification and claims hereof. Particular metal values are recovered from their aqueous solutions by using sulfonamidophenols dissolved in essentially water-immiscible liquid hydrocarbon solvents. The extraction process involves contacting the metal value containing aqueous solution with the solution of sulfonamidophenol in essentially water-immiscible liquid hydrocarbon solvent and stripping the metal values from the loaded organic phase.

    摘要翻译： 公开了某些磺酰胺苯酚，其金属络合物和所述化合物在基本上与水不混溶的液体烃溶剂中的溶液。 磺酰胺苯酚具有结构式：其中R 1，R 2，R 3和R 4如本说明书和权利要求书中所定义。 通过使用溶解在基本上与水不混溶的液体烃溶剂中的磺酰胺酚从其水溶液中回收特定的金属值。 提取过程包括使含金属含量的水溶液与基本上与水不混溶的液体烃溶剂中的磺酰胺基苯溶液接触并从负载的有机相中汽提金属值。

    .beta.-Diketones and the use thereof as metal extractants
    10.
    发明授权
    .beta.-Diketones and the use thereof as metal extractants 失效
    β-二酮及其作为金属萃取剂的用途

    公开(公告)号：US4175012A

    公开(公告)日：1979-11-20

    申请号：US641195

    申请日：1975-12-15

    申请人： Kenneth D. MacKay ,  Edgar R. Rogier

    发明人： Kenneth D. MacKay ,  Edgar R. Rogier

    IPC分类号： C07C49/92 ,  C22B3/26 ,  C25C1/12 ,  C01B3/00

    CPC分类号： C07C255/00 ,  C07C49/92 ,  C22B3/0021 ,  Y02P10/234

    摘要： New .beta.-diketones of the structure ##STR1## where R is phenyl or alkyl substituted phenyl, R' is alkyl, alkyl substituted phenyl or chloro substituted phenyl and R" is H or --CN with the provisos that; (1) when R is phenyl, R' is a branched chain alkyl group of at least seven carbon atoms and (2) when R is alkyl substituted phenyl, the number of carbon atoms in the alkyl substituent or substituents is at least 7 and at least one such alkyl substituent is branched chain. Process of recovering copper and nickel from their aqueous solutions by the use of the new .beta.-diketones.

    摘要翻译： 其中R是苯基或烷基取代的苯基，R'是烷基，烷基取代的苯基或氯取代的苯基，R“是H或-CN的结构的新的β-二酮，条件是： （1）R为苯基时，R'为至少7个碳原子的支链烷基，（2）当R为烷基取代苯基时，烷基取代基或碳原子数为7以上， 至少一个这样的烷基取代基是支链的。 通过使用新的β-二酮从其水溶液中回收铜和镍的工艺。