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公开(公告)号：US07615671B2
公开(公告)日：2009-11-10
申请号：US12274787
申请日：2008-11-20
IPC分类号： C07C29/149 , C07C29/141 , C07C29/145
CPC分类号： C07C29/149 , C07C31/207 , C07C31/202 , C07C31/205
摘要： Disclosed is a process for the preparation of 1,2-glycols by hydrogenation of 1,2-dioxygenated organic compounds in the presence of a catalyst composition comprising a ruthenium compound, a trivalent phosphorus compound selected from 1,1,1-tris(diarylphosphinomethyl)alkyl or substituted alkyl, and a promoter selected from Lewis acids, protic acids having an ionization constant (Ki) of 5×10−3 or greater, and onium salts. The process is useful for the hydrogenation of glycolic acid or derivatives thereof to ethylene glycol.
摘要翻译： 公开了在催化剂组合物存在下1,2-二氧化有机化合物的氢化制备1,2-二醇的方法，该催化剂组合物包含钌化合物，三价磷化合物，其选自1,1,1-三（二芳基膦基甲基 ）烷基或取代的烷基，以及选自路易斯酸，电离常数（Ki）为5×10 -3或更大的质子酸和鎓盐的促进剂。 该方法可用于将乙醇酸或其衍生物氢化成乙二醇。
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公开(公告)号：US20120046500A1
公开(公告)日：2012-02-23
申请号：US12889065
申请日：2010-09-23
IPC分类号： C07C29/147
CPC分类号： B01J31/2404 , B01J31/24 , B01J31/2409 , B01J31/4053 , B01J2531/0238 , B01J2531/821 , C07C29/149 , C07C29/86 , Y02P20/52 , Y02P20/582 , Y02P20/584 , C07C31/202
摘要： Disclosed is a process for the extractive recovery of a homogeneous ruthenium catalyst from the reaction product of the hydrogenation of glycolic acid, glycolate esters, and/or glycolic acid oligomers with an extractant comprising a hydrophobic solvent and an optional hydrophilic solvent. The ruthenium catalyst, which can include 1,1,1-tris(diaryl- or dialkylphosphinomethyl)alkane ligands, can be recovered from the hydrophobic extract phase by back extraction with a hydrophilic solvent and recycled to a process for the preparation of ethylene glycol by the hydrogenation of glycolic acid and glycolic acid derivatives.
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公开(公告)号：US20120046481A1
公开(公告)日：2012-02-23
申请号：US13208399
申请日：2011-08-12
申请人： Scott Donald Barnicki , Jeffrey Scott Kanel , Kenneth Wayne Hampton, JR. , Eduardo Gallas Cervo
发明人： Scott Donald Barnicki , Jeffrey Scott Kanel , Kenneth Wayne Hampton, JR. , Eduardo Gallas Cervo
IPC分类号： C07F19/00
CPC分类号： B01J31/24 , B01J31/2409 , B01J31/4053 , B01J2531/0238 , B01J2531/821 , C07C29/149 , C07C29/86 , Y02P20/52 , Y02P20/582 , Y02P20/584 , C07C31/202
摘要： Disclosed is a process for the extractive recovery of a homogeneous ruthenium catalyst from the reaction product of the hydrogenation of glycolic acid, glycolate esters, and/or glycolic acid oligomers with an extractant comprising a hydrophobic solvent and an optional hydrophilic solvent. The ruthenium catalyst, which can include 1,1,1-tris(diaryl- or dialkylphosphinomethyl)alkane ligands, can be recovered from the hydrophobic extract phase by back extraction with a hydrophilic solvent and recycled to a process for the preparation of ethylene glycol by the hydrogenation of glycolic acid and glycolic acid derivatives.
摘要翻译： 公开了从乙醇酸，乙醇酸酯和/或乙醇酸低聚物的氢化与包含疏水性溶剂和任选的亲水性溶剂的萃取剂的反应产物中提取回收均相钌催化剂的方法。 可以通过用亲水溶剂反萃取从疏水萃取相中回收可以包括1,1,1-三（二芳基 - 或二烷基膦基甲基）烷烃配体的钌催化剂，并循环到制备乙二醇的方法中 乙醇酸和乙醇酸衍生物的氢化。
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公开(公告)号：US08466328B2
公开(公告)日：2013-06-18
申请号：US12889065
申请日：2010-09-23
IPC分类号： C07C27/04
CPC分类号： B01J31/2404 , B01J31/24 , B01J31/2409 , B01J31/4053 , B01J2531/0238 , B01J2531/821 , C07C29/149 , C07C29/86 , Y02P20/52 , Y02P20/582 , Y02P20/584 , C07C31/202
摘要： Disclosed is a process for the extractive recovery of a homogeneous ruthenium catalyst from the reaction product of the hydrogenation of glycolic acid, glycolate esters, and/or glycolic acid oligomers with an extractant comprising a hydrophobic solvent and an optional hydrophilic solvent. The ruthenium catalyst, which can include 1,1,1-tris(diaryl- or dialkylphosphinomethyl)alkane ligands, can be recovered from the hydrophobic extract phase by back extraction with a hydrophilic solvent and recycled to a process for the preparation of ethylene glycol by the hydrogenation of glycolic acid and glycolic acid derivatives.
摘要翻译： 公开了从乙醇酸，乙醇酸酯和/或乙醇酸低聚物的氢化与包含疏水性溶剂和任选的亲水性溶剂的萃取剂的反应产物中提取回收均相钌催化剂的方法。 可以通过用亲水性溶剂反萃取从疏水萃取相中回收可包括1,1,1-三（二芳基 - 或二烷基膦基甲基）烷烃配体的钌催化剂，并循环至制备乙二醇的方法 乙醇酸和乙醇酸衍生物的氢化。
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公开(公告)号：US20090143612A1
公开(公告)日：2009-06-04
申请号：US12274787
申请日：2008-11-20
IPC分类号： C07C69/003 , C07C53/08 , C07C27/04
CPC分类号： C07C29/149 , C07C31/207 , C07C31/202 , C07C31/205
摘要： Disclosed is a process for the preparation of 1,2-glycols by hydrogenation of 1,2-dioxygenated organic compounds in the presence of a catalyst composition comprising a ruthenium compound, a trivalent phosphorus compound selected from 1,1,1-tris(diarylphosphinomethyl)alkyl or substituted alkyl, and a promoter selected from Lewis acids, protic acids having an ionization constant (Ki) of 5×10−3 or greater, and onium salts. The process is useful for the hydrogenation of glycolic acid or derivatives thereof to ethylene glycol.
摘要翻译： 公开了在催化剂组合物存在下1,2-二氧化有机化合物的氢化制备1,2-二醇的方法，该催化剂组合物包含钌化合物，三价磷化合物，其选自1,1,1-三（二芳基膦基甲基 ）烷基或取代的烷基，以及选自路易斯酸，电离常数（Ki）为5×10 -3或更大的质子酸和鎓盐的促进剂。 该方法可用于将乙醇酸或其衍生物氢化成乙二醇。
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公开(公告)号：US08829248B2
公开(公告)日：2014-09-09
申请号：US13208399
申请日：2011-08-12
申请人： Scott Donald Barnicki , Jeffrey Scott Kanel , Kenneth Wayne Hampton, Jr. , Eduardo Gallas Cervo
发明人： Scott Donald Barnicki , Jeffrey Scott Kanel , Kenneth Wayne Hampton, Jr. , Eduardo Gallas Cervo
IPC分类号： C07C29/149 , C07C29/80 , B01J31/40 , C07C29/86 , B01J31/24
CPC分类号： B01J31/24 , B01J31/2409 , B01J31/4053 , B01J2531/0238 , B01J2531/821 , C07C29/149 , C07C29/86 , Y02P20/52 , Y02P20/582 , Y02P20/584 , C07C31/202
摘要： Disclosed is a process for the extractive recovery of a homogeneous ruthenium catalyst from the reaction product of the hydrogenation of glycolic acid, glycolate esters, and/or glycolic acid oligomers with an extractant comprising a hydrophobic solvent and an optional hydrophilic solvent. The ruthenium catalyst, which can include 1,1,1-tris(diaryl- or dialkylphosphinomethyl)alkane ligands, can be recovered from the hydrophobic extract phase by back extraction with a hydrophilic solvent and recycled to a process for the preparation of ethylene glycol by the hydrogenation of glycolic acid and glycolic acid derivatives.
摘要翻译： 公开了从乙醇酸，乙醇酸酯和/或乙醇酸低聚物的氢化与包含疏水性溶剂和任选的亲水性溶剂的萃取剂的反应产物中提取回收均相钌催化剂的方法。 可以通过用亲水性溶剂反萃取从疏水萃取相中回收可包括1,1,1-三（二芳基 - 或二烷基膦基甲基）烷烃配体的钌催化剂，并循环至制备乙二醇的方法 乙醇酸和乙醇酸衍生物的氢化。
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