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公开(公告)号：US08829248B2
公开(公告)日：2014-09-09
申请号：US13208399
申请日：2011-08-12
申请人： Scott Donald Barnicki , Jeffrey Scott Kanel , Kenneth Wayne Hampton, Jr. , Eduardo Gallas Cervo
发明人： Scott Donald Barnicki , Jeffrey Scott Kanel , Kenneth Wayne Hampton, Jr. , Eduardo Gallas Cervo
IPC分类号： C07C29/149 , C07C29/80 , B01J31/40 , C07C29/86 , B01J31/24
CPC分类号： B01J31/24 , B01J31/2409 , B01J31/4053 , B01J2531/0238 , B01J2531/821 , C07C29/149 , C07C29/86 , Y02P20/52 , Y02P20/582 , Y02P20/584 , C07C31/202
摘要： Disclosed is a process for the extractive recovery of a homogeneous ruthenium catalyst from the reaction product of the hydrogenation of glycolic acid, glycolate esters, and/or glycolic acid oligomers with an extractant comprising a hydrophobic solvent and an optional hydrophilic solvent. The ruthenium catalyst, which can include 1,1,1-tris(diaryl- or dialkylphosphinomethyl)alkane ligands, can be recovered from the hydrophobic extract phase by back extraction with a hydrophilic solvent and recycled to a process for the preparation of ethylene glycol by the hydrogenation of glycolic acid and glycolic acid derivatives.
摘要翻译： 公开了从乙醇酸，乙醇酸酯和/或乙醇酸低聚物的氢化与包含疏水性溶剂和任选的亲水性溶剂的萃取剂的反应产物中提取回收均相钌催化剂的方法。 可以通过用亲水性溶剂反萃取从疏水萃取相中回收可包括1,1,1-三（二芳基 - 或二烷基膦基甲基）烷烃配体的钌催化剂，并循环至制备乙二醇的方法 乙醇酸和乙醇酸衍生物的氢化。
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公开(公告)号：US20120046481A1
公开(公告)日：2012-02-23
申请号：US13208399
申请日：2011-08-12
申请人： Scott Donald Barnicki , Jeffrey Scott Kanel , Kenneth Wayne Hampton, JR. , Eduardo Gallas Cervo
发明人： Scott Donald Barnicki , Jeffrey Scott Kanel , Kenneth Wayne Hampton, JR. , Eduardo Gallas Cervo
IPC分类号： C07F19/00
CPC分类号： B01J31/24 , B01J31/2409 , B01J31/4053 , B01J2531/0238 , B01J2531/821 , C07C29/149 , C07C29/86 , Y02P20/52 , Y02P20/582 , Y02P20/584 , C07C31/202
摘要： Disclosed is a process for the extractive recovery of a homogeneous ruthenium catalyst from the reaction product of the hydrogenation of glycolic acid, glycolate esters, and/or glycolic acid oligomers with an extractant comprising a hydrophobic solvent and an optional hydrophilic solvent. The ruthenium catalyst, which can include 1,1,1-tris(diaryl- or dialkylphosphinomethyl)alkane ligands, can be recovered from the hydrophobic extract phase by back extraction with a hydrophilic solvent and recycled to a process for the preparation of ethylene glycol by the hydrogenation of glycolic acid and glycolic acid derivatives.
摘要翻译： 公开了从乙醇酸，乙醇酸酯和/或乙醇酸低聚物的氢化与包含疏水性溶剂和任选的亲水性溶剂的萃取剂的反应产物中提取回收均相钌催化剂的方法。 可以通过用亲水溶剂反萃取从疏水萃取相中回收可以包括1,1,1-三（二芳基 - 或二烷基膦基甲基）烷烃配体的钌催化剂，并循环到制备乙二醇的方法中 乙醇酸和乙醇酸衍生物的氢化。
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公开(公告)号：US20120046500A1
公开(公告)日：2012-02-23
申请号：US12889065
申请日：2010-09-23
IPC分类号： C07C29/147
CPC分类号： B01J31/2404 , B01J31/24 , B01J31/2409 , B01J31/4053 , B01J2531/0238 , B01J2531/821 , C07C29/149 , C07C29/86 , Y02P20/52 , Y02P20/582 , Y02P20/584 , C07C31/202
摘要： Disclosed is a process for the extractive recovery of a homogeneous ruthenium catalyst from the reaction product of the hydrogenation of glycolic acid, glycolate esters, and/or glycolic acid oligomers with an extractant comprising a hydrophobic solvent and an optional hydrophilic solvent. The ruthenium catalyst, which can include 1,1,1-tris(diaryl- or dialkylphosphinomethyl)alkane ligands, can be recovered from the hydrophobic extract phase by back extraction with a hydrophilic solvent and recycled to a process for the preparation of ethylene glycol by the hydrogenation of glycolic acid and glycolic acid derivatives.
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公开(公告)号：US08466328B2
公开(公告)日：2013-06-18
申请号：US12889065
申请日：2010-09-23
IPC分类号： C07C27/04
CPC分类号： B01J31/2404 , B01J31/24 , B01J31/2409 , B01J31/4053 , B01J2531/0238 , B01J2531/821 , C07C29/149 , C07C29/86 , Y02P20/52 , Y02P20/582 , Y02P20/584 , C07C31/202
摘要： Disclosed is a process for the extractive recovery of a homogeneous ruthenium catalyst from the reaction product of the hydrogenation of glycolic acid, glycolate esters, and/or glycolic acid oligomers with an extractant comprising a hydrophobic solvent and an optional hydrophilic solvent. The ruthenium catalyst, which can include 1,1,1-tris(diaryl- or dialkylphosphinomethyl)alkane ligands, can be recovered from the hydrophobic extract phase by back extraction with a hydrophilic solvent and recycled to a process for the preparation of ethylene glycol by the hydrogenation of glycolic acid and glycolic acid derivatives.
摘要翻译： 公开了从乙醇酸，乙醇酸酯和/或乙醇酸低聚物的氢化与包含疏水性溶剂和任选的亲水性溶剂的萃取剂的反应产物中提取回收均相钌催化剂的方法。 可以通过用亲水性溶剂反萃取从疏水萃取相中回收可包括1,1,1-三（二芳基 - 或二烷基膦基甲基）烷烃配体的钌催化剂，并循环至制备乙二醇的方法 乙醇酸和乙醇酸衍生物的氢化。
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公开(公告)号：US08785686B2
公开(公告)日：2014-07-22
申请号：US13431335
申请日：2012-03-27
申请人： Scott Donald Barnicki , Stephen Neal Falling , Jeffrey Scott Kanel , Robert Sterling Kline , Peter Borden Mackenzie , Andrew James Vetter
发明人： Scott Donald Barnicki , Stephen Neal Falling , Jeffrey Scott Kanel , Robert Sterling Kline , Peter Borden Mackenzie , Andrew James Vetter
CPC分类号： B01D11/0492 , B01J31/0225 , B01J31/0227 , B01J31/40 , B01J2231/321 , C07C51/12 , C07C51/48 , Y02P20/584 , C07C59/06
摘要： Disclosed is a process for the extractive recovery of an acid catalyst from an aqueous mixture of glycolic acid with an extraction solvent comprising a tertiary amine or an onium carboxylate compound, a modifier, and a diluent. The acid catalyst, which can comprise strong acids such as sulfuric acid, alkyl sulfonic acids, and fluoroalkyl sulfonic acids, can be recovered by back extraction with aqueous formaldehyde and recycled to a process for the preparation of glycolic acid by the acid-catalyzed carbonylation of formaldehyde. Also disclosed is a process for the preparation of glycolic acid by the acid-catalyzed hydrocarboxylation of formaldehyde.
摘要翻译： 公开了一种从乙醇酸的水性混合物与包含叔胺或羧酸铝化合物，改性剂和稀释剂的萃取溶剂萃取回收酸催化剂的方法。 可以包含强酸如硫酸，烷基磺酸和氟代烷基磺酸的酸催化剂可以通过用甲醛水溶液反萃取回收，并循环至通过酸催化的羰基化反应制备乙醇酸的方法 甲醛。 还公开了通过酸催化的甲醛加氢制备乙醇酸的方法。
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公开(公告)号：US20120215027A1
公开(公告)日：2012-08-23
申请号：US13431335
申请日：2012-03-27
申请人： Scott Donald Barnicki , Stephen Neal Falling , Jeffrey Scott Kanel , Robert Sterling Kline , Peter Borden Mackenzie , Andrew James Vetter
发明人： Scott Donald Barnicki , Stephen Neal Falling , Jeffrey Scott Kanel , Robert Sterling Kline , Peter Borden Mackenzie , Andrew James Vetter
IPC分类号： C07C51/12
CPC分类号： B01D11/0492 , B01J31/0225 , B01J31/0227 , B01J31/40 , B01J2231/321 , C07C51/12 , C07C51/48 , Y02P20/584 , C07C59/06
摘要： Disclosed is a process for the extractive recovery of an acid catalyst from an aqueous mixture of glycolic acid with an extraction solvent comprising a tertiary amine or an onium carboxylate compound, a modifier, and a diluent. The acid catalyst, which can comprise strong acids such as sulfuric acid, alkyl sulfonic acids, and fluoroalkyl sulfonic acids, can be recovered by back extraction with aqueous formaldehyde and recycled to a process for the preparation of glycolic acid by the acid-catalyzed carbonylation of formaldehyde. Also disclosed is a process for the preparation of glycolic acid by the acid-catalyzed hydrocarboxylation of formaldehyde.
摘要翻译： 公开了一种从乙醇酸的水性混合物与包含叔胺或羧酸铝化合物，改性剂和稀释剂的萃取溶剂萃取回收酸催化剂的方法。 可以包含强酸如硫酸，烷基磺酸和氟代烷基磺酸的酸催化剂可以通过用甲醛水溶液反萃取回收，并循环至通过酸催化的羰基化反应制备乙醇酸的方法 甲醛。 还公开了通过酸催化的甲醛加氢制备乙醇酸的方法。
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公开(公告)号：US08709376B2
公开(公告)日：2014-04-29
申请号：US12889045
申请日：2010-09-23
申请人： Scott Donald Barnicki , Stephen Neal Falling , Jeffrey Scott Kanel , Robert Sterling Kline , Peter Borden Mackenzie
发明人： Scott Donald Barnicki , Stephen Neal Falling , Jeffrey Scott Kanel , Robert Sterling Kline , Peter Borden Mackenzie
IPC分类号： C01B17/90 , C07C309/30 , C07C59/06 , C07C51/42
CPC分类号： B01D11/0492 , B01J31/0225 , B01J31/0227 , B01J31/4092 , C07C51/48 , C07C303/44 , C07C315/06 , Y02P20/584 , C07C59/06 , C07C309/06 , C07C309/05 , C07C317/04
摘要： Disclosed is a process for the extractive recovery of an acid catalyst from an aqueous mixture of glycolic acid with an extraction solvent comprising a tertiary amine or an onium carboxylate compound, a modifier, and a diluent. The acid catalyst, which can comprise strong acids such as sulfuric acid, alkyl sulfonic acids, and fluoroalkyl sulfonic acids, can be recovered by back extraction with aqueous formaldehyde and recycled to a process for the preparation of glycolic acid by the acid-catalyzed carbonylation of formaldehyde.
摘要翻译： 公开了一种从乙醇酸的水性混合物与包含叔胺或羧酸铝化合物，改性剂和稀释剂的萃取溶剂萃取回收酸催化剂的方法。 可以包含强酸如硫酸，烷基磺酸和氟代烷基磺酸的酸催化剂可以通过用甲醛水溶液反萃取回收，并循环至通过酸催化的羰基化反应制备乙醇酸的方法 甲醛。
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公开(公告)号：US20120078010A1
公开(公告)日：2012-03-29
申请号：US12889045
申请日：2010-09-23
申请人： Scott Donald Barnicki , Stephen Neal Falling , Jeffrey Scott Kanel , Robert Sterling Kline , Peter Borden Mackenzie
发明人： Scott Donald Barnicki , Stephen Neal Falling , Jeffrey Scott Kanel , Robert Sterling Kline , Peter Borden Mackenzie
IPC分类号： C07C51/10
CPC分类号： B01D11/0492 , B01J31/0225 , B01J31/0227 , B01J31/4092 , C07C51/48 , C07C303/44 , C07C315/06 , Y02P20/584 , C07C59/06 , C07C309/06 , C07C309/05 , C07C317/04
摘要： Disclosed is a process for the extractive recovery of an acid catalyst from an aqueous mixture of glycolic acid with an extraction solvent comprising a tertiary amine or an onium carboxylate compound, a modifier, and a diluent. The acid catalyst, which can comprise strong acids such as sulfuric acid, alkyl sulfonic acids, and fluoroalkyl sulfonic acids, can be recovered by back extraction with aqueous formaldehyde and recycled to a process for the preparation of glycolic acid by the acid-catalyzed carbonylation of formaldehyde.
摘要翻译： 公开了一种从乙醇酸的水性混合物与包含叔胺或羧酸铝化合物，改性剂和稀释剂的萃取溶剂萃取回收酸催化剂的方法。 可以包含强酸如硫酸，烷基磺酸和氟代烷基磺酸的酸催化剂可以通过用甲醛水溶液反萃取回收，并循环至通过酸催化的羰基化反应制备乙醇酸的方法 甲醛。
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9.发明申请公开(公告)号：US20130310608A1
公开(公告)日：2013-11-21
申请号：US13474837
申请日：2012-05-18
摘要： Disclosed is a process for reducing the emission of volatile organic compounds that are produced during the ketonization of carboxylic acids to ketones. The ketonization of carboxylic acids produces a gaseous by-product stream containing carbon dioxide and volatile organic compounds. This gaseous by-product stream can be fed to a direct-fired furnace used to heat the ketonization reaction feed streams where the volatile organic compounds are destroyed by combustion in the furnace. The carbon dioxide stream further acts as a diluent for the fuel to the furnace.
摘要翻译： 公开了一种减少在将羧酸酮化成酮时产生的挥发性有机化合物的排放的方法。 羧酸的酮化产生含有二氧化碳和挥发性有机化合物的气态副产物流。 这种气态副产物流可以进料到用于加热酮化反应进料流的直接燃烧炉，其中挥发性有机化合物通过在炉中燃烧而被破坏。 二氧化碳流还充当用于燃料的炉的稀释剂。
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10.发明申请HYDROCARBOXYLATION OF METHYLENE DIPROPIONATE IN THE PRESENCE OF A PROPIONIC ACID AND A HOMOGENEOUS CATALYST 有权丙酸与均相催化剂存在下亚甲基二苯甲酸的烷基化反应公开(公告)号：US20130261329A1
公开(公告)日：2013-10-03
申请号：US13431402
申请日：2012-03-27
IPC分类号： C07C67/36 , C07C29/149 , C07C51/12
CPC分类号： C07C51/12 , C07C29/149 , C07C51/09 , C07C67/08 , C07C67/36 , C07C59/06 , C07C69/24 , C07C69/675 , C07C31/202
摘要： Disclosed is a process for the production and purification of glycolic acid or glycolic acid derivatives by the carbonylation of methylene dipropionate in the presence of a homogeneous acid catalyst and propionic acid. This invention discloses hydrocarboxylations and corresponding homogeneous acid catalyst and glycolic acid separations. The homogeneous acid catalyst is readily separated from the hydrocarboxylation reaction effluent and recycled and the propionic acid is readily removed from the glycolic acid and the propionic acid is recycled
摘要翻译： 公开了一种在均相酸催化剂和丙酸存在下通过二丙酸亚甲酯的羰基化生产和纯化乙醇酸或乙醇酸衍生物的方法。 本发明公开了加氢羧化和相应的均相酸催化剂和乙醇酸分离。 均相酸催化剂容易从加氢羧化反应流出物中分离并再循环，丙酸容易从乙醇酸中除去，丙酸被再循环
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