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1.发明授权Production of poly(arylene sulfide sulfone) with excess water to alkali metal sulfide 失效生产具有超级水的聚（亚磺酸硫磺酸盐）至碱性金属硫化物
公开(公告)号：US5093467A
公开(公告)日：1992-03-03
申请号：US369962
申请日：1989-06-22
申请人： Takehiko Sakane , Toshikazu Kato , Kensuke Ogawara
发明人： Takehiko Sakane , Toshikazu Kato , Kensuke Ogawara
CPC分类号： C08G75/20 , C08G75/0236 , C08G75/0254
摘要： An improved process for producing poly(arylene sulfide sulfone) of increased molecular weight is provided. The process employs an Li salt of C.sub.1 -C.sub.20 carboxylic acid as a polymerization auxiliary and is carried out in an organic amide solvent by reacting a dihalogenated aromatic sulfone with an alkali metal sulfide in the presence of 10-15 moles of water per mole of the alkali metal sulfide at temperatures within the range of from 160.degree. C. to 230.degree. C.
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公开(公告)号：US5258442A
公开(公告)日：1993-11-02
申请号：US943160
申请日：1992-09-10
申请人： Toshikazu Kato , Yasuhisa Ogita , Kensuke Ogawara
发明人： Toshikazu Kato , Yasuhisa Ogita , Kensuke Ogawara
摘要： There is disclosed a polyphenylene sulfide resin composition which comprises: (a) 100 parts by weight of a polyphenylene sulfide resin; and (b) from about 0.1 to about 10 parts by weight of finely divided calcium carbonate having a mean particle size of less than about 0.5 .mu.m and a BET surface area of greater than about 15 m.sup.2 /g. The resin composition is improved in that it exhibits no or little corrosive action on metals and that it shows excellent mechanical strength.
摘要翻译： 公开了一种聚苯硫醚树脂组合物，其包含：（a）100重量份的聚苯硫醚树脂; 和（b）约0.1至约10重量份的平均粒度小于约0.5μm的细碎碳酸钙和大于约15m 2 / g的BET表面积。 树脂组合物的改进在于其对金属没有或几乎没有腐蚀作用，并且其表现出优异的机械强度。
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公开(公告)号：US5097003A
公开(公告)日：1992-03-17
申请号：US363573
申请日：1989-06-07
申请人： Satoshi Tomagou , Toshikazu Kato , Kensuke Ogawara
发明人： Satoshi Tomagou , Toshikazu Kato , Kensuke Ogawara
IPC分类号： C08G75/02
CPC分类号： C08G75/024 , C08G75/0254 , C08G75/0295
摘要： A process for producing a polyphenylene sulfide ketone polymer comprising reacting a dihalogen compound of the general formula ##STR1## wherein X and X', which may be the same or different, each represents a fluorine, chlorine, bromine or iodine atom, with an alkali metal sulfide in a polar solvent in such a way that the alkali metal sulfide is not deprived of free water or the water of hydration in the polar solvent before polymerization is started, and that the reaction is performed at a temperature in the range of from 80.degree. to 170.degree. C. in the initial period of polymerization until the percentage of residual unreacted dihalogen compound is reduced to 2% or below, with the subsequent reaction being performed at a temperature in the range of from 200.degree. to 345.degree. C.
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公开(公告)号：US4895959A
公开(公告)日：1990-01-23
申请号：US363692
申请日：1989-06-09
申请人： Toshikazu Kato , Hiroshi Inoue , Kensuke Ogawara
发明人： Toshikazu Kato , Hiroshi Inoue , Kensuke Ogawara
IPC分类号： C07D207/26 , C07D207/267
CPC分类号： C07D207/267
摘要： A method for purifying N-methyl-2-pyrrolidone containing thiophenol and/or diphenyl disulfide is disclosed, comprising adding a polyhalogenated aromatic compound and an alkali metal hydroxide and/or an alkali metal carbonate to the N-methyl-2-pyrrolidone containing thiophenol and/or diphenyl disulfide, heat treating the mixture, and subjecting the mixture to separation by distillation. The thiophenol and/or diphenyl disulfide can be removed with ease and at low cost.
摘要翻译： 公开了一种用于纯化含有苯硫酚和/或二苯基二硫化物的N-甲基-2-吡咯烷酮的方法，包括向含有N-甲基-2-吡咯烷酮的苯硫酚中加入多卤代芳族化合物和碱金属氢氧化物和/或碱金属碳酸盐 和/或二苯基二硫醚，热处理混合物，并通过蒸馏使混合物分离。 苯硫酚和/或二苯基二硫化物可以容易且以低成本除去。
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公开(公告)号：US5032672A
公开(公告)日：1991-07-16
申请号：US361201
申请日：1989-06-05
申请人： Toshikazu Kato , Hiroshi Inoue , Kensuke Ogawara
发明人： Toshikazu Kato , Hiroshi Inoue , Kensuke Ogawara
IPC分类号： C08G75/02
CPC分类号： C08G75/025
摘要： An improved process for preparing poly(phenylene sulfide) is provided. In the process, an additional amount of solvent is introduced into the reaction mixture, when a conversion of at least 80% of dihalobenzene, one of the reactants, has been achieved. By the measure, heavy scaling which has been experienced with the conventional processes is effectively inhibited.
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公开(公告)号：US4981947A
公开(公告)日：1991-01-01
申请号：US288342
申请日：1988-12-22
CPC分类号： C08G75/0254 , C08G69/42 , C08G75/0236
摘要： A class of amide group-containing aromatic dihalide compounds are sulfidized to provide a novel class of aromatic sulfideamide polymers increased in crystalline melting point (T.sub.m). The polymers exhibit excellent resistance to high temperatures, resistance to solvents, flame-retardant properties and improved mechanical properties.
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公开(公告)号：US5151495A
公开(公告)日：1992-09-29
申请号：US609141
申请日：1990-11-05
申请人： Hiroshi Inoue , Toshikazu Kato , Kensuke Ogawara
发明人： Hiroshi Inoue , Toshikazu Kato , Kensuke Ogawara
CPC分类号： C08G75/0254
摘要： In a process for producing poly (p-phenylenesulfide) from an alkali metal sulfide and a p-dihalobenzene, a product polymer of an advantageously increased molecular weight is obtained by: providing a mixture comprising an alkali metal sulfide, a polar aprotic solvent, a sodium salt of an aliphatic carboxylic acid represented by the general formula: RCOONa (where R is an aliphatic hydrocarbon group having 1-20 carbon atoms), the content of water present in said mixture apart from any water of hydration or crystallization which may be contained in said sulfide and sodium salt being in the range of 5 to 20 moles per mole of said sulfide; thermally dehydrating said sulfide component in said mixture by removing at least part of the water from said mixture; and then contacting the resulting dehydrated mixture with a p-dihalobenzene.
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公开(公告)号：US5037953A
公开(公告)日：1991-08-06
申请号：US611382
申请日：1990-11-13
申请人： Hiroshi Inoue , Toshikazu Kato , Kensuke Ogawara
发明人： Hiroshi Inoue , Toshikazu Kato , Kensuke Ogawara
IPC分类号： C08G75/02
CPC分类号： C08G75/0254
摘要： In a process for producing poly (p-phenylenesulfide) from an alkali metal sulfide and a p-dihalobenzene, a product polymer of an advantageously increased molecular weight is obtained by: providing a mixture comprising an alkali metal sulfide, a polar aprotic solvent and a carboxylic acid sodium salt represented by the general formula: ZCOONa (wherein Z is a C.sub.6 -C.sub.20 aromatic hydrocarbon group or a substituted or unsubstituted pyridyl group ##STR1## where substituents R, which may be the same or different, represent each a C.sub.1 -C.sub.20 organic radical and n is an integer of from 0 to 4), the content of water present in said mixture apart from any water of hydration or crystallization which may be contained in said alkali metal sulfide and carboxylic acid sodium salt being at least 5 moles per mole of said alkali metal sulfide present; thermally dehydrating said alkali metal sulfide in said mixture by removing at least part of the water from said mixture; and then contacting the resulting dehydrated mixture with a p-dihalobenzene so as to produce the intended polymer.
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公开(公告)号：US4958003A
公开(公告)日：1990-09-18
申请号：US288881
申请日：1988-12-23
CPC分类号： C08G75/0236 , C08G75/0254
摘要： A class of amide group-containing aromatic dihalide compounds are sulfidized together with a class of aromatic dihalide compounds to provide a novel class of aromatic sulfideamide polymers increased in crystalline melting point (T.sub.m). The polymers exhibit excellent resistance to high temperatures, resistance to solvents, flame-retardant properties and improved mechanical properties.
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公开(公告)号：US4883702A
公开(公告)日：1989-11-28
申请号：US198657
申请日：1988-05-23
申请人： Masatoshi Sato , Kensuke Ogawara , Noriaki Emura
发明人： Masatoshi Sato , Kensuke Ogawara , Noriaki Emura
CPC分类号： H05K1/0373 , C08K7/08 , C08K7/14 , C08K2201/016 , H05K1/0228 , H05K2201/0209 , H05K2201/0248 , H05K2201/0251 , Y10T428/24355 , Y10T428/31533
摘要： A polyphenylene sulfide composition useful for plating is disclosed, comprising a polyphenylene sulfide resin, glass fibers, and potassium titanate fibers. Molded articles of this composition, when plated after etching, provide a plated article which is excellent in appearance and peel strength. Thus these plated articles can be used in outer applications, such as electric parts and automobile parts.
摘要翻译： 公开了一种可用于电镀的聚苯硫醚组合物，其包含聚苯硫醚树脂，玻璃纤维和钛酸钾纤维。 该组合物的成型体在蚀刻后进行电镀时，提供外观和剥离强度优异的电镀品。 因此，这些电镀制品可以用于外部应用中，例如电气部件和汽车部件。
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