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公开(公告)号：US07388057B2
公开(公告)日：2008-06-17
申请号：US11812892
申请日：2007-06-22
申请人： Akikazu Amagai , Kenzi Ishii , Kiyonari Hiramatsu , Makoto Miyamoto , Daisuke Ohno , Katsutoshi Yamazaki , Yasumasa Norisue
发明人： Akikazu Amagai , Kenzi Ishii , Kiyonari Hiramatsu , Makoto Miyamoto , Daisuke Ohno , Katsutoshi Yamazaki , Yasumasa Norisue
CPC分类号： C08G59/063 , C08G65/44 , C08G65/485 , C08G2650/20 , C08L2312/00 , H05K1/0326 , Y10T428/24994 , Y10T428/31511
摘要： A bifunctional phenylene ether oligomer containing monophenylene and biphenylene moieties can be rendered thermosetting by reacting the terminal phenolic hydroxyl groups with a) a cyanogen halide to introduce terminal cyanate groups, b) a halogenated glycidyl to form terminal epoxy groups, or c) an allyl halide to produce allylic terminal groups. The epoxy-terminated phenylene ether oligomer can be further reacted acrylic and/or methacrylic acid to yield an epoxy di(meth)acrylate which can be further modified with a carboxylic acid or anhydride to obtain and acid-modified epoxy di(meth)acrylate.
摘要翻译： 含有单亚苯基和亚联苯部分的双功能亚苯基醚低聚物可通过使末端酚羟基与a）卤化氰反应引入末端氰酸酯基团，b）卤代缩水甘油基形成末端环氧基，或c）烯丙基卤化物 以产生烯丙基末端基团。 环氧基封端的亚苯基醚低聚物可以进一步与丙烯酸和/或甲基丙烯酸反应，得到环氧二（甲基）丙烯酸酯，可用羧酸或酸酐进一步改性，得到酸改性环氧二（甲基）丙烯酸酯。
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公开(公告)号：US5160787A
公开(公告)日：1992-11-03
申请号：US754997
申请日：1991-09-05
申请人： Morio Gaku , Kenzi Ishii , Takamasa Nakai
发明人： Morio Gaku , Kenzi Ishii , Takamasa Nakai
IPC分类号： B32B15/08 , C08K5/45 , H01L23/552 , H05K1/03
CPC分类号： H01L23/552 , B32B15/08 , C08K5/45 , H01L2924/0002 , H05K1/0373 , Y10S428/901 , Y10T428/261 , Y10T428/31525 , Y10T428/31529 , Y10T428/31688 , Y10T442/2607 , Y10T442/3415 , Y10T442/656
摘要： An electrical laminate having an ability to absorb or shield ultraviolet rays having wavelength of 300-420 nm which comprises (i) at least one thermosetting resin-impregnated substrate, (ii) said substrate and a metal foil or (iii) said substrate, a metal foil and an adhesive layer for the metal foil comprising a thermosetting resin, characterized in that the thermosetting resin constituting part or all of said substrates or constituting said adhesive layer contains 0.2-6.0% by weight of a light absorber (A) on the basis of weight of the thermosetting resin, said light absorber is (a) an alkylthioxantone or a mixture of (a) said alkylthioxantone and (b) an ultraviolet rays-absorber.
摘要翻译： 具有吸收或屏蔽波长为300-420nm的紫外线的能力的电层压板，其包括（i）至少一种热固性树脂浸渍基材，（ii）所述基材和金属箔或（iii）所述基材， 金属箔和用于包含热固性树脂的金属箔的粘合剂层，其特征在于，构成所述基材的一部分或全部或构成所述粘合剂层的热固性树脂在基础上含有0.2-6.0重量％的光吸收体（A） 所述光吸收剂为（a）烷基噻吨酮或（a）所述烷基噻吨酮和（b）紫外线吸收剂的混合物。
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3.发明授权Bifunctional phenylene ether oligomer, its derivatives, its use and process for the production thereof 有权双官能亚苯基醚低聚物，其衍生物，其用途及其制备方法公开(公告)号：US06962744B2
公开(公告)日：2005-11-08
申请号：US10851290
申请日：2004-05-24
申请人： Akikazu Amagai , Kenzi Ishii , Kiyonari Hiramatsu , Makoto Miyamoto , Daisuke Ohno , Katsutoshi Yamazaki , Yasumasa Norisue
发明人： Akikazu Amagai , Kenzi Ishii , Kiyonari Hiramatsu , Makoto Miyamoto , Daisuke Ohno , Katsutoshi Yamazaki , Yasumasa Norisue
CPC分类号： C08G59/063 , C08G65/44 , C08G65/485 , C08G2650/20 , C08L2312/00 , H05K1/0326 , Y10T428/24994 , Y10T428/31511
摘要： A bifunctional phenylene ether oligomer of the formula (1), obtained by oxidation polymerization of a bivalent phenol of the formula (2) and a monovalent phenol of the formula (3), (wherein —X— is represented by the formula (2′), and Y—O— is represented by the formula (3), R2, R3, R4, R8, R9, R10 and R11 in the formula (2′) and the formula (3′) being required not to be a hydrogen atom, and its use.
摘要翻译： 通过式（2）的二价苯酚和式（3）的一价苯酚的氧化聚合获得的式（1）的双官能亚苯基醚低聚物（其中-X-由式（2'）表示， ），YO-由式（3）表示，式（2'）和式（3'）中的R 2，R 3，R 4，R 8，R 9，R 10和R 11不需要为氢原子， 及其用途。
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公开(公告)号：US07446154B2
公开(公告)日：2008-11-04
申请号：US12068925
申请日：2008-02-13
申请人： Akikazu Amagai , Kenzi Ishii , Kiyonari Hiramatsu , Makoto Miyamoto , Daisuke Ohno , Katsutoshi Yamazaki , Yasumasa Norisue
发明人： Akikazu Amagai , Kenzi Ishii , Kiyonari Hiramatsu , Makoto Miyamoto , Daisuke Ohno , Katsutoshi Yamazaki , Yasumasa Norisue
CPC分类号： C08G59/063 , C08G65/44 , C08G65/485 , C08G2650/20 , C08L2312/00 , H05K1/0326 , Y10T428/24994 , Y10T428/31511
摘要： A bifunctional phenylene ether oligomer of the formula (1), obtained by oxidation polymerization of a bivalent phenol of the formula (2) and a monovalent phenol of the formula (3), HO—YaO—X—OY—ObH (1) HO—X—OH (2) Y—OH (3) wherein —X— is represented by the formula (2′), and Y—O— is represented by the formula (3), R2, R3, R4, R8, R9, R10 and R11 in the formula (2′) and the formula (3′) being required not to be a hydrogen atom, and its use.
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5.发明申请Bifunctional phenylene ether oligomer, its derivatives, its use and process for the production thereof 有权双官能亚苯基醚低聚物，其衍生物，其用途及其制备方法公开(公告)号：US20080154006A1
公开(公告)日：2008-06-26
申请号：US12068925
申请日：2008-02-13
申请人： Akikazu Amagai , Kenzi Ishii , Kiyonari Hiramatsu , Makoto Miyamoto , Daisuke Ohno , Katsutoshi Yamazaki , Yasumasa Norisue
发明人： Akikazu Amagai , Kenzi Ishii , Kiyonari Hiramatsu , Makoto Miyamoto , Daisuke Ohno , Katsutoshi Yamazaki , Yasumasa Norisue
IPC分类号： C08F20/06 , C07D303/12
CPC分类号： C08G59/063 , C08G65/44 , C08G65/485 , C08G2650/20 , C08L2312/00 , H05K1/0326 , Y10T428/24994 , Y10T428/31511
摘要： A bifunctional phenylene ether oligomer of the formula (1), obtained by oxidation polymerization of a bivalent phenol of the formula (2) and a monovalent phenol of the formula (3), HO—YaO—X—OY—ObH (1) HO—X—OH (2) Y—OH (3) wherein —X— is represented by the formula (2′), and Y—O— is represented by the formula (3), R2, R3, R4, R8, R9, R10 and R11 in the formula (2′) and the formula (3′) being required not to be a hydrogen atom, and its use.
摘要翻译： 通过式（2）的二价苯酚和式（3）的一价苯酚的氧化聚合得到的式（1）的双功能亚苯基醚低聚物，<？在线式描述=“In-line 公式“end =”lead“？> H（1）<？in-line-formula description =”In “公式”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> HO-X-OH（2）<？in-line-formula description = “在线公式”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> Y-OH（3）<？in-line-formula description = 其中-X-由式（2'）表示，YO-由式（3）表示：R2，R3，R4，R8，R9，R10 并且式（2'）和式（3'）中的R 11不需要为氢原子，并且其用途。
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6.发明申请Bifunctional phenylene ether oligomer, its derivatives, its use and process for the production thereof 有权双官能亚苯基醚低聚物，其衍生物，其用途及其制备方法公开(公告)号：US20070265423A1
公开(公告)日：2007-11-15
申请号：US11812892
申请日：2007-06-22
申请人： Akikazu Amagai , Kenzi Ishii , Kiyonari Hiramatsu , Makoto Miyamoto , Daisuke Ohno , Katsutoshi Yamazaki , Yasumasa Norisue
发明人： Akikazu Amagai , Kenzi Ishii , Kiyonari Hiramatsu , Makoto Miyamoto , Daisuke Ohno , Katsutoshi Yamazaki , Yasumasa Norisue
CPC分类号： C08G59/063 , C08G65/44 , C08G65/485 , C08G2650/20 , C08L2312/00 , H05K1/0326 , Y10T428/24994 , Y10T428/31511
摘要： A bifunctional phenylene ether oligomer of the formula (1), obtained by oxidation polymerization of a bivalent phenol of the formula (2) and a monovalent phenol of the formula (3), wherein —X— is represented by the formula (2′), and Y—O— is represented by the formula (3), R2, R3, R4, R8, R9, R10 and R11 in the formula (2′) and the formula (3′) being required not to be a hydrogen atom, and its use.
摘要翻译： 通过式（2）的二价苯酚和式（3）的一价苯酚的氧化聚合获得的式（1）的双功能亚苯基醚低聚物，其中-X-由式（2'）表示， ，YO-由式（3）表示，式（2'）和式（3'）中的R2，R3，R4，R8，R9，R10和R11不为氢原子， 其使用。
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公开(公告)号：US07247682B2
公开(公告)日：2007-07-24
申请号：US11110917
申请日：2005-04-21
申请人： Akikazu Amagai , Kenzi Ishii , Kiyonari Hiramatsu , Makoto Miyamoto , Daisuke Ohno , Katsutoshi Yamazaki , Yasumasa Norisue
发明人： Akikazu Amagai , Kenzi Ishii , Kiyonari Hiramatsu , Makoto Miyamoto , Daisuke Ohno , Katsutoshi Yamazaki , Yasumasa Norisue
CPC分类号： C08G59/063 , C08G65/44 , C08G65/485 , C08G2650/20 , C08L2312/00 , H05K1/0326 , Y10T428/24994 , Y10T428/31511
摘要： A bifunctional phenylene ether oligomer of the formula (1), obtained by oxidation polymerization of a bivalent phenol of the formula (2) and a monovalent phenol of the formula (3), wherein —X— is represented by the formula (2′), and Y—O— is represented by the formula (3), R2, R3, R4, R8, R9, R10 and R11 in the formula (2′) and the formula (3′) being required not to be a hydrogen atom, and its use.
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公开(公告)号：US20050186430A1
公开(公告)日：2005-08-25
申请号：US11110917
申请日：2005-04-21
申请人： Akikazu Amagai , Kenzi Ishii , Kiyonari Hiramatsu , Makoto Miyamoto , Daisuke Ohno , Katsutoshi Yamazaki , Yasumasa Norisue
发明人： Akikazu Amagai , Kenzi Ishii , Kiyonari Hiramatsu , Makoto Miyamoto , Daisuke Ohno , Katsutoshi Yamazaki , Yasumasa Norisue
CPC分类号： C08G59/063 , C08G65/44 , C08G65/485 , C08G2650/20 , C08L2312/00 , H05K1/0326 , Y10T428/24994 , Y10T428/31511
摘要： A bifunctional phenylene ether oligomer of the formula (1), obtained by oxidation polymerization of a bivalent phenol of the formula (2) and a monovalent phenol of the formula (3), HO—YaO—X—OY—ObH (1) HO—X—OH (2) Y—OH (3) wherein —X— is represented by the formula (2′), and Y—O— is represented by the formula (3), R2, R3, R4, R8, R9, R10 and R11 in the formula (2′) and the formula (3′) being required not to be a hydrogen atom, and its use.
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9.发明授权Bifunctional phenylene ether oligomer, its derivatives, its use and process for the production thereof 有权双官能亚苯基醚低聚物，其衍生物，其用途及其制备方法公开(公告)号：US06794481B2
公开(公告)日：2004-09-21
申请号：US10180507
申请日：2002-06-27
申请人： Akikazu Amagai , Kenzi Ishii , Kiyonari Hiramatsu , Makoto Miyamoto , Daisuke Ohno , Katsutoshi Yamazaki , Yasumasa Norisue
发明人： Akikazu Amagai , Kenzi Ishii , Kiyonari Hiramatsu , Makoto Miyamoto , Daisuke Ohno , Katsutoshi Yamazaki , Yasumasa Norisue
IPC分类号： C08G6538
CPC分类号： C08G59/063 , C08G65/44 , C08G65/485 , C08G2650/20 , C08L2312/00 , H05K1/0326 , Y10T428/24994 , Y10T428/31511
摘要： A bifunctional phenylene ether oligomer of the formula (1), obtained by oxidation polymerization of abivalent phenol of the formula (2) and a monovalent phenol of the formula (3), H&Brketopenst;O—Y&Brketclosest;a&Parenopenst;O—X—O&Parenclosest;&Brketopenst;Y—O&Brketclosest;bH (1) HO—X—OH (2) Y—OH (3) wherein —X— is represented by the formula (2′), and Y—O— is represented by the formula (3), R2, R3, R4, R8, R9, R10 and R11 in the formula (2′) and the formula (3′) being required not to be a hydrogen atom, and its use.
摘要翻译： 通过式（2）的二价苯酚的氧化聚合和式（3）的一价苯酚得到的式（1）的双功能亚苯基醚低聚物，其中-X-由式（2'）表示， （3）所示的式（3）中，式（2'）和式（3'）中的R 2，R 3，R 4，R 8，R 9，R 10，R 11不需要为氢原子， 使用。
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公开(公告)号：US4917758A
公开(公告)日：1990-04-17
申请号：US354954
申请日：1989-05-19
申请人： Koichi Ishizuka , Morio Gaku , Kenzi Ishii , Hidenori Kinbara , Masakazu Motegi
发明人： Koichi Ishizuka , Morio Gaku , Kenzi Ishii , Hidenori Kinbara , Masakazu Motegi
CPC分类号： C23F1/18 , H05K3/06 , H05K2203/0353
摘要： A method for preparing a thin copper foil-clad substrate for the manufacture therefrom of circuit boards, which comprises subjecting a copper foil-clad circuit board substrate comprising an electrically insulating support having provided on one or both sides thereof a copper foil having an average thickness of 12 .mu.m or more to etching with an etching solution for copper, the etching being performed such that the whole surface of the copper foil is etched at a predetermined etching rate selected from the range of from 0.01 to 0.3 .mu.m/sec, thereby to reduce the thickness of the copper foil on at least one side of the insulating support to 10 to 80% of its original thickness, and the variation of the thickness of the copper foil remaining after the etching is within .+-.2.0 .mu.m on the basis of a desired thickness.
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