Abstract:
Artificial graphite particles, having a secondary particle structure in which a plurality of primary particles composed of graphite are clustered or bonded together, and having a layer structure in which the edge portion of the primary particles is bent in a polyhedral shape.
Abstract:
A lithium secondary battery, which comprises a positive electrode, a negative electrode containing a lithium ion-storable/dischargeable negative electrode-active material and a lithium ion conductive, non-aqueous electrolytic solution or polymer electrolyte can have distinguished charging/discharging characteristics and a higher safety, when the negative electrode material contains particles comprising carbonaceous materials and at least one of elements capable of forming a compound with Li; the elements have a melting point of at least 900° C. and a thermal expansion coefficient of not more than 9 ppm/K at room temperature; the particles are embedded in a plurality of layers of the carbonaceous materials; the particles being subjected to a mechanical treatment to make particle sizes of the particles smaller than the initial particle size in advance.
Abstract:
A silica glass production process that can prevent cracks from occurring during the step of gel drying. In a process for producing silica glass, comprising the steps of subjecting a partial polycondensation product of alkoxysilane to hydrolysis in the presence of a solvent, an organic polymeric compound and a basic catalyst to form a sol, making the sol into a gel, drying the gel to form a dry gel, and firing the dry gel to obtain a glass, a salt is caused to exist in a concentration not less than 1.times.10.sup.-4 mol based on 100 g of the partial polycondensation product of alkoxysilane in the step of subjecting the partial polycondensation product of alkoxysilane to hydrolysis to form a sol.
Abstract:
In order to provide a nonaqueous electrolyte secondary battery negative electrode material that has an excellent discharging capacity, the charge/discharge efficiency and the charge load characteristics, a manufacturing method thereof, a nonaqueous electrolyte secondary battery negative electrode with the negative electrode material and a nonaqueous electrolyte secondary battery, the invention provides a nonaqueous electrolyte secondary battery negative electrode material including graphite particles that have a block-like structure where a plurality of flat graphite fine particles assembles or bonds non-parallel with each other, the aspect ratio of 5 or less and a volume of fine pores in the range of 10 to 105 nm in a volume of 400 to 2000 cm3/kg; and a layer of carbon formed on a surface of the graphite particle, wherein a ratio (by weight ratio) of the layer of carbon to the graphite particle is in the range of 0.001 to 0.01, a manufacturing method thereof, a nonaqueous electrolyte secondary battery negative electrode with the negative electrode material and a nonaqueous electrolyte secondary battery.
Abstract:
A lithium secondary battery, which comprises a positive electrode, a negative electrode containing a lithium ion-storable/dischargeable negative electrode-active material and a lithium ion conductive, non-aqueous electrolytic solution or polymer electrolyte can have distinguished charging/discharging characteristics and a higher safety, when the negative electrode material contains particles comprising carbonaceous materials and at least one of elements capable of forming a compound with Li; the elements have a melting point of at least 900° C. and a thermal expansion coefficient of not more than 9 ppm/K at room temperature; the particles are embedded in a plurality of layers of the carbonaceous materials; the particles being subjected to a mechanical treatment to make particle sizes of the particles smaller than the initial particle size in advance.
Abstract:
Artificial graphite particles, having a secondary particle structure in which a plurality of primary particles composed of graphite are clustered or bonded together, and having a layer structure in which the edge portion of the primary particles is bent in a polyhedral shape.
Abstract:
In order to provide a nonaqueous electrolyte secondary battery negative electrode material that has an excellent discharging capacity, the charge/discharge efficiency and the charge load characteristics, a manufacturing method thereof, a nonaqueous electrolyte secondary battery negative electrode with the negative electrode material and a nonaqueous electrolyte secondary battery, the invention provides a nonaqueous electrolyte secondary battery negative electrode material including graphite particles that have a block-like structure where a plurality of flat graphite fine particles assembles or bonds non-parallel with each other, the aspect ratio of 5 or less and a volume of fine pores in the range of 10 to 105 nm in a volume of 400 to 2000 cm3/kg; and a layer of carbon formed on a surface of the graphite particle, wherein a ratio (by weight ratio) of the layer of carbon to the graphite particle is in the range of 0.001 to 0.01, a manufacturing method thereof, a nonaqueous electrolyte secondary battery negative electrode with the negative electrode material and a nonaqueous electrolyte secondary battery.
Abstract:
Artificial graphite particles, having a secondary particle structure in which a plurality of primary particles composed of graphite are clustered or bonded together, and having a layer structure in which the edge portion of the primary particles is bent in a polyhedral shape.