摘要:
The invention relates to a method for producing copolymers made from isobutene and at least one vinylaromatic component. Said method consists of polymerising isobutene or a hydrocarbon mixture containing isobutene with at least one vinylaromatic compound in the presence of a solvent-stable transistion metal complex comprising slightly co-ordinating anions as a polymerisation catalyst. The invention also relates to copolymers made of isobutene and at least one vinylaromatic compound, which can be obtained by means of said inventive method, in addition to specific functionalisation products therefrom.
摘要:
Many variables in processes such as those using turbocompressors and turbines must be limited or constrained. Limit control loops are provided for the purpose of limiting these variables. By using a combination of closed loop and open loop limit control schemes, excursions into unfavorable operation can be more effectively avoided. Transition between open loop and closed loop may be enhanced by testing the direction and magnitude of the rate at which the limit variable is changing. If the rate of change indicates recovery is imminent, control is passed back to the closed loop limit control function.
摘要:
Many variables in processes such as those using turbocompressors and turbines must be limited or constrained. Limit control loops are provided for the purpose of limiting these variables. By using a combination of closed loop and open loop limit control schemes, excursions into unfavorable operation can be more effectively avoided. Transition between open loop and closed loop may be enhanced by testing the direction and magnitude of the rate at which the limit variable is changing. If the rate of change indicates recovery is imminent, control is passed back to the closed loop limit control function.
摘要:
A method of surge protection for a dynamic compressor that has a corresponding compressor map. A control system continually calculates an equivalent polytropic head parameter in order to define a surge limit line. The system then calculates a control parameter and determines the distance the control parameter to the surge limit line wherein the control parameter is dynamic to changes in compressor load and invariant to changes in suction conditions and gas compressibility. As a result of the distance of the control parameter to the surge limit line, the surge valve of a dynamic compressor is actuated to prevent surge.
摘要:
Many variables in processes such as those using turbocompressors and turbines must be limited or constrained. Limit control loops are provided for the purpose of limiting these variables. By using a combination of closed loop and open loop limit control schemes, excursions into unfavorable operation can be more effectively avoided. Transition between open loop and closed loop may be enhanced by testing the direction and magnitude of the rate at which the limit variable is changing. If the rate of change indicates recovery is imminent, control is passed back to the closed loop limit control function.
摘要:
The invention relates to a solvent-stable metal catalyst having slightly coordinating counter anions of formula I [M(L)a(Z)b]m+m(A−)(I), wherein M represents a transition metal of groups 3-12 of the periodic system, a lanthanide or a metal of groups 2 or 13 of the periodic system; L represents a solvent molecule; Z represents a mono or polycharged ligand; A− represents a slightly or non coordinated anion; a represents a whole number which is greater than or equal to 1; b represents a whole number which is greater than or equal to 1, whereby the total from a and b is between 4 and 8, and m represents a whole number from 1 6. The invention also relates to a method for polymerising olefinically unsaturated compounds in the presence of said catalyst and copolymers which are made of monomers comprising isobutene and at least one vinylaromatic compound which is obtained according to said inventive method.
摘要翻译:本发明涉及一种溶剂稳定的金属催化剂,其具有式I的轻微配位的反阴离子[M(L)a(Z)b + m + (I),其中M表示周期系统的基团3-12的过渡金属,镧系元素或周期性体系的基团2或13的金属; L表示溶剂分子; Z表示单或多电荷配体; A SUP>表示轻度或非配位的阴离子; a表示大于或等于1的整数; b表示大于或等于1的整数,其中a和b的总数在4和8之间,m表示从1 6起的整数。本发明还涉及一种聚合烯属不饱和化合物的方法, 所述催化剂和共聚物的存在由根据本发明方法获得的包含异丁烯和至少一种乙烯基芳族化合物的单体制成。
摘要:
Aspects of the present disclosure provide methods, devices, and computer-readable storage media that support adaptive scheduling of electric vehicles (EVs) of an EV fleet for order deliveries. In some implementations, one or more aspects of the adaptive EV scheduling may be customized for EVs. For example, the adaptive EV scheduling may include identifying an energy efficient route that also reduces stress on a battery of an EV and may be based at least in part on a charging parameter associated with the EV. In some examples, the charging parameter may include one or more of a state of charge (SOC) associated with the battery, a state of health (SOH) associated with the battery, a location of a charging station for the EV, an average charging duration associated with the EV, or an intelligent charging parameter associated with the EV.
摘要:
A method of correcting surge control parameters that includes providing a dynamic compressor having a compressor, driver, surge valve, and control system. The control system establishes surge control parameters such as surge detection lines, surge limit lines, and then detects the onset of a surge in the dynamic compressor. When the surge is detected the control system measures variables of the dynamic compressor such as fluid pressure, fluid speed, power, speed and valve position and based on these variables the control system automatically corrects the surge control parameters based on these variables at the time of the onset of the surge is detected. Advisory information is provided by control system to user for corrective actions to prevent surge.
摘要:
A method is provided for controlling fuel flow to the combustor of a gas generator turbine during sudden changes in load or during a surge cycle of the process turbocompressor. Surge control is initiated by analog input signals emanating from various devices located throughout the compressor-process system. The fuel control system includes input signals from the gas turbine driver. These signals are acted upon by the fuel control system which transmits a signal to a fuel valve actuator that controls the valve that meters fuel to the combustor. In addition to this sequence of control communication, however, is a rate-of-change in the amount of the fuel provided. The rate of the increase of the amount of fuel is determined by current operating functions of the fuel control system. However, because of the characteristics of general load rejection and recovery, and the abrupt nature of surge, the rate of change in the flow rate of fuel is extremely high. This rapid increase of fuel to the combustor may lead to dangerous excursions in temperature, resulting in high temperatures in gas turbine elements. Consequently, a new function is added to the fuel control system's operation whereby improved regulation of the rate of increase of fuel is achieved. This new function receives a signal that either surge or a change in load has been detected. Next, a signal is transmitted to the fuel valve actuator, regulating fuel to the combustor, thus power to the power turbine, thereby preventing overspeeding. After that, the rate of change of the fuel valve is limited for a period of time. Once recovery has been accomplished, the change rate of the fuel valve is gradually returned to a normal operating setting.
摘要:
A method of preventing surge in a dynamic compressor is disclosed. The method includes providing an anti-surge valve having an adjustable opening for increasing the flow through a dynamic compressor. The next step is sensing process conditions in the dynamic control to determine a compressor load variable. A control system estimates a process disturbance model using the compressor load variable. The control system then adjusts a safety margin using a rate limited response and initiates a closed loop response using process feedback based on the process disturbance model. The control system adjusts the opening of the anti-surge valve according to the safety margin and closed loop response.