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1.发明授权Enhancement of alkylation catalysts for improved supercritical fluid regeneration 有权用于改进超临界流体再生的烷基化催化剂的增强公开(公告)号：US07592282B2
公开(公告)日：2009-09-22
申请号：US10986742
申请日：2004-11-11
申请人： Daniel M. Ginosar , Lucia Petkovic
发明人： Daniel M. Ginosar , Lucia Petkovic
CPC分类号： C07C2/66 , B01J29/084 , B01J29/18 , B01J29/60 , B01J29/7007 , B01J35/023 , B01J37/009 , B01J2229/10 , B01J2229/38 , Y02P20/544
摘要： A method of modifying an alkylation catalyst to reduce the formation of condensed hydrocarbon species thereon. The method comprises providing an alkylation catalyst comprising a plurality of active sites. The plurality of active sites on the alkylation catalyst may include a plurality of weakly acidic active sites, intermediate acidity active sites, and strongly acidic active sites. A base is adsorbed to a portion of the plurality of active sites, such as the strongly acidic active sites, selectively poisoning the strongly acidic active sites. A method of modifying the alkylation catalyst by providing an alkylation catalyst comprising a pore size distribution that sterically constrains formation of the condensed hydrocarbon species on the alkylation catalyst or by synthesizing the alkylation catalyst to comprise a decreased number of strongly acidic active sites is also disclosed, as is a method of improving a regeneration efficiency of the alkylation catalyst.
摘要翻译： 一种改性烷基化催化剂以减少其上的稠合烃物质形成的方法。 该方法包括提供包含多个活性位点的烷基化催化剂。 烷基化催化剂上的多个活性位点可以包括多个弱酸性活性位点，中间酸性活性位点和强酸性活性位点。 碱被吸附到多个活性位点的一部分，例如强酸性活性位点，选择性地中毒强酸性活性位点。 还公开了通过提供烷基化催化剂来改性烷基化催化剂的方法，所述烷基化催化剂包含空间上约束烷基化催化剂上的稠合烃物质的形成的孔径分布，或通过合成烷基化催化剂以包含减少数量的强酸性活性位点， 以及提高烷基化催化剂的再生效率的方法也是如此。
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公开(公告)号：US20060252950A1
公开(公告)日：2006-11-09
申请号：US11123607
申请日：2005-05-06
申请人： Daniel Ginosar , Robert Fox , Lucia Petkovic
发明人： Daniel Ginosar , Robert Fox , Lucia Petkovic
IPC分类号： C07C51/43
摘要： A method of producing an alkyl ester. The method comprises providing an alcohol and a triglyceride or fatty acid. An expanding gas is dissolved into the alcohol to form a gas expanded solvent. The alcohol is reacted with the triglyceride or fatty acid in a single phase to produce the alkyl ester. The expanding gas may be a nonpolar expanding gas, such as carbon dioxide, methane, ethane, propane, butane, pentane, ethylene, propylene, butylene, pentene, isomers thereof, and mixtures thereof, which is dissolved into the alcohol. The gas expanded solvent may be maintained at a temperature below, at, or above a critical temperature of the expanding gas and at a pressure below, at, or above a critical pressure of the expanding gas.
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公开(公告)号：US20060100089A1
公开(公告)日：2006-05-11
申请号：US10986742
申请日：2004-11-11
申请人： Daniel Ginosar , Lucia Petkovic
发明人： Daniel Ginosar , Lucia Petkovic
IPC分类号： B01J21/20
CPC分类号： C07C2/66 , B01J29/084 , B01J29/18 , B01J29/60 , B01J29/7007 , B01J35/023 , B01J37/009 , B01J2229/10 , B01J2229/38 , Y02P20/544
摘要： A method of modifying an alkylation catalyst to reduce the formation of condensed hydrocarbon species thereon. The method comprises providing an alkylation catalyst comprising a plurality of active sites. The plurality of active sites on the alkylation catalyst may include a plurality of weakly acidic active sites, intermediate acidity active sites, and strongly acidic active sites. A base is adsorbed to a portion of the plurality of active sites, such as the strongly acidic active sites, selectively poisoning the strongly acidic active sites. A method of modifying the alkylation catalyst by providing an alkylation catalyst comprising a pore size distribution that sterically constrains formation of the condensed hydrocarbon species on the alkylation catalyst or by synthesizing the alkylation catalyst to comprise a decreased number of strongly acidic active sites is also disclosed, as is a method of improving a regeneration efficiency of the alkylation catalyst.
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4.发明申请CATALYTIC STRUCTURES INCLUDING CATALYST MATERIALS IN POROUS ZEOLITE MATERIALS, AND METHODS OF FORMING SAME 审中-公开包含多孔沸石材料中催化材料的催化结构及其形成方法公开(公告)号：US20110092356A1
公开(公告)日：2011-04-21
申请号：US12970643
申请日：2010-12-16
IPC分类号： B01J29/04 , B01J29/08 , B01J29/18 , B01J29/70 , B01J29/83 , B01J29/85 , B01J29/40 , B01J37/02 , B82Y30/00
CPC分类号： B01J29/061 , B01J29/005 , B01J29/035 , B01J29/041 , B01J29/072 , B01J29/40 , B01J29/46 , B01J29/80 , B01J37/0018 , C07C1/20 , C07C2529/46 , C07C2529/84 , C07C2529/85 , C10G3/45 , C10G3/47 , C10G3/49 , C10G3/50 , C10G2400/20 , C10G2400/22 , Y02P30/40 , C07C11/02
摘要： Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing a formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing a formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by a crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures. Catalytic structures are fabricated by forming a zeolite material at least partially around a template structure, removing the template structure, and introducing a catalytic material into the zeolite material.
摘要翻译： 催化结构包括设置在沸石材料内的催化材料。 催化材料可能能够催化从一氧化碳和/或二氧化碳形成甲醇，并且沸石材料可以能够催化甲醇形成烃分子。 催化材料可以包括铜和氧化锌。 沸石材料可以包括基本上由沸石材料的晶体结构限定的第一多个孔和分散在整个沸石材料中的第二多个孔。 合成烃分子的系统还包括催化结构。 合成烃分子的方法包括使氢和一氧化碳和二氧化碳中的至少一种与这种催化结构接触。 催化结构通过至少部分地围绕模板结构形成沸石材料，去除模板结构以及将催化材料引入到沸石材料中来制造。
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5.发明申请METHODS FOR RECOVERING A SOLVENT FROM A FLUID VOLUME AND METHODS OF REMOVING AT LEAST ONE COMPOUND FROM A NONPOLAR SOLVENT 有权从流体体积中回收溶剂的方法和从非溶剂中除去至少一种化合物的方法公开(公告)号：US20130008861A1
公开(公告)日：2013-01-10
申请号：US13177962
申请日：2011-07-07
IPC分类号： B01D35/18
CPC分类号： B01D11/0292 , B01D17/047
摘要： A method of removing a nonpolar solvent from a fluid volume that includes at least one nonpolar compound, such as a fat, an oil or a triglyceride, is provided. The method comprises contacting a fluid volume with an expanding gas to expand the nonpolar solvent and form a gas-expanded solvent. The gas-expanded solvent may have a substantially reduced density in comparison to the at least one nonpolar compound and/or a substantially reduced capacity to solubilize the nonpolar compound, causing the nonpolar compounds to separate from the gas-expanded nonpolar solvent into a separate liquid phase. The liquid phase including the at least one nonpolar compound may be separated from the gas-expanded solvent using conventional techniques. After separation of the liquid phase, at least one of the temperature and pressure may be reduced to separate the nonpolar solvent from the expanding gas such that the nonpolar solvent may be recovered and reused.
摘要翻译： 提供了从包含至少一种非极性化合物（例如脂肪，油或甘油三酸酯）的流体体积中除去非极性溶剂的方法。 该方法包括使流体体积与膨胀气体接触以膨胀非极性溶剂并形成气体膨胀溶剂。 气体膨胀溶剂与至少一种非极性化合物相比可具有显着降低的密度和/或增加非极性化合物溶解能力的基本上降低的作用，导致非极性化合物与气体膨胀的非极性溶剂分离成单独的液体 相。 可以使用常规技术将包含至少一种非极性化合物的液相与气体膨胀溶剂分离。 在分离液相后，可以降低至少一个温度和压力，以将非极性溶剂与膨胀气体分离，使得非极性溶剂可以回收和重复使用。
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