公开(公告)号：US20060252950A1

公开(公告)日：2006-11-09

申请号：US11123607

申请日：2005-05-06

申请人： Daniel Ginosar ,  Robert Fox ,  Lucia Petkovic

发明人： Daniel Ginosar ,  Robert Fox ,  Lucia Petkovic

IPC分类号： C07C51/43

CPC分类号： C11C3/003 ,  C07C67/03 ,  C07C67/08 ,  Y02E50/13 ,  C07C69/24 ,  C07C69/52

摘要： A method of producing an alkyl ester. The method comprises providing an alcohol and a triglyceride or fatty acid. An expanding gas is dissolved into the alcohol to form a gas expanded solvent. The alcohol is reacted with the triglyceride or fatty acid in a single phase to produce the alkyl ester. The expanding gas may be a nonpolar expanding gas, such as carbon dioxide, methane, ethane, propane, butane, pentane, ethylene, propylene, butylene, pentene, isomers thereof, and mixtures thereof, which is dissolved into the alcohol. The gas expanded solvent may be maintained at a temperature below, at, or above a critical temperature of the expanding gas and at a pressure below, at, or above a critical pressure of the expanding gas.

公开(公告)号：US20060100089A1

公开(公告)日：2006-05-11

申请号：US10986742

申请日：2004-11-11

申请人： Daniel Ginosar ,  Lucia Petkovic

发明人： Daniel Ginosar ,  Lucia Petkovic

IPC分类号： B01J21/20

CPC分类号： C07C2/66 ,  B01J29/084 ,  B01J29/18 ,  B01J29/60 ,  B01J29/7007 ,  B01J35/023 ,  B01J37/009 ,  B01J2229/10 ,  B01J2229/38 ,  Y02P20/544

摘要： A method of modifying an alkylation catalyst to reduce the formation of condensed hydrocarbon species thereon. The method comprises providing an alkylation catalyst comprising a plurality of active sites. The plurality of active sites on the alkylation catalyst may include a plurality of weakly acidic active sites, intermediate acidity active sites, and strongly acidic active sites. A base is adsorbed to a portion of the plurality of active sites, such as the strongly acidic active sites, selectively poisoning the strongly acidic active sites. A method of modifying the alkylation catalyst by providing an alkylation catalyst comprising a pore size distribution that sterically constrains formation of the condensed hydrocarbon species on the alkylation catalyst or by synthesizing the alkylation catalyst to comprise a decreased number of strongly acidic active sites is also disclosed, as is a method of improving a regeneration efficiency of the alkylation catalyst.

公开(公告)号：US20110092356A1

公开(公告)日：2011-04-21

申请号：US12970643

申请日：2010-12-16

申请人： Harry W. Rollins ,  Lucia Petkovic ,  Daniel M. Ginosar

发明人： Harry W. Rollins ,  Lucia Petkovic ,  Daniel M. Ginosar

IPC分类号： B01J29/04 ,  B01J29/08 ,  B01J29/18 ,  B01J29/70 ,  B01J29/83 ,  B01J29/85 ,  B01J29/40 ,  B01J37/02 ,  B82Y30/00

CPC分类号： B01J29/061 ,  B01J29/005 ,  B01J29/035 ,  B01J29/041 ,  B01J29/072 ,  B01J29/40 ,  B01J29/46 ,  B01J29/80 ,  B01J37/0018 ,  C07C1/20 ,  C07C2529/46 ,  C07C2529/84 ,  C07C2529/85 ,  C10G3/45 ,  C10G3/47 ,  C10G3/49 ,  C10G3/50 ,  C10G2400/20 ,  C10G2400/22 ,  Y02P30/40 ,  C07C11/02

摘要： Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing a formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing a formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by a crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures. Catalytic structures are fabricated by forming a zeolite material at least partially around a template structure, removing the template structure, and introducing a catalytic material into the zeolite material.

摘要翻译： 催化结构包括设置在沸石材料内的催化材料。 催化材料可能能够催化从一氧化碳和/或二氧化碳形成甲醇，并且沸石材料可以能够催化甲醇形成烃分子。 催化材料可以包括铜和氧化锌。 沸石材料可以包括基本上由沸石材料的晶体结构限定的第一多个孔和分散在整个沸石材料中的第二多个孔。 合成烃分子的系统还包括催化结构。 合成烃分子的方法包括使氢和一氧化碳和二氧化碳中的至少一种与这种催化结构接触。 催化结构通过至少部分地围绕模板结构形成沸石材料，去除模板结构以及将催化材料引入到沸石材料中来制造。

公开(公告)号：US07592282B2

公开(公告)日：2009-09-22

申请号：US10986742

申请日：2004-11-11

申请人： Daniel M. Ginosar ,  Lucia Petkovic

发明人： Daniel M. Ginosar ,  Lucia Petkovic

IPC分类号： B01J38/48 ,  B01J38/64 ,  B01J38/66 ,  B01J38/02 ,  B01J21/20 ,  B01J23/90 ,  B01J25/04

CPC分类号： C07C2/66 ,  B01J29/084 ,  B01J29/18 ,  B01J29/60 ,  B01J29/7007 ,  B01J35/023 ,  B01J37/009 ,  B01J2229/10 ,  B01J2229/38 ,  Y02P20/544

摘要： A method of modifying an alkylation catalyst to reduce the formation of condensed hydrocarbon species thereon. The method comprises providing an alkylation catalyst comprising a plurality of active sites. The plurality of active sites on the alkylation catalyst may include a plurality of weakly acidic active sites, intermediate acidity active sites, and strongly acidic active sites. A base is adsorbed to a portion of the plurality of active sites, such as the strongly acidic active sites, selectively poisoning the strongly acidic active sites. A method of modifying the alkylation catalyst by providing an alkylation catalyst comprising a pore size distribution that sterically constrains formation of the condensed hydrocarbon species on the alkylation catalyst or by synthesizing the alkylation catalyst to comprise a decreased number of strongly acidic active sites is also disclosed, as is a method of improving a regeneration efficiency of the alkylation catalyst.

摘要翻译： 一种改性烷基化催化剂以减少其上的稠合烃物质形成的方法。 该方法包括提供包含多个活性位点的烷基化催化剂。 烷基化催化剂上的多个活性位点可以包括多个弱酸性活性位点，中间酸性活性位点和强酸性活性位点。 碱被吸附到多个活性位点的一部分，例如强酸性活性位点，选择性地中毒强酸性活性位点。 还公开了通过提供烷基化催化剂来改性烷基化催化剂的方法，所述烷基化催化剂包含空间上约束烷基化催化剂上的稠合烃物质的形成的孔径分布，或通过合成烷基化催化剂以包含减少数量的强酸性活性位点， 以及提高烷基化催化剂的再生效率的方法也是如此。