公开(公告)号：US07666969B2

公开(公告)日：2010-02-23

申请号：US11746676

申请日：2007-05-10

申请人： Georg Loessel ,  Manfred Meisenberger ,  Gerhard Staiger

发明人： Georg Loessel ,  Manfred Meisenberger ,  Gerhard Staiger

IPC分类号： C08G77/12 ,  C08G77/20

CPC分类号： C08G77/12 ,  C08G77/06 ,  C08G77/20 ,  C09D183/04

摘要： One-component, H-siloxane-containing addition-crosslinkable silicone resins, are prepared by charging a reactor with water and a solvent mixture of at least one aromatic solvent and at least one alkyl ester, adding a chlorosilane mixture containing an Si—H functional silane and a silane bearing an unsaturated hydrosilylatable group with stirring, the temperature not being above 50° C., separating an aqueous phase comprising a one-component, H-siloxane-containing addition-crosslinkable silicone resin, and washing the phase comprising the one-component, H-siloxane-containing addition-crosslinkable silicone resin in at least two washing steps to reduce residual HCl content, a final washing carried out using a 0.01%-1.0% strength aqueous solution of a base with a pH between 7.00-8.50, at a temperature of 20-50° C.

摘要翻译： 通过向反应器中加入含有至少一种芳香族溶剂和至少一种烷基酯的溶剂混合物，加入含有Si-H官能团的氯代硅烷混合物来制备含单硅氧烷的可加成交联硅氧烷树脂 硅烷和含有不饱和可氢化甲硅烷基的基团的硅烷在搅拌下，温度不高于50℃，分离含有单组分的含H-硅氧烷的可加成交联的有机硅树脂的水相，并洗涤包含一个 - 组分，含H-硅氧烷的可加成交联的有机硅树脂，至少两个洗涤步骤以减少残留的HCl含量，最后的洗涤使用0.01％-1.0％强度的碱的水溶液进行，pH为7.00-8.50 ，温度为20-50℃

公开(公告)号：US20070265410A1

公开(公告)日：2007-11-15

申请号：US11746676

申请日：2007-05-10

申请人： Georg Loessel ,  Manfred Meisenberger ,  Gerhard Staiger

发明人： Georg Loessel ,  Manfred Meisenberger ,  Gerhard Staiger

IPC分类号： C08G77/12

CPC分类号： C08G77/12 ,  C08G77/06 ,  C08G77/20 ,  C09D183/04

摘要： One-component, H-siloxane-containing addition-crosslinkable silicone resins, are prepared by charging a reactor with water and a solvent mixture of at least one aromatic solvent and at least one alkyl ester, adding a chlorosilane mixture containing an Si—H functional silane and a silane bearing an unsaturated hydrosilylatable group with stirring, the temperature not being above 50° C., separating an aqueous phase comprising a one-component, H-siloxane-containing addition-crosslinkable silicone resin, and washing the phase comprising the one-component, H-siloxane-containing addition-crosslinkable silicone resin in at least two washing steps to reduce residual HCl content, a final washing carried out using a 0.01%-1.0% strength aqueous solution of a base with a pH between 7.00-8.50, at a temperature of 20-50° C.

摘要翻译： 通过向反应器中加入含有至少一种芳香族溶剂和至少一种烷基酯的溶剂混合物，加入含有Si-H官能团的氯代硅烷混合物来制备含单硅氧烷的可加成交联硅氧烷树脂 硅烷和含有不饱和可氢化甲硅烷基的基团的硅烷在搅拌下，温度不高于50℃，分离含有单组分的含H-硅氧烷的可加成交联的有机硅树脂的水相，并洗涤包含一个 - 组分，含H-硅氧烷的可加成交联的有机硅树脂，至少两个洗涤步骤，以减少残留的HCl含量，最后的洗涤使用0.01％-1.0％强度的碱的水溶液进行，pH为7.00-8.50 ，温度为20-50℃

公开(公告)号：US4526944A

公开(公告)日：1985-07-02

申请号：US240103

申请日：1981-03-03

申请人： Gerhard Staiger

发明人： Gerhard Staiger

IPC分类号： C08F10/00 ,  C08F4/64

CPC分类号： C08F10/00 ,  Y10S526/906

摘要： A process for the preparation of homopolymers and copolymers of .alpha.-monoolefins by means of a Ziegler-Natta catalyst system comprising (1) a halide of trivalent titanium, (2) an oxygen compound (ester) having a specific formula and (3) an aluminum-alkyl, the titanium halide (1) and the oxygen compound (2) being milled together before use, wherein the catalyst system employed contains, as a further component, (4) a phenolic compound of the formula ##STR1## where R.sup.3 is C.sub.1 -C.sub.6 -alkyl, R.sup.4 is hydrogen or C.sub.1 -C.sub.6 -alkyl, p is an integer from 0 to 5 and q is an integer from 1 to 5.

摘要翻译： 一种通过齐格勒 - 纳塔催化剂体系制备α-单烯烃的均聚物和共聚物的方法，包括（1）三价钛的卤化物，（2）具有特定式的氧化合物（酯）和（3） 烷基铝，卤化钛（1）和氧化合物（2）在使用前被研磨在一起，其中所用的催化剂体系包含作为另外的组分的（4）式（Ia）的酚类化合物，其中R3是 C 1 -C 6烷基，R 4是氢或C 1 -C 6烷基，p是0至5的整数，q是1至5的整数。

公开(公告)号：US4503240A

公开(公告)日：1985-03-05

申请号：US517980

申请日：1983-07-28

申请人： Gerhard Staiger ,  Antonio Macri

发明人： Gerhard Staiger ,  Antonio Macri

IPC分类号： B01J21/00 ,  C07C29/10 ,  C07C51/08 ,  C07D303/04 ,  C07D307/92 ,  C07D311/92

CPC分类号： C07D307/92 ,  C07C255/00 ,  C07C29/10 ,  C07C51/08 ,  C07C2103/10

摘要： Process for the preparation of 8,12-epoxy-13,14,15,16-tetranorlabdane by way of converting farnesyl bromide to farnesyl cyanide, followed by the saponification of the farnesyl cyanide to homofarnesic acid which is then cyclized to norambreinolide in the presence of titanium tetrachloride, converting the norambreinolide with LiAlH.sub.4 to 8-hydroxy-13,14,15,16-tetranorlabdane-12-ol, and cyclization of the diol in the presence of POCl.sub.3 to 8,12-epoxy-13,14,15,16-tetranorlabdane. The resulting product exhibits an amber scent, used in perfumery.

摘要翻译： 通过将法呢基溴化物转化为法呢基氰化物制备8,12-环氧-13,14,15,16-四硝基拉丹的方法，然后将法呢烯氰化物皂化成高锰酸，然后在存在下将其环化为诺巴芹宁 的四氯化钛，将诺拉曲宁醇与LiAlH 4转化为8-羟基-13,14,15,16-四去甲二醇-12-醇，并将二醇在POCl 3存在下环化为8,12-环氧-13,14,15 ，16-tetranorlabdane。 所得产品表现出琥珀香味，用于香料。

公开(公告)号：US20100076170A1

公开(公告)日：2010-03-25

申请号：US12521923

申请日：2008-01-22

申请人： Gerhard Staiger

发明人： Gerhard Staiger

IPC分类号： C08G77/06

CPC分类号： C08G77/04 ,  C08G77/06

摘要： A targeted molecular weight of an organopolysiloxane is obtained in a two stage hydrolysis by hydrolyzing a chlorosilane with from 0.002 to 0.6 mol of water in a first step in the presence of alcohol, in which the pressure and/or temperature are adjusted such that following further hydrolysis in a second step, the targeted molecular weight is obtained.

摘要翻译： 有机聚硅氧烷的目标分子量通过在醇的存在下在第一步中水解含有0.002至0.6mol水的氯代硅烷在两阶段水解中获得，其中调节压力和/或温度使得继续进一步 在第二步中水解，得到目标分子量。

公开(公告)号：US20090287009A1

公开(公告)日：2009-11-19

申请号：US12446959

申请日：2007-11-02

申请人： Paul Fuchs ,  Norbert Ellinger ,  Klaus Kaeppler ,  Gerhard Staiger

发明人： Paul Fuchs ,  Norbert Ellinger ,  Klaus Kaeppler ,  Gerhard Staiger

IPC分类号： C07F7/12 ,  B01D1/00

CPC分类号： B01D1/0017

摘要： Mixtures containing high boiling and low boiling components, at least one component being dissociatable into ions, are separated effectively by heating by passing an alternating electrical current through the mixture. The process is particularly effective in the workup of crude alkylchlorosilanes from the direct synthesis.

摘要翻译： 含有高沸点和低沸点组分的混合物，至少一种可离解成离子的组分通过使交流电流通过混合物而被加热而被有效地分离。 该方法在直接合成粗烷基氯硅烷的后处理中特别有效。

公开(公告)号：US4639541A

公开(公告)日：1987-01-27

申请号：US727027

申请日：1985-04-25

申请人： Gerhard Staiger ,  Tassilo Selmayr ,  Peter Kinzel ,  Anneliese Reutter

发明人： Gerhard Staiger ,  Tassilo Selmayr ,  Peter Kinzel ,  Anneliese Reutter

IPC分类号： C07C69/612 ,  C07C79/46 ,  C07C69/76

CPC分类号： C07C69/65

摘要： Substituted phenylactic acid iodopropargyl ester compounds of the general formula: ##STR1## in which R may represent hydrogen, fluorine, chlorine, bromine, iodine, methoxy, 1-imidazolyl or 1,2,4-triazolyl, X represents one or more of the same or different substituents selected from fluorine, chlorine, bromine, iodine, cyano, nitro, carboxyl, an alkyl having from 1 to 12 carbon atoms, an alkoxy having from 1 to 12 carbon atoms, a cycloalkyl having from 3 to 6 carbon atoms, formyl, acetyl, propionyl, benzoyl, phenylsulfonyl, phenyl, phenoxy, and substituted phenyl and phenoxy groups having from 1 to 3 substituents selected from fluorine, chlorine, bromine, nitro, methyl or methoxy, and n is an integer from 1 to 5 and may be zero provided that R does not represent hydrogen. The invention also relates to a process of making the compounds, which are effective ingredients of biocidal agents.

摘要翻译： 取代的苯甲酸碘代炔丙基酯化合物，其通式为：其中R可以代表氢，氟，氯，溴，碘，甲氧基，1-咪唑基或1,2,4-三唑基，X代表一个或多个 相同或不同的选自氟，氯，溴，碘，氰基，硝基，羧基，具有1至12个碳原子的烷基，具有1至12个碳原子的烷氧基，具有3至6个碳原子的环烷基， 甲酰基，乙酰基，丙酰基，苯甲酰基，苯基磺酰基，苯基，苯氧基和取代的苯基和具有1至3个选自氟，氯，溴，硝基，甲基或甲氧基的取代基的苯氧基，n为1至5的整数， 可以为零，条件是R不表示氢。 本发明还涉及制备作为杀生物剂的有效成分的化合物的方法。

公开(公告)号：US4579919A

公开(公告)日：1986-04-01

申请号：US673337

申请日：1984-11-20

申请人： Gerhard Staiger ,  Wolfgang Gruber

发明人： Gerhard Staiger ,  Wolfgang Gruber

IPC分类号： C08F4/10 ,  C08F4/16 ,  C08F10/00 ,  C08F4/02

CPC分类号： C08F10/00

摘要： .alpha.-Monoolefins are polymerized using a catalyst system which comprises (1) a titanium component obtained by first (1.a) preparing an intermediate from (1.a.1) titanium tetrachloride, (1.a.2) a modifier and (1.a.3) a magnesium alcoholate, and the (1.b) preparing the titanium component from (1.b.1) titanium tetrachloride, (1.b.2) the intermediate from (1.a) and, if required, (1.b.3) a further modifier, (2) an alkylaluminum and (3) a cocatalyst. In this process, (i) the titanium component (1) used is obtained by first (1.1) preparing a first intermediate from (1.1.1) titanium tetrachloride, (1.1.2) a modifier obtained from (1.1.2.1) a titanate and (1.1.2.2) a phthaloyl dichloride, and (1.1.3) a magnesium alcoholate, then (1.2) preparing a second intermediate from (1.2.1) titanium tetrachloride, (1.2.2) the intermediate from (1.1) and, if required, (1.2.3) a phthaloyl dichloride as a further modifier, and finally (1.3) preparing the titanium component from (1.3.1) titanium tetrachloride and (1.3.2) the intermediate from (1.2), and (ii) the cocatalyst (3) used is a trialkoxysilane.

摘要翻译： α-烯烃使用催化剂体系进行聚合，所述催化剂体系包括（1）通过首先（1.a）从（1.a）四氯化钛制备中间体，（1.a.2）改性剂和（ 1.a.3）一种醇镁，和（1.b）从（1.b.1）四氯化钛制备钛组分，（1.b.2）中间体为（1.a），如果 （1.b.3）另一种改性剂，（2）烷基铝和（3）助催化剂。 在该方法中，（i）使用的钛组分（1）首先（1.1）由（1.1.1）四氯化钛制备第一中间体，（1.1.2）由（1.1.2.1）得到的改性剂钛酸酯 和（1.1.2.2）邻苯二甲酰二氯化物，和（1.1.3）醇镁酸盐，然后（1.2）从（1.1.1）四氯化钛（1.2.1）制备第二中间体，（1.2.2）（1.1）中间体， （1.2.3）邻苯二甲酰二氯作为其他改性剂，最后（1.3）从（1.3.1）四氯化钛制备钛组分和（1.3.2）中间体（1.2）和（ii） 所用的助催化剂（3）是三烷氧基硅烷。

公开(公告)号：US4224184A

公开(公告)日：1980-09-23

申请号：US57087

申请日：1979-07-12

申请人： Gerhard Staiger

发明人： Gerhard Staiger

IPC分类号： C08F4/64 ,  C08F10/00

CPC分类号： C08F10/00

摘要： A special process for the preparation of a titanium component for polymerization catalysts of the Ziegler-Natta type, wherein (1) in a first stage (1.1) an alcoholate of the formula Mg(OR).sub.2, where R is lower alkyl, and (1.2) benzoyl chloride are milled together in a particular molar ratio in a vibratory ball mill under particular milling conditions, especially a relatively low temperature, in the absence of a diluent, thereafter (2) in a second stage (2.1) the material resulting from stage (1) is brought together with (2.2) titanium tetrachloride in a particular ratio, the batch is kept at an elevated temperature for some time, with constant mixing, and the resulting solid is isolated, excess titanium tetrachloride being removed, and finally (3) in a third stage (3.1) the solid resulting from stage (2) is again brought together with (3.2) titanium tetrachloride in a particular ratio, the batch is again kept at an elevated temperature for some time, with constant mixing, and the resulting solid, constituting the novel titanium component, is isolated, excess titanium tetrachloride being removed. The novel titanium component permits the preparation of .alpha.-monoolefin polymers in high yield and with high isotacticity.

摘要翻译： 一种用于制备齐格勒 - 纳塔型聚合催化剂的钛组分的特殊方法，其中（1）在第一阶段（1.1）中，式Mg（OR）2的醇化物，其中R是低级烷基，和（ 1.2）苯甲酰氯在振动球磨机中在特定的研磨条件下，特别是相对较低的温度下，在不存在稀释剂的情况下以特定的摩尔比一起研磨，此后（2）在第二阶段（2.1）中得到的材料 阶段（1）以（2.2）的四氯化钛以特定的比例与（2.2）四氯化钛合并，将该批次保持在升高的温度下一段时间，不断混合，分离所得固体，除去过量的四氯化钛，最后（ 3）在第三阶段（3.1）中，将从阶段（2）得到的固体以特定的比例再次与（3.2）四氯化钛一起使用，将该批次再次保持在升高的温度下一段时间，持续混合，和 结果 构成新的钛组分的固体被分离，除去过量的四氯化钛。 新型钛组分允许以高产率和高全同立构度制备α-单烯烃聚合物。

公开(公告)号：US4224183A

公开(公告)日：1980-09-23

申请号：US54864

申请日：1979-07-05

申请人： Gerhard Staiger

发明人： Gerhard Staiger

IPC分类号： C08F4/64 ,  C08F10/00

CPC分类号： C08F10/00

摘要： A special process for the preparation of a titanium component for polymerization catalysts of the Ziegler-Natta type, wherein (1) in a first stage (1.1) an alcoholate of the formula Mr(OR).sub.2, where R is lower alkyl and (1.2) a chlorotoluene of the formula ##STR1## where X is chlorine or hydrogen, are milled together in a particular molar ratio in a vibratory ball mill under particular milling conditions, especially a relatively low temperature, in the absence of a diluent, thereafter (2) in a second stage (2.1) the material resulting from stage (1) is brought together with (2.2) titanium tetrachloride in a particular ratio, the batch is kept for some time at an elevated temperature, with constant mixing, and the resulting solid is isolated, excess titanium tetrachloride being separated off, and finally (3) in a third stage (3.1) the solid resulting from stage (2) is again brought together with (3.2) titanium tetrachloride in a particular ratio, the batch is again kept for some time at an elevated temperature, with constant mixing, and the resulting solid, constituting the novel titanium component, is isolated, excess titanium tetrachloride being removed. The novel titanium compound permits the production of polymers of .alpha.-monoolefins not only in high yield but also with high isotacticity.

摘要翻译： 一种用于制备齐格勒 - 纳塔型聚合催化剂的钛组分的特殊方法，其中（1）在第一阶段（1.1）中式（OR）2的醇化物，其中R是低级烷基和（1.2 ）其中X是氯或氢的式“IMAGE”的氯甲苯在振动球磨机中在特定的研磨条件下，特别是在相对低的温度下，在不存在稀释剂的情况下，以特定的摩尔比碾磨在一起，之后（2 ）在第二阶段（2.1）中，将由阶段（1）产生的材料以（2.2）的四氯化钛以特定的比例混合在一起，将该批次在恒定混合下在升高的温度下保持一段时间， 被分离出，过量的四氯化钛被分离出来，最后（3）在第三阶段（3.1）中，将从阶段（2）得到的固体再次以（3.2）的四氯化钛与特定的比例重合，再次保持该批次 在一段时间内 升高的温度，恒定混合，并且分离出构成新的钛组分的所得固体，除去过量的四氯化钛。 新型钛化合物不仅可以高收率生产α-单烯烃聚合物，而且具有高全同立构规整度。