公开(公告)号：US06815506B2

公开(公告)日：2004-11-09

申请号：US10268789

申请日：2002-10-11

申请人： Masaaki Takashima ,  Katsutaka Yokoi ,  Minoru Tsuneyoshi

发明人： Masaaki Takashima ,  Katsutaka Yokoi ,  Minoru Tsuneyoshi

IPC分类号： C08L3304

CPC分类号： C08L23/16 ,  C08L23/00 ,  C08L23/0869 ,  C08L23/12 ,  C08L33/08 ,  C08L2207/04 ,  Y10T428/139 ,  C08L2666/04 ,  C08L2666/02

摘要： A thermoplastic elastomer composition having excellent heat aging characteristics, weather resistance, low-temperature physical properties, oil resistance and flexibility, and moldings using the same, such as hoses, are disclosed. The thermoplastic elastomer composition is obtained by dynamically heat treating a mixture containing (A) an olefin resin, (B) an unsaturated group-containing acrylic rubber, and (D) an inorganic filler in the presence of (E) a crosslinking agent, the component (B) comprising (B1) from 55 to 94.99% by weight of a structural unit derived from an acrylic acid alkyl ester monomer and/or an acrylic acid alkoxyalkyl ester monomer, (B2) from 0.01 to 20% by weight of a structural unit derived from a monomer having a carbon-carbon double bond in a side chain thereof, (B3) from 5 to 30% by weight of a structural unit derived from an unsaturated acrylonitrile monomer, and (B4) from 0 to 30% by weight of a structural unit derived from a monomer copolymerizable therewith, provided that the sum of (B1), (B2), (B3) and (B4) is 100% by weight.

摘要翻译： 公开了具有优异的热老化特性，耐候性，低温物理性能，耐油性和柔软性的热塑性弹性体组合物和使用该热塑性弹性体组合物的软管。 热塑性弹性体组合物通过在（E）交联剂的存在下动态热处理含有（A）烯烃树脂，（B）不饱和基团的丙烯酸橡胶和（D）无机填料）的混合物， 组分（B），其包含（B1）55至94.99重量％的衍生自丙烯酸烷基酯单体和/或丙烯酸烷氧基烷基酯单体的结构单元，（B2）0.01至20重量％的结构 来源于其侧链中具有碳 - 碳双键的单体的单元，（B3）5〜30重量％的衍生自不饱和丙烯腈单体的结构单元，和（B4）0〜30重量％ （B1），（B2），（B3）和（B4）之和为100重量％的单体衍生自可与其共聚的单体的结构单元。

公开(公告)号：US06458883B1

公开(公告)日：2002-10-01

申请号：US09480793

申请日：2000-01-11

申请人： Masaaki Takashima ,  Kiyonori Kita ,  Takao Yamazaki ,  Minoru Tsuneyoshi

发明人： Masaaki Takashima ,  Kiyonori Kita ,  Takao Yamazaki ,  Minoru Tsuneyoshi

IPC分类号： C08K304

CPC分类号： C08L101/12 ,  C08K3/04 ,  C08L9/02 ,  C08L9/04 ,  C08L9/08 ,  C08L19/003 ,  C08L21/00 ,  C08L2666/08

摘要： The present invention provides a conductive rubber composition with a low hardness and low distortion, and exhibiting less variations in volume specific resistance value and less dependence on environment, a manufacturing method thereof, and further, a conductive rubber member using the same. The conductive rubber composition of the present invention contains a particulate polymer (A1, crosslinked particulate polymer, and the like), an uncrosslinked polymer (A2), and a conductivity imparting agent (B). The particulate polymer (A1) is a nonpolar polymer (SBR, and the like), the uncrosslinked (A2) is a polar polymer (NBR, and the like), and the more conductivity imparting agent (B) exists in the uncrosslinked polymer than in the crosslinked particulate polymer. This composition can be obtained by starting the kneading of the above-described respective compounds at such a temperature (T C.) that the Mooney viscosity of the uncrosslinked polymer is equal or less than the Mooney viscosity of particulate polymer. The particulate polymer (A1) preferably has an average particle diameter of 25 mm or less, and a Duro A hardness of 45 to 80. The conductive rubber member, according to the present invention, can be obtained by molding the above-described conductive rubber composition and then vulcanizing it.

摘要翻译： 本发明提供一种导电性橡胶组合物，其硬度低，变形小，体积比电阻值的变化小，对环境的依赖性小，其制造方法以及使用该导电性橡胶组合物的导电性橡胶构件。 本发明的导电性橡胶组合物含有粒状聚合物（A1，交联粒状聚合物等），未交联聚合物（A2）和导电性赋予剂（B）。 颗粒聚合物（A1）是非极性聚合物（SBR等），未交联的（A2）是极性聚合物（NBR等），并且在未交联的聚合物中存在较多的导电性赋予剂（B） 在交联的颗粒聚合物中。 可以通过在未交联聚合物的门尼粘度等于或小于颗粒状聚合物的门尼粘度的温度（T℃）下开始捏合上述各种化合物来获得该组合物。 粒状聚合物（A1）的平均粒径优选为25mm以下，Duro A硬度为45〜80。本发明的导电性橡胶构件可以通过将上述导电性橡胶 然后硫化。

公开(公告)号：US4942202A

公开(公告)日：1990-07-17

申请号：US263882

申请日：1988-10-28

申请人： Yoshiaki Zama ,  Itsuki Umeda ,  Yasuhiko Takemura ,  Masaaki Takashima ,  Yuichi Funabashi ,  Junichiro Watanabe ,  Kiyoshi Takeda ,  Hiromichi Yoshida

发明人： Yoshiaki Zama ,  Itsuki Umeda ,  Yasuhiko Takemura ,  Masaaki Takashima ,  Yuichi Funabashi ,  Junichiro Watanabe ,  Kiyoshi Takeda ,  Hiromichi Yoshida

IPC分类号： C08L21/00 ,  C08C19/30 ,  C08F8/00 ,  C08F8/32 ,  C08K5/14 ,  C08L23/08 ,  C08L23/16 ,  C08L27/12 ,  C08L71/02 ,  C08L83/04 ,  C08L83/07

CPC分类号： C08L83/04 ,  C08L23/08 ,  C08L23/16 ,  C08L27/12 ,  C08L71/02 ,  C08G77/16 ,  C08G77/18 ,  C08G77/20 ,  C08G77/24 ,  C08G77/26 ,  C08G77/70

摘要： A rubber composition that is prepared by reacting an organic peroxide, under shear deformation, with 3-70 parts by weight of silicone rubber (I), 30-97 parts by weight of a saturated elastomer (II) that substantially fails to be crosslinked with an organic peroxide when it is used alone, and 0-20 parts by weight of another elastomer (III) that is co-crosslinkable with component (I) in the presence of an organic peroxide and which is also co-crosslinkable or highly miscible with component (II) [where (I)+(II)+(III)=100 parts by weight].

摘要翻译： 通过在剪切变形下使有机过氧化物与3-70重量份硅橡胶（I）反应制备的橡胶组合物，30-97重量份基本上不能与 单独使用有机过氧化物，和0-20重量份在有机过氧化物存在下与组分（I）共交联并且也可共交联或高度混溶的另一种弹性体（III） 组分（II）[其中（I）+（II）+（III）= 100重量份]。

公开(公告)号：US5010137A

公开(公告)日：1991-04-23

申请号：US156118

申请日：1988-02-16

申请人： Itsuki Umeda ,  Masaaki Takashima ,  Yoshiaki Zama ,  Yasuhiko Takemura ,  Yuichi Funabashi ,  Junichiro Watanabe ,  Kiyoshi Takeda ,  Makoto Matsumoto

发明人： Itsuki Umeda ,  Masaaki Takashima ,  Yoshiaki Zama ,  Yasuhiko Takemura ,  Yuichi Funabashi ,  Junichiro Watanabe ,  Kiyoshi Takeda ,  Makoto Matsumoto

IPC分类号： C08L9/02 ,  C08L21/00 ,  C08L23/16 ,  C08L71/03 ,  C08L83/04 ,  C08L83/05 ,  C08L83/07 ,  F16J15/10 ,  F16L11/04

CPC分类号： C08L23/16 ,  C08L21/00 ,  C08L23/0869 ,  C08L71/03 ,  C08L83/04 ,  C08L9/00 ,  C08L9/02 ,  C08G77/12 ,  C08G77/20 ,  C08L2312/00

摘要： A rubber composition obtained by compounding (B) from 0.005 to 50 parts by weight of an polyorganohydrogensiloxane and (C) from 0.00001 to 1 part by weight of a compound of a transition metal belonging to the group VIII with (A) 100 parts by weight of a rubber-forming polymer mainly comprising (I) from 3 to 70% by weight of a polyorganosiloxane represented by the formula: ##EQU1## wherein R represents a substituted or unsubstituted monovalent organic group, 0.02 to 10 mole % of which being a vinyl group; and a represents a number of from 1.900 to 2.004,and having a degree of polymerization of from 500 to 10,000 and (II) from 30 to 97% by weight of organic rubber, and subjecting the resulting compound to hydrosilylation while effecting shear deformation. The rubber composition is excellent in roll processing properties, mechanical strength, heat resistance, and low-temperature property and is suitable as oil seal and rubber hose.