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    Guanidine compound and asymmetric reaction using the same
    1.
    发明授权
    Guanidine compound and asymmetric reaction using the same 有权
    胍化合物和使用其的不对称反应

    公开(公告)号：US07781425B2

    公开(公告)日：2010-08-24

    申请号：US10589814

    申请日：2005-02-09

    申请人： Masahiro Terada ,  Hitoshi Ube ,  Shigeko Yokoyama ,  Hideo Shimizu

    发明人： Masahiro Terada ,  Hitoshi Ube ,  Shigeko Yokoyama ,  Hideo Shimizu

    IPC分类号： C07D223/28 ,  C07D301/00 ,  C07D303/32

    CPC分类号： C07C205/26 ,  B01J31/0244 ,  B01J31/0251 ,  C07B53/00 ,  C07C205/16 ,  C07C205/53 ,  C07D223/14 ,  C07D301/12 ,  C07D303/32

    摘要： A guanidine compound having a biaryl skeleton represented by the following formula (1), which is useful as a catalyst for various asymmetric reactions. (wherein R1, R2 and R3 each independently represent a hydrogen atom, a hydrocarbon group optionally having substituent(s), or a heterocyclic group optionally having substituent(s); R4 to R15 each independently represent a hydrogen atom, a hydrocarbon group optionally having substituent(s), a heterocyclic group optionally having substituent(s), a hydroxy group, an alkoxy group optionally having substituent(s), an aryloxy group optionally having substituent(s), an acyl group, an alkoxycarbonyl group optionally having substituent(s), an aryloxycarbonyl group optionally having substituent(s), a carbamoyl group optionally having substituent(s), an alkylthiocarbonyl group optionally having substituent(s), an arylthiocarbonyl group optionally having substituent(s), a carboxyl group, an alkylthio group optionally having substituent(s), an arylthio group optionally having substituent(s), an amino group or a substituted amino group, or a substituted silyl group; or in any combination of R1 to R15, these substituents may be taken together to form a ring; and X1 to X8 represent a hydrogen atom or a nitrogen atom, provided that, in the case of a nitrogen atom, there is no substituent on X1 to X8.

    摘要翻译： 具有由下式（1）表示的联芳基骨架的胍化合物，其可用作各种不对称反应的催化剂。 （其中R 1，R 2和R 3各自独立地表示氢原子，任选具有取代基的烃基或任选具有取代基的杂环基; R 4至R 15各自独立地表示氢原子，任选具有 取代基，任选具有取代基的杂环基，羟基，任选具有取代基的烷氧基，任选具有取代基的芳氧基，酰基，任选具有取代基的烷氧基羰基（ s），任选具有取代基的芳氧基羰基，任选具有取代基的氨基甲酰基，任选具有取代基的烷硫基羰基，任选具有取代基的芳硫基羰基，羧基，烷硫基 任选具有取代基，任选具有取代基的芳硫基，氨基或取代的氨基或取代的甲硅烷基;或者R 1至R 1的任何组合 如图5所示，这些取代基可以一起形成环; 并且X1至X8表示氢原子或氮原子，条件是在氮原子的情况下，在X1至X8上不存在取代基。

    Guanidine Compound and Asymmetric Reaction Using the Same
    2.
    发明申请
    Guanidine Compound and Asymmetric Reaction Using the Same 有权
    胍化合物和使用其的不对称反应

    公开(公告)号：US20080154036A1

    公开(公告)日：2008-06-26

    申请号：US10589814

    申请日：2005-02-09

    申请人： Masahiro Terada ,  Hitoshi Ube ,  Shigeko Yokoyama ,  Hideo Shimizu

    发明人： Masahiro Terada ,  Hitoshi Ube ,  Shigeko Yokoyama ,  Hideo Shimizu

    IPC分类号： C07D223/14

    CPC分类号： C07C205/26 ,  B01J31/0244 ,  B01J31/0251 ,  C07B53/00 ,  C07C205/16 ,  C07C205/53 ,  C07D223/14 ,  C07D301/12 ,  C07D303/32

    摘要： A guanidine compound having a biaryl skeleton represented by the following formula (1), which is useful as a catalyst for various asymmetric reactions. (wherein R1, R2 and R3 each independently represent a hydrogen atom, a hydrocarbon group optionally having substituent(s), or a heterocyclic group optionally having substituent(s); R4 to R15 each independently represent a hydrogen atom, a hydrocarbon group optionally having substituent(s), a heterocyclic group optionally having substituent(s), a hydroxy group, an alkoxy group optionally having substituent(s), an aryloxy group optionally having substituent(s), an acyl group, an alkoxycarbonyl group optionally having substituent(s), an aryloxycarbonyl group optionally having substituent(s), a carbamoyl group optionally having substituent(s), an alkylthiocarbonyl group optionally having substituent(s), an arylthiocarbonyl group optionally having substituent(s), a carboxyl group, an alkylthio group optionally having substituent(s), an arylthio group optionally having substituent(s), an amino group or a substituted amino group, or a substituted silyl group; or in any combination of R1 to R15, these substituents may be taken together to form a ring; and X1 to X8 represent a hydrogen atom or a nitrogen atom, provided that, in the case of a nitrogen atom, there is no substituent on X1 to X8.

    摘要翻译： 具有由下式（1）表示的联芳基骨架的胍化合物，其可用作各种不对称反应的催化剂。 （其中R 1，R 2，R 3和R 3）各自独立地表示氢原子，任选具有取代基的烃基或 任选具有取代基的杂环基团; R 4至R 15各自独立地表示氢原子，任选具有取代基的烃基，任选具有取代基的杂环基 取代基，羟基，任选具有取代基的烷氧基，任选具有取代基的芳氧基，酰基，任选具有取代基的烷氧基羰基，任选具有取代基的芳氧基羰基， s），任选具有取代基的氨基甲酰基，任选具有取代基的烷硫基羰基，任选具有取代基的芳硫基羰基，羧基，任选具有取代基的烷硫基，芳硫基 任选具有取代基，氨基或取代的氨基，或亚 取代甲硅烷基; 或者R 1至R 15的任何组合，这些取代基可以一起形成环; 并且X 1至X 8表示氢原子或氮原子，条件是在氮原子的情况下，X 1上不存在取代基 到X 8。

    Process for production of amines
    3.
    发明申请
    Process for production of amines 有权
    胺的生产工艺

    公开(公告)号：US20070142639A1

    公开(公告)日：2007-06-21

    申请号：US10587279

    申请日：2005-01-26

    申请人： Masahiro Terada ,  Daisuke Uraguchi ,  Keiichi Sorimachi ,  Hideo Shimizu

    发明人： Masahiro Terada ,  Daisuke Uraguchi ,  Keiichi Sorimachi ,  Hideo Shimizu

    IPC分类号： C07F9/02 ,  C07D215/12 ,  C07D307/02

    CPC分类号： C07C231/08 ,  B01J31/0258 ,  B01J2231/346 ,  C07C221/00 ,  C07C245/14 ,  C07C245/18 ,  C07C269/06 ,  C07D307/58 ,  C07F9/657127 ,  C07F9/65742 ,  C07F9/65744 ,  C07F9/6578 ,  C07F9/65842 ,  C07F9/65848 ,  C07C233/76 ,  C07C271/18

    摘要： A process for producing an amine which is characterized by reacting an imine with a nucleophilic compound (except a trialkylsilyl vinyl ether) in the presence of a phosphoric acid derivative represented by the formula (1): wherein A1 represents a spacer; X1 and X2 represent each independently a divalent nonmetal atom or a divalent nonmetal atomic group; and Y1 is oxygen or sulfur. The invention provides a process by which amines (particularly optically active amines) useful as intermediates of medicines, agricultural chemicals, or the like can be produced without special post-treatment in high yield at high optical purity; and phosphoric acid derivatives (particularly optically active phosphoric acid derivatives) useful in the production of the amines.

    摘要翻译： 一种制备胺的方法，其特征在于在式（1）表示的磷酸衍生物存在下使亚胺与亲核化合物（三烷基甲硅烷基乙烯基醚除外）反应：其中A 1〜 代表间隔物; X 1和X 2各自独立地表示二价非金属原子或二价非金属原子团; 和Y 1是氧或硫。 本发明提供了一种以高光学纯度可高产率地用于药物，农药等作为中间体的胺（特别是光学活性胺）而不进行特殊后处理的方法。 和可用于制备胺的磷酸衍生物（特别是光学活性磷酸衍生物）。

    Process for production of amines
    4.
    发明授权
    Process for production of amines 有权
    胺的生产工艺

    公开(公告)号：US07902207B2

    公开(公告)日：2011-03-08

    申请号：US10587279

    申请日：2005-01-26

    申请人： Masahiro Terada ,  Daisuke Uraguchi ,  Keiichi Sorimachi ,  Hideo Shimizu

    发明人： Masahiro Terada ,  Daisuke Uraguchi ,  Keiichi Sorimachi ,  Hideo Shimizu

    IPC分类号： C07F9/02

    CPC分类号： C07C231/08 ,  B01J31/0258 ,  B01J2231/346 ,  C07C221/00 ,  C07C245/14 ,  C07C245/18 ,  C07C269/06 ,  C07D307/58 ,  C07F9/657127 ,  C07F9/65742 ,  C07F9/65744 ,  C07F9/6578 ,  C07F9/65842 ,  C07F9/65848 ,  C07C233/76 ,  C07C271/18

    摘要： A process for producing an amine which is characterized by reacting an imine with a nucleophilic compound (except a trialkylsilyl vinyl ether) in the presence of a phosphoric acid derivative represented by the formula (1): wherein A1 represents a spacer; X1 and X2 represent each independently a divalent nonmetal atom or a divalent nonmetal atomic group; and Y1 is oxygen or sulfur. The invention provides a process by which amines (particularly optically active amines) useful as intermediates of medicines, agricultural chemicals, or the like can be produced without special post-treatment in high yield at high optical purity; and phosphoric acid derivatives (particularly optically active phosphoric acid derivatives) useful in the production of the amines.

    摘要翻译： 一种制备胺的方法，其特征在于在由式（1）表示的磷酸衍生物存在下使亚胺与亲核化合物（三烷基甲硅烷基乙烯基醚除外）反应：其中A1表示间隔基; X1和X2各自独立地表示二价非金属原子或二价非金属原子团; Y1是氧或硫。 本发明提供了一种以高光学纯度可高产率地用于药物，农药等作为中间体的胺（特别是光学活性胺）而不进行特殊后处理的方法。 和可用于制备胺的磷酸衍生物（特别是光学活性磷酸衍生物）。

    Belt buckle device
    5.
    发明授权
    Belt buckle device 有权
    皮带扣装置

    公开(公告)号：US08663135B2

    公开(公告)日：2014-03-04

    申请号：US12987432

    申请日：2011-01-10

    申请人： Takashi Hirata ,  Hideo Shimizu

    发明人： Takashi Hirata ,  Hideo Shimizu

    IPC分类号： A61H3/00

    CPC分类号： A61H3/00 ,  A44B11/28 ,  A61H1/024 ,  A61H1/0244 ,  A61H2201/0192 ,  A61H2201/1215 ,  A61H2201/163 ,  A61H2201/1642 ,  A61H2201/165 ,  A61H2201/1676 ,  A61H2201/1697 ,  A61H2201/5061 ,  A61H2201/5069 ,  H01F7/0231

    摘要： In a belt buckle device including a tongue piece (75, 76; 210; 310) connected to an end of a belt extending in a longitudinal direction and a hook member (68, 70; 220; 320) configured to be selectively connected to the tongue piece by engaging a first lateral bar of the tongue piece in a hook opening (111; 226; 326) defined by a hook portion (71, 72; 225; 324) thereof, a longitudinal dimension (B) between the free end of the tongue piece and a base end side of the first lateral bar is substantially equal to or smaller than a width (A) of the entrance of the hook opening, and the effective thickness (C) of the first lateral bar is greater than the width (A) of the entrance of the hook opening. Thus, the first lateral bar is held inside the hook opening as long as the tongue piece is kept in a flat position in a reliable manner. In particular, the first lateral bar can be freely introduced into the hook opening simply by raising the base end of the tongue piece while the first lateral bar is applied to the entrance of the hook opening so that the belt buckle device can be readily fastened even when the belt buckle device cannot be viewed from a proper viewing angle. Also, the belt buckle device can be readily fastened with a minimum dexterity requirement and very quickly.

    摘要翻译： 在带扣装置中，包括连接到沿纵向延伸的带的端部的舌片（75,76; 210; 310）和钩构件（68,70; 220; 320），所述钩构件被配置为选择性地连接到 舌片通过将舌片的第一侧杆接合在由钩部分（71,72; 225; 324）限定的钩形开口（111; 226; 326）中，其纵向尺寸（B）在 舌片和第一侧杆的基端侧基本上等于或小于钩开口的入口的宽度（A），并且第一横杆的有效厚度（C）大于宽度 （A）吊钩开口的入口。 因此，只要舌片以可靠的方式保持在平坦位置，第一侧杆就保持在钩开口内。 特别地，第一侧杆可以简单地通过提升舌片的基端部而自由地引入钩形开口，同时第一侧杆施加到钩形开口的入口，使得带扣装置甚至可以容易地紧固 当皮带扣装置不能从正确的视角观察时。 此外，带扣装置可以以最小的灵巧要求容易地紧固并且非常快。

    Encryption device
    6.
    发明授权
    Encryption device 有权
    加密设备

    公开(公告)号：US08538017B2

    公开(公告)日：2013-09-17

    申请号：US13192122

    申请日：2011-07-27

    申请人： Tsukasa Endo ,  Hideo Shimizu ,  Yuichi Komano ,  Hanae Ikeda ,  Atsushi Shimbo

    发明人： Tsukasa Endo ,  Hideo Shimizu ,  Yuichi Komano ,  Hanae Ikeda ,  Atsushi Shimbo

    IPC分类号： H04L9/00

    CPC分类号： H04L9/003 ,  H04L9/0631 ,  H04L2209/046 ,  H04L2209/24

    摘要： According to one embodiment, in an encryption device, a segmentation unit segments masked plain data into pieces of first segmented data. A first processing unit generates pieces of second segmented data from the pieces of first segmented data. A nonlinear transform unit generates pieces of third segmented data transformed from the pieces of second segmented data. A data integration unit integrates fourth segmented data to generate masked encrypted data. An unmask processing unit generates encrypted data from the masked encrypted data. The exclusive OR of the pieces of second segmented data matches the exclusive OR of input data, subjected to nonlinear transform processing and calculated from the plain data, and the first mask. The exclusive OR of the pieces of third segmented data matches the exclusive OR of transform data, obtained when the nonlinear transform processing is performed on the input data, and the second mask.

    摘要翻译： 根据一个实施例，在加密设备中，分割单元将屏蔽的普通数据分割成多个第一分段数据。 第一处理单元从第一分段数据生成第二分段数据。 非线性变换单元生成从第二分割数据变换的第三分段数据。 数据集成单元集成第四分段数据以生成被掩蔽的加密数据。 解密处理单元从掩蔽的加密数据生成加密数据。 第二分段数据的异或与进行非线性变换处理并从普通数据计算的输入数据的异或与第一掩码相匹配。 第三分段数据的异或与对输入数据执行非线性变换处理时获得的变换数据的异或与第二掩码相匹配。

    Walking assistance device
    10.
    发明授权
    Walking assistance device 有权
    行走辅助装置

    公开(公告)号：US08409119B2

    公开(公告)日：2013-04-02

    申请号：US12785013

    申请日：2010-05-21

    申请人： Hideo Shimizu ,  Tatsuya Noda ,  Taiji Koyama

    发明人： Hideo Shimizu ,  Tatsuya Noda ,  Taiji Koyama

    IPC分类号： A61H1/02 ,  A61H1/00

    CPC分类号： A61H3/008 ,  A61H1/0244 ,  A61H3/00 ,  A61H2201/1215 ,  A61H2201/163 ,  A61H2201/1642 ,  A61H2201/165 ,  A61H2201/1676 ,  B25J9/0006

    摘要： A walking assistance device including a pelvic frame (10) extending from a lower back to each lateral side of a user, and a belly belt (20) for securing the pelvic frame in position. A power generator (30) is attached to each lateral side of the pelvic frame. A power transmitting arm (40) can be attached to an output member (33) of the power generator simply by hooking an upper part of a base end (41) of the power transmitting arm onto an upper groove (38) of the output member, and pushing a latch member or a slider (46) provided in a lower part of the base end onto a lower groove (39) of the output member. The user wearing the pelvic frame (10) can easily attach the power transmitting arm (40) to the output end of the power generator (30) by easily using a single hand without requiring help.

    摘要翻译： 一种行走辅助装置，包括从使用者的下背部延伸到每个侧面的骨盆框架（10）和用于将骨盆框架固定就位的腹部带（20）。 发电机（30）安装在骨盆框架的每个侧面。 动力传递臂（40）可以简单地通过将动力传递臂的基端（41）的上部钩在输出构件的上槽（38）上而附接到发电机的输出构件（33） 并且将设置在基端的下部的闩锁构件或滑块（46）推到输出构件的下槽（39）上。 佩戴骨盆框架（10）的使用者可以容易地使用单手而不需要帮助就可以容易地将动力传递臂（40）附接到发电机（30）的输出端。