公开(公告)号：US20140113007A1

公开(公告)日：2014-04-24

申请号：US14122554

申请日：2012-05-30

申请人： Ryo Kato ,  Kanefusa Hara ,  Masanori Yanagida

发明人： Ryo Kato ,  Kanefusa Hara ,  Masanori Yanagida

IPC分类号： A01N59/08 ,  C01B11/02

CPC分类号： A01N59/08 ,  A01N59/00 ,  C01B11/024 ,  A01N25/08

摘要： Provided is a chlorine dioxide-generating product comprising an inorganic porous carrier carrying a chlorite and an alkali agent. In the product, the alkali agent is carried in an amount of more than 0.7 molar equivalent and not more than 2 molar equivalents relative to the amount of the chlorite carried, and the product has a water content of 10% by weight or less. The chlorine dioxide-generating product can stably generate chlorine dioxide gas in an amount that sufficiently achieves deodorization, sterilization, virus removal, mold prevention, antisepsis, or the like of spatial environments, foods, or others but exerts no harmful effect on humans, over a long period of time.

摘要翻译： 本发明提供了一种二氧化氯产生产物，其包含载有亚氯酸盐和碱剂的无机多孔载体。 在该产品中，相对于所携带的亚氯酸盐的量，碱剂的用量大于0.7摩尔当量且不大于2摩尔当量，并且该产品的含水量为10重量％以下。 产生二氧化氯的产品可以稳定地产生二氧化氯气体，其量足以实现空间环境，食品或其它物质的除臭，杀菌，病毒去除，防霉，防腐等，但不对人造成有害影响 很长一段时间。

公开(公告)号：US06180287B2

公开(公告)日：2001-01-30

申请号：US09101971

申请日：1998-07-30

申请人： Masayoshi Watanabe ,  Katsuhito Miura ,  Masanori Yanagida ,  Hiroki Higobashi ,  Takahiro Endo

发明人： Masayoshi Watanabe ,  Katsuhito Miura ,  Masanori Yanagida ,  Hiroki Higobashi ,  Takahiro Endo

IPC分类号： H01M618

CPC分类号： H01G9/025 ,  C08G59/145 ,  C08G59/22 ,  C08G65/14 ,  C08G65/22 ,  C08G65/223 ,  C08G65/24 ,  C08K5/0008 ,  C08L71/02 ,  H01M6/181 ,  H01M10/052 ,  H01M10/0565 ,  C08L71/00

摘要： A solid polymer electrolyte obtained by blending (1) a polyether copolymer having a main chain, which is derived form ethylene oxide, and a side chain having two oligooxyethylene groups, (2) an electrolyte salt compound, and, if necessary, (3) a plasticizer which is any one of an aprotic organic solvent or a derivative or metal salt of a polyalkylene glycol having a number-average molecular weight of 200 to 5,000 or a metal salt of the derivative, is superior in ionic conductivity and also superior in processability, moldability and mechanical strength to a conventional solid electrolyte. A secondary battery is constructed by using the solid polymer electrolyte in combination with a lithium metal negative electrode and a lithium cobaltate positive electrode.

摘要翻译： 通过共混（1）具有来自环氧乙烷的主链的聚醚共聚物和具有两个低聚氧乙烯基的侧链，（2）电解质盐化合物，以及如果需要，（3） 作为数均分子量为200〜5000的聚亚烷基二醇的非质子性有机溶剂或衍生物或金属盐或该衍生物的金属盐中的任一种的增塑剂，离子导电性优异，加工性优异 ，成型性和机械强度。 通过使用固体聚合物电解质与锂金属负极和钴酸锂正极组合来构建二次电池。

公开(公告)号：US6159389A

公开(公告)日：2000-12-12

申请号：US265802

申请日：1999-03-10

申请人： Katsuhito Miura ,  Masanori Yanagida ,  Hiroki Higobashi ,  Seiji Nakamura

发明人： Katsuhito Miura ,  Masanori Yanagida ,  Hiroki Higobashi ,  Seiji Nakamura

IPC分类号： H01G9/025 ,  C08G65/14 ,  C08G65/22 ,  C08G65/24 ,  C08G65/32 ,  C08G65/329 ,  C08L71/00 ,  H01B1/12 ,  H01G9/028 ,  H01G11/06 ,  H01G11/22 ,  H01G11/24 ,  H01G11/30 ,  H01G11/46 ,  H01G11/54 ,  H01G11/56 ,  H01G11/62 ,  H01G11/64 ,  H01G11/86 ,  H01M6/18 ,  H01M10/05 ,  H01M10/0565 ,  H01G1/74

CPC分类号： H01M10/052 ,  C08G65/14 ,  C08G65/22 ,  C08G65/24 ,  H01M10/0565

摘要： A polyether copolymer having a weight-average molecular weight of 10.sup.4 to 10.sup.7, comprising 5 to 40% by mol of a repeating unit derived from epichlorohydrin, 95 to 60% by mol of a repeating unit derived from ethylene oxide, and 0.001 to 15% by mol of a crosslinkable repeating unit derived from a reactive oxirane compound, gives a provide a crosslinked solid polymer electrolyte which is superior in processability, moldability, mechanical strength, flexibility and heat resistance, and has markedly improved ionic conductivity.

摘要翻译： 重均分子量为104〜107的聚醚共聚物，含有5〜40摩尔％的来自表氯醇的重复单元，95〜60摩尔％的来源于环氧乙烷的重复单元和0.001〜15重量％ 提供衍生自活性环氧乙烷化合物的可交联重复单元，得到提供加工性，成型性，机械强度，柔软性和耐热性优异的交联固体聚合物电解质，并且具有显着提高的离子导电性。

公开(公告)号：US06201071B1

公开(公告)日：2001-03-13

申请号：US09242880

申请日：1999-04-19

申请人： Katsuhito Miura ,  Masanori Yanagida ,  Kazumasa Hinoue ,  Yoshiro Furukawa

发明人： Katsuhito Miura ,  Masanori Yanagida ,  Kazumasa Hinoue ,  Yoshiro Furukawa

IPC分类号： C08G6391

CPC分类号： H01M10/052 ,  C08G65/22 ,  H01M6/181 ,  H01M10/0565

摘要： A solid polymer electrolyte containing a polyether copolymer having a weight-average molecular weight of 104 to 107 which may optionally be cross-linked and which contains (A) 1 to 99% by mol of a repeating unit derived from a monomer represented by the formula (I):  wherein R1 represents a divalent organic group, (B) 99 to 1% by mol of a repeating unit derived from ethylene oxide, and (C) 0 to 15% by mol of a repeating unit derived from a monomer having one epoxy group and at least one reactive functional group, an electrolyte salt compound, and a plasticizer has an excellent ionic conductivity.

摘要翻译： 一种含有重均分子量为104〜107的聚醚共聚物的固体聚合物电解质，其可以任选地交联，并且含有（A）1至99摩尔％的由式 （I）表示：其中，R1表示二价有机基团，（B）99〜1摩尔％来源于环氧乙烷的重复单元，（C）0〜15摩尔％ 环氧基和至少一个反应性官能团，电解质盐化合物和增塑剂具有优异的离子导电性。

公开(公告)号：US09295262B2

公开(公告)日：2016-03-29

申请号：US14122554

申请日：2012-05-30

申请人： Ryo Kato ,  Kanefusa Hara ,  Masanori Yanagida

发明人： Ryo Kato ,  Kanefusa Hara ,  Masanori Yanagida

IPC分类号： C01B11/02 ,  A01N59/08 ,  A01N59/00

CPC分类号： A01N59/08 ,  A01N59/00 ,  C01B11/024 ,  A01N25/08

摘要： Provided is a chlorine dioxide-generating product comprising an inorganic porous carrier carrying a chlorite and an alkali agent. In the product, the alkali agent is carried in an amount of more than 0.7 molar equivalent and not more than 2 molar equivalents relative to the amount of the chlorite carried, and the product has a water content of 10% by weight or less. The chlorine dioxide-generating product can stably generate chlorine dioxide gas in an amount that sufficiently achieves deodorization, sterilization, virus removal, mold prevention, antisepsis, or the like of spatial environments, foods, or others but exerts no harmful effect on humans, over a long period of time.

摘要翻译： 本发明提供了一种二氧化氯产生产物，其包含载有亚氯酸盐和碱剂的无机多孔载体。 在该产品中，相对于所携带的亚氯酸盐的量，碱剂的用量大于0.7摩尔当量且不大于2摩尔当量，并且该产品的含水量为10重量％以下。 产生二氧化氯的产品可以稳定地产生二氧化氯气体，其量足以实现空间环境，食品或其它物质的除臭，杀菌，病毒去除，防霉，防腐等，但不对人造成有害影响 很长一段时间。

公开(公告)号：US06878491B1

公开(公告)日：2005-04-12

申请号：US09417135

申请日：1999-10-13

申请人： Katsuhito Miura ,  Masanori Yanagida ,  Hiroki Higobashi ,  Shouhei Matsui

发明人： Katsuhito Miura ,  Masanori Yanagida ,  Hiroki Higobashi ,  Shouhei Matsui

IPC分类号： H01B1/06 ,  C08F290/14 ,  C08F299/02 ,  C08G65/04 ,  C08G65/14 ,  C08G65/22 ,  C08G77/12 ,  C08K3/00 ,  C08K3/24 ,  C08K5/42 ,  C08L71/02 ,  H01M10/05 ,  H01M10/0565 ,  H01M6/18

CPC分类号： C08G65/22 ,  C08G65/14 ,  H01M10/052 ,  H01M10/0565 ,  H01M2300/0085

摘要： A polyether copolymer having a weight-average molecular weight of 104 to 107, formed from 3 to 30% by mol of a repeating unit derived from propylene oxide, 96 to 69% by mol of a repeating unit derived from ethylene oxide, and 0.01 to 15% by mol of a crosslinkable repeating unit derived from a reactive oxirane compound, gives a provide a crosslinked solid polymer electrolyte which is superior in processability, moldability, mechanical strength, flexibility and heat resistance, and has markedly improved ionic conductivity.

摘要翻译： 重均分子量为10 4〜10 7的聚醚共聚物，由3〜30摩尔％的来源于环氧丙烷的重复单元形成，96〜69摩尔％的衍生自 环氧乙烷，0.01〜15摩尔％的来自反应性环氧乙烷化合物的交联性重复单元，提供加工性，成型性，机械强度，柔软性和耐热性优异的交联固体高分子电解质，并且显着改善 离子电导率。

公开(公告)号：US5968681A

公开(公告)日：1999-10-19

申请号：US958664

申请日：1997-10-28

申请人： Katsuhito Miura ,  Masanori Yanagida ,  Hiroki Higobashi ,  Takahiro Endo

发明人： Katsuhito Miura ,  Masanori Yanagida ,  Hiroki Higobashi ,  Takahiro Endo

IPC分类号： C08G65/14 ,  C08G65/22 ,  C08L71/02 ,  H01B1/12 ,  H01M6/18 ,  H01M6/00

CPC分类号： H01M6/181 ,  C08G65/14 ,  C08G65/22 ,  C08L71/02 ,  H01B1/122

摘要： A polyether copolymer prepared from 5 to 95% by mol of a monomer of the formula (I), 95 to 5% by mol of a monomer of the formula (II) and 0 to 15% by mol of a monomer of the formula (III) or (IV) as a crosslinking component; the copolymer having a weight-average molecular weight within the range from 10.sup.3 to 10.sup.7 : ##STR1## The copolymer of the present invention provides a polymer solid electrolyte having such a feature that it is superior in ionic conductivity and also superior in processability, moldability, mechanical strength and flexibility to a conventional solid electrolyte.

摘要翻译： 将由式（I）的单体为5〜95摩尔％，式（II）的单体为95〜5摩尔％和式（II）的单体为0〜15摩尔％的单体制备的聚醚共聚物， III）或（IV）作为交联组分; 该共聚物的重均分子量在103〜107的范围内。本发明的共聚物提供了具有离子导电性优异，加工性，成型性，机械强度优异的特征的高分子固体电解质， 对常规固体电解质的灵活性。