公开(公告)号：US5276072A

公开(公告)日：1994-01-04

申请号：US985417

申请日：1992-12-04

申请人： Toshiyuki Ishii ,  Mitsuo Yamada ,  Motoi Tanimoto ,  Kenshiro Tobinaga

发明人： Toshiyuki Ishii ,  Mitsuo Yamada ,  Motoi Tanimoto ,  Kenshiro Tobinaga

IPC分类号： C08G59/02 ,  C08G59/04 ,  C08G59/12 ,  C08G59/14 ,  C08G59/16 ,  C08G59/26 ,  C08G59/42 ,  C08G59/50 ,  C08G59/62 ,  C09D5/44 ,  C09D163/00 ,  C08K3/20 ,  C08L63/02

CPC分类号： C09D163/00 ,  C08G59/02 ,  C08G59/04 ,  C08G59/12 ,  C08G59/1444 ,  C08G59/1455 ,  C08G59/26 ,  C08G59/42 ,  C08G59/50 ,  C08G59/62 ,  C09D5/4449

摘要： Oxazolidone ring-containing epoxy resins (a) produced by the reaction between a diglycidyl ether or ester and an organic diisocyanate are reacted with (b) a first active hydrogen compound such as mono- or diols, mono- or dicarboxylic acids in less than a stoichiometric amount in terms of the active hydrogen atom relative to the epoxy group, and then with (c) a second active hydrogen compound such as amines or sulfide-acid mixtures or polycarboxylic acids in a stoichiometric amount relative to the remaining epoxy group. The resulting hydrophilic modified resin has an oxazolidone ring-containing backbone terminated with an ionizable group. A water-borne paints are formulated from the hydrophilic modified resin by dispersing in an aqueous medium containing a crosslinker and a neutralizing agent.

摘要翻译： 通过二缩水甘油醚或酯与有机二异氰酸酯之间的反应制备的含恶唑烷酮环的环氧树脂（a）与（b）第一活性氢化合物如单或二醇，单羧酸或二羧酸在少于一 然后与（c）第二活性氢化合物如胺或硫化物 - 酸混合物或相对于剩余环氧基的化学计量的多元羧酸。 所得亲水改性树脂具有以可离子化基团封端的含恶唑烷酮环的骨架。 通过分散在含有交联剂和中和剂的水性介质中，由亲水改性树脂配制水性涂料。

公开(公告)号：US20060281854A1

公开(公告)日：2006-12-14

申请号：US11449747

申请日：2006-06-09

申请人： Tsuyoshi Imamura ,  Yuki Fujimura ,  Toshiaki Indou ,  Motoi Tanimoto ,  Kanji Takahashi

发明人： Tsuyoshi Imamura ,  Yuki Fujimura ,  Toshiaki Indou ,  Motoi Tanimoto ,  Kanji Takahashi

IPC分类号： C08L31/00

CPC分类号： C09D5/448 ,  C08F220/18 ,  C08F220/34 ,  C25D13/10

摘要： Disclosed is an acrylic copolymer type of cissing inhibitor effective in restraining both of self-cissing and oil cissing. The cissing inhibitor for the cationic electrodeposition coating compositions is a polymer having a number-average molecular weight of 1000 to 50000 obtained by polymerizing a monomer mixture containing (A) a polymerizable unsaturated group-containing monomer having a chain hydrocarbon group with a carbon number of 6 or more and (B) a polymerizable unsaturated group-containing monomer having an amino group, characterized in that the amount of the polymerizable unsaturated group-containing monomer (A) occupied in the above-mentioned monomer mixture is 20% by mass or more, the total amount of the above-mentioned polymerizable unsaturated group-containing monomer (A) and polymerizable unsaturated group-containing monomer (B) is 40% by mass or more and the amount of the above-mentioned polymerizable unsaturated group-containing monomer (B) is larger than that of the above-mentioned polymerizable unsaturated group-containing monomer (A).

摘要翻译： 公开了一种丙烯酸共聚物类型的止痛抑制剂，其有效地抑制自我发瘾和油脂化。 用于阳离子电沉积涂料组合物的起泡抑制剂是通过聚合含有（A）具有碳数为1的链状烃基的可聚合不饱和基团的单体的单体混合物而获得的数均分子量为1000〜50000的聚合物 6以上，（B）具有氨基的可聚合不饱和基团的单体，其特征在于，上述单体混合物中所含的含聚合性不饱和基团的单体（A）的含量为20质量％以上 上述含聚合不饱和基团的单体（A）和含可聚合不饱和基团的单体（B）的总量为40质量％以上，并且上述含聚合不饱和基团的单体（ B）大于上述可聚合不饱和基团的单体（A）。

公开(公告)号：US5360839A

公开(公告)日：1994-11-01

申请号：US45431

申请日：1993-04-13

申请人： Motoi Tanimoto ,  Tatsuo Yoshida ,  Kenshiro Tobinaga ,  Yuji Toyoda

发明人： Motoi Tanimoto ,  Tatsuo Yoshida ,  Kenshiro Tobinaga ,  Yuji Toyoda

IPC分类号： C08F8/32 ,  C08F220/26 ,  C08F220/28 ,  C09D5/44 ,  C08J3/20 ,  C08K3/20 ,  C08L63/00

CPC分类号： C09D5/4473

摘要： Cathodic electrodeposition paints are rendered hardly susceptible to oil droplet-induced craters by incorporating an amine-modified acrylic copolymer of t-butyl (meth)acrylate with a hydroxyl group-containing monomer and an oxirane ring-containing monomer in the form of an aqueous emulsion. The amine-modified acrylic copolymer may be an adduct with a half blocked organic diisocyanate. The paint gives a cured film substantially free from oil droplet-induced craters and having a good adhesion to an overcoating and a good surface smoothness.

摘要翻译： 通过将（甲基）丙烯酸叔丁酯与含羟基的单体和含环氧乙烷环的单体的胺改性的丙烯酸共聚物以水乳液的形式引入，阴极电沉积涂料几乎不易受油滴诱导的凹坑的影响 。 胺改性的丙烯酸共聚物可以是与半封端的有机二异氰酸酯的加合物。 油漆产生基本上没有油滴诱发的凹坑的固化膜，并且对外涂层具有良好的粘附性和良好的表面光滑度。