Thermosetting composition and process for preparing fiber-reinforced composites
    2.
    发明授权
    Thermosetting composition and process for preparing fiber-reinforced composites 有权
    热固性组合物和制备纤维增强复合材料的方法

    公开(公告)号:US09309354B2

    公开(公告)日:2016-04-12

    申请号:US14117878

    申请日:2012-06-06

    摘要: A two-component curable epoxy resin system is disclosed. The resin system includes an epoxy resin component containing at least 80% by weight of a polyglycidyl ether of a polyphenol that has an epoxy equivalent weight of up to about 200 and contains no more than 2% by weight of monohydrolyzed resin species. The system also includes a hardener mixture that has an amino hydrogen equivalent weight of from 35 to 90 and contains at least 90% by weight of a mixture of (i) from 5 to 75% of the combined weight of (i), (ii) and (iii) of one or more compounds that have at least two primary and/or secondary aliphatic amino groups and which have no phenolic groups; (ii) from 10 to 95% of the combined weight of (i), (ii) and (iii) of one or more aminophenol compounds that contain one or more primary and/or secondary aliphatic amino groups and at least one phenolic group and (iii) from 0 to 50% of the combined weight of (i), (ii) and (iii) of one or more phenolic compounds that contain two or more phenolic groups and do not contain primary or secondary amino groups. The epoxy resin component and hardener mixture are present in amounts sufficient to provide from 1.05 to 1.35 equivalents of aliphatic amine hydrogens per equivalent of epoxide groups provided by the epoxy resin component. The system has beneficial curing characteristics that make it useful for producing fiber-reinforced composites in a resin transfer molding process.

    摘要翻译: 公开了一种双组分可固化环氧树脂体系。 该树脂体系包含环氧树脂组分,其含有至少80重量%的多酚的多缩水甘油醚,其环氧当量为至多约200,并且含有不超过2重量%的单水解树脂种类。 该系统还包括具有35至90的氨基氢当量的固化剂混合物,并且含有至少90重量%的(i)(i),(i),(ii)的组合重量的5至75重量% )和(iii)一种或多种具有至少两个伯和/或仲脂族氨基并且不具有酚基的化合物; (ii)含有一个或多个伯和/或仲脂族氨基和至少一个酚基的一种或多种氨基苯酚化合物的(i),(ii)和(iii)的组合重量的10至95% (iii)含有两个或多个酚基并且不含伯或仲氨基的一种或多种酚类化合物的(i),(ii)和(iii)的组合重量的0至50%。 环氧树脂组分和硬化剂混合物的存在量足以提供每环氧树脂组分提供的每当量环氧基团1.05-1.35当量的脂族胺氢。 该系统具有有益的固化特性,使其可用于在树脂传递模塑工艺中生产纤维增强复合材料。

    THERMOSETTING COMPOSITION AND PROCESS FOR PREPARING FIBER-REINFORCED COMPOSITES
    3.
    发明申请
    THERMOSETTING COMPOSITION AND PROCESS FOR PREPARING FIBER-REINFORCED COMPOSITES 有权
    热固化组合物和制备纤维增强复合材料的方法

    公开(公告)号:US20140213698A1

    公开(公告)日:2014-07-31

    申请号:US14117878

    申请日:2012-06-06

    IPC分类号: C08G59/62 C08K7/06

    摘要: A two-component curable epoxy resin system is disclosed. The resin system includes an epoxy resin component containing at least 80% by weight of a polyglycidyl ether of a polyphenol that has an epoxy equivalent weight of up to about 200 and contains no more than 2% by weight of monohydrolyzed resin species. The system also includes a hardener mixture that has an amino hydrogen equivalent weight of from 35 to 90 and contains at least 90% by weight of a mixture of (i) from 5 to 75% of the combined weight of (i), (ii) and (iii) of one or more compounds that have at least two primary and/or secondary aliphatic amino groups and which have no phenolic groups; (ii) from 10 to 95% of the combined weight of (i), (ii) and (iii) of one or more aminophenol compounds that contain one or more primary and/or secondary aliphatic amino groups and at least one phenolic group and (iii) from 0 to 50% of the combined weight of (i), (ii) and (iii) of one or more phenolic compounds that contain two or more phenolic groups and do not contain primary or secondary amino groups. The epoxy resin component and hardener mixture are present in amounts sufficient to provide from 1.05 to 1.35 equivalents of aliphatic amine hydrogens per equivalent of epoxide groups provided by the epoxy resin component. The system has beneficial curing characteristics that make it useful for producing fiber-reinforced composites in a resin transfer molding process.

    摘要翻译: 公开了一种双组分可固化环氧树脂体系。 该树脂体系包含环氧树脂组分,其含有至少80重量%的多酚的多缩水甘油醚,其环氧当量为至多约200,并且含有不超过2重量%的单水解树脂种类。 该系统还包括具有35至90的氨基氢当量的固化剂混合物,并且含有至少90重量%的(i)(i),(i),(ii)的组合重量的5至75重量% )和(iii)一种或多种具有至少两个伯和/或仲脂族氨基并且不具有酚基的化合物; (ii)含有一个或多个伯和/或仲脂族氨基和至少一个酚基的一种或多种氨基苯酚化合物的(i),(ii)和(iii)的组合重量的10至95% (iii)含有两个或多个酚基并且不含伯或仲氨基的一种或多种酚类化合物的(i),(ii)和(iii)的组合重量的0至50%。 环氧树脂组分和硬化剂混合物的存在量足以提供每环氧树脂组分提供的每当量环氧基团1.05-1.35当量的脂族胺氢。 该系统具有有益的固化特性,使其可用于在树脂传递模塑工艺中生产纤维增强复合材料。

    CARBONATE POLYMER BLENDS WITH REDUCED GLOSS
    5.
    发明申请
    CARBONATE POLYMER BLENDS WITH REDUCED GLOSS 审中-公开
    碳酸钙聚合物与减少的GLOSS混合

    公开(公告)号:US20100210778A1

    公开(公告)日:2010-08-19

    申请号:US12679819

    申请日:2008-08-25

    IPC分类号: C08K3/34 C08L23/10 C08L69/00

    摘要: Disclosed is a carbonate polymer blend composition comprising (a) a carbonate polymer, (b) a propylene polymer, (c) a compatibilizing graft copolymer, (d) a polymer selected from a graft modified propylene polymer and/or an alpha-olefin carboxylic acid copolymer, and/or an olefin block copolymer, optionally (e) a filler, (f) optionally a thermoplastic resin other than (a), (b), (c), or (d) and (g) optionally one or more additive selected from stabilizers, pigments, mold release agents, flow enhancers, or antistatic agents. Said carbonate polymer blend composition has a good balance of physical properties, impact resistance, process-ability, and reduced gloss in molded articles.

    摘要翻译: 公开了一种碳酸酯聚合物共混物组合物,其包含(a)碳酸酯聚合物,(b)丙烯聚合物,(c)相容性接枝共聚物,(d)选自接枝改性丙烯聚合物和/或α-烯烃羧酸 酸性共聚物和/或烯烃嵌段共聚物,任选地(e)填料,(f)任选的(a),(b),(c)或(d)和(g) 更多的选自稳定剂,颜料,脱模剂,流动增强剂或抗静电剂的添加剂。 所述碳酸酯聚合物共混物组合物在成型制品中具有良好的物理性能,抗冲击性,加工性能和降低的光泽的平衡。