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1.发明授权Diene-bis-aquo-rhodium(I) complexes, process for preparing them and their use 失效二烯 - 双 - 水 - 铑（I）络合物，其制备方法及其应用公开(公告)号：US07312349B2
公开(公告)日：2007-12-25
申请号：US10570018
申请日：2004-08-10
Applicant: Andreas Rivas-Nass , Gerhard Peter , Jürgen Widmer , Ralf Karch , Oliver Briel
Inventor： Andreas Rivas-Nass , Gerhard Peter , Jürgen Widmer , Ralf Karch , Oliver Briel
CPC classification number: B01J31/2291 , B01J31/2295 , B01J31/24 , B01J2231/321 , B01J2231/323 , B01J2231/643 , B01J2231/645 , B01J2531/822 , C07F15/0073
Abstract: Diene-bis-aquo-rhodium(I) complex of the general formula [Rh(diene)(H2O)2]X where diene is a cyclic diene and X is a noncoordinating anion.
Abstract translation: 具有通式[Rh（二烯）（H 2 O 2）2 X]的二烯 - 双 - 水 - 铑（I）络合物，其中二烯是环状二烯和X 是非配位阴离子。
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公开(公告)号：US06686495B2
公开(公告)日：2004-02-03
申请号：US09977253
申请日：2001-10-16
Applicant: Matthias Beller , Mario Gómez-Andreu , Alexander Zapf , Ralf Karch , Ingo Kleinwächter , Oliver Briel
Inventor： Matthias Beller , Mario Gómez-Andreu , Alexander Zapf , Ralf Karch , Ingo Kleinwächter , Oliver Briel
IPC: C07C266
CPC classification number: C07B37/04
Abstract: A process for the preparation of mono-, bi- or poly-functional biaryls in the presence of a metal complex of the general formula IV as catalyst.
Abstract translation: 在通式IVa催化剂的金属络合物的存在下制备单，双或多官能联芳基的方法。
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公开(公告)号：US07615659B2
公开(公告)日：2009-11-10
申请号：US10533492
申请日：2003-10-30
Applicant: Bernd Kayser , Ralf Karch , Oliver Briel , Ingo Kleinwächter
Inventor： Bernd Kayser , Ralf Karch , Oliver Briel , Ingo Kleinwächter
CPC classification number: C07F15/006
Abstract: The present invention relates to a process for preparing a palladium(0) compound, comprising the reaction of a palladium compound with one or more compounds of the general formula I, II or III in the presence of a base: Term-O—{[Si(R16)(CR19CR17R18)O]v[Si(R20)2O]w}-Term (III). The Palladium(0) compounds are suitable as homogeneous catalysts, as a precursor for preparing homogeneous catalysts, as a precursor for preparing homogeneous catalysts in situ or as a precursor for preparing heterogeneous catalysts.
Abstract translation: 本发明涉及一种制备钯（0）化合物的方法，其包括在碱存在下钯钯化合物与一种或多种通式I，II或III化合物的反应：Term-O - {[ Si（R16）（CR19CR17R18）O] v [Si（R20）2O] w} -Term（III）。 钯（0）化合物适合作为均相催化剂，作为制备均相催化剂的前体，作为原位制备均相催化剂的前体或作为制备非均相催化剂的前体。
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4.发明申请Diene-bis-aquo-rhodium(i) complexes, process for preparing them and their use 失效二烯 - 双 - 铑（ⅰ）络合物，其制备方法及其应用公开(公告)号：US20070142654A1
公开(公告)日：2007-06-21
申请号：US10570018
申请日：2004-08-10
Applicant: Andreas Rivas-Nass , Gerhard Peter , Jurgen Widmer , Ralf Karch , Oliver Briel
Inventor： Andreas Rivas-Nass , Gerhard Peter , Jurgen Widmer , Ralf Karch , Oliver Briel
CPC classification number: B01J31/2291 , B01J31/2295 , B01J31/24 , B01J2231/321 , B01J2231/323 , B01J2231/643 , B01J2231/645 , B01J2531/822 , C07F15/0073
Abstract: Diene-bis-aquo-rhodium(I) complex of the general formula [Rh(diene)(H2O)2]X where diene is a cyclic diene and X is a noncoordinating anion.
Abstract translation: 具有通式[Rh（二烯）（H 2 O 2）2 X]的二烯 - 双 - 水 - 铑（I）络合物，其中二烯是环状二烯和X 是非配位阴离子。
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Patent Agency Ranking
5.发明申请Use of a Phosphorus Containing Ligand and a Cyclic Organic Ligand in a Transition Metal Compound 有权在过渡金属化合物中使用含有配体和循环有机配体的磷公开(公告)号：US20080221345A1
公开(公告)日：2008-09-11
申请号：US11995442
申请日：2006-07-12
Applicant: Roland Winde , Ralf Wilhelm Karch , Andreas Rivas-Nass , Oliver Briel , Robert Paul Tooze , Grant Stephen Forman , Wolfgang Hubert Meyer
Inventor： Roland Winde , Ralf Wilhelm Karch , Andreas Rivas-Nass , Oliver Briel , Robert Paul Tooze , Grant Stephen Forman , Wolfgang Hubert Meyer
IPC: C07F15/00
CPC classification number: C07F15/0046 , B01J31/2265 , B01J31/2419 , B01J2231/543 , B01J2531/821 , C07C6/04 , C07C2531/24 , C07C11/02
Abstract: According to the present invention there is provided a compound in the form of a transition metal compound including a transition metal, a phosphorus containing ligand, and a cyclic organic ligand. The phosphorus containing ligand is a heterocyclic organic compound with a ligating phosphorus atom which ligates with the transition metal, and which ligating phosphorus atom is an atom in the heterocyclic ring structure of the heterocyclic organic compound. The cyclic organic ligand is a cyclic organic compound with a ligating carbon atom in the cyclic ring structure of the cyclic organic compound which ligates with the transition metal by means of a double bound. The invention also relates to a method preparing such a compound and a metathesis reaction wherein such a compound is used as a catalyst.
Abstract translation: 根据本发明，提供了包含过渡金属，含磷配位体和环状有机配体的过渡金属化合物形式的化合物。 含磷配体是具有连接磷原子的杂环有机化合物，其与过渡金属连接，并且其中连接的磷原子是杂环有机化合物的杂环结构中的原子。 环状有机配体是在环状有机化合物的环状结构中具有连接碳原子的环状有机化合物，其通过双键与过渡金属连接。 本发明还涉及制备这种化合物的方法和复分解反应，其中使用这种化合物作为催化剂。
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6.发明申请Novel nickel-carbene, palladium-carbene and platinum-carbene complexes, their produciton and use in catalytic reactions 有权新的镍 - 卡宾，钯 - 卡宾和铂 - 卡宾络合物，它们的生产和用于催化反应公开(公告)号：US20060122398A1
公开(公告)日：2006-06-08
申请号：US10523894
申请日：2003-08-07
Applicant: Ralf Karch , Oliver Briel , Bernd Kayser , Matthias Beller , Kumaravel Selvakumar , Anja Frisch , Alexander Zapf
Inventor： Ralf Karch , Oliver Briel , Bernd Kayser , Matthias Beller , Kumaravel Selvakumar , Anja Frisch , Alexander Zapf
IPC: C07F15/00 , C07C319/02 , C07F7/20
CPC classification number: B01J31/2291 , B01J31/2265 , B01J31/2273 , B01J31/2295 , B01J2231/20 , B01J2231/30 , B01J2231/4205 , B01J2531/824 , B01J2531/828 , B01J2531/847 , C07F15/006 , C07F15/0086 , C07F15/04
Abstract: The invention relates to novel monocarbene complexes of nickel, palladium or platinum with electron-deficient olefin ligands, to their preparation and to their use in the homogeneous catalysis of organic reactions.
Abstract translation: 本发明涉及镍，钯或铂与电子缺乏烯烃配体的新颖单烯烃络合物，其制备及其在均相催化有机反应中的应用。
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7.发明授权Use of a phosphorus containing ligand and a cyclic organic ligand in a transition metal compound 有权在过渡金属化合物中使用含磷配体和环状有机配体公开(公告)号：US07671224B2
公开(公告)日：2010-03-02
申请号：US11995442
申请日：2006-07-12
Applicant: Roland Winde , Ralf Wilhelm Karch , Andreas Rivas-Nass , Oliver Briel , Robert Paul Tooze , Grant Stephen Forman , Wolfgang Hubert Meyer
Inventor： Roland Winde , Ralf Wilhelm Karch , Andreas Rivas-Nass , Oliver Briel , Robert Paul Tooze , Grant Stephen Forman , Wolfgang Hubert Meyer
CPC classification number: C07F15/0046 , B01J31/2265 , B01J31/2419 , B01J2231/543 , B01J2531/821 , C07C6/04 , C07C2531/24 , C07C11/02
Abstract: According to the present invention there is provided a compound in the form of a transition metal compound including a transition metal, a phosphorus containing ligand, and a cyclic organic ligand. The phosphorus containing ligand is a heterocyclic organic compound with a ligating phosphorus atom which ligates with the transition metal, and which ligating phosphorus atom is an atom in the heterocyclic ring structure of the heterocyclic organic compound. The cyclic organic ligand is a cyclic organic compound with a ligating carbon atom in the cyclic ring structure of the cyclic organic compound which ligates with the transition metal by means of a double bound. The invention also relates to a method preparing such a compound and a metathesis reaction wherein such a compound is used as a catalyst.
Abstract translation: 根据本发明，提供了包含过渡金属，含磷配位体和环状有机配体的过渡金属化合物形式的化合物。 含磷配体是具有连接磷原子的杂环有机化合物，其与过渡金属连接，并且其中连接的磷原子是杂环有机化合物的杂环结构中的原子。 环状有机配体是在环状有机化合物的环状结构中具有连接碳原子的环状有机化合物，其通过双键与过渡金属连接。 本发明还涉及制备这种化合物的方法和复分解反应，其中使用这种化合物作为催化剂。
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8.发明授权Nickel-carbene, palladium-carbene and platinum-carbene complexes, their production and use in catalytic reactions 有权镍 - 卡宾，钯 - 卡宾和铂 - 卡宾络合物，它们的生产和用于催化反应公开(公告)号：US07268233B2
公开(公告)日：2007-09-11
申请号：US10523894
申请日：2003-08-07
Applicant: Ralf Karch , Oliver Briel , Bernd Kayser , Matthias Beller , Kumaravel Selvakumar , Anja Frisch , Alexander Zapf
Inventor： Ralf Karch , Oliver Briel , Bernd Kayser , Matthias Beller , Kumaravel Selvakumar , Anja Frisch , Alexander Zapf
CPC classification number: B01J31/2291 , B01J31/2265 , B01J31/2273 , B01J31/2295 , B01J2231/20 , B01J2231/30 , B01J2231/4205 , B01J2531/824 , B01J2531/828 , B01J2531/847 , C07F15/006 , C07F15/0086 , C07F15/04
Abstract: The invention relates to novel monocarbene complexes of nickel, palladium or platinum with electron-deficient olefin ligands, to their preparation and to their use in the homogeneous catalysis of organic reactions.
Abstract translation: 本发明涉及镍，钯或铂与电子缺乏烯烃配体的新颖单烯烃络合物，其制备及其在均相催化有机反应中的应用。
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公开(公告)号：US20060106239A1
公开(公告)日：2006-05-18
申请号：US10533492
申请日：2003-10-30
Applicant: Bernd Kayser , Ralf Karch , Oliver Briel , Ingo Kleinwachter
Inventor： Bernd Kayser , Ralf Karch , Oliver Briel , Ingo Kleinwachter
IPC: C07F15/00
CPC classification number: C07F15/006
Abstract: The present invention relates to a process for preparing a palladium(0) compound, comprising the reaction of a palladium compound with one or more compounds of the general formula I, II or III in the presence of a base: Term-O—{[Si(R16)(CR19CR17R18)O]v[Si(R20)2O]w}-Term (III). The Palladium(0) compounds are suitable as homogeneous catalysts, as a precursor for preparing homogeneous catalysts, as a precursor for preparing homogeneous catalysts in situ or as a precursor for preparing heterogeneous catalysts.
Abstract translation: 本发明涉及一种制备钯（0）化合物的方法，包括钯化合物与一种或多种通式I，II或III化合物在碱存在下的反应： 公式描述=“在线公式”end =“lead”？术语-O - {[Si（R 16）16（CR 16）
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