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    Process for catalytically preparing aromatic or heteroaromatic nitriles
    7.
    发明授权
    Process for catalytically preparing aromatic or heteroaromatic nitriles 有权
    用于催化制备芳族或杂芳族腈的方法

    公开(公告)号：US08314243B2

    公开(公告)日：2012-11-20

    申请号：US11986398

    申请日：2007-11-21

    申请人： Nikolaus Müller ,  Wolfgang Mägerlein ,  Alain Cotté ,  Matthias Beller ,  Thomas Schareina ,  Alexander Zapf

    发明人： Nikolaus Müller ,  Wolfgang Mägerlein ,  Alain Cotté ,  Matthias Beller ,  Thomas Schareina ,  Alexander Zapf

    IPC分类号： C07D211/78 ,  A01N43/38

    CPC分类号： C07B37/04 ,  C07C1/26 ,  C07C17/10 ,  C07C2529/40 ,  C07D213/61 ,  C07C9/00 ,  C07C19/075

    摘要： A process is described for catalytically preparing optionally substituted aromatic or heteroaromatic nitrites of the general formula (I) Ar—CN  (I) by reacting the corresponding aryl halides of the general formula (II) Ar—X  (II) in which X is chlorine, bromine, iodine, triflate, nonaflate, mesylate or tosylate and Ar is an optionally substituted aromatic or heteroaromatic radical, characterized in that the reaction is performed in the presence of a palladium compound, a phosphine of the general formula (III) or (IV) where R is an alkyl radical and R′, R″ and R′″ are each an alkyl radical or an aryl radical or heteroaryl radical and A is an alkylene or arylene radical, and potassium hexacyanoferrate(II) or potassium hexacyanoferrate(III), optionally in a solvent and optionally with addition of a base.

    摘要翻译： 描述了通过使通式（II）Ar-X（II）的相应芳基卤反应其中X为氯的方法催化制备通式（I）Ar-CN（I）的任选取代的芳族或杂芳族亚硝酸盐的方法 溴，碘，三氟甲磺酸酯，壬酸酯，甲磺酸酯或甲苯磺酸酯，Ar是任选取代的芳族或杂芳族基团，其特征在于反应在钯化合物，通式（III）或（IV） ）其中R是烷基，R'，R“和R”“各自是烷基或芳基或杂芳基，A是亚烷基或亚芳基，六氰基铁酸钾（II）或六氰基铁酸钾（III） ，任选地在溶剂中和任选地加入碱。

    Phosphanes, their method of production and use in metal complexes
    10.
    发明授权
    Phosphanes, their method of production and use in metal complexes 失效
    磷化物，它们的生产和使用方法在金属络合物中

    公开(公告)号：US06225504B1

    公开(公告)日：2001-05-01

    申请号：US09331826

    申请日：1999-06-23

    申请人： Sandra Bogdanovic ,  Matthias Beller ,  Alexander Zapf ,  Jurgen Krauter

    发明人： Sandra Bogdanovic ,  Matthias Beller ,  Alexander Zapf ,  Jurgen Krauter

    IPC分类号： C07F950

    CPC分类号： B01J31/2404 ,  B01J31/20 ,  B01J31/2447 ,  B01J2231/321 ,  B01J2231/4205 ,  B01J2231/4211 ,  B01J2231/4261 ,  B01J2531/0272 ,  B01J2531/821 ,  B01J2531/824 ,  C07H15/203 ,  Y02P20/55

    摘要： A process for the preparation of the formula Ar13−xP[(Ar2(OZ)y]x  I wherein Ar1 and Ar2 are individually aromatic of 6 to 20 carbon atoms or heteroaromatic of 4 to 9 carbon atoms, each unsubstituted or substituted with at least one member of the group consisting of halogen, carboxyl, —OH, alkyl of 1 to 6 carbon atoms, phenyl and naphthyl, Ar1 has one valence and R2 has y+1 valences, x is an integer of 1, 2 or 3, y is 1 or 2, Z is carbohydrate with a glycosidic bond comprising reacting a hydrocarbon halide of the formula Z′—X  II when Z′ has the definition of Z with —OH protected and X is chlorine, bromine or fluorine with a phosphane of the formula Ar13−xP[(Ar2 (OH)y]x  III in a multi-phase reaction medium in the presence of a base and a phase transfer catalyst to form a phosphane of the formula Ar13−xP[(Ar2(OZ1)y]x  IV and removal of the protective groups to form a compound of Formula I, metal complexes thereof and various processes.

    摘要翻译： 制备糠醛的方法Ar1和Ar2分别为6至20个碳原子的芳族或4至9个碳原子的杂芳族化合物，每个未取代或被至少一个由卤素，羧基，-OH， 具有1至6个碳原子的烷基，苯基和萘基，Ar 1具有一个化合价，R 2具有y + 1价，x是1,2或3的整数，y是1或2，Z是具有糖苷键的碳水化合物， 在碱和相转移催化剂存在下形成多相反应介质的烃卤化物，以形成下式的膦并除去保护基以形成式I化合物，其金属络合物和各种方法。