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公开(公告)号：US20150024106A1
公开(公告)日：2015-01-22
申请号：US14378565
申请日：2013-02-12
申请人： Thomas Hüller , Juergen Haberland , Olivier Zehnacker , Karl Ludovici , Gerda Oswald , Ulrich Bongers
发明人： Thomas Hüller , Juergen Haberland , Olivier Zehnacker , Karl Ludovici , Gerda Oswald , Ulrich Bongers
IPC分类号： A23G3/38
摘要： The invention relates to processes for producing hard sweets from isomalt while maintaining strict pHs, and also to mixed compositions containing isomalt and optionally pH buffer substances having a defined pH.
摘要翻译： 本发明涉及从异麦芽酮糖制造硬糖同时保持严格的pH值的方法，以及含有异麦芽酮糖醇和任选的具有规定pH值的pH缓冲物质的混合组合物。
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公开(公告)号：US20120247144A1
公开(公告)日：2012-10-04
申请号：US13514167
申请日：2010-11-24
IPC分类号： F25B15/06 , C10M169/04
摘要： The invention relates to an operating medium for an absorption refrigeration device, comprising 5 to 30 wt % water and 65 to 95 wt % of a sorption agent comprising lithium bromide and at least one ionic liquid and wherein the sorption agent comprises ionic liquid and lithium bromide in a weight ratio of 0.5:1 to 5:1, having a lower friction coefficient compared to an operating medium comprising water and lithium bromide.
摘要翻译： 本发明涉及一种用于吸收式制冷装置的操作介质，包括5至30重量％的水和65至95重量％的包含溴化锂和至少一种离子液体的吸附剂，其中所述吸附剂包括离子液体和溴化锂 重量比为0.5：1至5：1，与包含水和溴化锂的操作介质相比具有较低的摩擦系数。
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公开(公告)号：US20110257429A1
公开(公告)日：2011-10-20
申请号：US13141456
申请日：2010-02-01
申请人： Alexander Schraven , Thomas Tacke , Thomas Haas , Christoph Kobler , Dieter Buss , Axel Ronneburg , Olivier Zehnacker
发明人： Alexander Schraven , Thomas Tacke , Thomas Haas , Christoph Kobler , Dieter Buss , Axel Ronneburg , Olivier Zehnacker
CPC分类号： C07C51/02 , C07C59/00 , C07C55/10 , C07C59/01 , C07C55/00 , C07C65/00 , C07C59/08 , C07C63/00
摘要： The invention relates to an improved method for releasing an organic acid, preferably a carbon, sulfone or phosphone acid, particularly an alpha or beta hydroxycarbon acid, from the ammonia salt thereof by releasing and removing ammoniac and simultaneous extraction of the released acid, having an amine as a suitable extraction means from the aqueous phase. This method corresponds to a reactive extraction. The reactive extraction of an organic acid from the aqueous ammonia salt solution thereof can be significantly improved by the use of a strip medium or carrier gas, such as nitrogen, air, water vapor or inert gases such as argon. The released ammoniac is removed from the aqueous solution by the continuous gas flow and can be resupplied into a production process. The free acid can be obtained by a method such as distillation, rectification, crystallization, reextraction, chromatography, adsorption or by a membrane method from the extraction means.
摘要翻译： 本发明涉及通过释放和除去氨和同时提取释放的酸的有机酸，优选碳，砜或膦酸，特别是α或β羟基碳酸从其氨盐释放的改进方法，其具有 胺作为来自水相的合适的提取方法。 该方法对应于反应萃取。 通过使用带状介质或载气如氮气，空气，水蒸汽或惰性气体如氩气，可以显着地改善有机酸从其氨水溶液中的反应萃取。 通过连续气流将释放的氨水从水溶液中除去，并且可以再供给到生产过程中。 游离酸可以通过蒸馏，精馏，结晶，再萃取，色谱法，吸附法或从提取方法通过膜法等方法得到。
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公开(公告)号：US08809576B2
公开(公告)日：2014-08-19
申请号：US13141456
申请日：2010-02-01
申请人： Alexander Schraven , Thomas Tacke , Thomas Haas , Christoph Kobler , Dieter Buss , Axel Ronneburg , Olivier Zehnacker
发明人： Alexander Schraven , Thomas Tacke , Thomas Haas , Christoph Kobler , Dieter Buss , Axel Ronneburg , Olivier Zehnacker
IPC分类号： C07F9/22
CPC分类号： C07C51/02 , C07C59/00 , C07C55/10 , C07C59/01 , C07C55/00 , C07C65/00 , C07C59/08 , C07C63/00
摘要： The invention relates to an improved method for releasing an organic acid, preferably a carbon, sulfone or phosphone acid, particularly an alpha or beta hydroxycarbon acid, from the ammonia salt thereof by releasing and removing ammoniac and simultaneous extraction of the released acid, having an amine as a suitable extraction means from the aqueous phase. This method corresponds to a reactive extraction. The reactive extraction of an organic acid from the aqueous ammonia salt solution thereof can be significantly improved by the use of a strip medium or carrier gas, such as nitrogen, air, water vapor or inert gases such as argon. The released ammoniac is removed from the aqueous solution by the continuous gas flow and can be resupplied into a production process. The free acid can be obtained by a method such as distillation, rectification, crystallization, reextraction, chromatography, adsorption or by a membrane method from the extraction means.
摘要翻译： 本发明涉及通过释放和除去氨和同时提取释放的酸的有机酸，优选碳，砜或膦酸，特别是α或β羟基碳酸从其氨盐中释放的改进方法，其具有 胺作为来自水相的合适的提取方法。 该方法对应于反应萃取。 通过使用带状介质或载气如氮气，空气，水蒸汽或惰性气体如氩气，可以显着地改善有机酸从其氨水溶液中的反应萃取。 通过连续气流将释放的氨水从水溶液中除去，并且可以再供给到生产过程中。 游离酸可以通过蒸馏，精馏，结晶，再萃取，色谱法，吸附法或从提取方法通过膜法等方法得到。
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公开(公告)号：US08703451B2
公开(公告)日：2014-04-22
申请号：US13002519
申请日：2009-04-29
申请人： Thomas Haas , Thomas Tacke , Achim Marx , Alexander Schraven , Olivier Zehnacker , Eva Maria Wittmann
发明人： Thomas Haas , Thomas Tacke , Achim Marx , Alexander Schraven , Olivier Zehnacker , Eva Maria Wittmann
CPC分类号： C12P7/40 , C07C51/02 , C07C51/41 , C07C51/47 , C12P7/42 , C07C59/01 , C07C59/06 , C07C59/255 , C07C59/08 , C07C59/265
摘要： A process for the preparation of free carboxylic acids including: A) preparation of carboxylic acid by a biological cell located in an aqueous medium with addition of an amine of formula (I) where R1, R2 and R3, independently of one another, are identical or different, branched or unbranched, optionally substituted hydrocarbon radicals or H; B) for cases where the added amine A) is water-soluble, addition of a water-insoluble amine of formula (I), where, in A) or B), a multiphase system is obtained and the corresponding ammonium carboxylate is formed from the water-insoluble amine and the carboxylic acid; C) removal of the water-insoluble phase; and D) heating of the water-insoluble phase with release of free carboxylic acid.
摘要翻译： 一种制备游离羧酸的方法，包括：A）通过加入式（I）的胺的位于水性介质中的生物细胞制备羧酸，其中R1，R2和R3彼此独立地相同 或不同的支链或非支链的任选取代的烃基或H; B）对于添加的胺A）是水溶性的，加入式（I）的水不溶性胺，其中在A）或B）中获得多相体系，并且相应的羧酸铵由 水不溶性胺和羧酸; C）去除水不溶性相; 和D）释放游离羧酸时加热水不溶性相。
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6.发明申请ABSORPTION HEAT PUMP AND SORBENT FOR AN ABSORPTION HEAT PUMP COMPRISING METHANESULFONIC ACID 审中-公开吸收式热泵和吸收式吸收热泵包含甲磺酸公开(公告)号：US20150308720A1
公开(公告)日：2015-10-29
申请号：US14646516
申请日：2013-11-05
CPC分类号： F25B15/02 , C09K5/047 , C09K5/10 , F25B30/04 , Y02A30/277 , Y02B30/62 , Y02P20/124
摘要： The invention relates to the use of methanesulphonic acid as sorption medium in an absorption heat pump; a sorption medium for an absorption heat pump which comprises methanesulphonic acid and an ionic liquid; and an absorption heat pump having an absorber, a desorber, a condenser, an evaporator and a working medium comprising a volatile refrigerant and a sorption medium, wherein the sorption medium comprises methanesulphonic acid.
摘要翻译： 本发明涉及甲磺酸作吸附介质在吸收式热泵中的应用; 用于吸收热泵的吸附介质，其包含甲磺酸和离子液体; 以及具有吸收器，解吸器，冷凝器，蒸发器和包含挥发性制冷剂和吸附介质的工作介质的吸收式热泵，其中所述吸附介质包含甲磺酸。
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公开(公告)号：US08696928B2
公开(公告)日：2014-04-15
申请号：US13514167
申请日：2010-11-24
IPC分类号： C09K5/10
摘要： The invention relates to an operating medium for an absorption refrigeration device, comprising 5 to 30 wt % water and 65 to 95 wt % of a sorption agent comprising lithium bromide and at least one ionic liquid and wherein the sorption agent comprises ionic liquid and lithium bromide in a weight ratio of 0.5:1 to 5:1, having a lower friction coefficient compared to an operating medium comprising water and lithium bromide.
摘要翻译： 本发明涉及一种用于吸收式制冷装置的操作介质，包括5至30重量％的水和65至95重量％的包含溴化锂和至少一种离子液体的吸附剂，其中所述吸附剂包括离子液体和溴化锂 重量比为0.5：1至5：1，与包含水和溴化锂的操作介质相比具有较低的摩擦系数。
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公开(公告)号：US20130219949A1
公开(公告)日：2013-08-29
申请号：US13883573
申请日：2011-11-04
摘要： A working medium comprising at least one refrigerant, at least one monohydric aliphatic alcohol having from 6 to 10 carbon atoms and at least one ionic liquid composed of at least one organic cation and at least one anion shows an improved efficiency COP in an absorption heat pump compared to working media which do not contain an alcohol having from 6 to 10 carbon atoms.
摘要翻译： 包含至少一种制冷剂，至少一种具有6-10个碳原子的一元脂族醇和至少一种由至少一种有机阳离子和至少一种阴离子组成的离子液体的工作介质显示出在吸收式热泵中提高的COP效率 与不含有6至10个碳原子的醇的工作介质相比。
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9.发明申请ABSORPTION HEAT PUMP WITH SORBENT COMPRISING A LITHIUM SALT AND AN ORGANIC SALT WITH THE SAME ANION 审中-公开具有包含盐酸盐和有机酸的阳离子吸收热泵公开(公告)号：US20130031931A1
公开(公告)日：2013-02-07
申请号：US13641692
申请日：2011-04-18
IPC分类号： F25B15/00
摘要： An absorption heat pump with a sorbent comprising a lithium salt and at least one organic salt with an organic cation Q+, the lithium salt and organic salt having the same anion, the anion having a molar mass of not more than 200 g/mol and not being halide, and the organic cation Q+ having a molar mass of not more than 200 g/mol, exhibits an improved degassing range of the working medium composed of refrigerant and sorbent.
摘要翻译： 一种具有吸附剂的吸收热泵，其包含锂盐和至少一种有机阳离子Q +的有机盐，所述锂盐和有机盐具有相同的阴离子，所述阴离子的摩尔质量不大于200g / mol，而不是 是卤化物，摩尔质量不大于200g / mol的有机阳离子Q +表现出由制冷剂和吸附剂组成的工作介质的脱气范围的改善。
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10.发明申请ABSORPTION HEAT PUMP WITH SORBENT COMPRISING LITHIUM CHLORIDE AND AN ORGANIC CHLORIDE SALT 审中-公开具有氯化锂和有机氯化物盐的吸收吸热泵公开(公告)号：US20130031930A1
公开(公告)日：2013-02-07
申请号：US13641591
申请日：2011-04-14
IPC分类号： F25B15/00
摘要： An absorption heat pump with a sorbent which comprises lithium chloride and at least one salt Q+Cl− with an organic cation Q+ and the shared anion chloride, the organic cation Q+ having a molar mass of not more than 200 g/mol, exhibits an improved degassing range of the working medium composed of refrigerant and sorbent.
摘要翻译： 具有吸附剂的吸收热泵包括氯化锂和至少一种具有有机阳离子Q +的盐Q + Cl-和共用阴离子氯化物，摩尔质量不超过200g / mol的有机阳离子Q +表现出 改善由制冷剂和吸附剂组成的工作介质的脱气范围。
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