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    Method for the preparation of olefin polymerisation catalyst
    1.
    发明授权
    Method for the preparation of olefin polymerisation catalyst 失效
    烯烃聚合催化剂的制备方法

    公开(公告)号：US08143184B2

    公开(公告)日：2012-03-27

    申请号：US11597865

    申请日：2005-06-02

    申请人： Thomas Garoff ,  Päivi Waldvogel

    发明人： Thomas Garoff ,  Päivi Waldvogel

    IPC分类号： B01J31/02 ,  B01J31/04 ,  C08F4/64 ,  C08F4/646

    CPC分类号： C08F10/00 ,  C08F4/6548 ,  C08F4/6546 ,  C08F4/6555

    摘要： The invention is directed to a process for producing an olefin polymerization catalyst wherein a solution of a soluble magnesium complex containing an element of is Group 13 or 14 of the Periodic Table (IUPAC) is contacted with a halogen containing transition metal compound of Group 3 to 10 of the Periodic Table (IUPAC) to obtain a solid catalyst complex comprising as essential components Mg, said element of is Group 13 or 14 of the Periodic Table (IUPAC) and said transition metal compound.

    摘要翻译： 本发明涉及一种生产烯烃聚合催化剂的方法，其中含有元素周期表（IUPAC）的第13或14族的可溶性镁络合物的溶液与第3族的含卤素的过渡金属化合物接触， 10的元素周期表（IUPAC），以获得包含作为必需组分Mg的固体催化剂络合物，所述元素是元素周期表（IUPAC）的第13或14族和所述过渡金属化合物。

    Method for the preparation of olefin polymerization catalysts
    3.
    发明授权
    Method for the preparation of olefin polymerization catalysts 有权
    烯烃聚合催化剂的制备方法

    公开(公告)号：US07238637B2

    公开(公告)日：2007-07-03

    申请号：US10515997

    申请日：2002-12-18

    申请人： Thomas Garoff ,  Kari Pesonen ,  Päivi Waldvogel ,  Timo V. Laine ,  Peter Denifl ,  Jarmo Lindroos

    发明人： Thomas Garoff ,  Kari Pesonen ,  Päivi Waldvogel ,  Timo V. Laine ,  Peter Denifl ,  Jarmo Lindroos

    IPC分类号： C08F4/642 ,  C08F4/64 ,  C08F4/02

    CPC分类号： C08F10/00 ,  C08F4/651 ,  C08F4/6546 ,  C08F4/6555

    摘要： The invention provides a process for producing an olefin polymerization catalyst comprising a catalyst component formed by contacting at least (a) a compound of Group 1 to 3 of the Periodic Table (IUPAC) with (b) a transition metal compound of Group 4 to 10 of the Periodic Table (IUPAC) or a compound of an actinide or lanthanide, in the form of solid catalyst particles, said process comprising: (1) preparing a solution from said compounds; (2) dispersing said solution to a solvent immiscible therewith and inert in relation to said compounds, to obtain an emulsion in which said solution forms the dispersed phase; and (3) solidifying the catalyst component in the dispersed droplets.

    摘要翻译： 本发明提供了一种生产烯烃聚合催化剂的方法，其包括通过使（a）元素周期表（IUPAC）中第1至3族的化合物与（b）第4族至第10族的过渡金属化合物 的周期表（IUPAC）或者以固体催化剂颗粒的形式的锕系元素或镧系元素的化合物，所述方法包括：（1）制备所述化合物的溶液; （2）将所述溶液分散到与其不混溶的溶剂中，并相对于所述化合物惰性，得到其中所述溶液形成分散相的乳液; 和（3）在分散的液滴中固化催化剂组分。

    Process for producing a homogeneous polyethylene material in the presence of a catalyst
    4.
    发明授权
    Process for producing a homogeneous polyethylene material in the presence of a catalyst 有权
    在催化剂存在下制备均匀的聚乙烯材料的方法

    公开(公告)号：US06455642B1

    公开(公告)日：2002-09-24

    申请号：US09674854

    申请日：2000-11-07

    申请人： Ole Jan Myhre ,  Auli Nummila-Pakarinen ,  Jarmo Lindroos ,  Päivi Waldvogel ,  Thomas Garoff

    发明人： Ole Jan Myhre ,  Auli Nummila-Pakarinen ,  Jarmo Lindroos ,  Päivi Waldvogel ,  Thomas Garoff

    IPC分类号： C08F444

    CPC分类号： C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08L23/06 ,  C08L2205/02 ,  Y10S526/901 ,  Y10S526/905 ,  C08F4/651 ,  C08F4/6555 ,  C08F2/001 ,  C08L2666/04 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/19 ,  C08F2500/02 ,  C08F2500/01

    摘要： The present invention concerns a process for producing homogeneous polyethylene materials and processes for making high density, medium density and low density films therefrom. The process involves producing a polyethylene composition in a multistage reaction sequence of successive polymerization stages in the presence of an ethylene-polymerizing catalyst system. According to the invention, the process is carried out using an unsupported catalyst having magnesium and titanium as active constituents, in at least one loop polymerization stage and at least one gas phase polymerization stage and, operated with different amounts of hydrogen and comonomers to produce a high molecular weight portion in one of the polymerization stages and a low molecular weight portion in another so as to provide a polyethylene composition with the low molecular weight part having a MFR2 of 250 g/10 min or more. With this process it is possible to obtain homogeneous bimodal polyethylene material.

    摘要翻译： 本发明涉及用于制造均匀的聚乙烯材料的方法和由其制备高密度，中密度和低密度的薄膜的方法。 该方法包括在乙烯聚合催化剂体系的存在下，在连续聚合阶段的多阶段反应顺序中制备聚乙烯组合物。 根据本发明，该方法使用具有镁和钛作为活性成分的无载体催化剂，在至少一个环聚合阶段和至少一个气相聚合阶段中进行，并且用不同量的氢和共聚单体操作以产生 在一个聚合阶段中的高分子量部分和另一个聚合阶段中的低分子量部分，从而提供具有250g / 10分钟以上的MFR 2的低分子量部分的聚乙烯组合物。 通过该方法，可以获得均匀的双峰聚乙烯材料。

    MULTI-STAGE PROCESS FOR PRODUCING MULTI-MODAL LINEAR LOW DENSITY POLYETHYLENE
    6.
    发明申请
    MULTI-STAGE PROCESS FOR PRODUCING MULTI-MODAL LINEAR LOW DENSITY POLYETHYLENE 有权
    用于生产多模式线性低密度聚乙烯的多级方法

    公开(公告)号：US20110263801A1

    公开(公告)日：2011-10-27

    申请号：US13126496

    申请日：2010-02-22

    申请人： Thomas Garoff ,  Päivi Waldvogel ,  Kalle Kallio ,  Virginie Eriksson ,  Aki Aittola ,  Esa Kokko

    发明人： Thomas Garoff ,  Päivi Waldvogel ,  Kalle Kallio ,  Virginie Eriksson ,  Aki Aittola ,  Esa Kokko

    IPC分类号： C08F10/02 ,  C08F4/685 ,  C08F2/34 ,  C08F2/12

    CPC分类号： C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F2410/03 ,  Y10T428/139 ,  C08F4/6357 ,  C08F4/685 ,  C08F2/001 ,  C08F2500/07 ,  C08F2500/12 ,  C08F2500/05 ,  C08F2500/18 ,  C08F210/14 ,  C08F2500/08

    摘要： Multi-stage polymerization process for the production of a multi-modal linear low density polyethylene in at least two staged reactors connected in series comprising at least (i) polymerizing in a first slurry phase stage ethylene monomers and optionally one or more alpha-olefin comonomers, in the presence of a Ziegler-Natta polymerization catalyst system to obtain a first polyethylene fraction component (A) (ii) polymerizing in a second gas or slurry phase stage ethylene monomers and one or more alpha-olefine comonomers, in the presence of a Ziegler-Natta polymerization catalyst system to obtain a second polyethylene fraction component (B), whereby the Ziegler-Natta polymerization catalyst system comprises: 1) a solid procatalyst formed by contacting at least: a) a Mg-alcoholate complex of the formula (I): Mg(OR1)2-n(R1)n, wherein each R1 independently represents a C1-C20 hydrocarbyl group and 0

    摘要翻译： 用于在至少两个串联反应器中连续串联生产多模式线性低密度聚乙烯的多级聚合方法，包括至少（i）在第一浆料相阶段聚合乙烯单体和任选的一种或多种α-烯烃共聚单体 在齐格勒 - 纳塔聚合催化剂体系存在下，得到第一聚乙烯级分组分（A）（ⅱ）在第二种气相或淤浆相阶段中聚合乙烯单体和一种或多种α-烯烃共聚单体，在 齐格勒 - 纳塔聚合催化剂体系，以获得第二聚乙烯部分组分（B），由此齐格勒 - 纳塔聚合催化剂体系包括：1）通过使至少与下式接触形成的固体前催化剂：a）式 ）：Mg（OR 1）2-n（R 1）n，其中每个R 1独立地表示C 1 -C 20烃基且0

    Olefin polymerization catalyst component, its preparation and use
    9.
    发明授权
    Olefin polymerization catalyst component, its preparation and use 有权
    烯烃聚合催化剂组分，其制备和应用

    公开(公告)号：US06620758B1

    公开(公告)日：2003-09-16

    申请号：US09286437

    申请日：1999-04-06

    申请人： Jarmo Lindroos ,  Solveig Johansson ,  Päivi Waldvogel

    发明人： Jarmo Lindroos ,  Solveig Johansson ,  Päivi Waldvogel

    IPC分类号： B01J3100

    CPC分类号： C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08L23/04 ,  C08L2205/02 ,  C08L2314/02 ,  C08F4/025 ,  C08F4/6555 ,  C08L2666/04 ,  C08F2500/12 ,  C08F2500/17

    摘要： A catalyst having high activity independent of the hydrogen concentration and low gel productivity in the polymerization of ethylene has been prepared. The preparation comprises the steps of reacting: a support comprising a magnesium halide compound having the formula (1): (RO)2−nMgXn  (1)  wherein R is a C1-C20 alkyl or a C7-C26 aralkyl, each the same or different, X is a halogen, and n is an integer 1 or 2; a compound having the formula (2): R1n1Mm1X1(3m1−n1)  (2)  wherein M is B or Al, each same or different R1 is a C1-C10 alkyl, each same or different X1 is a halogen, m1 is 1 or 2, n1 is 1 or 2 when m1 is 1 and n1 is an integer from 1 to 5 when m1 is 2; a magnesium composition containing magnesium bonded to a hydrocarbyl and magnesium bonded to a hydrocarbyl oxide, said magnesium composition having the empirical formula (3): R2n2(R3O)2−n2Mg  (3)  wherein each same or different R2 is a C1-C20 alkyl each same or different R3 is a C1-C20 alkyl, n2 is between 0.01 and 1.99, which is the contact product of a dialkyl magnesium and an alcohol in a molar ratio of alcohol to dialkyl magnesium of 1.8-1.98 mol/mol, and; a titanium halide compound having the formula (4): (R4O)n3TiX24−n3  (4)  wherein each same or different R4 is a C1-C20 alkyl, each same or different X2 is a halogen, and n3 is 0 or an integer 1-3.

    摘要翻译： 已经制备了具有独立于乙烯聚合中的氢浓度和低凝胶生产率的高活性的催化剂。 该制备方法包括以下步骤：使包含具有式（1）的卤化镁化合物的载体：其中R是C1-C20烷基或C7-C26芳烷基，各自相同或不同，X是卤素，n 为整数1或2;具有式（2）的化合物：其中M为B或Al，各自相同或不同，R1为C1-C10烷基，各自相同或不同，X1为卤素，m1为1或2， 当m1为1时，n1为1或2，当m1为2时，n1为1至5的整数;镁与镁基键合到烃基和镁上键合到烃基氧化物上的镁组合物，所述镁组合物具有经验式（3） ：其中每个相同或不同的R 2是各自相同或不同的C 1 -C 20烷基，R 3是C 1 -C 20烷基，n 2在0.01和1.99之间，其是以醇的摩尔比计的二烷基镁和醇的接触产物 至1.8-1.98mol / mol的二烷基镁;和具有式（4）的卤化钛化合物：其中各自相同或不同的R 4为 C 1 -C 20烷基，各自相同或不同，X 2为卤素，n 3为0或整数1-3。