公开(公告)号：US5698103A

公开(公告)日：1997-12-16

申请号：US726371

申请日：1996-10-04

申请人： Paul R. Kurek

发明人： Paul R. Kurek

IPC分类号： B01J31/40 ,  B01J38/50 ,  B01D11/04

CPC分类号： B01J31/1815 ,  B01J31/4015 ,  B01J31/403 ,  B01J38/50 ,  B01J2231/70 ,  B01J2531/025 ,  B01J2531/845 ,  B01J31/0237

摘要： Sweetening of sour hydrocarbon feedstocks by contacting with an aqueous solution of a metal chelate as an oxidation catalyst in the presence of oxygen is hindered by the difficulty of recovering metal chelate. Extraction of the aqueous phase with a liquid secondary amine with low water solubility removes a main portion of the metal chelate, usually a mixture of polysulfonated cobalt phthalocyanines, from the aqueous phase, and subsequent recovery of the chelate from the amine extract enables a viable alternative to feed bed processes.

摘要翻译： 通过在氧气存在下与作为氧化催化剂的金属螯合物的水溶液接触来使酸性烃原料的甜化受到金属螯合物的回收困难的阻碍。 用具有低水溶性的液体仲胺萃取水相除去金属螯合物的主要部分，通常是来自水相的多磺化钴酞菁的混合物，随后从胺提取物中回收螯合物使其成为可行的替代物 喂床工艺。

公开(公告)号：US5273663A

公开(公告)日：1993-12-28

申请号：US16355

申请日：1993-02-11

申请人： Paul R. Kurek ,  Robert R. Frame ,  Tom N. Kalnes ,  Mark D. Moser

发明人： Paul R. Kurek ,  Robert R. Frame ,  Tom N. Kalnes ,  Mark D. Moser

IPC分类号： C02F1/72 ,  C02F1/78 ,  C02F9/00 ,  C02F11/08

CPC分类号： C02F9/00 ,  C02F11/08 ,  C02F1/72 ,  C02F1/722 ,  C02F1/725 ,  C02F1/78 ,  C02F2101/18 ,  Y10S210/904

摘要： The oxidation of cyanide under acid conditions using oxygen as the oxidizing agent can be effected under mild reaction conditions when certain metal chelates are used as catalysts. Especially effective chelates are metal phthalocyanines, particularly where the metal is vanadium or a member of the iron group metals. The oxidation can be effected homogeneously using water soluble metal chelates, or can be performed heterogeneously, especially in a continuous fashion using a packed bed reactor, by using suitable water-insoluble metal chelates, especially when supported on appropriate carriers.

摘要翻译： 使用氧作为氧化剂的酸性条件下氰化物的氧化可以在温和的反应条件下进行，当某些金属螯合物用作催化剂时。 特别有效的螯合物是金属酞菁，特别是金属是钒或铁族金属的成分时。 可以使用水溶性金属螯合物均匀地进行氧化，或者通过使用合适的水不溶性金属螯合物，特别是当在适当的载体上负载时，可以使用填充床反应器，特别是以连续的方式进行非均匀地进行氧化。

公开(公告)号：US5073654A

公开(公告)日：1991-12-17

申请号：US633873

申请日：1990-12-26

申请人： Blaise J. Arena ,  Paul R. Kurek

发明人： Blaise J. Arena ,  Paul R. Kurek

IPC分类号： C07C2/86

CPC分类号： C07C2/864 ,  C07C2102/10 ,  C07C2529/70

摘要： Continuous methylation of tetralin with methanol over several solid acid catalysts affords a mixture of 5-methyltetralin and 6-methyltetralin with selectivity of better than 65% at high conversions. Zeolite .beta. is a particularly effective catalyst insofar as it catalyzes the reaction at a temperature approximately 100.degree. C. lower than that required for silica-aluminas. However, the reaction temperature is quite sensitive to the concentration of methanol in the feedstock.

摘要翻译： 通过几种固体酸催化剂连续甲基化甲醇与甲醇，在高转化率下提供5-甲基四氢萘酚和6-甲基四氢化萘的混合物，其选择性优于65％。 沸石β是一种特别有效的催化剂，只要它在比二氧化硅 - 氧化铝所需的温度低约100℃的温度下催化反应即可。 然而，反应温度对原料中甲醇的浓度非常敏感。

公开(公告)号：US5013565A

公开(公告)日：1991-05-07

申请号：US562879

申请日：1990-08-03

申请人： Edward J. St. Martin ,  Paul R. Kurek ,  Elaine F. Schumacher

发明人： Edward J. St. Martin ,  Paul R. Kurek ,  Elaine F. Schumacher

IPC分类号： A23L1/275 ,  C09B61/00

CPC分类号： C09B61/00 ,  A23L5/46 ,  A23L5/47 ,  Y10S435/911

摘要： The orange, water-insoluble pigments monascorubrin and rubropunctatin elaborated by Monascus species can be converted to high purity red, water-soluble pigments by reaction with stoichiometric quantities of organic materials bearing a primary amine functionality. These pigments are suitable as colorants for a broad variety of edible formulations, especially those intended for human consumption, and often serve as suitable replacements for FD&C Red No. 2 and Red No. 4.

摘要翻译： 通过与化学计量的具有伯胺官能团的有机材料反应，橙红色水不溶性颜料红曲霉素和红曲霉素由红曲霉物质制成，可以转化为高纯度的红色水溶性颜料。 这些颜料适合作为各种可食用配方的着色剂，特别是用于人类消费的食品，并且通常用作FD＆C红2号和红4号的合适替代品。

公开(公告)号：US5013564A

公开(公告)日：1991-05-07

申请号：US562880

申请日：1990-08-03

申请人： Edward J. St. Martin ,  Paul R. Kurek ,  Elaine F. Schumacher ,  Ronald P. Rohrbach

发明人： Edward J. St. Martin ,  Paul R. Kurek ,  Elaine F. Schumacher ,  Ronald P. Rohrbach

IPC分类号： A23L1/275 ,  C09B61/00

CPC分类号： C09B61/00 ,  A23L5/46 ,  A23L5/47 ,  Y10S435/911

摘要： The yellow pigments which result from reaction of the Monascus pigments monascorubrin and rubropunctatin with amines followed by reduction of the ring carbonyl moiety to an hydroxyl group have excellent properties for their use as food colorants. Yellow pigments made from amino acid esters, dipeptide esters, and amines of sugar alcohols have particular promise as desirable food colorants which are effective at levels which impart no objectionable taste to foods.

摘要翻译： 由红曲霉色素monascorubrin和rubropunctatin与胺反应产生的黄色颜料，随后将羰基部分还原成羟基，它们用作食品着色剂具有优异的性能。 由氨基酸酯，二肽酯和糖醇制成的黄色颜料具有特别的希望，作为所希望的食品着色剂，其在对食物不产生令人不快的味道的水平上是有效的。

公开(公告)号：US4758251A

公开(公告)日：1988-07-19

申请号：US78442

申请日：1987-07-27

申请人： Raymond J. Swedo ,  Paul R. Kurek

发明人： Raymond J. Swedo ,  Paul R. Kurek

IPC分类号： B01D71/38 ,  B01D53/22

CPC分类号： B01D71/38

摘要： Thin film composite membranes having as a permselective layer a film of a homopolymer of certain vinyl alkyl ethers are useful in the separation of various gases. Such homopolymers have a molecular weight of greater than 30,000 and the alkyl group of the vinyl alkyl monomer has from 4 to 20 carbon atoms with branching within the alkyl moiety at least at the carbon atom bonded to the ether oxygen or at the next adjacent carbon atom. These membranes show excellent hydrolytic stability, especially in the presence of acidic or basic gaseous components.

摘要翻译： 作为选择选择层的某些乙烯基烷基醚的均聚物的膜的薄膜复合膜可用于分离各种气体。 这种均聚物具有大于30,000的分子量，乙烯基烷基单体的烷基具有4至20个碳原子，在烷基部分内具有至少在与醚氧结合的碳原子处或在下一相邻碳原子处具有支链 。 这些膜显示出优异的水解稳定性，特别是在酸性或碱性气体组分的存在下。

公开(公告)号：US4482741A

公开(公告)日：1984-11-13

申请号：US569367

申请日：1984-01-09

申请人： Paul R. Kurek

发明人： Paul R. Kurek

IPC分类号： C07C209/48 ,  C07C85/12

CPC分类号： C07C209/48

摘要： Xylylenediamines may be prepared by reducing the corresponding phthalonitrile with hydrogen in the presence of a catalyst comprising cobalt promoted with titanium composited on a solid support with the added presence of ammonia. By utilizing this particular catalyst with ammonia and a solvent comprising a xylylenediamine, it is possible to effect the reduction at temperatures in the range of from about 80.degree. to about 125.degree. C. and at a pressure not greater than 1000 psig. By utilizing various components of the system it is possible to attain yields of the desired product in excess of 90%.

摘要翻译： 苯二甲胺可以通过在催化剂的存在下用氢还原相应的邻苯二甲腈来制备，所述催化剂包含用钛复合的催化剂，所述钛在固体载体上加入，同时加入氨的存在。 通过用氨和包含苯二甲胺的溶剂利用该特定的催化剂，可以在约80-约125℃的温度和不高于1000psig的压力下进行还原。 通过利用系统的各种组分，可以获得超过90％的所需产物的产率。

公开(公告)号：US06670509B1

公开(公告)日：2003-12-30

申请号：US10120821

申请日：2002-04-11

申请人： Paul R. Kurek ,  David W. House

发明人： Paul R. Kurek ,  David W. House

IPC分类号： C07C4500

CPC分类号： C07C45/33 ,  C07C49/04

摘要： A process for oxygenating organic substrates such as aliphatic hydrocarbons has been developed. The process involves contacting the organic substrate with oxygen in the presence of a bicyclo imide promoter and a metal co-catalyst. The process is preferably carried out using sulfolane as the solvent. Optionally, the oxygenated product can be hydrogenated to give the corresponding alcohol which can optionally in turn be dehydrated to provide the corresponding olefin.

摘要翻译： 已经开发了用于对有机底物进行氧化的方法，例如脂族烃。 该方法包括在双环酰亚胺助催化剂和金属助催化剂存在下使有机底物与氧接触。 该方法优选使用环丁砜作为溶剂进行。 任选地，氧化产物可以被氢化得到相应的醇，其可以任选地依次脱水以提供相应的烯烃。

公开(公告)号：US5254138A

公开(公告)日：1993-10-19

申请号：US878369

申请日：1992-05-04

申请人： Paul R. Kurek

发明人： Paul R. Kurek

IPC分类号： C08F8/44 ,  C10L1/224 ,  C10L1/232 ,  C10L1/233 ,  C10L1/2387 ,  C10L10/00 ,  C10L10/04 ,  C10L1/18 ,  C10L1/22

CPC分类号： C10L10/04 ,  C08F8/44 ,  C10L1/224 ,  C10L1/232 ,  C10L1/2335 ,  C10L1/2387 ,  C10L10/06

摘要： Conductive fuel detergent compositions which posses not only the desirable characteristics of minimizing unwanted deposits on internal engine surface such as intake systems or port fuel injectors and exhibiting anticorrosion characteristics but also have conductive properties comprise quaternary succinimides which are characterized by having an oligomeric alkyl moiety on the succinimide ring. The additive may be prepared by condensing a (polyalkyl)succinic anhydride with a polyamino hydroxyalkyl quaternary ammonium salt, where the latter is formed by the reaction of a .OMEGA.-haloepoxide with a tertiary amine followed by reaction of the resulting product with a polyamine.

摘要翻译： 导电燃料洗涤剂组合物不仅具有将内部发动机表面上不期望的沉积物（例如进气系统或端口燃料喷射器）最小化并具有抗腐蚀特性但具有导电性能的期望特性包括季铵琥珀酰亚胺，其特征在于在其上具有低聚烷基部分 琥珀酰亚胺环。 添加剂可以通过将（多烷基）琥珀酸酐与聚氨基羟烷基季铵盐缩合来制备，其中后者通过OMEGA-卤代环氧化物与叔胺的反应形成，随后将所得产物与多胺反应。

公开(公告)号：US06395943B1

公开(公告)日：2002-05-28

申请号：US09371455

申请日：1999-08-10

申请人： Paul R. Kurek ,  Robert R. Frame

发明人： Paul R. Kurek ,  Robert R. Frame

IPC分类号： C07C720

CPC分类号： C07B63/04 ,  C08F2/40

摘要： A process is disclosed for inhibiting the polymerization of vinyl aromatic compounds, such as styrene, during its distillation. The process involves adding a mixture of at least two inhibitors to the vinyl aromatic compound. One such combination is N,N′-di-2-butyl-N,N′,4-dinitroso-1,4-diaminobenzene and dinitrocresol. A stabilizer such as N,N′-di-2-butyl-1,4-diaminobenzene can also be added.

摘要翻译： 公开了一种在蒸馏期间抑制乙烯基芳族化合物如苯乙烯的聚合的方法。 该方法包括向乙烯基芳族化合物中加入至少两种抑制剂的混合物。 一种这样的组合是N，N'-二-2-丁基-N，N'，4-二亚硝基1,4-二氨基苯和二硝基甲酚。 也可以加入N，N'-二-2-丁基-1,4-二氨基苯等稳定剂。