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公开(公告)号：US5510451A
公开(公告)日：1996-04-23
申请号：US289329
申请日：1994-08-11
CPC分类号： C08G69/44
摘要： The invention deals with copolyester amides built up from units derived from terephthalic acid, 1,4-butane-diol and 1,4-butane diamine.
摘要翻译： 本发明涉及由衍生自对苯二甲酸，1,4-丁二醇和1,4-丁二胺的单元构成的共聚酯酰胺。
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公开(公告)号：US5268445A
公开(公告)日：1993-12-07
申请号：US905171
申请日：1992-06-24
CPC分类号： C08G69/44
摘要： The invention relates to segmented copolyesteramides built up from units derived from one or more flexible segments, 1,4-butanediol, 1,4-butanediamine and terephthalic.
摘要翻译： 本发明涉及由衍生自一个或多个柔性链段，1,4-丁二醇，1,4-丁二胺和对苯二甲酸的单元构成的分段共聚酯酰胺。
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公开(公告)号：US20120108693A1
公开(公告)日：2012-05-03
申请号：US13376901
申请日：2010-05-31
IPC分类号： C08G65/40
CPC分类号： C08G69/42 , C08G69/40 , C08L81/06 , C08L2205/05 , C08L77/00
摘要： The present invention relates to polyarylene ether block copolymers according to the general formula A-K-X-K-A, where—X— is a polyarylene ether segment with number-average molar mass of at least 5000 g/mol, andA— is a segment of the general structure R2NH—(R1—NH—CO—Ar—CO—NH)n—R1—NH—, in which R1 is a linear or branched alkylene group having from 2 to 12 carbon atoms and Ar is an arylene group having from 6 to 18 carbon atoms, and R2 is selected from aryloyl, alkyloyl, and H, and in which the number average of n is from 1 to 3, andthere is a coupling group K of the structure —CO—Ar3—CO— linking each A to X, in which Ar3 is an aromatic group having from 6 to 18 carbon atoms.The present invention also relates to a process for the production of the polyarylene ether block copolymers of the invention, to polymer compositions comprising the polyarylene ether block copolymers of the invention, and also to the use thereof for the production of moldings, of films, of fibers, or of foams.
摘要翻译： 本发明涉及根据通式AKXKA的聚亚芳基醚嵌段共聚物，其中-X-是具有至少5000g / mol的数均摩尔质量的聚亚芳基醚链段，A-是通式结构的一部分R2NH - （R1-NH-CO-Ar-CO-NH）n-R1-NH-，其中R1是具有2至12个碳原子的直链或支链亚烷基，Ar是具有6至18个碳原子的亚芳基 原子，R 2选自芳氧基，烷酰基和H，其中n的数均为1〜3，并且存在连接各A至X的结构-CO-Ar 3 -CO的结合基团K ，其中Ar 3是具有6至18个碳原子的芳族基团。 本发明还涉及本发明的聚亚芳基醚嵌段共聚物的制备方法，包括本发明的聚亚芳基醚嵌段共聚物的聚合物组合物，以及其用于生产模制品的用途 纤维，或泡沫。
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公开(公告)号：US4716214A
公开(公告)日：1987-12-29
申请号：US913313
申请日：1986-09-30
摘要： A process is disclosed for the preparation of polytetramethylene adipamide by heating in a first reaction zone, the salt of 1,4-diaminobutane and adipic acid, with from 0-25 wt. % of other polymide-forming compounds, at a pressure between 5 and 100 bars to form a prepolymer, then passing the prepolymer containing liquid reaction mixture to a second reaction zone wherein the temperature of the liquid reaction mixture is maintained above its solidification point while the pressure is simultaneously reduced, then subjecting the prepolymer containing liquid reaction mixture to after-condensation in at least one subsequent reaction zone.
摘要翻译： 公开了通过在第一反应区（1,4-二氨基丁烷和己二酸的盐）中加热0-25重量份的1,4-丁二醇己二酰胺制备方法。 ％的其他形成聚酰亚胺的化合物，在5至100巴之间的压力下形成预聚物，然后将含有液体反应混合物的预聚物通入第二反应区，其中液体反应混合物的温度保持在其固化点以上，而 同时降低压力，然后使含有液体反应混合物的预聚物在至少一个后续反应区中进行后冷凝。
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公开(公告)号：US08524853B2
公开(公告)日：2013-09-03
申请号：US13376901
申请日：2010-05-31
IPC分类号： C08G8/02
CPC分类号： C08G69/42 , C08G69/40 , C08L81/06 , C08L2205/05 , C08L77/00
摘要： The present invention relates to polyarylene ether block copolymers according to the general formula A-K—X—K-A, where —X— is a polyarylene ether segment with number-average molar mass of at least 5000 g/mol, and A- is a segment of the general structure R2NH—(R1—NH—CO—Ar—CO—NH)n—R1—NH—, in which R1 is a linear or branched alkylene group having from 2 to 12 carbon atoms and Ar is an arylene group having from 6 to 18 carbon atoms, and R2 is selected from aryloyl, alkyloyl, and H, and in which the number average of n is from 1 to 3, and there is a coupling group K of the structure —CO—Ar3—CO— linking each A to X, in which Ar13 is an aromatic group having from 6 to 18 carbon atoms. The present invention also relates to a process for the production of the polyarylene ether block copolymers of the invention, to polymer compositions comprising the polyarylene ether block copolymers of the invention, and also to the use thereof for the production of moldings, of films, of fibers, or of foams.
摘要翻译： 本发明涉及根据通式AKXKA的聚亚芳基醚嵌段共聚物，其中-X-是具有至少5000g / mol的数均摩尔质量的聚亚芳基醚链段，A-是通式结构的一部分R2NH - （R1-NH-CO-Ar-CO-NH）n-R1-NH-，其中R1是具有2至12个碳原子的直链或支链亚烷基，Ar是具有6至18个碳原子的亚芳基 原子，R 2选自芳氧基，烷酰基和H，其中n的数均为1〜3，并且存在连接各A至X的结构-CO-Ar 3 -CO的结合基团K ，其中Ar 13是具有6至18个碳原子的芳族基团。 本发明还涉及本发明的聚亚芳基醚嵌段共聚物的制备方法，包括本发明的聚亚芳基醚嵌段共聚物的聚合物组合物，以及其用于制备模制品的用途 纤维，或泡沫。
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公开(公告)号：US4460762A
公开(公告)日：1984-07-17
申请号：US247545
申请日：1981-03-25
CPC分类号： C08G69/28
摘要： A process is described for the preparation of high-molecular weight white polyamides, substantially consisting of units of --NH--(CH.sub.2).sub.4 --NH--CO(CH.sub.2).sub.4 --CO--, by the after-condensation of a corresponding low-molecular prepolymer, consisting substantially of a molecular chain of units of --NH--(CH.sub.2).sub.4 --NH--CO(CH.sub.2).sub.4 --CO--, in which process the prepolymer which is employed has been prepared in the presence of an excess of 0.5 to 15 moles-% of 1,4-diaminobutane with respect to the quantity stoichiometrically equivalent to the adipic acid applied. This prepolymer is thereafter subjected to the after-condensation reaction in the solid phase in an atmosphere containing water vapor.
摘要翻译： 描述了制备基本上由-NH-（CH 2）4 -NH-CO（CH 2）4 -CO-的单元组成的高分子量白色聚酰胺的方法，通过相应的低分子量 预聚物，其基本上由-NH-（CH 2）4 -NH-CO（CH 2）4 -CO-单元的分子链组成，其中所用的预聚物在过量的0.5至 15摩尔％的1,4-二氨基丁烷相对于所施加的己二酸的化学计量等效量。 此后，该预聚物在含有水蒸汽的气氛中在固相中进行后缩合反应。
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公开(公告)号：US4408036A
公开(公告)日：1983-10-04
申请号：US247548
申请日：1981-03-25
摘要： A process for the preparation of white nylon 4,6 polyamide of high molecular weight from a tetramethylenediamine adipic acid prepolymer, formed under controlled conditions of temperature and water vapor pressure and wherein the plurality of cyclical end-groups in the prepolymer does not exceed 0.20 mg. equivalent per gram of prepolymer.
摘要翻译： 一种在温度和水蒸汽压力的控制条件下由四亚甲基二胺己二酸预聚物制备高分子量的白色尼龙4,6聚酰胺的方法，其中预聚物中的多个循环端基不超过0.20mg 。 相当于每克预聚物。
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8.发明授权Copolyamide from tetramethylene diamine, adipic acid and terephthalic acid 失效来自四亚甲基二胺，己二酸和对苯二甲酸的共聚酰胺
公开(公告)号：US4868280A
公开(公告)日：1989-09-19
申请号：US231558
申请日：1988-08-12
申请人： Reinoud J. Gaymans
发明人： Reinoud J. Gaymans
CPC分类号： C08G69/265
摘要： The invention relates to a novel grade of copolymides of tetramethyleneadipamide (nylon 4.6) and tetramethyleneterephthalamide (nylon 4.T) containing a mole fraction nylon 4.T of 0.1 to 0.6 and having such a degree of orientation that the melting temperature shows little dependence on the composition of the copolyamide and remains relatively low and which copolyamides have good mechanical properties.
摘要翻译： 本发明涉及一种新型级别的四亚甲基己二酰胺（尼龙4.6）和四亚甲基对苯二甲酰胺（尼龙4.T）的共聚物，其含有0.1至0.6的摩尔分数尼龙4.T，具有这样的取向度，使得熔融温度几乎不依赖于 共聚酰胺的组成和保持相对较低，哪些共聚酰胺具有良好的机械性能。
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公开(公告)号：US4446304A
公开(公告)日：1984-05-01
申请号：US451337
申请日：1982-12-20
IPC分类号： C08L77/00 , B29C33/38 , B29C67/24 , C08G69/00 , C08G69/26 , C08G69/28 , C08G69/48 , C08L77/06
CPC分类号： B29C67/24 , C08G69/48 , B29K2077/00
摘要： Shaped articles are described molded from a nylon 4,6 polyamide, substantially consisting of [NH--(CH.sub.2).sub.4 --NH--CO(CH.sub.2).sub.4 --CO] units and having a relative viscosity, measured at 20.degree. C., on a solution in 96% sulfuric acid containing 1 g of polyamide in 100 ml of solution, of at least 2.0, and having highly stable high temperature, zinc-ion and chloride ion resistance characteristics.
摘要翻译： 描述由尼龙4,6聚酰胺成形的成形制品，其基本上由[NH-（CH 2）4 -NH-CO（CH 2）4 -CO]单元组成，并且在20℃下测量的相对粘度 溶液在含有1g聚酰胺的96％硫酸溶液中，至少为2.0，具有高度稳定的高温，锌离子和氯离子电阻特性。
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