Abstract:
The instant invention pertains to the use of an antistatic composition comprising a polar thermoplastic polymer and an ionic liquid as antistatic additive for non-polar thermo-plastic or elastomeric polymers. Further aspects of the invention are a process for the preparation of an antistatic non-polar thermoplastic or elastomeric polymer which process comprises incorporating therein a mixture of a polar thermoplastic polymer and an ionic liquid and the composition of a polar thermoplastic polymer, an ionic liquid and a non-polar thermoplastic or elastomeric polymer.
Abstract:
The thermoplastic molding composition comprises, based on the thermoplastic molding composition, a) as component A, at least one thermoplastic matrix polymer selected from poly-amides, polyesters, polyacetals, and polysulfones, where this can also take the form of polymer blend, b) as component B, from 0.1 to 5% by weight of at least one highly branched or hyperbranched polymer which has functional groups which can react with the matrix polymer of component A, and c) as component C, from 0.1 to 15% by weight of conductive carbon fillers selected from carbon nanotubes, graphenes, carbon black, graphite, and mixtures thereof, with the exclusion of specific thermoplastic molding compositions.
Abstract:
The present invention relates to polyarylene ether block copolymers according to the general formula A-K-X-K-A, where—X— is a polyarylene ether segment with number-average molar mass of at least 5000 g/mol, andA— is a segment of the general structure R2NH—(R1—NH—CO—Ar—CO—NH)n—R1—NH—, in which R1 is a linear or branched alkylene group having from 2 to 12 carbon atoms and Ar is an arylene group having from 6 to 18 carbon atoms, and R2 is selected from aryloyl, alkyloyl, and H, and in which the number average of n is from 1 to 3, andthere is a coupling group K of the structure —CO—Ar3—CO— linking each A to X, in which Ar3 is an aromatic group having from 6 to 18 carbon atoms.The present invention also relates to a process for the production of the polyarylene ether block copolymers of the invention, to polymer compositions comprising the polyarylene ether block copolymers of the invention, and also to the use thereof for the production of moldings, of films, of fibers, or of foams.
Abstract:
The invention relates to processes for the production of a composite component via multicomponent injection molding, where the composite component comprises a main body composed of a thermoplastic A) and an external layer composed of a foamed thermoplastic B), where the main body is produced in a first process step a) via injection molding of the thermoplastic A) and subsequent hardening of the same in an injection mold, and an external layer is injected on to the main body in a second process step b) which follows directly, via injection molding of a mixture comprising the thermoplastic B) and comprising a chemical blowing agent, and the mixture is subsequently hardened in the same injection mold, with somewhat extended cavity, and the external layer injected on to the main body is foamed in a further process step d) via introduction of heat, and the composite component is solidified via cooling in a final process step e), where an essential feature of the invention is that it comprises using, as thermoplastic B) in the mixture used in process step b), at least one polyamide whose modulus of elasticity derived from the tensile test (tensile modulus) Et is from 1 MPa to 250 MPa (determined to DIN EN ISO 527 of April 1996) in the entire temperature range from 70° C. to 180° C., and using, as chemical blowing agent in the mixture used in process step b), one or more substances present in non-polymerized form.The invention further relates to composite components and to reinforced load-bearing elements, where these can be produced by said processes, and also to mixtures, and to the use of said mixtures for the production of composite components.
Abstract translation:本发明涉及通过多组分注射成型生产复合部件的方法,其中复合部件包括由热塑性A)构成的主体和由发泡热塑性B)组成的外层,其中主体被制成 第一工艺步骤a)通过注塑成型热塑性塑料A),然后在注模中随后硬化,并且在通过注塑成型的第二工艺步骤b)中将外层注入到主体上 的包含热塑性B)并且包含化学发泡剂的混合物,然后将该混合物在相同的注塑模具中硬化,具有稍微延伸的空腔,并且在另外的工艺步骤d中喷射注入主体的外层 ),并且通过最终工艺步骤e)中的冷却将复合组分固化,其中本发明的基本特征是其包含 在工艺步骤b)中使用的混合物中使用至少一种由拉伸试验(拉伸模量)Et得到的弹性模量为1MPa至250MPa(根据DIN EN ISO 527确定的聚酰胺) 在整个温度范围为70℃至180℃的范围内,并且使用在工艺步骤b)中使用的混合物中的化学发泡剂,以非聚合形式存在的一种或多种物质。 本发明还涉及复合部件和增强的承载元件,其中这些元件可以通过所述方法生产,并且还涉及混合物,以及所述混合物用于生产复合部件的用途。
Abstract:
Thermoplastic molding compositions comprisingA) from 10 to 99.9% by weight of at least one thermoplastic polyamide B) from 0.1 to 50% by weight of a copolymer obtainable via (i) preparation of at least one reaction mixture (a) via free-radical copolymerization of one or more monoethylenically unsaturated monomeric compound(s) (monomer(s) B1) with one or more compound(s) selected from the group of itaconic acid, mesaconic acid, fumaric acid, maleic acid, aconitic acid, glutaconic acid, and salts, esters, and anhydrides thereof (monomer(s) B2), and (ii) if appropriate, reaction of at least one of the copolymers obtained in step (i) with one or more crosslinking agent(s) (b), and C) from 0 to 60% by weight of further additives, where the total of the percentages by weight of components A) to C) is 100%.
Abstract:
The present invention relates to polyarylene ether block copolymers according to the general formula A-K—X—K-A, where —X— is a polyarylene ether segment with number-average molar mass of at least 5000 g/mol, and A- is a segment of the general structure R2NH—(R1—NH—CO—Ar—CO—NH)n—R1—NH—, in which R1 is a linear or branched alkylene group having from 2 to 12 carbon atoms and Ar is an arylene group having from 6 to 18 carbon atoms, and R2 is selected from aryloyl, alkyloyl, and H, and in which the number average of n is from 1 to 3, and there is a coupling group K of the structure —CO—Ar3—CO— linking each A to X, in which Ar13 is an aromatic group having from 6 to 18 carbon atoms. The present invention also relates to a process for the production of the polyarylene ether block copolymers of the invention, to polymer compositions comprising the polyarylene ether block copolymers of the invention, and also to the use thereof for the production of moldings, of films, of fibers, or of foams.
Abstract:
The thermoplastic molding composition comprises, based on the thermoplastic molding composition, a) at least one polyamide, copolyamide or a polyamide-comprising polymer blend as component A, b) from 0.1 to 10% by weight of carbon nanotubes, graphenes or mixtures thereof as component B, c) from 0.1 to 3% by weight of ionic liquids as component C, wherein the thermoplastic molding composition does not comprise any polyamide-12 units.
Abstract:
The thermoplastic molding composition comprises, based on the thermoplastic molding composition, a) at least one polyamide, copolyamide or a polyamide-comprising polymer blend as component A, b) from 0.1 to 10% by weight of carbon nanotubes, graphenes or mixtures thereof as component B, c) from 0.1 to 3% by weight of ionic liquids as component C, wherein the thermoplastic molding composition does not comprise any polyamide-12 units.
Abstract:
The invention relates to processes for the production of a composite component via multicomponent injection molding, where the composite component comprises a main body composed of a thermoplastic and an external layer composed of a foamed thermoplastic. The main body is produced via injection molding and subsequent hardening of the thermoplastic. A mixture of the foamed thermoplastic and a chemical blowing agent is injected onto the main body, subsequently hardened in the same injection mold, and foamed by heating. The composite component is solidified via cooling. The foamed thermoplastic is at least one polyamide whose modulus of elasticity is from 1 MPa to 250 MPa in the entire temperature range from 70° C. to 180° C. The chemical blowing agent is in non-polymerized form.
Abstract:
The thermoplastic molding composition comprises, based on the thermoplastic molding composition, a) as component A, at least one polyamide or copolyamide, or one polymer blend comprising polyamide, b) as component B, from 3 to 20% by weight of carbon black or graphite, or a mixture thereof, c) as component C, from 0.1 to 3% by weight of ionic liquids.