Dyes derived from dihydro-carbazolium salts
    1.
    发明授权
    Dyes derived from dihydro-carbazolium salts 有权
    衍生自二氢咔唑鎓盐的染料

    公开(公告)号:US5892056A

    公开(公告)日:1999-04-06

    申请号:US129660

    申请日:1998-08-05

    摘要: 2-Methyl-4,4a-dihydro-3H-carbazolium salts that are useful as dye precursors and dyes derived from those precursors are disclosed. The salts are described by the formula ##STR1## wherein R.sup.1 represents an alkyl, aryl, sulfoalkyl, carboxyalkyl, sulfatoalkyl, alkoxyalkyl, acyloxyalkyl, dialkylaminoalkylene, cycloaminoalkylene, acyl, or alkenyl group having from 1 to 18 carbon atoms; R.sup.2 represents an alkyl group having up to 18 carbon atoms; R.sup.3 represents hydrogen or an alkyl group having from 1 to 18 carbon atoms; R.sup.4 represents hydrogen or an alkyl group having from 1 to 18 carbon atoms; R.sup.5 represents hydrogen, nitro, carboxyl, sulfo, hydroxy, halogen, phospho, or an alkoxy, thioalkoxy, oxyalkyl, acyl, alkyl, aryl, or amino group having up to 18 carbon atoms; wherein any two groups R.sup.5, or R.sup.4 and a group R.sup.5, or R.sup.1 and R.sup.4 may together form a substituted or unsubstituted aryl, heteroaryl, aliphatic, or heteroaliphatic ring; X represents an anion; and a and b represent positive integers such that a equals b.The salts have a partially saturated ring system that rigidifies the chromophore in the precursor and in dyes derived from it. The rigidified chromophores have narrowed absorption bands relative to corresponding non-rigid chromophores. Dyes prepared from the dye precursors of the invention typically have good solubility in non-polar solvents.

    摘要翻译: 公开了可用作染料前体的2-甲基-4,4a-二氢-3H-咔唑鎓盐和衍生自那些前体的染料。 这些盐通过下式描述:其中R1代表具有1至18个碳原子的烷基,芳基,磺基烷基,羧烷基,硫烷基烷基,烷氧基烷基,酰氧基烷基,二烷基氨基亚烷基,环氨基亚烷基,酰基或烯基; R 2表示具有至多18个碳原子的烷基; R3代表氢或具有1至18个碳原子的烷基; R4代表氢或具有1至18个碳原子的烷基; R5代表具有至多18个碳原子的氢,硝基,羧基,磺基,羟基,卤素,磷酸基或烷氧基,硫代烷氧基,烷氧基,酰基,烷基,芳基或氨基; 其中任何两个基团R 5或R 4和基团R 5,或R 1和R 4可以一起形成取代或未取代的芳基,杂芳基,脂族或杂脂族环; X表示阴离子; a和b表示正整数,使得a等于b。 盐具有部分饱和的环体系,其使前体中的发色团和衍生自其的染料硬化。 刚性发色团相对于相应的非刚性发色团具有缩窄的吸收带。 由本发明的染料前体制备的染料通常在非极性溶剂中具有良好的溶解性。

    Method of forming a structured surface using ablatable radiation sensitive material
    3.
    发明授权
    Method of forming a structured surface using ablatable radiation sensitive material 有权
    使用可消融的辐射敏感材料形成结构化表面的方法

    公开(公告)号:US08796583B2

    公开(公告)日:2014-08-05

    申请号:US10944586

    申请日:2004-09-17

    IPC分类号: B23K26/00

    摘要: A structured surface is formed with the method of the present invention. The method of making this structured surface includes the steps of applying an ablatable radiation sensitive coating on the major surface of the substrate, and exposing the ablatable radiation sensitive coating to radiation such that exposed portions of the ablatable radiation sensitive coating ablate from the substrate to form a structured surface. The structured surface then includes a substrate and a pattern of structures framed by at least one separation bank. The method may also include the steps of depositing a flowable material on to the structures and the separation bank to form a pattern of flowable material in the structures.

    摘要翻译: 用本发明的方法形成结构化表面。 制造该结构化表面的方法包括以下步骤:将可消融的辐射敏感涂层施加在基底的主表面上,并将可消融的辐射敏感涂层暴露于辐射,使得可烧蚀的辐射敏感涂层的暴露部分从基底上烧蚀以形成 结构化表面。 结构化表面然后包括基底和由至少一个分离堤构成的结构图案。 该方法还可以包括以下步骤:将可流动材料沉积到结构和分离组上以在结构中形成可流动材料的图案。

    2-methyl-4,4a-dihydro-3H-carbazolium salts and dyes derived therefrom
    4.
    发明授权
    2-methyl-4,4a-dihydro-3H-carbazolium salts and dyes derived therefrom 失效
    2-甲基-4,4a-二氢-3H-咔唑鎓盐和由其衍生的染料

    公开(公告)号:US5831098A

    公开(公告)日:1998-11-03

    申请号:US851517

    申请日:1992-03-16

    摘要: 2-Methyl-4,4a-dihydro-3H-carbazolium salts that are useful as dye precursors and dyes derived from those precursors are disclosed. The salts are described by the formula ##STR1## wherein R.sup.1 represents an alkyl, aryl, sulfoalkyl, carboxyalkyl, sulfatoalkyl, alkoxyalkyl, acyloxyalkyl, dialkylarinoalkylene, cycloaminoalkylene, acyl, or alkenyl group having from 1 to 18 carbon atoms; R.sup.2 represents an alkyl group having up to 18 carbon atoms; R.sup.3 represents hydrogen or an alkyl group having from 1 to 18 carbon atoms; R.sup.4 represents hydrogen or an alkyl group having from 1 to 18 carbon atoms; R.sup.5 represents hydrogen, nitro, carboxyl, sulfo, hydroxy, halogen, phospho, or an alkoxy, thioalkoxy, oxyalkyl, acyl, alkyl, aryl, or amino group having up to 18 carbon atoms; wherein any two groups R.sup.5, or R.sup.4 and a group R.sup.5, or R.sup.1 and R.sup.4 may together form a substituted or unsubstituted aryl, heteroaryl, aliphatic, or heteroaliphatic ring; X represents an anion; and a and b represent positive integers such that a equals b. The salts have a partially saturated ring system that rigidifies the chromophore in the precursor and in dyes derived from it. The rigidified chromophores have narrowed absorption bands relative to corresponding non-rigid chromophores. Dyes prepared from the dye precursors of the invention typically have good solubility in non-polar solvents.

    摘要翻译: 公开了可用作染料前体的2-甲基-4,4a-二氢-3H-咔唑鎓盐和衍生自那些前体的染料。 该盐通过下式描述:其中R 1表示具有1至18个碳原子的烷基,芳基,磺烷基,羧烷基,硫烷基烷基,烷氧基烷基,酰氧基烷基,二烷基亚氨基亚烷基,环氨基亚烷基,酰基或烯基; R 2表示具有至多18个碳原子的烷基; R3代表氢或具有1至18个碳原子的烷基; R4代表氢或具有1至18个碳原子的烷基; R5代表具有至多18个碳原子的氢,硝基,羧基,磺基,羟基,卤素,磷酸基或烷氧基,硫代烷氧基,烷氧基,酰基,烷基,芳基或氨基; 其中任何两个基团R 5或R 4和基团R 5,或R 1和R 4可以一起形成取代或未取代的芳基,杂芳基,脂族或杂脂族环; X表示阴离子; a和b表示正整数,使得a等于b。 盐具有部分饱和的环体系,其使前体中的发色团和衍生自其的染料硬化。 刚性发色团相对于相应的非刚性发色团具有缩窄的吸收带。 由本发明的染料前体制备的染料通常在非极性溶剂中具有良好的溶解性。