公开(公告)号：US07981389B2

公开(公告)日：2011-07-19

申请号：US11342773

申请日：2006-01-30

Applicant: Paul T Fanson ,  Hirohito Hirata ,  Masaya Ibe ,  Steven L Suib ,  Young Chan Son

Inventor： Paul T Fanson ,  Hirohito Hirata ,  Masaya Ibe ,  Steven L Suib ,  Young Chan Son

IPC: B01D53/56 ,  B01D53/86 ,  B01D53/04 ,  B01D53/94 ,  B01D53/22 ,  B01D53/00 ,  C01B13/00 ,  F01N3/00 ,  F01N3/10

CPC classification number: C10G15/08 ,  C10G11/00 ,  C10G11/02 ,  Y02T10/22

Abstract: A process for cracking hydrocarbons at atmospheric pressure includes the following steps: providing a catalyst, passing a gaseous hydrocarbon over the catalyst and exposing the catalyst to microwave energy. The hydrocarbons are broken down into lower Carbon number molecules.

Abstract translation: 在大气压下裂解烃的方法包括以下步骤：提供催化剂，使气态烃在催化剂上通过并将催化剂暴露于微波能量。 烃被分解成较低的碳数分子。

公开(公告)号：US07355075B2

公开(公告)日：2008-04-08

申请号：US11424688

申请日：2006-06-16

Applicant: Shanthakumar Sithambaram ,  Young-Chan Son ,  Steven L. Suib

Inventor： Shanthakumar Sithambaram ,  Young-Chan Son ,  Steven L. Suib

IPC: C07C251/04 ,  C07C251/16

CPC classification number: C07C249/02 ,  C07C2601/08 ,  C07C2601/14 ,  C07D241/06 ,  C07D333/22 ,  C07C251/08 ,  C07C251/16 ,  C07C251/18 ,  C07C251/24

Abstract: A method for forming an imine comprises reacting a first reactant comprising a hydroxyl functionality, a carbonyl functionality, or both a hydroxyl functionality and a carbonyl functionality with a second reactant having an amine functionality in the presence of ordered porous manganese-based octahedral molecular sieves and an oxygen containing gas at a temperature and for a time sufficient for the imine to be produced.

Abstract translation: 一种形成亚胺的方法包括在有序多孔锰基八面体分子筛存在下使包含羟基官能团，羰基官能团或羟基官能团和羰基官能团的第一反应物与具有胺官能度的第二反应物反应，以及 在足以产生亚胺的温度和时间内加入含氧气体。

公开(公告)号：US5429870A

公开(公告)日：1995-07-04

申请号：US991887

申请日：1992-12-17

Applicant: Michael A. Kmetz ,  John M. Laliberte ,  Steven L. Suib ,  Francis S. Galasso

Inventor： Michael A. Kmetz ,  John M. Laliberte ,  Steven L. Suib ,  Francis S. Galasso

IPC: C04B35/80 ,  C04B35/628 ,  C23C16/32 ,  C23C16/38 ,  B32B9/00

CPC classification number: C04B35/6286 ,  C04B35/563 ,  C04B35/565 ,  C04B35/62844 ,  C04B35/62868 ,  C04B35/62873 ,  C04B35/62897 ,  C04B35/806 ,  C23C16/32 ,  C04B2235/5228 ,  C04B2235/524 ,  C04B2235/5244 ,  C04B2235/5248 ,  C04B2235/614 ,  C04B2235/96 ,  C04B2235/9684 ,  Y10T428/2918 ,  Y10T428/292

Abstract: A fiber is coated with boron carbide by contacting the fiber with a reaction mixture of a boron source and a carbon source at a temperature of at least about 1050.degree. C. such that the boron source and carbon source react with each other to produce a boron carbide coating on the fiber. The fiber comprises aluminum oxide, SiC, or Si.sub.3 N.sub.4 and the boron carbide coating comprises up to about 40 atomic percent boron.

Abstract translation: 通过使纤维与硼源和碳源的反应混合物在至少约1050℃的温度下接触使纤维涂覆有碳化硼，使得硼源和碳源彼此反应以产生硼 纤维上的碳化物涂层。 纤维包括氧化铝，SiC或Si 3 N 4，并且碳化硼涂层包含至多约40原子百分比的硼。

公开(公告)号：US08987160B2

公开(公告)日：2015-03-24

申请号：US13072683

申请日：2011-03-26

Applicant: Steven L. Suib ,  Boxun Hu ,  Eric Rolland Kreidler ,  Christopher James Brooks

Inventor： Steven L. Suib ,  Boxun Hu ,  Eric Rolland Kreidler ,  Christopher James Brooks

IPC: B01J29/06 ,  B01J23/34 ,  B01J27/22 ,  B01J35/00 ,  B01J23/889 ,  B01J37/02 ,  B01J37/16 ,  B01J37/18 ,  C10G2/00 ,  C07C51/367

CPC classification number: B01J35/002 ,  B01J23/34 ,  B01J23/8892 ,  B01J27/22 ,  B01J37/0201 ,  B01J37/16 ,  B01J37/18 ,  B01J2203/063 ,  B01J2229/183 ,  B01J2229/186 ,  C07C51/367 ,  C10G2/33 ,  C10G2/332 ,  C10G2/334 ,  C07C59/245

Abstract: Cryptomelane-type manganese oxide octahedral molecular sieves (OMS-2) supported Fe and Co catalysts are utilized in a method for producing hydrocarbons by a Fischer-Tropsch mechanism. The hydrocarbon producing method includes providing a catalyst of a manganese oxide-based octahedral molecular sieve nanofibers with an active catalyst component of at least one of iron, cobalt, nickel, copper, manganese, vanadium, zinc, and mixtures thereof, and further containing an alkali metal. The formation of iron carbides and cobalt carbides by exposing the catalyst to conditions sufficient to form those carbides is also taught. After the catalyst has been appropriately treated, a carbon source and a hydrogen source are provided and contacted with the catalyst to thereby form a hydrocarbon containing product. The catalyst have high catalytic activity and selectivity (75%) for C2+ hydrocarbons in both CO hydrogenation and CO2 hydrogenation. Highly selective syntheses of high value jet fuel, C2-C6 alkenes, C2-C6 carboxylic acids; α-hydroxylic acids and their derivatives have been realized by tuning the oxidation ability of OMS-2 supports and by doping with Cu2+ ions.

Abstract translation: 在通过费 - 托机制生产烃的方法中，使用了Cryportelane型锰氧化物八面体分子筛（OMS-2）负载的Fe和Co催化剂。 烃生产方法包括提供一种氧化锰基八面体分子筛纳米纤维的催化剂，其具有铁，钴，镍，铜，锰，钒，锌及其混合物中的至少一种的活性催化剂组分，并且还含有 碱金属。 还教导了通过将催化剂暴露于足以形成这些碳化物的条件来形成碳化铁和碳化钴。 在催化剂被适当处理之后，提供碳源和氢源并与催化剂接触，从而形成含烃产品。 该催化剂在CO氢化和二氧化碳加氢过程中对于C2 +烃具有较高的催化活性和选择性（75％）。 高选择性合成高价值喷气燃料，C2-C6烯烃，C2-C6羧酸; 通过调节OMS-2载体的氧化能力和掺杂Cu2 +离子已经实现了α-羟基酸及其衍生物。

公开(公告)号：US20120241327A1

公开(公告)日：2012-09-27

申请号：US13430209

申请日：2012-03-26

Applicant: Steven L. SUIB ,  Christopher James BROOKS ,  Samuel FRUEH ,  Boxun HU ,  Eric Rolland KREIDLER

Inventor： Steven L. SUIB ,  Christopher James BROOKS ,  Samuel FRUEH ,  Boxun HU ,  Eric Rolland KREIDLER

IPC: C25B3/00 ,  C25B9/08

CPC classification number: C25B1/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/16 ,  C25B3/04 ,  C25B9/08 ,  Y02P20/142

Abstract: The present teachings are directed toward an electrocatalytic cell including a barrier, having at least a first side and a second side opposite the first side, comprising a material permeable to oxygen ions and impermeable to at least CO2, CO, H2, H2O and hydrocarbons, an electrical power supply in communication with the barrier, a catalyst adjacent the first side of the barrier, a supply of feedstock components in communication with the first side of the barrier, a supply of a carrier gas component in communication with the second side of the barrier; wherein the feedstock components contact the catalyst and react to form hydrocarbon-containing components and oxygen-containing components, and the electrical power supply biases the barrier to thereby conduct oxygen ions from the first side to the second side. Also presented are a device and methods for producing carbon nanotubes.

Abstract translation: 本教导涉及包括阻挡物的电催化电池，其具有至少第一侧和与第一侧相对的第二侧，包括可渗透氧离子的材料，并且至少不能透过至少CO 2，CO，H 2，H 2 O和烃， 与屏障连通的电源，与屏障的第一侧相邻的催化剂，与阻挡层的第一侧连通的原料组分的供应，与第二侧连通的载气组分的供应 屏障; 其中所述原料组分与所述催化剂接触并反应以形成含烃组分和含氧组分，并且所述电力供应偏置所述屏障，从而将氧离子从所述第一侧传导至所述第二侧。 还提出了用于生产碳纳米管的装置和方法。

公开(公告)号：US07829492B2

公开(公告)日：2010-11-09

申请号：US11342776

申请日：2006-01-30

Applicant: Paul T Fanson ,  Hirohito Hirata ,  Masaya Ibe ,  Steven L Suib ,  Sinue Gomez ,  Kinga Malinger

Inventor： Paul T Fanson ,  Hirohito Hirata ,  Masaya Ibe ,  Steven L Suib ,  Sinue Gomez ,  Kinga Malinger

IPC: B01J38/06

CPC classification number: B01J38/10 ,  B01D53/007 ,  B01D53/8625 ,  B01D53/9431 ,  B01D53/96 ,  B01D2255/91 ,  B01D2259/806 ,  B01J37/346 ,  B01J38/00 ,  B01J38/02 ,  F01N3/202 ,  Y02T10/22 ,  Y02T10/26

Abstract: A process for removing sulfur and sulfur compounds from a catalyst includes the following steps: exposing the catalyst to a reducing atmosphere and exposing the catalyst to microwave energy. Desorption of the sulfur and sulfur compounds from the catalyst occurs at a temperature less than 600 degrees centigrade.

Abstract translation: 从催化剂中除去硫和硫化合物的方法包括以下步骤：将催化剂暴露于还原气氛中并将催化剂暴露于微波能量。 硫和硫化合物从催化剂中的脱附发生在低于600摄氏度的温度下。

公开(公告)号：US5279808A

公开(公告)日：1994-01-18

申请号：US991885

申请日：1992-12-17

Applicant: Youming Xiao ,  Beng J. Tan ,  Steven L. Suib ,  Francis S. Galasso

Inventor： Youming Xiao ,  Beng J. Tan ,  Steven L. Suib ,  Francis S. Galasso

IPC: C01B21/06 ,  C01B21/072 ,  C01B21/076 ,  C01B2/072 ,  C01B2/076

CPC classification number: C01B21/0726 ,  C01B21/06 ,  C01B21/0765 ,  C01P2002/72

Abstract: A metal nitride powder can be made by heating a reactant powder that includes an oxide or hydroxide of Al, Ti, or Zr to a reaction temperature in a nonreactive atmosphere. The heated reactant powder is contacted with a gaseous reactant mixture comprising a nitrogen source and a carbon source. The molar ratio of nitrogen to carbon in the gaseous reactant mixture is at least about 15. The reactant powder is maintained at the reaction temperature for a sufficient time to convert a portion of it to metal nitride powder.

Abstract translation: 可以通过将包含Al，Ti或Zr的氧化物或氢氧化物的反应物粉末加热至非反应性气氛中的反应温度来制备金属氮化物粉末。 加热的反应物粉末与包含氮源和碳源的气态反应物混合物接触。 气态反应物混合物中氮与碳的摩尔比至少约为15.反应物粉末在反应温度下保持足够的时间以将其一部分转化为金属氮化物粉末。

公开(公告)号：US20120322645A1

公开(公告)日：2012-12-20

申请号：US13328492

申请日：2011-12-16

Applicant: Eric H. Jordan ,  Steven L. Suib ,  Aparna Iyer ,  Jacquelynn Garofano ,  Chun-Hu Chen

Inventor： Eric H. Jordan ,  Steven L. Suib ,  Aparna Iyer ,  Jacquelynn Garofano ,  Chun-Hu Chen

IPC: B29B9/12 ,  C04B35/01 ,  B82Y30/00

CPC classification number: C01B13/185 ,  B82Y30/00 ,  B82Y40/00 ,  C01B13/18 ,  C01F5/06 ,  C01F7/162 ,  C01F17/0043 ,  C01P2002/72 ,  C01P2004/04 ,  C01P2004/64 ,  C04B35/053 ,  C04B35/505 ,  C04B35/624 ,  C04B35/6267 ,  C04B35/62675 ,  C04B35/632 ,  C04B35/636 ,  C04B35/645 ,  C04B2235/3206 ,  C04B2235/3225 ,  C04B2235/3244 ,  C04B2235/447 ,  C04B2235/80 ,  C04B2235/9653

Abstract: Nanocomposites of multi-phase metal oxide ceramics have been produced from water soluble salts of the resulting metal oxides by a foaming esterification sol-gel method. The evolution of volatile gases at elevated temperature during the esterification reaction causes the formation of a foam product. Nanocomposites of multi-phase metal oxide ceramics have also been produced by a cation polymer precursor method. In this second method, the metal cations are chelated by the polymer and the resulting product is gelled and foamed. Calcination of the resulting foams gives nanocomposite powders with extremely fine, uniform grains and phase domains. These microstructures are remarkably stable both under post-calcination heat treatment and during consolidation by hot-pressing.

Abstract translation: 多相金属氧化物陶瓷的纳米复合材料通过发泡酯化溶胶 - 凝胶法由所得金属氧化物的水溶性盐制得。 在酯化反应过程中挥发性气体在高温下的演变导致泡沫产物的形成。 还通过阳离子聚合物前体方法制备了多相金属氧化物陶瓷的纳米复合材料。 在该第二种方法中，金属阳离子被聚合物螯合，所得产物凝胶化并发泡。 所得泡沫的煅烧产生具有极细，均匀的晶粒和相域的纳米复合粉末。 这些微观结构在后煅烧热处理和通过热压固结期间都非常稳定。

公开(公告)号：US07468171B2

公开(公告)日：2008-12-23

申请号：US11342777

申请日：2006-01-30

Applicant: Paul T Fanson ,  Hirohito Hirata ,  Masaya Ibe ,  Steven L Suib ,  Vinit Makwana

Inventor： Paul T Fanson ,  Hirohito Hirata ,  Masaya Ibe ,  Steven L Suib ,  Vinit Makwana

IPC: B01D53/56 ,  B01D53/94 ,  F01N3/10 ,  F01N3/18

CPC classification number: B01D53/8625 ,  B01D53/007 ,  B01D2259/806

Abstract: A process for decomposing nitrogen oxides includes the following steps: providing a catalyst, passing a gaseous nitrogen oxide over the catalyst and exposing the catalyst to microwave energy. The gaseous nitrogen oxide is broken down into nitrogen and oxygen molecules.

Abstract translation: 分解氮氧化物的方法包括以下步骤：提供催化剂，使气态氮氧化物通过催化剂并将催化剂暴露于微波能量。 气态氮氧化物分解成氮和氧分子。

公开(公告)号：US06646127B2

公开(公告)日：2003-11-11

申请号：US09970069

申请日：2001-10-02

Applicant: Russell E. Malz, Jr. ,  Young-Chan Son ,  Steven L. Suib

Inventor： Russell E. Malz, Jr. ,  Young-Chan Son ,  Steven L. Suib

IPC: C07D21140

CPC classification number: C07D211/74

Abstract: A process for the synthesis of 2,2,6,6-tetramethyl-4-oxopiperidine is disclosed wherein the process comprises reacting in a liquid phase reaction mixture: A) at least one acetone compound, and B) at least one ammonia donor compound, in the presence of a catalytically effective amount of a crystalline aluminosilicate containing calcium.

Abstract translation: 公开了一种合成2,2,6,6-四甲基-4-氧代哌啶的方法，其中该方法包括在液相反应混合物中反应：A）至少一种丙酮化合物，和B）至少一种氨供体化合物， 在催化有效量的含有钙的结晶硅铝酸盐的存在下。