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公开(公告)号:US4082864A
公开(公告)日:1978-04-04
申请号:US480090
申请日:1974-06-17
申请人: Ernest G. Kendall , Roger T. Pepper
发明人: Ernest G. Kendall , Roger T. Pepper
CPC分类号: C23C16/38 , C22C49/14 , C23C16/545 , D02G3/02 , Y10T428/12438 , Y10T428/12486 , Y10T428/12625 , Y10T428/12743 , Y10T428/249927 , Y10T428/2916 , Y10T428/2918 , Y10T428/2944 , Y10T428/2949 , Y10T428/30 , Y10T428/31678
摘要: A carbon fiber reinforced metal matrix composite is produced by depositing a metal boride coating on the surface of the fibers and subsequently immersing the fibers in a molten bath of the metal matrix material. The boride coating is formed by passing carbon fiber through a gaseous mixture of chlorides of the metal and boron in the presence of zinc vapor at elevated temperatures. The subsequent reaction deposits out a submicron lamina of metal boride on the carbon fibers serving to enhance wetting of the fibers by the molten metal, with the lamina preventing chemical reaction between the fibers and metal matrix materials and also providing a strong mechanical bond therebetween.
摘要翻译: 通过在纤维表面上沉积金属硼化物涂层并随后将纤维浸入金属基质材料的熔池中来制备碳纤维增强金属基复合材料。 硼化物涂层通过在高温下在锌蒸气存在下使碳纤维通过金属和硼的氯化物的气体混合物而形成。 随后的反应在碳纤维上沉积金属硼化物的亚微米层,用于增强熔融金属对纤维的润湿,而薄层防止了纤维与金属基体材料之间的化学反应,并且在它们之间提供了强大的机械结合。
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公开(公告)号:US4776995A
公开(公告)日:1988-10-11
申请号:US899022
申请日:1986-08-22
申请人: Daniel C. Nelson , Roger T. Pepper
发明人: Daniel C. Nelson , Roger T. Pepper
摘要: A carbonizable body is formed by infusing a plurality of preoxidized, preferably stabilized by known processing to have about 9 to 14 weight percent oxygen, polyacrylonitrile fibers in a polar liquid plasticizer, preferably water, capable of extracting a tarry leachate from the fibers. The infusion of the fibers in the plasticizer is continued for a sufficient time for a substantial amount of leachate to form on the surface of the fibers, and are then consolidated or diffusion-bonded to one another or other fibers, as by orienting the treated fibers in a mold and subjecting them to isostatic pressing at relatively low temperatures and pressure. Further processing of the consolidated fibers with appropriate heat treatment in an inert atmosphere will produce a carbonized bulk product with higher values of Young's modulus for the carbonized material than have been previously achieved at such carbonization temperatures. This carbonaceous product can be truly graphitized by subsequent heat treatment to obtain material with a modulus of at least 40.times.10.sup.6 psi, and a tensile strength of at least 20.times.10.sup.3 psi.
摘要翻译: 可通过将多种预氧化,优选通过已知方法进行稳定化而形成可碳化体,以在极性液体增塑剂(优选水)中具有约9至14重量%的氧,聚丙烯腈纤维,其能够从纤维中提取焦油沥出液。 将增塑剂中的纤维输注持续足够的时间,以在纤维的表面上形成大量的浸出液,然后通过将处理过的纤维取向来固化或扩散粘合到彼此或其它纤维上 并在相对较低的温度和压力下进行等静压。 在惰性气氛中进行适当热处理的固结纤维的进一步加工将产生碳化散体产品,碳化材料的杨氏模量值高于之前在这样的碳化温度下实现的杨氏模量。 该碳质产品可以通过随后的热处理而被真正石墨化,以获得具有至少40×10 6 psi的模量和至少20×10 3 psi的拉伸强度的材料。
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公开(公告)号:US4215764A
公开(公告)日:1980-08-05
申请号:US701562
申请日:1976-07-01
CPC分类号: G10K11/165 , E04B1/84
摘要: An acoustical insulating material comprises a fiber reinforced lead composite sheet or panel. In a preferred embodiment of the invention the fibers are substantially axially parallel aligned with one another. The frequency absorption and transmission characteristics of the material may be varied by mechanically stressing the material, e.g. as by placing the material under tension in the direction of fiber orientation.
摘要翻译: 绝缘材料包括纤维增强的铅复合片或面板。 在本发明的优选实施例中,纤维基本上轴向平行地彼此对准。 材料的频率吸收和传输特性可以通过机械应力材料来改变,例如, 通过将材料张紧在纤维取向的方向。
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公开(公告)号:US5773122A
公开(公告)日:1998-06-30
申请号:US744361
申请日:1996-11-07
CPC分类号: C04B35/83 , Y10T428/24124 , Y10T428/24174 , Y10T428/30 , Y10T442/3504 , Y10T442/3715 , Y10T442/659
摘要: Layered carbon-carbon composites having improved interlaminar tensile strength are disclosed together with a process for making such composites. A metal catalyst is first deposited on a panel comprising a plurality of layers of carbon fiber cloth. The panel is then exposed to a gaseous hydrocarbon in an inert atmosphere at elevated temperature in order to promote the growth of graphite whiskers between the carbon cloth layers.
摘要翻译: 公开了具有改善的层间拉伸强度的层状碳 - 碳复合材料以及制备这种复合材料的方法。 金属催化剂首先沉积在包含多层碳纤维布的面板上。 然后将板在高温下在惰性气氛中暴露于气态烃,以促进碳布层之间的石墨晶须的生长。
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公开(公告)号:US4777093A
公开(公告)日:1988-10-11
申请号:US36084
申请日:1987-04-09
申请人: Daniel C. Nelson , Roger T. Pepper
发明人: Daniel C. Nelson , Roger T. Pepper
CPC分类号: C04B35/83 , D01F9/22 , Y10S428/902 , Y10T428/30
摘要: A carbonizable body is formed by infusing a plurality of preoxidized (preferably stabilized by known processing to have about 9 to 14 weight percent oxygen) polyacrylonitrile fibers in a polar liquid plasticizer, preferably water, capable of extracting a tarry leachate from the fibers. The infusion of the fibers in the plasticizer is continued for a sufficient time for a substantial amount of leachate to form on the surface of the fibers, and are then consolidated or diffusion-bonded to one another or other fibers, as by orienting the treated fibers in a mold and subjecting them to isostatic pressing at relatively low temperatures and pressure. Further processing of the consolidated fibers with appropriate heat treatment in an inert atmosphere will produce a carbonized bulk product with higher values of Young's modulus for the carbonized material than have been previously achieved at such carbonization temperatures. This carbonaceous product can be truly graphitized by subsequent heat treatment to obtain material with a modulus of at least 40.times.10.sup.6 psi, and a tensile strength of at least 20.times.10.sup.3 psi.
摘要翻译: 通过在能够从纤维中提取焦油沥出液的极性液体增塑剂(优选水)中注入多种预氧化(优选通过已知方法稳定化以具有约9至14重量%的氧)聚丙烯腈纤维形成可碳化体。 将增塑剂中的纤维输注持续足够的时间,以在纤维的表面上形成大量的浸出液,然后通过将处理过的纤维取向来固化或扩散粘合到彼此或其它纤维上 并在相对较低的温度和压力下进行等静压。 在惰性气氛中进行适当热处理的固结纤维的进一步加工将产生碳化散体产品,碳化材料的杨氏模量值高于之前在这样的碳化温度下实现的杨氏模量。 该碳质产品可以通过随后的热处理而被真正石墨化,以获得具有至少40×10 6 psi的模量和至少20×10 3 psi的拉伸强度的材料。
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公开(公告)号:US4145471A
公开(公告)日:1979-03-20
申请号:US624809
申请日:1975-10-22
申请人: Ernest G. Kendall , Roger T. Pepper
发明人: Ernest G. Kendall , Roger T. Pepper
CPC分类号: C23C16/38 , C22C49/14 , C23C16/545 , D02G3/02 , Y10T428/12438 , Y10T428/12486 , Y10T428/12625 , Y10T428/12743 , Y10T428/249927 , Y10T428/2916 , Y10T428/2918 , Y10T428/2944 , Y10T428/2949 , Y10T428/30 , Y10T428/31678
摘要: A carbon fiber reinforced metal matrix composite is produced by depositing a metal boride coating on the surface of the fibers and subsequently immersing the fibers in a molten bath of the metal matrix material. The boride coating is formed by passing carbon fiber through a gaseous mixture of chlorides of the metal and boron in the presence of zinc vapor at elevated temperatures. The subsequent reaction deposits out a submicron lamina of metal boride on the carbon fibers serving to enhance wetting of the fibers by the molten metal, with the lamina preventing chemical reaction between the fibers and metal matrix materials and also providing a strong mechanical bond therebetween.
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公开(公告)号:US5597611A
公开(公告)日:1997-01-28
申请号:US591147
申请日:1990-10-01
CPC分类号: C04B35/83 , Y10T428/24124 , Y10T428/24174 , Y10T428/30 , Y10T442/3504 , Y10T442/3715 , Y10T442/659
摘要: Layered carbon-carbon composites having improved interlaminar tensile strength are disclosed together with a process for making such composites. A metal catalyst is first deposited on a panel comprising a plurality of layers of carbon fiber cloth. The panel is then exposed to a gaseous hydrocarbon in an inert atmosphere at elevated temperature in order to promote the growth of graphite whiskers between the carbon cloth layers.
摘要翻译: 公开了具有改善的层间拉伸强度的层状碳 - 碳复合材料以及制备这种复合材料的方法。 金属催化剂首先沉积在包含多层碳纤维布的面板上。 然后将板在高温下在惰性气氛中暴露于气态烃,以促进碳布层之间的石墨晶须的生长。
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公开(公告)号:US4072516A
公开(公告)日:1978-02-07
申请号:US613333
申请日:1975-09-15
申请人: Roger T. Pepper , Thomas A. Zack
发明人: Roger T. Pepper , Thomas A. Zack
IPC分类号: C22C47/08 , C01B31/00 , C04B35/83 , C22C47/00 , C22C47/02 , C22C47/04 , C22C49/14 , D06M11/00 , D06M11/77 , D06M11/79 , D06M11/83 , D06M23/08 , D06M101/00 , D06M101/40 , H01B1/04 , H01C1/04
CPC分类号: C22C49/14
摘要: A novel graphite fiber/metal composite material in which the graphite fibers have an adherent coating of silicon oxide and silicon carbide. The coating protects the graphite surface from attack by carbide forming matrix metals such as aluminum, titanium, magnesium and nickel. In a preferred embodiment of the invention the coating is formed by an intermediate temperature vapor deposition technique involving the reduction of silicon tetrachloride in the presence of hydrogen and an oxygen containing gas.
摘要翻译: 一种新型石墨纤维/金属复合材料,其中石墨纤维具有氧化硅和碳化硅的粘附涂层。 涂层可保护石墨表面免受碳化物形成基体金属如铝,钛,镁和镍的侵蚀。 在本发明的优选实施方案中,通过中间温度气相沉积技术形成涂层,其涉及在氢气和含氧气体存在下还原四氯化硅。
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公开(公告)号:US5200370A
公开(公告)日:1993-04-06
申请号:US615025
申请日:1990-11-16
申请人: James R. Lennox , Roger T. Pepper , Paul V. Chayka
发明人: James R. Lennox , Roger T. Pepper , Paul V. Chayka
IPC分类号: C04B35/622
CPC分类号: C04B35/62227 , Y10S505/704 , Y10S505/74
摘要: Monocrystalline ceramic fibers are disclosed together with a process for preparing such fibers. Polycrystalline ceramic fibers in a tow are coated with a coating that is chemically substantially non-reactive with the ceramic (e.g. alumina fibers coated with molybdenum), and the coated fibers are drawn through a heating zone maintained at a temperature high enough to melt the fibers without melting the coating. The coated fibers are withdrawn from the heating zone and cooled rapidly enough to form a substantially monocrystalline ceramic. The protective coating may thereafter be removed to leave a tow of substantially single-crystal ceramic fibers. Monocrystalline ceramic fibers about 8-20 microns in diameter are prepared by the disclosed process.
摘要翻译: 公开了单晶陶瓷纤维以及制备这种纤维的方法。 丝束中的多晶陶瓷纤维涂覆有与陶瓷化学上基本上不反应的涂层(例如涂覆有钼的氧化铝纤维),并且涂覆的纤维被拉伸通过保持在足够高的温度以熔化纤维的加热区域 不熔化涂层。 将涂覆的纤维从加热区中取出并迅速冷却,形成基本上单晶陶瓷。 此后可以除去保护涂层以留下基本上单晶陶瓷纤维的丝束。 通过公开的方法制备直径约8-20微米的单晶陶瓷纤维。
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公开(公告)号:US4776994A
公开(公告)日:1988-10-11
申请号:US899021
申请日:1986-08-22
申请人: Daniel C. Nelson , Roger T. Pepper
发明人: Daniel C. Nelson , Roger T. Pepper
摘要: A carbonizable body is formed by infusing a plurality of preoxidized, preferably stabilized by known processing to have about 17 to 30 weight percent oxygen, fibers prepared from pitch, in a non-polar liquid plasticizer, typically quinoline, capable of extracting a tarry leachate from the fibers. The infusion of the fibers in the plasticizer is continued for a sufficient time for a substantial amount of leachate to form on the surface of the fibers. The treated fibers are then consolidated or diffusion-bonded to one another or other fibers, as by orienting the treated fibers in a mold and subjecting them to isostatic pressing at relatively low temperatures and pressure. Further processing of the consolidated fibers with appropriate heat treatment in an inert atmosphere will produce a carbonized bulk product with higher values of Young's modulus for the carbonized material than have been previously achieved at such carbonization temperatures. This carbonaceous product can be truly graphitized by subsequent heat treatment to obtain material with a modulus of at least 40.times.10.sup.6 psi, and a tensile strength of at least 20.times.10.sup.3 psi.
摘要翻译: 可通过注入多种预氧化,优选通过已知方法稳定化而形成的可碳化体通过在非极性液体增塑剂(通常为喹啉)中具有约17至30重量%的氧,由间距制备的纤维形成,其能够提取沥青渗滤液 纤维。 将增塑剂中的纤维的输注持续足够的时间,以在纤维的表面上形成大量的浸出液。 然后将经处理的纤维固化或扩散粘合到彼此或其它纤维上,如将经处理的纤维定向在模具中并在相对低的温度和压力下进行等静压。 在惰性气氛中进行适当热处理的固结纤维的进一步加工将产生碳化散体产品,碳化材料的杨氏模量值高于之前在这样的碳化温度下实现的杨氏模量。 该碳质产品可以通过随后的热处理而被真正石墨化,以获得具有至少40×10 6 psi的模量和至少20×10 3 psi的拉伸强度的材料。
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