公开(公告)号：US5367173A

公开(公告)日：1994-11-22

申请号：US128651

申请日：1993-09-30

申请人： Romano Morlotti

发明人： Romano Morlotti

IPC分类号： C09K11/67 ,  C09K11/77 ,  C09K11/78 ,  G03B42/02 ,  G03C5/17 ,  G21K4/00 ,  G01N23/04

CPC分类号： G21K4/00 ,  C09K11/7744 ,  C09K11/7746 ,  C09K11/7768 ,  C09K11/7769 ,  G21K2004/06

摘要： The present invention relates to new phosphors for use in panels, apparatus and methods for recording and reproducing a high energy radiation image, including the steps of stimulating a phosphor image-wise exposed to radiation and detecting the fluorescent light emitted by said phosphor upon stimulation, said phosphor being a green emitting terbium activated alkali metal tantalate, doped with at least one element selected in the group consisting of Mg, Ca, Sr, Ba, Al, Ga, Ge, Pb, Bi, transition elements and lanthanides.

摘要翻译： 本发明涉及用于记录和再现高能量辐射图像的面板，装置和方法中的新型荧光体，包括以下步骤：刺激以图像方式暴露于辐射的荧光体，并在刺激时检测由所述荧光体发射的荧光， 所述荧光体是绿色发射的铽激活的碱金属钽酸盐，掺杂有选自Mg，Ca，Sr，Ba，Al，Ga，Ge，Pb，Bi，过渡元素和镧系元素中的至少一种元素。

公开(公告)号：US5540947A

公开(公告)日：1996-07-30

申请号：US329218

申请日：1994-10-26

申请人： Romano Morlotti ,  Sergio Pizzini ,  Laura Oggioni

发明人： Romano Morlotti ,  Sergio Pizzini ,  Laura Oggioni

IPC分类号： C09K11/08 ,  C09K11/77 ,  C09K11/79 ,  G03C5/17 ,  G21K4/00 ,  B05D5/06

CPC分类号： C09K11/7774 ,  G21K4/00 ,  G21K2004/06

摘要： An X-ray intensifying screen comprises a support and a layer containing a direct emission phosphor formed without a binder. The preferred direct emission phosphor is a rare earth silicate phosphor. Said X-ray intensifying screen is useful in the methods for recording and reproducing high energy radiation images. A process for the preparation of the binderless phosphor layer by reactive spray pyrolysis is also disclosed.

摘要翻译： X射线增强屏幕包括支撑体和包含没有粘合剂形成的直接发射荧光体的层。 优选的直接发射荧光体是稀土硅酸盐荧光体。 所述X射线增强屏幕在用于记录和再现高能辐射图像的方法中是有用的。 还公开了通过反应性喷雾热解制备无粘合剂磷光体层的方法。

公开(公告)号：US5332907A

公开(公告)日：1994-07-26

申请号：US86089

申请日：1993-07-06

申请人： Romano Morlotti

发明人： Romano Morlotti

IPC分类号： G03B42/02 ,  C09K11/77 ,  C09K11/85 ,  G21K4/00 ,  G01N23/04

CPC分类号： G21K4/00 ,  C09K11/7705 ,  C09K11/7773 ,  G21K2004/06

摘要： A method for recording and reproducing a radiation image comprising the steps of (i) causing a phosphor, which can be stimulated with visible or infrared radiations, to absorb a high energy radiation passing through an object, (ii) stimulating phosphor with visible or infrared radiations to release the energy stored as fluorescent light, and (iii) detecting fluorescent light with light detecting means, wherein the photostimulable phosphor is selected from the group consisting of green-emitting trivalent erbium activated barium ytterbium halides, trivalent erbium activated barium fluorohalides and solid solutions thereof, optionally comprising an alkali metal halide. Apparatus for recording and reproducing a radiation image using the above described method. Radiation image storage panel containing the above described photostimulable phosphors. Light-stimulable phosphors selected within the group consisting of green-emitting trivalent erbium activated barium ytterbium halides, trivalent erbium activated barium fluorohalides and solid solutions thereof, optionally comprising an alkali metal halide.

摘要翻译： 一种用于记录和再现辐射图像的方法，包括以下步骤：（i）使可以被可见光或红外辐射刺激的荧光体吸收通过物体的高能量辐射，（ii）用可见光或红外线刺激磷光体 辐射以释放作为荧光灯储存的能量，以及（iii）用光检测装置检测荧光，其中可光激发荧光体选自发绿光三价铒活化钡镱卤化物，三价铒活化钡氟卤化物和固体 其任选地包含碱金属卤化物。 使用上述方法记录和再现放射线图像的装置。 含有上述可光激发荧光体的辐射图像存储面板。 选自绿色发光三价铒活化钡镱卤化物，三价铒活化钡氟卤化物及其固溶体的光刺激性荧光体，任选地包含碱金属卤化物。

公开(公告)号：US5272088A

公开(公告)日：1993-12-21

申请号：US52286

申请日：1993-04-26

申请人： Romano Morlotti

发明人： Romano Morlotti

IPC分类号： G01N31/22 ,  G01N33/50 ,  F21V9/16 ,  H01L21/306

CPC分类号： G01N31/223 ,  Y10T436/20 ,  Y10T436/204998

摘要： Europium activated magnesium oxide phosphors are described as useful photoluminescent materials, to be used in methods for detecting the presence or determining the concentration of carbon dioxide in a sample, comprising the steps of a) exposing to a predetermined wavelength range radiation a carbon dioxide-quenchable photoluminescent phosphor put in contact with the sample to cause the phosphor to store energy radiation, b) stimulating the photoluminescent phosphor with infrared radiation to release the stored energy as photoluminescent light, c) detecting and measuring the intensity of said photoluminescent light and d) correlating the measured intensity with an intensity of the photoluminescent light previously measured at a given reference carbon dioxide pressure value.

摘要翻译： 铕激活的氧化镁荧光体被描述为有用的光致发光材料，用于检测样品中存在或确定二氧化碳浓度的方法，包括以下步骤：a）暴露于预定波长范围辐射二氧化碳可淬火 光致发光荧光体与样品接触以引起荧光体存储能量辐射，b）用红外辐射刺激光致发光荧光体以释放储存的能量作为光致发光光，c）检测和测量所述光致发光光的强度，以及d）相关 测量的强度与先前在给定的参考二氧化碳压力值下测量的光致发光的强度。

公开(公告)号：US5003181A

公开(公告)日：1991-03-26

申请号：US498323

申请日：1990-03-23

申请人： Romano Morlotti

发明人： Romano Morlotti

IPC分类号： G01N21/64 ,  C09K11/77 ,  C09K11/79 ,  G03B42/02 ,  G21K4/00

CPC分类号： G21K4/00 ,  C09K11/7774

摘要： A method for recording and reproducing a radiation image comprising the steps of (i) causing a visible or infrared radiation stimulable phosphor to absorb a high-energy radiation passing through an object, (ii) stimulating said phosphor with visible or infrared radiation to release the stored energy as fluorescent light and (iii) detecting said fluoroescent light with light detecting means, is characterized by the fact that the photostimulable phosphor is selected within the group of rare earth orthosilicates activated with a first activator comprising cerium and/or terbium and a second activator comprising zirconium and/or samarium, wherein rare earth is one of (a) yttrium, (b) yttrium and lutetium and (c) yttrium, lutetium and gadolinium.Panel for storing a radiation image containing the above described photostimulable phosphors.Phosphors selected within the group of rare earth orthosilicates activated with a first activator comprising certium and/or terbium and a second activator comprising zirconium and/or samarium, wherein rare earth is one of (a) yttrium, (b) yttrium and lutetium and (c) yttrium, lutetium and gadolinium.

公开(公告)号：US4792691A

公开(公告)日：1988-12-20

申请号：US68642

申请日：1987-06-30

申请人： Romano Morlotti ,  Florian Krawietz

发明人： Romano Morlotti ,  Florian Krawietz

IPC分类号： C09K11/56 ,  C09K11/60 ,  C09K11/66 ,  G03B42/02 ,  G21K4/00 ,  H04N1/04 ,  G01T1/10 ,  C09K1/22

CPC分类号： C09K11/567 ,  C09K11/602 ,  C09K11/668 ,  G21K4/00

摘要： A method for recording and reproducing a radiation image comprising the steps of (i) causing a phosphor, which can be stimulated by light radiation, to absorb a radiation passing through an object, (ii) stimulating said phosphor with light radiation to release the stored energy as fluorescent light, and (iii) detecting said fluorescent light with light detecting means, is characterized by the fact that said stimulating radiation is in the range of the visible light and the detected fluorescent light is in the range of the infrared radiation. Infrared emitting photostimulable phosphors include barium or strontium sulfates or solid solutions thereof doped with alkali metal ions. A method for obtaining said phosphors comprises heating at a temperature of at least 600.degree. C. A radiation image storage panel includes phosphors which, upon stimulation with visible light, emit radiation in the range of infrared region.

公开(公告)号：US5365071A

公开(公告)日：1994-11-15

申请号：US115826

申请日：1993-09-03

申请人： Romano Morlotti

发明人： Romano Morlotti

IPC分类号： C09K11/00 ,  C09K11/77 ,  C09K11/86 ,  G21K4/00 ,  C09K11/61

CPC分类号： G21K4/00 ,  C09K11/7774 ,  G21K2004/06

摘要： The present invention relates to new phosphors for use in panels, apparatus and methods for recording and reproducing a high energy radiation image, including the steps of stimulating a phosphor image-wise exposed to radiation and detecting the fluorescent light emitted by said phosphor upon stimulation, said phosphor being a UV-blue-emitting trivalent cerium activated rare earth metal halo-silicate, optionally co-activated with one or more co-activators selected from the group consisting of Tb, Zr and Sm.

摘要翻译： 本发明涉及用于记录和再现高能量辐射图像的面板，装置和方法中的新型荧光体，包括以下步骤：刺激以图像方式暴露于辐射的荧光体，并在刺激时检测由所述荧光体发射的荧光， 所述磷光体是发射紫外线蓝色的三价铈活化的稀土金属卤代硅酸盐，任选地与一种或多种选自Tb，Zr和Sm的共激活剂共同活化。

公开(公告)号：US5124564A

公开(公告)日：1992-06-23

申请号：US283572

申请日：1988-12-13

申请人： Claude Fouassier ,  Romano Morlotti

发明人： Claude Fouassier ,  Romano Morlotti

IPC分类号： C09K11/59 ,  C09K11/77 ,  G03B42/02 ,  G21K4/00

CPC分类号： G21K4/00 ,  C09K11/7734

摘要： A method for recording and reproducing a radiation image comprising the steps of (i) causing a visible radiation stimulable phosphor to absorb a high-energy radiation passing through an object, (ii) stimulating said phosphor with visible radiation to release the stored energy as fluorescent light and (iii) detecting said fluorescent light with light detecting means, is characterized by the fact that the photostimulable phosphor is selected within the group of divalent europium activated alkali earth metal halosilicates.Apparatus for recording and reproducing a radiation image using the above described method.Panel for storing a radiation image containing the above described photostimulable phosphors.Phosphors selected within the group of alkali earth metal halosilicates activated with divalent europium in the presence of Al and/or Ga and/or Na and/or K.

公开(公告)号：US4928017A

公开(公告)日：1990-05-22

申请号：US284298

申请日：1988-12-14

申请人： Sibylle Kemmler-Sack ,  Romano Morlotti ,  Jurgen Reichardt

发明人： Sibylle Kemmler-Sack ,  Romano Morlotti ,  Jurgen Reichardt

IPC分类号： C09K11/77 ,  C09K11/79 ,  G03B42/02 ,  G03C20060101 ,  G21K4/00

CPC分类号： C09K11/7774 ,  G21K4/00

摘要： Phosphors constituted by terbium and/or cerium activated lutetium-gadolinium-yttrium silicates have shown a high visible-light emission efficiency upon exposure to high energy radiation.Said phosphors are useful in the methods for recording and reproducing high energy radiation images.