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公开(公告)号：US4496632A
公开(公告)日：1985-01-29
申请号：US450173
申请日：1982-12-16
申请人： Ronald L. Camp , Edward M. Dexheimer , Basil Thir
发明人： Ronald L. Camp , Edward M. Dexheimer , Basil Thir
IPC分类号： C10M107/34 , D06M13/165 , D06M15/53 , B32B27/34 , C10M1/20
CPC分类号： D06M13/165 , D06M7/00 , D06M2200/40 , Y10T428/2933 , Y10T428/2969
摘要： Relates to lubricating thermoplastic synthetic fibers comprising the application to said fibers of a modified polyoxyalkylene polyol which polyol is modified by capping all of the hydroxyl groups with benzyl, aryl, substituted benzyl or aryl groups or alkyl groups having 1 to 4 carbon atoms.
摘要翻译： 涉及润滑热塑性合成纤维，其包括向所述纤维施用改性聚氧化烯多元醇，所述改性聚氧化烯多元醇通过用苄基，芳基，取代的苄基或芳基或具有1至4个碳原子的烷基封端所有羟基而被改性。
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2.发明授权Fiber lubricants based upon ethylene oxide capped polyethers of tetrahydrofuran and ethylene oxide 失效基于环氧乙烷封端的四氢呋喃和环氧乙烷聚醚的纤维润滑剂
公开(公告)号：US4198464A
公开(公告)日：1980-04-15
申请号：US909879
申请日：1978-05-26
IPC分类号： D02G3/36 , D06M13/165
CPC分类号： D06M13/165 , D06M7/00 , C10M2209/107 , D06M2200/40 , Y10T428/2907 , Y10T428/31511
摘要： There are disclosed surface lubricants or processing aids for synthetic fibers particularly polyester, polyacrylic, and polyamide (nylon) fibers or mixtures thereof comprising an ethylene oxide capped heteric polymer of tetrahydrofuran (tetramethylene oxide) and ethylene oxide designated as a heteric/block copolymer having the formula:Y--(A).sub.n --(C.sub.2 H.sub.4 0).sub.m --H].sub.xwherein Y is the residue formed by the removal of x atoms of active hydrogen from an initiator preferably having a total of not more than 20 carbon atoms and free of elements other than carbon, hydrogen, and oxygen, said initiator having 1 to about 5 reactive hydrogen atoms and preferably being selected from the group consisting of water, alkylene glycols, polyalkylene glycols, alkanols, phenols, and alkyl phenols; A is a heteric mixture of ethylene oxide and tetramethylene oxide residues derived from the reaction of ethylene oxide and tetramethylene oxide in the respective ratio by weight of 1:4 to 4:1; x is an integer of 1 to about 5; n is an integer such that the total heteric ethylene oxide-tetramethylene oxide residue weight, n x, is about 90 to about 10 percent by weight of the total oxyalkylene weight of the compound; m is an integer such that the total ethylene oxide residue weight in the cap portion of the compound, m x, is about 10 to about 90 percent, by weight, of the total oxyalkylene weight of the compound; and the total molecular weight of said heteric mixture, n x, is about 500 to about 6000.
摘要翻译： 公开了用于合成纤维的表面润滑剂或加工助剂，特别是聚酯，聚丙烯酸和聚酰胺（尼龙）纤维或其混合物，其包含四氢呋喃（环氧丁烷）和指定为杂多/嵌段共聚物的环氧乙烷封端杂多聚合物，其具有 式：Y-（A）n-（C 2 H 40）m H] x其中Y是通过从优选总共不超过20个碳原子并且不含元素的引发剂除去活性氢的x原子而形成的残基 碳，氢和氧，所述引发剂具有1至约5个反应性氢原子，优选选自水，亚烷基二醇，聚亚烷基二醇，链烷醇，酚和烷基酚; A是由环氧乙烷和四氢呋喃的反应衍生的环氧乙烷和四氢呋喃氧化物的混合物，其重量比为1:4至4:1; x为1〜5的整数， n是整数，使得总杂环氧乙烷 - 四氢呋喃氧化物残余物重量，n x为化合物的总氧化烯重量的约90至约10重量％ m是使化合物的盖部分中的总环氧乙烷残基重量m x为化合物总氧化烯重量的约10至约90重量％的整数; 并且所述杂化混合物的总分子量n x为约500至约6000。
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3.发明授权Polyether-based thickeners with additives for increased efficiency in aqueous systems 失效具有增加水性体系效率的添加剂的聚醚类增稠剂
公开(公告)号：US4395351A
公开(公告)日：1983-07-26
申请号：US252165
申请日：1981-04-08
申请人： Ronald L. Camp
发明人： Ronald L. Camp
IPC分类号： C10M173/02 , B01J13/00
CPC分类号： C10M173/02 , C10M2201/02 , C10M2209/107 , C10M2215/04 , C10M2215/042 , C10M2215/044 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/30 , C10M2221/043 , C10M2223/04 , C10M2223/042 , C10M2223/043 , C10M2225/00 , C10M2225/02 , C10N2240/08 , C10N2250/02
摘要： Polyether-based thickeners for aqueous systems, said polyethers having molecular weights of about 1000 to about 25,000 which are modified by reaction with at least one glycidyl ether having a carbon chain length of about 12 to about 18 carbon atoms, exhibit increased thickening efficiency in the presence of certain organic additives. These are ethoxylated phosphate esters or mixtures of said esters with water-soluble amines. The polyethers contain about 1 to about 20 percent by weight, based upon the weight of the liquid polyether, of a glycidyl ether. Polyether-based thickeners containing an ethoxylated phosphate ester, or said ester in admixture with a water-soluble amine, and thickened aqueous compositions are disclosed together with processes for the preparation of thickened aqueous systems. The polyether-based thickeners of the invention are particularly useful for thickening water or water-glycol mixtures which are useful as hydraulic fluids.
摘要翻译： 用于水性体系的聚醚类增稠剂，所述具有约1000至约25,000的分子量的聚醚通过与至少一个具有约12至约18个碳原子的碳链长度的缩水甘油醚的反应进行改性而显示出增加的增稠效率 存在某些有机添加剂。 这些是乙氧基化磷酸酯或所述酯与水溶性胺的混合物。 聚醚包含约1至约20重量％，基于液体聚醚的重量，缩水甘油醚。 公开了含有乙氧基化磷酸酯或与水溶性胺混合的所述酯和增稠水性组合物的聚醚类增稠剂以及制备增稠水性体系的方法。 本发明的基于聚醚的增稠剂特别可用于增稠水或水 - 乙二醇混合物，其可用作液压油。
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4.发明授权Thickening aqueous systems with alpha-olefin oxide-modified liquid polyether thickeners 失效用α-烯烃氧化物改性的液体聚醚增稠剂增稠含水体系
公开(公告)号：US4354956A
公开(公告)日：1982-10-19
申请号：US170498
申请日：1980-07-21
申请人： Ronald L. Camp
发明人： Ronald L. Camp
CPC分类号： C10M3/00 , C08G65/2606 , C10M2201/02 , C10M2209/107 , C10N2240/08 , C10N2250/02
摘要： New liquid thickeners for aqueous liquids are obtained by capping a liquid straight chain polyoxyalkylene compound derived from ethylene oxide or ethylene oxide and at least one other lower alkylene oxide by reacting said alkylene oxides with at least one active hydrogen-containing initiator having only one active hydrogen atom. The new thickeners are prepared at a molecular weight of about 1000 to about 25,000 utilizing an alpha-olefin oxide having a carbon chain of about 12 to about 18 aliphatic carbon atoms. Both block and heteric polyoxyalkylene compounds are useful. Alternatively, the new thickeners can be made by copolymerizing ethylene oxide or mixed lower alkylene oxides in the presence of said alpha-olefin oxide. The new thickeners exhibit an unexpected increase in viscosity in aqueous systems as compared with prior art liquid polyether thickening agents. The alpha-olefin oxide modified polyether thickening agents of the invention are useful in both water-based and water-glycol based hydraulic fluids.
摘要翻译： 用于水性液体的新型液体增稠剂通过使所述环氧烷与至少一种仅具有一个活性氢的活性氢的引发剂反应来封端来自环氧乙烷或环氧乙烷的液体直链聚氧化烯化合物和至少一种其它低级环氧烷烃 原子。 使用具有约12至约18个脂族碳原子的碳链的α-烯烃氧化物，以约1000至约25,000的分子量制备新的增稠剂。 嵌段和杂多聚氧化烯化合物都是有用的。 或者，新的增稠剂可以通过在所述α-烯烃氧化物的存在下共聚环氧乙烷或混合的低级烯化氧来制备。 与现有技术的液体聚醚增稠剂相比，新型增稠剂在水性体系中的粘度出现意料之外的增加。 本发明的α-烯烃氧化物改性的聚醚增稠剂可用于水基和水 - 乙二醇型液压油。
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公开(公告)号：US06357678B1
公开(公告)日：2002-03-19
申请号：US09430856
申请日：1999-10-29
IPC分类号： B02C1700
CPC分类号： C01B39/026
摘要： Particulate synthetic zeolite is micronized in a liquid organic medium to form a micronized zeolite product having an average (mean) particle size of about 2 microns or less and containing at least 90% by weight, based on the dry weight of the zeolite product, if isolated, of particles no larger than about 5 microns. Preferably, the micronized zeolite product has a mean particle size of 1 micron or less, and at least 90% by weight of the zeolite product, based on the dry weight of the zeolite product, if isolated, has a particle size of 2 microns or less. The liquid organic medium used is (a) inert or substantially inert, (b) devoid or substantially devoid of water, and (c) devoid of a dispersant.
摘要翻译： 颗粒状合成沸石在液体有机介质中微粉化以形成平均（平均）粒度为约2微米或更小并且基于沸石产物的干重至少包含90重量％的微粉化沸石产物，如果 分离的不大于约5微米的颗粒。 优选地，微粉化的沸石产物具有1微米或更小的平均粒度，并且基于沸石产物的干重，至少90重量％的沸石产物，如果分离，其粒径为2微米，或 减。 所使用的液体有机介质是（a）惰性或基本上惰性的，（b）不含或基本上不含水，和（c）不含分散剂。
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6.发明授权
公开(公告)号：US4555549A
公开(公告)日：1985-11-26
申请号：US675018
申请日：1984-11-26
CPC分类号： C08G65/2609 , B29C33/62 , C08L71/02
摘要： The instant invention relates to a rubber lubricant composition characterized by complete wetting of the elastomer surface both before and after vulcanization which gives a matte finish on cooling down that remains soft and does not flake off. This comprises (1) polyoxypropylene-polyoxyethylene block copolymer having a molecular weight of the polyoxypropylene hydrophobe of about 2500 to 4000 and containing 20 to 80 percent oxyethylene groups and (2) an oxyethylated oxypropylated higher alcohol.
摘要翻译： 本发明涉及一种橡胶润滑剂组合物，其特征在于在硫化之前和之后完全润湿弹性体表面，其在冷却时提供无光泽的表面，其保持柔软并且不会脱落。 这包括（1）聚氧丙烯 - 聚氧乙烯嵌段共聚物，该聚氧丙烯 - 聚氧乙烯嵌段共聚物的聚氧丙烯疏水物的分子量为约2500〜4000，含有20〜80％的氧化乙烯基，（2）氧乙基化的氧丙基化高级醇。
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7.发明授权Polyether-based thickeners with additives for increased efficiency in aqueous systems 失效具有增加水性体系效率的添加剂的聚醚类增稠剂
公开(公告)号：US4310436A
公开(公告)日：1982-01-12
申请号：US86836
申请日：1979-10-22
申请人： Ronald L. Camp
发明人： Ronald L. Camp
IPC分类号： C10M173/02 , B01J13/00
CPC分类号： C10M173/02 , C10M2201/02 , C10M2209/107 , C10M2215/04 , C10M2215/042 , C10M2215/044 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/30 , C10M2221/043 , C10M2223/04 , C10M2223/042 , C10M2223/043 , C10M2225/00 , C10M2225/02 , C10N2240/08 , C10N2250/02
摘要： Polyether-based thickeners for aqueous systems, said polyethers having molecular weights of about 1000 to about 25,000 which are modified by reaction with alpha-olefin oxides having about 12 to about 18 carbon atoms, exhibit increased thickening efficiency in the presence of certain organic additives. These are ethoxylated phosphate esters or mixtures of said esters with water-soluble amines. The polyethers contain about 1 to about 20 percent by weight, based upon the weight of the liquid polyether, of an alpha-olefin oxide. Polyether-based thickeners containing an ethoxylated phosphate ester, or said ester in admixture with a water-soluble amine, and thickened aqueous compositions are disclosed together with processes for the preparation of thickened aqueous systems. The polyether-based thickeners of the invention are particularly useful for thickening water or water-glycol mixtures which are useful as hydraulic fluids.
摘要翻译： 用于水性体系的聚醚基增稠剂，所述具有约1000至约25,000分子量的聚醚通过与具有约12至约18个碳原子的α-烯烃氧化物反应而改性，在某些有机添加剂的存在下表现出增加的增稠效率。 这些是乙氧基化磷酸酯或所述酯与水溶性胺的混合物。 聚醚包含约1至约20重量％，基于液体聚醚的重量计，α-烯烃氧化物。 公开了含有乙氧基化磷酸酯或与水溶性胺混合的所述酯和增稠水性组合物的聚醚类增稠剂以及制备增稠水性体系的方法。 本发明的基于聚醚的增稠剂特别可用于增稠水或水 - 乙二醇混合物，其可用作液压油。
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公开(公告)号：US4183821A
公开(公告)日：1980-01-15
申请号：US909744
申请日：1978-05-26
申请人： William K. Langdon , Ronald L. Camp
发明人： William K. Langdon , Ronald L. Camp
摘要： There are disclosed polyoxyalkylene compound demulsifying agents derived from tetrahydrofuran and C.sub.2 -C.sub.4 vicinal alkylene oxides which are heteric/block copolymers; a process for the preparation of said polyoxyalkylene compounds; a demulsified petroleum crude oil; and a batch or continuous process for the demulsification of crude petroleum oil.
摘要翻译： 公开了衍生自四氢呋喃的聚氧化烯化合物破乳剂和作为杂多嵌段共聚物的C 2 -C 4邻位环氧烷烃; 一种制备所述聚氧化烯化合物的方法; 破乳石油原油; 以及用于原油石油破乳的批次或连续过程。
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公开(公告)号：US4528075A
公开(公告)日：1985-07-09
申请号：US648319
申请日：1984-09-07
申请人： Michael J. Anchor , Ronald L. Camp
发明人： Michael J. Anchor , Ronald L. Camp
IPC分类号： C25D3/22
CPC分类号： C25D3/22
摘要： In accordance with the instant invention, there is provided a method for solubilizing benzylidene acetone in a zinc plating bath which comprises adding to said bath, a small amount of a Bisphenol initiated polyoxyalkylene compound.
摘要翻译： 根据本发明，提供了一种将亚苄基丙酮溶解在镀锌浴中的方法，其包括向所述浴中加入少量双酚引发的聚氧化烯化合物。
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公开(公告)号：US4288639A
公开(公告)日：1981-09-08
申请号：US086837
申请日：1979-10-22
申请人： Ronald L. Camp
发明人： Ronald L. Camp
IPC分类号： C07C41/02 , C08G65/26 , C10M173/02 , C07C43/11 , C07C43/164
CPC分类号： C10M173/02 , C08G65/2606 , C10M2201/02 , C10M2209/107 , C10N2240/08 , C10N2250/02
摘要： New liquid thickeners for aqueous liquids are obtained by capping a liquid straight chain polyoxyalkylene compound derived from ethylene oxide or ethylene oxide and at least one other lower alkylene oxide by reacting said alkylene oxides with at least one active hydrogen-containing initiator having only one active hydrogen atom. The new thickeners are prepared at a molecular weight of about 1000 to about 25,000 utilizing an alpha-olefin oxide having a carbon chain of about 12 to about 18 aliphatic carbon atoms. Both block and heteric polyoxyalkylene compounds are useful. Alternatively, the new thickeners can be made by copolymerizing ethylene oxide or mixed lower alkylene oxides in the presence of said alpha-olefin oxide. The new thickeners exhibit an unexpected increase in viscosity in aqueous systems as compared with prior art liquid polyether thickening agents. The alpha-olefin oxide modified polyether thickening agents of the invention are useful in both water-based and water-glycol based hydraulic fluids.
摘要翻译： 用于水性液体的新型液体增稠剂通过使所述环氧烷与至少一种仅具有一个活性氢的活性氢的引发剂反应来封端来自环氧乙烷或环氧乙烷的液体直链聚氧化烯化合物和至少一种其它低级环氧烷烃 原子。 使用具有约12至约18个脂族碳原子的碳链的α-烯烃氧化物，以约1000至约25,000的分子量制备新的增稠剂。 嵌段和杂多聚氧化烯化合物都是有用的。 或者，新的增稠剂可以通过在所述α-烯烃氧化物的存在下共聚环氧乙烷或混合的低级烯化氧来制备。 与现有技术的液体聚醚增稠剂相比，新型增稠剂在水性体系中的粘度出现意料之外的增加。 本发明的α-烯烃氧化物改性的聚醚增稠剂可用于水基和水 - 乙二醇型液压油。
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