公开(公告)号：US20120007263A1

公开(公告)日：2012-01-12

申请号：US13144207

申请日：2010-01-14

申请人： Klaus Leitner ,  Sameer Nalawade

发明人： Klaus Leitner ,  Sameer Nalawade

IPC分类号： B29B9/00 ,  C08G73/18 ,  C08J5/22

CPC分类号： C08G73/18 ,  C08G73/0627 ,  C08G73/0633 ,  H01M8/0289 ,  H01M8/103 ,  H01M8/1048 ,  H01M8/1072 ,  H01M8/109 ,  Y02E60/521 ,  Y02P70/56

摘要： Monomer beads which can be obtained according to a process in which i. one or more aromatic tetraamino compounds are mixed with one or more aromatic carboxylic acids comprising at least two acid groups per carboxylic acid monomer in an extruder and melted at 190° C.-270° C.; ii. the melt is dropletized at 190° C.-270° C. by means of a die located at the extruder outlet; iii. the liquid droplets are collected, cooled and allowed to solidify. The monomer beads are particularly suited to the production of a proton-conducting polymer membrane based on polyazoles.

摘要翻译： 可以根据以下步骤获得的单体珠粒，其中i。 在挤出机中将一种或多种芳族四氨基化合物与一种或多种包含每个羧酸单体的至少两个酸基团的芳族羧酸混合，并在190℃-270℃下熔融。 ii。 熔体通过位于挤出机出口处的模具在190℃-270℃下液滴化; iii。 收集液滴，冷却并使其固化。 单体珠特别适合于制备基于多唑的质子传导性聚合物膜。

公开(公告)号：US20160060417A1

公开(公告)日：2016-03-03

申请号：US14938095

申请日：2015-11-11

申请人： Andreas FUSSL ,  Bangaru SAMPATH ,  Maximilian HOFMANN ,  lngo BELLIN ,  Sameer NALAWADE ,  Klaus HAHN ,  Andreas KÜNKEL ,  Robert LOOS

发明人： Andreas FUSSL ,  Bangaru SAMPATH ,  Maximilian HOFMANN ,  lngo BELLIN ,  Sameer NALAWADE ,  Klaus HAHN ,  Andreas KÜNKEL ,  Robert LOOS

IPC分类号： C08J9/12

CPC分类号： C08J9/127 ,  C08J9/0061 ,  C08J9/16 ,  C08J9/18 ,  C08J2333/14 ,  C08J2367/02 ,  C08J2367/04 ,  C08J2463/00 ,  C08J2467/02 ,  C08L33/068 ,  C08L67/02 ,  C08L67/04 ,  C08L2666/02

摘要： The invention relates to a process for producing expandable pelletized material which comprises polylactic acid which comprises the following steps: a) melting and incorporation by mixing of polylactic acid, one or more further polymers, a diepoxide or polyepoxide, and one or more additives, b) incorporation by mixing of an organic blowing agent into the polymer melt by means of a static or dynamic mixer at a temperature of at least 140° C., c) discharging through a die plate with holes, the diameter of which at the exit from the die is at most 1.5 mm, and d) pelletizing the melt comprising blowing agent directly downstream of the die plate, and under water, at a pressure in the range from 1 to 20 bar. The invention further relates to expandable pelletized material which comprises polylactic acid and which is obtainable by said process.

摘要翻译： 本发明涉及一种生产可膨胀颗粒材料的方法，其包括聚乳酸，其包括以下步骤：a）通过混合聚乳酸，一种或多种其它聚合物，二环氧化物或聚环氧化物和一种或多种添加剂b ）通过在至少140℃的温度下通过静态或动态混合器将有机发泡剂混合到聚合物熔体中，c）通过具有孔的模板排出，孔的直径在出口处 模头最多为1.5mm，d）直接在模板的下游和在水下，在1至20巴的压力范围内造粒包含发泡剂的熔体。 本发明还涉及包含聚乳酸并且可通过所述方法获得的可膨胀颗粒材料。

公开(公告)号：US09212270B2

公开(公告)日：2015-12-15

申请号：US13522031

申请日：2011-01-06

申请人： Andreas Füβl ,  Bangaru Sampath ,  Maximilian Hofmann ,  Ingo Bellin ,  Sameer Nalawade ,  Klaus Hahn ,  Andreas Künkel ,  Robert Loos

发明人： Andreas Füβl ,  Bangaru Sampath ,  Maximilian Hofmann ,  Ingo Bellin ,  Sameer Nalawade ,  Klaus Hahn ,  Andreas Künkel ,  Robert Loos

IPC分类号： C08J9/16 ,  C08J9/18 ,  C08L67/02 ,  C08J9/00 ,  C08L67/04 ,  C08L33/06

CPC分类号： C08J9/127 ,  C08J9/0061 ,  C08J9/16 ,  C08J9/18 ,  C08J2333/14 ,  C08J2367/02 ,  C08J2367/04 ,  C08J2463/00 ,  C08J2467/02 ,  C08L33/068 ,  C08L67/02 ,  C08L67/04 ,  C08L2666/02

摘要： The invention relates to a process for producing expandable pelletized material which comprises polylactic acid which comprises the following steps: a) melting and incorporation by mixing of the following components: i) from 50 to 99.9% by weight, based on the total weight of components i to iii), of polylactic acid, ii) from 0 to 49.9% by weight, based on the total weight of components i to iii), of one or more further polymers, iii) from 0.1 to 2% by weight, based on the total weight of components i to iii), of a diepoxide or polyepoxide, and iv) from 0 to 10% by weight of one or more additives, b) incorporation by mixing of v) from 3 to 7% by weight, based on the total weight of components i to iv), of an organic blowing agent into the polymer melt by means of a static or dynamic mixer at a temperature of at least 140° C., c) discharging through a die plate with holes, the diameter of which at the exit from the die is at most 1.5 mm, and d) pelletizing the melt comprising blowing agent directly downstream of the die plate, and under water, at a pressure in the range from 1 to 20 bar. The invention further relates to expandable pelletized material which comprises polylactic acid and which is obtainable by said process, and also to specific expandable pelletized material which comprises polylactic acid and which has a proportion of from 3 to 7% by weight of an organic blowing agent, preferably n-pentane and particularly preferably isopentane. The invention further relates to a preferred process for producing expandable pelletized material which comprises blowing agent and which comprises polylactic acid, and which has low bulk density.

摘要翻译： 本发明涉及一种生产可膨胀颗粒材料的方法，其包括聚乳酸，其包括以下步骤：a）通过混合以下组分熔融和掺入：i）基于组分的总重量为50至99.9重量％ ii）0至49.9重量％，基于组分i至iii的总重量），一种或多种其它聚合物，iii）基于以下物质的0.1至2重量％，基于 组分i至iii），二环氧化物或聚环氧化物的总重量，和iv）0至10重量％的一种或多种添加剂，b）通过混合v）3至7重量％，基于 通过静态或动态混合器在至少140℃的温度下将有机发泡剂的总成分重量分配到聚合物熔体中，c）通过具有孔的模板排出，直径 其中在模具的出口处至多为1.5mm，以及d）将熔体造粒， 直接在模板的下游，并在水下，在1至20巴的压力范围内。 本发明还涉及包含聚乳酸并且可通过所述方法获得的可膨胀颗粒材料，还涉及包含聚乳酸并且具有3-7重量％的有机发泡剂的比例的特定的可膨胀颗粒状材料， 优选正戊烷，特别优选异戊烷。 本发明还涉及一种用于生产可膨胀颗粒材料的优选方法，其包括发泡剂，其包含聚乳酸，并且其堆积密度低。

公开(公告)号：US20130150468A1

公开(公告)日：2013-06-13

申请号：US13522031

申请日：2011-01-06

申请人： Andreas Füssi ,  Bangaru Sampath ,  Maximilian Hofmann ,  Ingo Bellin ,  Sameer Nalawade ,  Klaus Hahn ,  Andreas Künkel ,  Robert Loos

发明人： Andreas Füssi ,  Bangaru Sampath ,  Maximilian Hofmann ,  Ingo Bellin ,  Sameer Nalawade ,  Klaus Hahn ,  Andreas Künkel ,  Robert Loos

IPC分类号： C08J9/18

CPC分类号： C08J9/127 ,  C08J9/0061 ,  C08J9/16 ,  C08J9/18 ,  C08J2333/14 ,  C08J2367/02 ,  C08J2367/04 ,  C08J2463/00 ,  C08J2467/02 ,  C08L33/068 ,  C08L67/02 ,  C08L67/04 ,  C08L2666/02

摘要： The invention relates to a process for producing expandable pelletized material which comprises polylactic acid which comprises the following steps: a) melting and incorporation by mixing of the following components: i) from 50 to 99.9% by weight, based on the total weight of components i to iii), of polylactic acid, ii) from 0 to 49.9% by weight, based on the total weight of components i to iii), of one or more further polymers, iii) from 0.1 to 2% by weight, based on the total weight of components i to iii), of a diepoxide or polyepoxide, and iv) from 0 to 10% by weight of one or more additives, b) incorporation by mixing of v) from 3 to 7% by weight, based on the total weight of components i to iv), of an organic blowing agent into the polymer melt by means of a static or dynamic mixer at a temperature of at least 140° C., c) discharging through a die plate with holes, the diameter of which at the exit from the die is at most 1.5 mm, and d) pelletizing the melt comprising blowing agent directly downstream of the die plate, and under water, at a pressure in the range from 1 to 20 bar. The invention further relates to expandable pelletized material which comprises polylactic acid and which is obtainable by said process, and also to specific expandable pelletized material which comprises polylactic acid and which has a proportion of from 3 to 7% by weight of an organic blowing agent, preferably n-pentane and particularly preferably isopentane. The invention further relates to a preferred process for producing expandable pelletized material which comprises blowing agent and which comprises polylactic acid, and which has low bulk density.

摘要翻译： 本发明涉及一种生产可膨胀颗粒材料的方法，其包括聚乳酸，其包括以下步骤：a）通过混合以下组分熔融和掺入：i）基于组分的总重量为50至99.9重量％ ii）0至49.9重量％，基于组分i至iii的总重量），一种或多种其它聚合物，iii）基于以下物质的0.1至2重量％，基于 组分i至iii），二环氧化物或聚环氧化物的总重量，和iv）0至10重量％的一种或多种添加剂，b）通过混合v）3至7重量％，基于 通过静态或动态混合器在至少140℃的温度下将有机发泡剂的总成分重量分配到聚合物熔体中，c）通过具有孔的模板排出，直径 其中在模具的出口处至多为1.5mm，以及d）将熔体造粒， 直接在模板的下游，并在水下，在1至20巴的压力范围内。 本发明还涉及包含聚乳酸并且可通过所述方法获得的可膨胀颗粒材料，还涉及包含聚乳酸并且具有3-7重量％的有机发泡剂的比例的特定的可膨胀颗粒状材料， 优选正戊烷，特别优选异戊烷。 本发明还涉及一种用于生产可膨胀颗粒材料的优选方法，其包括发泡剂，其包含聚乳酸，并且其堆积密度低。

公开(公告)号：US09011738B2

公开(公告)日：2015-04-21

申请号：US13144207

申请日：2010-01-14

申请人： Klaus Leitner ,  Sameer Nalawade

发明人： Klaus Leitner ,  Sameer Nalawade

IPC分类号： B01D45/00 ,  H01M8/02 ,  C08G73/06 ,  C08G73/18 ,  H01M8/10

CPC分类号： C08G73/18 ,  C08G73/0627 ,  C08G73/0633 ,  H01M8/0289 ,  H01M8/103 ,  H01M8/1048 ,  H01M8/1072 ,  H01M8/109 ,  Y02E60/521 ,  Y02P70/56

摘要： Monomer beads which can be obtained according to a process in which i. one or more aromatic tetraamino compounds are mixed with one or more aromatic carboxylic acids comprising at least two acid groups per carboxylic acid monomer in an extruder and melted at 190° C.-270° C.; ii. the melt is dropletized at 190° C.-270° C. by means of a die located at the extruder outlet; iii. the liquid droplets are collected, cooled and allowed to solidify. The monomer beads are particularly suited to the production of a proton-conducting polymer membrane based on polyazoles.

摘要翻译： 可以根据以下步骤获得的单体珠粒，其中i。 在挤出机中将一种或多种芳族四氨基化合物与一种或多种包含每个羧酸单体的至少两个酸基团的芳族羧酸混合，并在190℃-270℃下熔融。 ii。 熔体通过位于挤出机出口处的模具在190℃-270℃下液滴化; iii。 收集液滴，冷却并使其固化。 单体珠特别适合于制备基于多唑的质子传导性聚合物膜。

公开(公告)号：US20130059141A1

公开(公告)日：2013-03-07

申请号：US13602870

申请日：2012-09-04

申请人： Andreas Füßl ,  Jan Kurt Walter Sandler ,  Sameer Nalawade ,  Tobias Heinz Steinke ,  Volker Warzelhan ,  Andreas Künkel ,  Klaus Hahn ,  Jerome Lohmann ,  Anna Katharina Brym

发明人： Andreas Füßl ,  Jan Kurt Walter Sandler ,  Sameer Nalawade ,  Tobias Heinz Steinke ,  Volker Warzelhan ,  Andreas Künkel ,  Klaus Hahn ,  Jerome Lohmann ,  Anna Katharina Brym

IPC分类号： C08L67/00 ,  E04B1/74 ,  C08L67/02 ,  C08J9/08 ,  C08K3/20

CPC分类号： C08J9/12 ,  C08J9/0095 ,  C08J2201/03 ,  C08J2367/04 ,  C08J2425/14 ,  C08J2467/02 ,  C08J2469/00

摘要： The present invention relates to foam layers based on a biodegradable polyester mixture PM, comprising: i) from 5 to 49% by weight, based on the total weight of components i to ii, of at least one polypropylene carbonate; ii) from 51 to 95% by weight, based on the total weight of components i to ii, of polylactic acid; iii) from 0 to 25% by weight, based on the total weight of components i to v, of a polyester composed of an (x1) aliphatic and/or (x2) aromatic dicarboxylic acid and of an (y) aliphatic diol; iv) from 0 to 5% by weight, based on the total weight of components i to v, of a copolymer which comprises epoxy groups and which is based on styrene, acrylate, and/or methacrylate; and v) from 0 to 15% by weight, based on the total weight of components i to v, of additives.

摘要翻译： 本发明涉及基于可生物降解的聚酯混合物PM的泡沫层，其包含：i）基于组分i至ii的总重量为5至49重量％的至少一种聚丙烯碳酸酯; ii）基于聚乳酸的组分i至ii的总重量的51至95重量％; iii）基于由（x1）脂族和/或（x2）芳族二羧酸和（y）脂族二醇组成的聚酯的组分i至v的总重量为0至25重量％ iv）基于组分i至v的总重量为0至5重量％的包含环氧基并且基于苯乙烯，丙烯酸酯和/或甲基丙烯酸酯的共聚物; 和v）0至15重量％，基于组分i至v的添加剂的总重量。

公开(公告)号：US20120029137A1

公开(公告)日：2012-02-02

申请号：US13196028

申请日：2011-08-02

申请人： Sachin Jain ,  Sameer Nalawade ,  Andreas Wollny ,  Angelika Homes ,  Gerhard Leiter ,  Motonori Yamamoto

发明人： Sachin Jain ,  Sameer Nalawade ,  Andreas Wollny ,  Angelika Homes ,  Gerhard Leiter ,  Motonori Yamamoto

IPC分类号： C08K3/40

CPC分类号： C08L67/02 ,  C08K7/14 ,  C08L67/00

摘要： The invention relates to thermoplastic molding compositions comprising: A) from 10 to 89% by weight of a polyethylene terephthalate or polybutylene terephthalate, B) from 10 to 60% by weight of a fibrous reinforcing material with a fiber length of from 2 to 24 mm, C) from 1 to 20% by weight of at least one polyester based on aliphatic and aromatic dicarboxylic acids and on an aliphatic dihydroxy compound, D) from 0 to 40% by weight of further additives, where the entirety of components A) to D) is 100%. The invention further relates to the use of thermoplastic molding compositions for producing long-fiber-reinforced pellets and to the pellets thus obtainable. The invention further relates to the use of pellets of this type for producing moldings of any type with good notched impact resistance, and to the resultant moldings.

摘要翻译： 本发明涉及热塑性模塑组合物，其包含：A）10至89重量％的聚对苯二甲酸乙二醇酯或聚对苯二甲酸丁二醇酯，B）10至60重量％的纤维增强材料，纤维长度为2至24毫米 ，C）1至20重量％的至少一种基于脂族和芳族二羧酸的聚酯和脂族二羟基化合物，D）0至40重量％的其它添加剂，其中组分A）至 D）为100％。 本发明还涉及热塑性模塑组合物用于生产长纤维增强颗粒的用途以及由此获得的颗粒。 本发明还涉及这种类型的粒料用于生产具有良好缺口耐冲击性的任何类型的模制品以及所得的模制品。

公开(公告)号：US20150197604A1

公开(公告)日：2015-07-16

申请号：US14667946

申请日：2015-03-25

申请人： Klaus Leitner ,  Sameer Nalawade

发明人： Klaus Leitner ,  Sameer Nalawade

IPC分类号： C08G73/18 ,  H01M8/10

CPC分类号： C08G73/18 ,  C08G73/0627 ,  C08G73/0633 ,  H01M8/0289 ,  H01M8/103 ,  H01M8/1048 ,  H01M8/1072 ,  H01M8/109 ,  Y02E60/521 ,  Y02P70/56

摘要： Monomer beads which can be obtained according to a process in which i. one or more aromatic tetraamino compounds are mixed with one or more aromatic carboxylic acids comprising at least two acid groups per carboxylic acid monomer in an extruder and melted at 190° C.-270° C.; ii. the melt is dropletized at 190° C.-270° C. by means of a die located at the extruder outlet; iii. the liquid droplets are collected, cooled and allowed to solidify. The monomer beads are particularly suited to the production of a proton-conducting polymer membrane based on polyazoles.

摘要翻译： 可以根据以下步骤获得的单体珠粒，其中i。 在挤出机中将一种或多种芳族四氨基化合物与一种或多种包含每个羧酸单体的至少两个酸基团的芳族羧酸混合，并在190℃-270℃下熔融。 ii。 熔体通过位于挤出机出口处的模具在190℃-270℃下液滴化; iii。 收集液滴，冷却并使其固化。 单体珠特别适合于制备基于多唑的质子传导性聚合物膜。

公开(公告)号：US20140357764A1

公开(公告)日：2014-12-04

申请号：US14346442

申请日：2012-09-12

申请人： Sachin Jain ,  Sameer Nalawade

发明人： Sachin Jain ,  Sameer Nalawade

IPC分类号： C08L77/02 ,  C08L27/06

CPC分类号： C08L77/02 ,  C08K9/06 ,  C08L25/06 ,  C08L27/06 ,  C08L33/068 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2205/035 ,  C08L67/02 ,  C08L67/04

摘要： The invention relates to a thermoplastic molding composition comprising: A) from 69 to 98% by weight, based on components A and B, of a thermoplastic selected from the group consisting of polyvinyl chloride, polystyrene, polymethyl methacrylate, polyamide, polybutylene terephthalate, and polyoxymethylene; B) from 2 to 31% by weight, based on components A and B, of a polymer mixture comprising: i) from 30 to 70% by weight, based on the total weight of components i to ii, of at least one polyester based on aliphatic and/or aromatic dicarboxylic acids and on an aliphatic dihydroxy compound; ii) from 70 to 30% by weight, based on the total weight of components i to ii, of polylactic acid; iii) from 0 to 10% by weight, based on the total weight of components i to iv, of a copolymer which contains epoxy groups and which is based on styrene, acrylate, and/or methacrylate; iv) from 0 to 15% by weight, based on the total weight of components i to iv, of nucleating agents, lubricants and antiblocking agents, waxes, antistatic agents, and defogging agents, or dyes; and C) from 0 to 40% by weight, based on components A to C, of other additional materials.

摘要翻译： 本发明涉及一种热塑性模塑组合物，其包含：A）基于组分A和B的69至98重量％的热塑性塑料，其选自聚氯乙烯，聚苯乙烯，聚甲基丙烯酸甲酯，聚酰胺，聚对苯二甲酸丁二醇酯和 聚甲醛; B）基于组分A和B的2至31重量％的聚合物混合物，其包含：i）基于组分i至ii的总重量的30至70重量％的至少一种聚酯基 在脂族和/或芳族二羧酸和脂族二羟基化合物上; ii）70至30重量％，基于组分i至ii的聚乳酸的总重量; iii）基于包含环氧基并且基于苯乙烯，丙烯酸酯和/或甲基丙烯酸酯的共聚物的组分i至iv的总重量为0至10重量％; iv）0至15重量％，基于成分i至iv的总重量，成核剂，润滑剂和防粘连剂，蜡，抗静电剂和除雾剂或染料; 和C）基于组分A至C的0至40重量％的其它另外的材料。

公开(公告)号：US20140303311A1

公开(公告)日：2014-10-09

申请号：US14346407

申请日：2012-09-12

申请人： Sachin Jain ,  Sameer Nalawade

发明人： Sachin Jain ,  Sameer Nalawade

IPC分类号： C08L77/02

CPC分类号： C08L77/02 ,  C08L77/00 ,  C08L67/02

摘要： The present invention relates to thermoplastic molding compositions comprising: A) from 80 to 99.5% by weight, based on components A and B, of a polyamide A; B) from 0.5 to 20% by weight, based on components A and B, of a copolyester B having an intrinsic viscosity according to DIN 53728 of from 150 to 320 cm3/g comprising: B1) from 40 to 80% by weight, based on the total weight of components B1 and B2, of at least one succinic, adipic, azelaic, sebacic or brassylic acid, or their ester-forming derivatives, or a mixture thereof, B2) from 20 to 60% by weight, based on the total weight of components B1 and B2, of terephthalic acid, or its ester-forming derivatives, or a mixture thereof, B3) from 98 to 102 mol %, based on components B1 and B2, of 1,4-butanediol or 1,3-propanediol, or a mixture thereof, as diol component, B4) from 0 to 1% by weight, based on component B, of a branching agent, B5) from 0 to 2% by weight, based on component B, of a chain extender, B6) from 0 to 2% by weight, based on component B, of further additional materials; C) from 0 to 60% by weight, based on components A to D, of a fibrous reinforcing material C; D) from 0 to 10% by weight, based on components A to D, of further additional materials D. The invention further relates to a process for increasing the notched impact resistance in polyamides, and also to the use of the abovementioned molding compositions for producing fibers, foils, and moldings, and also to fibers, foils, and moldings obtainable from said molding compositions.

摘要翻译： 本发明涉及热塑性模塑组合物，其包含：A）基于组分A和B的80至99.5重量％的聚酰胺A; B）基于组分A和B的0.5至20重量％的根据DIN 53728的特性粘度为150至320cm 3 / g的共聚酯B，其包含：B1）40至80重量％的基于 基于组分B1和B2的至少一种琥珀酸，己二酸，壬二酸，癸二酸或丁二酸或其酯形成衍生物或其混合物的组分B1和B2的总重量，B2）为20至60重量％，基于 组分B1和B2的对苯二甲酸或其成酯衍生物或其混合物的总重量，B3）98至102摩尔％，基于组分B1和B2，1,4-丁二醇或1,3 丙二醇或其混合物作为二醇组分，B4）基于组分B的0-1重量％的支化剂B 5）基于组分B的0-2重量％的链 增量剂，B6）0至2重量％，基于组分B的另外的另外的材料; C）0至60重量％，基于纤维增强材料C的组分A至D; D）基于组分A至D的0至10重量％的其它另外的材料D.本发明还涉及增加聚酰胺中的缺口耐冲击性的方法，并且还涉及使用上述模塑组合物 生产纤维，箔和模制品，以及可从所述模塑组合物获得的纤维，箔和模制品。