公开(公告)号：US4152340A

公开(公告)日：1979-05-01

申请号：US826128

申请日：1977-08-19

申请人： Serge-Yvon Delavarenne ,  Pierre Tellier

发明人： Serge-Yvon Delavarenne ,  Pierre Tellier

IPC分类号： C07C50/18 ,  C07C20060101 ,  C07C45/00 ,  C07C67/00 ,  C07C201/00 ,  C07C205/47 ,  C07C49/68

CPC分类号： C07C46/02

摘要： A process which comprises reacting 1,4,4a,5,8,8a,9a,10a-octahydro-anthraquinone with nitrobenzene in the presence of a catalytic amount of a basic compound soluble in the reaction medium and of an inhibitor of free radical reactions to produce anthraquinone.

公开(公告)号：US4128494A

公开(公告)日：1978-12-05

申请号：US822145

申请日：1977-08-05

申请人： Jean-Pierre Schirmann ,  Bernard Dubreux ,  Michel Bakes ,  Serge-Yvon Delavarenne ,  Marie-Christine Daude-Lagrave

发明人： Jean-Pierre Schirmann ,  Bernard Dubreux ,  Michel Bakes ,  Serge-Yvon Delavarenne ,  Marie-Christine Daude-Lagrave

IPC分类号： A61K8/22 ,  A61K8/38 ,  A61K8/42 ,  A61Q5/08 ,  A61Q19/02 ,  C11D3/39 ,  C23C22/06 ,  C11D3/395 ,  C11D7/54 ,  D06L3/02

CPC分类号： A61Q19/02 ,  A61K8/22 ,  A61K8/38 ,  A61K8/42 ,  A61Q5/08 ,  C11D3/3917 ,  C23C22/06

摘要： Novel percompound activators having the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, and R.sub.6 are the same or different and are hydrogen or certain substituted or unsubstituted straight or branched chain alkyl radicals, cycloalkyl radicals, or hydrocarbon radicals containing at least one aromatic ring, or R.sub.5 and/or R.sub.6 are COR.sub.7, where R.sub.7 is hydrogen or certain substituted or unsubstituted straight or branched chain alkyl radicals or hydrocarbon radicals containing at least one aromatic ring, the activators producing more rapid bleaching or oxidation at a given temperature or the same bleaching effect at a lower temperature and being useful for bleaching textile fibers, oils, fats, and waxes; hair and skin treatment; metal surface passivation; or purifying, sterilizing and disinfecting techniques.

摘要翻译： 具有式“IMAGE”的新型全合成活化剂，其中R 1，R 2，R 3，R 4，R 5和R 6相同或不同，为氢或某些取代或未取代的直链或支链烷基，环烷基或含有 至少一个芳环，或R 5和/或R 6为COR 7，其中R 7为氢或某些取代或未取代的直链或支链烷基或含有至少一个芳环的烃基，所述活化剂在给定的条件下产生更快的漂白或氧化 温度或在较低温度下具有相同的漂白效果，并且可用于漂白纺织纤维，油，脂肪和蜡; 头发和皮肤治疗; 金属表面钝化; 或净化，消毒和消毒技术。

公开(公告)号：US3972878A

公开(公告)日：1976-08-03

申请号：US548159

申请日：1975-02-07

申请人： Jean-Pierre Schirmann ,  Jean Combroux ,  Serge Yvon Delavarenne

发明人： Jean-Pierre Schirmann ,  Jean Combroux ,  Serge Yvon Delavarenne

IPC分类号： B01J27/00 ,  B01J31/02 ,  C07C20060101 ,  C07D20060101 ,  C07D213/77 ,  C07C109/00

CPC分类号： C07C251/88 ,  C07C249/16

摘要： Ammonia and aldehydes or ketones are selectively oxidized by hydrogen peroxide to the corresponding azines when they are reacted in the presence of both (a) an amide of a carboxylic acid having a pK greater than about 4.3 and (b) a co-catalyst having the general formula H--X--Y=Z, wherein H is hydrogen, X and Z are each an atom of oxygen or nitrogen and Y is an atom of carbon, nitrogen, arsenic, antimony, phosphorus, sulfur, selenium or tellurium; the atoms of X, Y, and Z carrying other substituents necessary to obey the rules of valence. Preferred co-catalysts include di(alkali metal) hydrogen phosphates, lower dialkyl phosphate esters, bicarbonates and p-toluene sulfonic acid. When 1.degree. or 2.degree. amines are also present, hydrazones are also formed along with the azines. Uses of the resultant products include their hydrolysis to hydrazines with recycling of aldehyde or ketone.

摘要翻译： 当它们在（a）pK大于约4.3的羧酸酰胺存在下反应时，氨和醛或酮被过氧化氢选择性氧化成相应的吖嗪，和（b）具有 通式为HXY = Z，其中H为氢，X和Z各自为氧原子或氮原子，Y为碳，氮，砷，锑，磷，硫，硒或碲的原子; X，Y和Z的原子带有遵守价态规则所必需的其他取代基。 优选的助催化剂包括二（碱金属）氢磷酸盐，低级二烷基磷酸酯，碳酸氢盐和对甲苯磺酸。 当还存在1或2 DEG胺时，腙也与吖嗪一起形成。 所得产物的用途包括它们用醛或酮的再循环将其水解成肼。

公开(公告)号：US4093656A

公开(公告)日：1978-06-06

申请号：US722232

申请日：1976-09-10

申请人： Jean Pierre Schirmann ,  Jean Combroux ,  Serge Yvon Delavarenne

发明人： Jean Pierre Schirmann ,  Jean Combroux ,  Serge Yvon Delavarenne

IPC分类号： C07C251/02 ,  B01J20060101 ,  C07C20060101 ,  C07C67/00 ,  C07C241/00 ,  C07C241/02 ,  C07C251/06 ,  C07C251/08 ,  C07C251/10 ,  C07C251/12 ,  C07C251/14 ,  C07C251/22 ,  C07C251/88 ,  C07C265/02 ,  C07C265/04 ,  C07C265/06 ,  C07C265/08 ,  C07C265/14 ,  C07C119/00

CPC分类号： C07C251/88

摘要： A process is described for the production of azines by contacting in the liquid phase ammonia, hydrogen peroxide and a carbonyl compound, either an aldehyde or a ketone. The reaction takes place in the presence of an amide (I) of a monocarboxylic or dicarboxylic acid, wherein at least one of the ionization constants is below 5 .times. 10.sup.-5, and further in the presence of an inorganic or organic catalyst (II), having the atomic structure H--X--Y.dbd.Z, H representing hydrogen, X and Z representing oxygen or nitrogen and Y representing carbon, nitrogen, phosphorus, arsenic, antimony, sulphur, selenium or tellurium. It is possible for X, Y or Z to carry other substituents, providing valency rules are obeyed. The process is carried out in the presence of the ammonium salt (III) of the carboxylic acid corresponding to the amide (I), at the rate of at least 0.1 mole of the ammonium salt (III) per mole of hydrogen peroxide employed.

摘要翻译： 描述了通过在液相氨，过氧化氢和羰基化合物（醛或酮）中接触来制备吖嗪的方法。 反应在一元羧酸或二羧酸的酰胺（I）存在下进行，其中至少一种电离常数低于5×10-5，进一步在无机或有机催化剂（II）的存在下， 原子结构为HXY = Z，H代表氢，X和Z表示氧或氮，Y表示碳，氮，磷，砷，锑，硫，硒或碲。 X，Y或Z可以携带其他取代基，提供价格规则。 该方法在对应于酰胺（I）的羧酸的铵盐（III）存在下，以每摩尔过氧化氢至少0.1摩尔铵盐（III）的速率进行。

公开(公告)号：US4026908A

公开(公告)日：1977-05-31

申请号：US678129

申请日：1976-04-19

申请人： Michele Pralus ,  Jean-Pierre Schirmann ,  Serge-Yvon Delavarenne

发明人： Michele Pralus ,  Jean-Pierre Schirmann ,  Serge-Yvon Delavarenne

IPC分类号： B01J23/00 ,  B01J31/00 ,  C07B61/00 ,  C07D301/12 ,  C07D303/04

CPC分类号： C07D303/04 ,  C07D301/12

摘要： The present invention relates to a new process for the catalytic epoxidation of olefins which comprises reacting an olefin of the formula ##STR1## in which R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which can be the same or different, represent either a hydrogen atom, a straight alkyl radical having 1 to 30 carbon atoms, a branched alkyl radical or cycloalkyl radical having 3 to 12 carbon atoms, a hydrocarbon radical having 6 to 12 carbon atoms and containing a phenyl group; or R.sub.1 and R.sub.2, or R.sub.3 or R.sub.4 together represent a straight or branched alkylene radical with 3 to 11 carbon atoms, (the radicals R.sub.1, R.sub.2, R.sub.3 and R.sub.4 can be unsaturated and/or substituted with functional groups which are stable in the reaction medium, such as hydroxy, chloro, fluoro, bromo, iodo, nitro (--NO.sub.2), nitroso (--NO), alkoxy, (--OR') amino (--NH.sub.2), carbonyl (=CO), alkylcarbonyl ##STR2## carboxylic acid (--COOH), carboxylic acid ester (--COOR'), amide or carbamyl (--CONH.sub.2), nitrile or cyano (--CN) groups, etc.), with hydrogen peroxide at a pH of between about 6 and 9 in the presence of a catalytic system containing at least one derivative of mercury and at least one derivative of the elements IVA, VA, VIA of the Mendeleev Periodic Table. The two fundamental constituents of the catalyst may either belong to distinct molecules or may form part of the same molecule, for example within a complex.

摘要翻译： 烯烃催化环氧化的新方法本发明涉及烯烃催化环氧化的新方法，该方法包括使式（I）的烯烃与式（Ⅰ）的烯烃反应，其中可以相同或不同的R 1，R 2，R 3和R 4表示氢 原子，碳原子数1〜30的直链烷基，碳原子数3〜12的支链烷基或环烷基，碳原子数6〜12的烃基，含有苯基; 或R 1和R 2或R 3或R 4一起表示具有3至11个碳原子的直链或支链亚烷基（基团R 1，R 2，R 3和R 4可以是不饱和的和/或被反应稳定的官能团取代） 介质，如羟基，氯，氟，溴，碘，硝基（-NO 2），亚硝基（-NO），烷氧基，（-OR'）氨基（-NH 2），羰基（= CO），烷基羰基 酸（-COOH），羧酸酯（-COOR'），酰胺或氨基甲酰基（-CONH 2），腈或氰基（-CN）基团等），其中过氧化氢的pH为约6至9， 含有至少一种汞衍生物和门多列夫周期表元素IVA，VA，VIA的至少一种衍生物的催化体系的存在。 催化剂的两个基本组分可以属于不同的分子，或者可以形成相同分子的一部分，例如在复合物内。