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    TOTAL ORGANIC CARBON (TOC) REDUCTION IN BRINE VIA CHLORINOLYSIS
    5.
    发明申请
    TOTAL ORGANIC CARBON (TOC) REDUCTION IN BRINE VIA CHLORINOLYSIS 审中-公开
    总有机碳（TOC）通过氯化锌在锌中的还原

    公开(公告)号：US20100193443A1

    公开(公告)日：2010-08-05

    申请号：US12670142

    申请日：2008-08-18

    申请人： Sunil K. Chaudhary ,  Bruce Hook ,  Christopher P. Christenson ,  Chauvel J. Jean ,  David West ,  Steve Gluck ,  Celio Lume Pereira ,  Istvan Lengyel ,  Frank Koester

    发明人： Sunil K. Chaudhary ,  Bruce Hook ,  Christopher P. Christenson ,  Chauvel J. Jean ,  David West ,  Steve Gluck ,  Celio Lume Pereira ,  Istvan Lengyel ,  Frank Koester

    IPC分类号： C02F9/04 ,  C02F1/42 ,  C02F1/76 ,  C02F101/30

    CPC分类号： C01D3/14 ,  C01B11/062 ,  C01D3/16

    摘要： A plurality of stages is employed to reduce the total organic carbon (TOC) content of a brine by-product stream to produce a recyclable brine stream having a TOC content of less than about 10 ppm. In a first stage treatment, a brine by-product stream may be subjected to chlorinolysis at a temperature of less than about 125 0C to obtain a chlorinolysis product having a TOC content of less than about 100 ppm, which may be treated in a second stage with activated carbon to obtain a TOC content of less than about 10 ppm. The chlorinolysis may be a reaction with sodium hypochlorite, which may be produced in situ by treatment of the brine by-product stream with chlorine gas and sodium hydroxide. The brine by-product stream may contain a high amount of difficult to remove glycerin, such as a brine by-product stream from the production of epichlorohydrin from glycerin.

    摘要翻译： 采用多个阶段来降低盐水副产物流的总有机碳（TOC）含量，以产生TOC含量小于约10ppm的可再循环盐水。 在第一阶段处理中，盐水副产物流可以在小于约125℃的温度下进行氯解，得到TOC含量小于约100ppm的氯解产物，其可以在第二阶段 用活性炭获得小于约10ppm的TOC含量。 氯解可能是次氯酸钠的反应，其可以通过用氯气和氢氧化钠处理盐水副产物流而原位产生。 盐水副产物流可能含有大量难以除去甘油，例如从丙三醇生产表氯醇的盐水副产物流。