公开(公告)号：US08921495B2

公开(公告)日：2014-12-30

申请号：US13822140

申请日：2011-09-22

申请人： John Bernard Horstman ,  Steven Swier

发明人： John Bernard Horstman ,  Steven Swier

IPC分类号： C08G77/44 ,  C08G77/48 ,  H01L23/29 ,  C08G77/14 ,  C08G77/54 ,  C08G77/26 ,  C08G77/00 ,  C08G77/04 ,  C08G77/16

CPC分类号： C08G77/44 ,  C08G77/04 ,  C08G77/14 ,  C08G77/16 ,  C08G77/26 ,  C08G77/48 ,  C08G77/54 ,  C08G77/70 ,  C08G77/80 ,  H01L23/296 ,  H01L2924/0002 ,  H01L2924/00

摘要： Solid compositions of organosiloxane block copolymers are disclosed having a refractive index greater than 1.5. The organosiloxane block copolymers comprise: 40 to 90 mole percent disiloxy units of the formula [R12SiC2/2] 9 10 to 60 mole percent trisiloxy units of the formula [R2SiO3/2] 0.5 to 35 mole percent silanol groups [≡SiOH] where R1 is independently a C1 to C30 hydrocarbyl, R2 is independently a C1 to C20 hydrocarbyl, wherein; the disiloxy units [R12SiC2/2] are arranged in linear blocks having an average of from 10 to 400 disiloxy units [R12SiC2/2] per linear block, the trisiloxy units [R12SiC3/2] are arranged in non-linear blocks having a molecular weight of at least 500 g/mol, and at least 30% of the non-linear blocks are crosslinked with each other, each linear block is linked to at least one non-linear block, and the organosiloxane block copolymer has a molecular weight (Mw) of at least 20,000 g/mole.

摘要翻译： 公开了折射率大于1.5的有机硅氧烷嵌段共聚物的固体组合物。 有机硅氧烷嵌段共聚物包含：40至90摩尔％的式[R 12 SiCl 2/2] 9的10-甲硅烷氧基单元10至60摩尔％的式[R 2 SiO 3/2]的3-甲硅烷氧基单元为0.5至35摩尔％的硅烷醇基[≡SiOH] 独立地为C1至C30烃基，R2独立地为C1至C20烃基，其中; 二甲硅烷氧基单元[R12SiC2 / 2]排列成每线性嵌段平均为10〜400个二甲硅烷基单元[R 12 SiCl 2/2]的线性嵌段，三硅氧烷单元[R 12 SiCl 3/2]排列在具有分子 至少500g / mol的重量，至少30％的非线性嵌段彼此交联，每个直链嵌段连接至少一个非线性嵌段，有机硅氧烷嵌段共聚物的分子量（ Mw）至少为20,000g / mol。

公开(公告)号：US20140031465A1

公开(公告)日：2014-01-30

申请号：US13983380

申请日：2012-02-01

申请人： John B. Horstman ,  Donald Liles ,  Steven Swier

发明人： John B. Horstman ,  Donald Liles ,  Steven Swier

IPC分类号： C09D183/10

CPC分类号： C09D183/10 ,  C08G77/16 ,  C08G77/44 ,  C08J3/03 ,  C08L83/10

摘要： The present disclosure provides aqueous silicone emulsions of a “resin-linear” organosiloxane block copolymers. The present disclosure further provides a process for making these emulsions by forming a mixture of an organosiloxane block copolymer, admixing a sufficient amount of water to the mixture from to form an emulsion, and optionally further shear mixing the emulsion. The present invention further relates to the cured and/or coating compositions prepared from the present emulsions.

摘要翻译： 本公开提供了“树脂 - 线性”有机硅氧烷嵌段共聚物的水性硅氧烷乳液。 本公开进一步提供了通过形成有机硅氧烷嵌段共聚物的混合物来制备这些乳液的方法，该混合物将足够量的水混合到混合物中以形成乳液，以及任选地进一步剪切混合乳液。 本发明还涉及由本发明的乳液制备的固化和/或涂层组合物。

公开(公告)号：US20130172496A1

公开(公告)日：2013-07-04

申请号：US13822140

申请日：2011-09-22

申请人： John Bernard Horstman ,  Steven Swier

发明人： John Bernard Horstman ,  Steven Swier

IPC分类号： C08G77/44

CPC分类号： C08G77/44 ,  C08G77/04 ,  C08G77/14 ,  C08G77/16 ,  C08G77/26 ,  C08G77/48 ,  C08G77/54 ,  C08G77/70 ,  C08G77/80 ,  H01L23/296 ,  H01L2924/0002 ,  H01L2924/00

摘要： Solid compositions of organosiloxane block copolymers are disclosed having a refractive index greater than 1.5. The organosiloxane block copolymers comprise: 40 to 90 mole percent disiloxy units of the formula [R12SiC2/2] 9 10 to 60 mole percent trisiloxy units of the formula [R2 SiO3/2] 0.5 to 35 mole percent silanol groups [≡SiOH] where R1 is independently a C1 to C30 hydrocarbyl, R2 is independently a C1 to C20 hydrocarbyl, wherein; the disiloxy units [R12SiC2/2] are arranged in linear blocks having an average of from 10 to 400 disiloxy units [R12SiC2/2] per linear block, the trisiloxy units [R12SiC3/2] are arranged in non-linear blocks having a molecular weight of at least 500 g/mol, and at least 30% of the non-linear blocks are crosslinked with each other, each linear block is linked to at least one non-linear block, and the organosiloxane block copolymer has a molecular weight (Mw) of at least 20,000 g/mole.

摘要翻译： 公开了折射率大于1.5的有机硅氧烷嵌段共聚物的固体组合物。 有机硅氧烷嵌段共聚物包括：40至90摩尔％的式[R 12 SiC 2/2] 9的10％至60摩尔％的式[R 2 SiO 3/2]的摩尔三羧基单元为0.5至35摩尔％的硅烷醇基[= SiOH] R 1独立地为C 1至C 30烃基，R 2独立地为C 1至C 20烃基，其中： 二甲硅烷氧基单元[R12SiC2 / 2]排列成每线性嵌段平均为10〜400个二甲硅烷基单元[R 12 SiCl 2/2]的线性嵌段，三硅氧烷单元[R 12 SiCl 3/2]排列在具有分子 至少500g / mol的重量，至少30％的非线性嵌段彼此交联，每个直链嵌段连接至少一个非线性嵌段，有机硅氧烷嵌段共聚物的分子量（ Mw）至少为20,000g / mol。

公开(公告)号：US20130165602A1

公开(公告)日：2013-06-27

申请号：US13822122

申请日：2011-09-22

申请人： John Bernard Horstman ,  Randall Schmidt ,  Steven Swier

发明人： John Bernard Horstman ,  Randall Schmidt ,  Steven Swier

IPC分类号： C08G77/44

CPC分类号： C08G77/44 ,  C08G77/04 ,  C08G77/14 ,  C08G77/16 ,  C08G77/26 ,  C08G77/48 ,  C08G77/54 ,  C08G77/70 ,  C08G77/80 ,  H01L23/296 ,  H01L2924/0002 ,  H01L2924/00

摘要： Solid compositions of organosiloxane block copolymers are disclosed having a tensile strength greater than 1.0 MPa and a % elongation at break greater than 40%. The organosiloxane block copolymers comprise: 40 to 90 mole percent disiloxy units of the formula [R12SiO2/2] 10 to 60 mole percent trisiloxy units of the formula [R2SiO3/2] 0.5 to 35 mole percent silanol groups [≡SiOH] where R1 is independently a C1 to C30 hydrocarbyl, R2 is independently a C1 to C20 hydrocarbyl, wherein; the disiloxy units [R12SiO2/2] are arranged in linear blocks having an average of from 10 to 400 disiloxy units [R12SiO2/2] per linear block, the trisiloxy units [R2SiO3/2] are arranged in non-linear blocks having a molecular weight of at least 500 g/mol, and at least 30% of the non-linear blocks are crosslinked with each other, each linear block is linked to at least one non-linear block, and the organosiloxane block copolymer has a molecular weight (Mw) of at least 20,000 g/mole.

摘要翻译： 公开了具有大于1.0MPa的拉伸强度和断裂伸长率大于40％的有机硅氧烷嵌段共聚物的固体组合物。 有机硅氧烷嵌段共聚物包括：40至90摩尔％的式[R 12 SiO 2/2]的10至60摩尔％的式[R 2 SiO 3/2]的三甲氧基单元的摩尔比为0.5至35摩尔％的硅烷醇基[= SiOH]的式 独立地为C 1至C 30烃基，R 2独立地为C 1至C 20烃基，其中; 二甲硅烷氧基单元[R 12 SiO 2/2]排列成每线性嵌段平均为10〜400个二甲硅烷基单元[R 12 SiO 2/2]的线性嵌段，三硅氧烷单元[R 2 SiO 3/2]排列在具有分子 至少500g / mol的重量，至少30％的非线性嵌段彼此交联，每个直链嵌段连接至少一个非线性嵌段，有机硅氧烷嵌段共聚物的分子量（ Mw）至少为20,000g / mol。

公开(公告)号：US20120125436A1

公开(公告)日：2012-05-24

申请号：US13318787

申请日：2010-06-02

申请人： Michelle Cummings ,  Horstman John Bernard ,  Ann Walstrom Norris ,  Steven Swier

发明人： Michelle Cummings ,  Horstman John Bernard ,  Ann Walstrom Norris ,  Steven Swier

IPC分类号： H01L31/0203 ,  F28F7/00

CPC分类号： C08G77/38 ,  C08L83/06 ,  H01L23/296 ,  H01L23/3737 ,  H01L31/048 ,  H01L31/0481 ,  H01L2924/0002 ,  H01L2924/3011 ,  Y02E10/50 ,  C08L83/00 ,  C08L2666/54 ,  H01L2924/00

摘要： This invention relates to the use of a thermoplastic elastomer comprising at least one silicone ionomer in the formation of electronic devices.

摘要翻译： 本发明涉及包含至少一种硅氧烷离聚物的热塑性弹性体在电子器件形成中的应用。

公开(公告)号：US08975327B2

公开(公告)日：2015-03-10

申请号：US13885250

申请日：2011-11-21

申请人： Ginam Kim ,  Steven Swier

发明人： Ginam Kim ,  Steven Swier

IPC分类号： C08L83/10 ,  C09J183/10 ,  B82Y10/00 ,  C08G77/04 ,  C08G77/00

CPC分类号： C08L83/10 ,  B82Y10/00 ,  C08G77/04 ,  C08G77/70 ,  C08L83/00 ,  C09J183/10 ,  G03F7/0002

摘要： A method for controlling morphology of a silicone organic block copolymer includes adding an MQ resin to the silicone organic block copolymer and annealing. The method is useful for forming thin films, which are useful in electronic device fabrication. The method is also useful for forming adhesives, release coatings, and reversible elastomers.

摘要翻译： 用于控制有机硅嵌段共聚物形态的方法包括向硅氧烷有机嵌段共聚物中加入MQ树脂并进行退火。 该方法对于形成用于电子器件制造的薄膜是有用的。 该方法也可用于形成粘合剂，脱模涂层和可逆弹性体。

公开(公告)号：US08957147B2

公开(公告)日：2015-02-17

申请号：US13822113

申请日：2011-09-21

申请人： Steven Swier ,  John Bernard Horstman

发明人： Steven Swier ,  John Bernard Horstman

IPC分类号： C08G77/44 ,  C08G77/48 ,  C08G77/54 ,  C09D183/10 ,  C08G77/14 ,  C08G77/26 ,  H01L23/29 ,  C08G77/04 ,  C08G77/00

CPC分类号： C09D183/10 ,  C08G77/04 ,  C08G77/14 ,  C08G77/26 ,  C08G77/44 ,  C08G77/48 ,  C08G77/54 ,  C08G77/70 ,  C08G77/80 ,  H01L23/296 ,  H01L2924/0002 ,  H01L2924/00

摘要： Organosiloxane block copolymers, curable compositions, and solid compositions derived from these block copolymers are disclosed. The organosiloxane block copolymers comprise: 40 to 90 mole percent disiloxy units of the formula [R12—SiO2/2] 10 to 60 mole percent trisiloxy units of the formula [R2SiO3/2] 0.5 to 35 mole percent silanol groups [≡SiOH] where R1 is independently a C1 to C30 hydrocarbyl, R2 is independently a C1 to C20 hydrocarbyl, wherein; the disiloxy units [R12SiO2/2] are arranged in linear blocks having an average of from 10 to 400 disiloxy units [R12SiO2/2] per linear block, the trisiloxy units [R2SiO3/2] are arranged in non-linear blocks having a molecular weight of at least 500 g/mol, and at least 30% of the non-linear blocks are crosslinked with each other, each linear block is linked to at least one non-linear block, and the organosiloxane block copolymer has a molecular weight (Mw) of at least 20,000 g/mole.

摘要翻译： 公开了有机硅氧烷嵌段共聚物，可固化组合物和衍生自这些嵌段共聚物的固体组合物。 有机硅氧烷嵌段共聚物包含：40至90摩尔％的式[R 12 -SiO 2/2] 10至60摩尔％的式[R 2 SiO 3/2]的3-甲硅烷氧基单元为0.5至35摩尔％的硅烷醇基[≡SiOH] R 1独立地为C 1至C 30烃基，R 2独立地为C 1至C 20烃基，其中： 二甲硅烷氧基单元[R 12 SiO 2/2]排列成每线性嵌段平均为10〜400个二甲硅烷基单元[R 12 SiO 2/2]的线性嵌段，三硅氧烷单元[R 2 SiO 3/2]排列在具有分子 至少500g / mol的重量，至少30％的非线性嵌段彼此交联，每个直链嵌段连接至少一个非线性嵌段，有机硅氧烷嵌段共聚物的分子量（ Mw）至少为20,000g / mol。

公开(公告)号：US08865830B2

公开(公告)日：2014-10-21

申请号：US13983380

申请日：2012-02-01

申请人： John B. Horstman ,  Donald Liles ,  Steven Swier

发明人： John B. Horstman ,  Donald Liles ,  Steven Swier

IPC分类号： C08K3/00 ,  C08L83/10 ,  C09D183/10 ,  C08G77/44 ,  C08J3/03

CPC分类号： C09D183/10 ,  C08G77/16 ,  C08G77/44 ,  C08J3/03 ,  C08L83/10

摘要： The present disclosure provides aqueous silicone emulsions of a “resin-linear” organosiloxane block copolymers. The present disclosure further provides a process for making these emulsions by forming a mixture of an organosiloxane block copolymer, admixing a sufficient amount of water to the mixture from to form an emulsion, and optionally further shear mixing the emulsion. The present invention further relates to the cured and/or coating compositions prepared from the present emulsions.

摘要翻译： 本公开提供了“树脂 - 线性”有机硅氧烷嵌段共聚物的水性硅氧烷乳液。 本公开进一步提供了通过形成有机硅氧烷嵌段共聚物的混合物来制备这些乳液的方法，该混合物将足够量的水混合到混合物中以形成乳液，以及任选地进一步剪切混合乳液。 本发明还涉及由本发明的乳液制备的固化和/或涂层组合物。

公开(公告)号：US20130171354A1

公开(公告)日：2013-07-04

申请号：US13822099

申请日：2011-09-21

申请人： John Bernard Horstman ,  Steven Swier

发明人： John Bernard Horstman ,  Steven Swier

IPC分类号： C08G77/44

CPC分类号： C09D183/10 ,  C08G77/04 ,  C08G77/14 ,  C08G77/26 ,  C08G77/44 ,  C08G77/48 ,  C08G77/54 ,  C08G77/70 ,  C08G77/80 ,  H01L23/296 ,  H01L2924/0002 ,  H01L2924/00

摘要： A process is disclosed for preparing a resin-linear organosiloxane block copolymer by reacting in a first step an endcapped linear organosiloxane and an organosiloxane resin to form a resin-linear organosiloxane block copolymer. The resulting resin-linear organosiloxane block copolymer is then crosslinked in a second step to sufficiently increase the average molecular weight of the resin-linear organosiloxane block copolymer by at least 50%. The resin-linear organosiloxanes block copolymers prepared by the disclosed process may provide optically solid compositions which may be considered as “reprocessable”.

摘要翻译： 公开了通过在第一步骤中使封端的线性有机硅氧烷和有机硅氧烷树脂反应形成树脂 - 线性有机硅氧烷嵌段共聚物来制备树脂 - 线性有机硅氧烷嵌段共聚物的方法。 然后将所得树脂 - 线性有机硅氧烷嵌段共聚物在第二步中进行交联，以充分提高树脂 - 线性有机硅氧烷嵌段共聚物的平均分子量至少50％。 通过公开的方法制备的树脂 - 线性有机硅氧烷嵌段共聚物可以提供可被认为是“可再加工的”的光学固体组合物。

公开(公告)号：US08329156B2

公开(公告)日：2012-12-11

申请号：US12809610

申请日：2008-12-18

申请人： John Bernard Horstman ,  Randall Schmidt ,  Steven Swier

发明人： John Bernard Horstman ,  Randall Schmidt ,  Steven Swier

IPC分类号： A61K31/765 ,  C08G77/14 ,  C08L83/06 ,  C09J5/06

CPC分类号： A61K31/765 ,  A61K8/893 ,  A61K2800/48 ,  A61Q19/00 ,  C08G77/14 ,  C08G77/398 ,  C08G77/70 ,  C08G2170/20 ,  C08L83/06 ,  C09J5/06 ,  C09J183/06

摘要： This invention relates to thermoplastic elastomers comprising at least one silicone ionomer. These thermoplastic elastomers may be reprocessed and/or recycled.

摘要翻译： 本发明涉及包含至少一种硅氧烷离聚物的热塑性弹性体。 这些热塑性弹性体可以被再加工和/或再循环。