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    Zero-valent transition metal complex and method for producing an organometallic compound using the same as a starting material
    1.
    发明授权
    Zero-valent transition metal complex and method for producing an organometallic compound using the same as a starting material 失效
    零价过渡金属络合物及使用其制造作为起始原料的有机金属化合物的方法

    公开(公告)号：US07361776B2

    公开(公告)日：2008-04-22

    申请号：US10543098

    申请日：2004-02-13

    申请人： Hiroshi Hiraike ,  Takeharu Morita ,  Fumiyuki Ozawa ,  Hiroyuki Katayama

    发明人： Hiroshi Hiraike ,  Takeharu Morita ,  Fumiyuki Ozawa ,  Hiroyuki Katayama

    IPC分类号： C07F15/00 ,  B01J31/00

    CPC分类号： C07F15/0046

    摘要： The present invention relates to a zero-valent transition metal complex which can be used as a starting material for producing a catalyst usable for producing a polyolefin by ring-opening metathesis polymerization of an olefin and an epothilone by ring-closing metathesis reaction, and a method for efficiently producing, at low cost, an organometallic compound useful as a catalyst, using the zero-valent transition metal complex as a starting material. Provided is a method for producing a zero-valent transition metal complex (C), which comprises reacting a divalent transition metal complex (A) with an olefin (B), the complex (A) being selected from the group consisting of a divalent ruthenium complex (A1) and a divalent osmium complex (A2), thereby obtaining a zero-valent transition metal complex (C), wherein the reaction is conducted under reducing conditions and after the reaction, the resultant crude product is extracted at high temperature using a saturated hydrocarbon as an extracting solvent. Also provided is a method for producing an organometallic compound, which comprises reacting the metal complex (C) with a specific compound (D) and a neutral ligand (E) in one step.

    摘要翻译： 本发明涉及一种零价过渡金属络合物，其可以用作制备可用于通过闭环复分解反应的烯烃和埃坡霉素的开环易位聚合制备聚烯烃的催化剂的原料，以及 以低成本有效地生产可用作催化剂的有机金属化合物的方法，使用零价过渡金属络合物作为起始原料。 提供了一种制备零价过渡金属络合物（C）的方法，其包括使二价过渡金属络合物（A）与烯烃（B）反应，所述络合物（A）选自二价钌 络合物（A <1> 1）和二价锇络合物（A 2 O 2），从而得到零价过渡金属络合物（C），其中反应在还原条件下进行 反应后，使用饱和烃作为提取溶剂，在高温下提取所得粗产物。 还提供了一种生产有机金属化合物的方法，其包括在一个步骤中使金属络合物（C）与特定化合物（D）和中性配体（E）反应。

    Process for synthesis of organometallic compounds
    2.
    发明授权
    Process for synthesis of organometallic compounds 失效
    合成有机金属化合物的方法

    公开(公告)号：US07098355B2

    公开(公告)日：2006-08-29

    申请号：US10489604

    申请日：2002-09-27

    申请人： Hiroshi Hiraike ,  Takeharu Morita ,  Fumiyuki Ozawa ,  Hiroyuki Katayama

    发明人： Hiroshi Hiraike ,  Takeharu Morita ,  Fumiyuki Ozawa ,  Hiroyuki Katayama

    IPC分类号： C07F15/00 ,  B01J31/00 ,  C08F4/80

    CPC分类号： C07F15/0046

    摘要： A method for synthesizing an organometallic compound, which is usefully utilized as a catalyst for manufacturing polyolefins by ring-opening metathesis polymerization of an olefin having strain in a molecule such as dicyclopentadiene or synthesizing epothilones by ring-dosing metathesis reaction, by an efficient and low cost synthesis method using a starting material which is easily available due to relatively simple chemical structure, and further without any possibility of coexistence of a vinylhetero compound or a vinyl compound exchanged which tends to accompany as an impurity in the system in conventional methods, characterized by reacting a starting material comprising a zero-valent transition metal complex (A) or a polyvalent transition metal complex (A′), a compound (B) or (B′) shown by the following general formula (1) or (4), respectively, and a neutral ligand (C) or (C′), in one step under non-reducing condition or reducing condition. R1Y1CR2X12  (1) R4Y2CR5X22  (4)

    摘要翻译： 一种合成有机金属化合物的方法，其有效地用作通过在诸如二环戊二烯的分子中具有应变的烯烃的开环易位聚合或通过环 - 给料复分解反应合成埃坡霉素来制备聚烯烃的催化剂，通过有效和低的 使用由于相对简单的化学结构容易获得的起始材料的成本合成方法，并且进一步不存在在常规方法中作为杂质伴随作为杂质的乙烯基杂化物或乙烯基化合物交换的任何可能性，其特征在于 使包含零价过渡金属络合物（A）或多价过渡金属络合物（A'）的起始材料，由以下通式（1）或（4）表示的化合物（B）或（B'）反应， 和中性配体（C）或（C'），在非还原条件或还原条件下一步。 <？in-line-formula description =“In-line Formulas”end =“lead”？> R＆lt; 1＆lt; 1＆lt; 1＆lt; CR 2＆ （1）<？in-line-formula description =“In-Line Formulas”end =“tail”？> <？in-line-formula description = “在线公式”end =“lead”？> R 2 2（4）<？in-line-formula description =“In-line Formulas”end =“tail”？>

    Melt-moldable thermoplastic norbornene resin composition and molded article and optical film both comprising the same
    4.
    发明授权
    Melt-moldable thermoplastic norbornene resin composition and molded article and optical film both comprising the same 失效
    可熔融成型的热塑性降冰片烯树脂组合物及其成型品和光学膜均包括它们

    公开(公告)号：US07015276B2

    公开(公告)日：2006-03-21

    申请号：US10381590

    申请日：2001-10-01

    申请人： Takeharu Morita ,  Hiroshi Hiraike ,  Shoji Nozato

    发明人： Takeharu Morita ,  Hiroshi Hiraike ,  Shoji Nozato

    IPC分类号： C08K5/54 ,  C08L65/00

    CPC分类号： C08L65/00

    摘要： A melt-moldable, thermoplastic norbornene resin composition characterized by being obtained by compounding (A) a base polymer comprising a thermoplastic norbornene resin with (B) an olefin compound having a number-average molecular weight of 200 to 10,000 and a softening point of 70 to 170° C.; and a molded article or optical film obtained by melt-molding or extrusion-molding the thermoplastic norbornene resin composition.

    摘要翻译： 一种可熔融模塑的热塑性降冰片烯树脂组合物，其特征在于通过将（A）包含热塑性降冰片烯树脂的基础聚合物与（B）数均分子量为200至10,000的烯烃化合物和软化点为70 至170℃。 以及通过熔融成型或挤出成型热塑性降冰片烯树脂组合物而获得的模制品或光学膜。

    Telechelic alkadiene polymers with crosslinkable end groups and methods for making the same
    5.
    发明授权
    Telechelic alkadiene polymers with crosslinkable end groups and methods for making the same 有权
    具有可交联端基的转铁链烯二聚物及其制备方法

    公开(公告)号：US06867274B2

    公开(公告)日：2005-03-15

    申请号：US10151757

    申请日：2002-05-21

    申请人： Bob R. Maughon ,  Takeharu Morita ,  Robert H. Grubbs

    发明人： Bob R. Maughon ,  Takeharu Morita ,  Robert H. Grubbs

    IPC分类号： C08F4/70 ,  C08F36/20 ,  C08F12/26 ,  C08F4/44 ,  C08F20/68 ,  C08F20/70

    CPC分类号： C08G61/08 ,  C08F2/38 ,  C08F36/20 ,  C08F290/06 ,  C08F290/14 ,  C08G59/00 ,  C08L19/006 ,  C08L53/02 ,  C08F4/26 ,  C08F4/80 ,  C08L2666/02 ,  C08L2666/14

    摘要： The present invention relates to telechelic polymers having crosslinkable end groups of the formula and methods for preparing the same wherein n is an integer; is an alkadienyl group; Y is an alkyl group; and Z is crosslinkable end group. In general, the inventive synthesis involves reacting a functionalized chain transfer agent having crosslinkable ends with a cycloalkene in the presence of a ruthenium or osmium catalyst of the formula wherein: M is ruthenium or osmium; X and X1 are independently any anionic ligand; L and L1 are any neutral electron donor ligand; R and R1 are each hydrogen or a substituted or unsubstituted substituent wherein the substituent is selected from the group consisting of C1-C20 alkyl, C2-C20 alkenyl, C1-C20 alkynyl, aryl, C1-C20 carboxylate, C1-C20 alkoxy, C2-C20 alkenyloxy, C2-C20 alkynyloxy, aryloxy, C2-C20 alkoxycarbonyl, C1-C20 alkylthio, C1-C20 alkylsulfonyl and C1-C20 alkylsulfinyl. In another aspect of the invention, methods for controlling the molecular weight of the resulting telechelic polymer are also presented.

    摘要翻译： 本发明涉及具有下式的可交联端基的遥爪聚合物及其制备方法，其中n为整数;是二甲苯基; Y为烷基; Z为可交联端基。 一般来说，本发明的合成方法包括在糠醛的钌或锇催化剂的存在下使具有可交联端的官能化链转移剂与环烯反应：M是钌或锇; X和X 1独立地是任何阴离子配体; L和L 1是任何中性电子给体配体; R和R 1各自是氢或取代或未取代的取代基，其中取代基选自C1-C20烷基，C2-C20烯基，C1- C20炔基，芳基，C1-C20羧酸酯，C1-C20烷氧基，C2-C20链烯氧基，C2-C20炔氧基，芳氧基，C2-C20烷氧基羰基，C1-C20烷硫基，C1-C20烷基磺酰基和C1-C20烷基亚磺酰基。 在本发明的另一方面，还提供了用于控制所得遥爪聚合物的分子量的方法。