公开(公告)号：US20130009088A1

公开(公告)日：2013-01-10

申请号：US13541992

申请日：2012-07-05

申请人： Takeshi YAO ,  Shogo Esaki ,  Motoakl Nishijima

发明人： Takeshi YAO ,  Shogo Esaki ,  Motoakl Nishijima

IPC分类号： H01M4/36 ,  H01F1/01 ,  H01M4/48 ,  C09K3/00

CPC分类号： H01M4/483 ,  H01F1/342 ,  H01L35/22 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525

摘要： An multiple inorganic compound structure according to the present invention is a multiple inorganic compound structure including a main crystalline phase, which main crystalline phase contains a sub crystalline phase inside the main crystalline phase, the sub crystalline phase having a non-metallic element arrangement identical to that of the main crystalline phase. A metal element identical to at least one metallic element included in the sub crystalline phase is formed as a solid solution in the main crystalline phase, and its crystal orientation in a main crystalline phase part is identical to that of the sub crystalline phase.

摘要翻译： 根据本发明的多重无机化合物结构是包含主结晶相的多重无机化合物结构，主结晶相在主结晶相内含有亚结晶相，亚结晶相的非金属元素排列与 主要结晶相。 形成与亚结晶相中所含的至少一种金属元素相同的金属元素作为主晶相中的固溶体，其主晶相部分的晶体取向与亚结晶相相同。

公开(公告)号：US20090233176A1

公开(公告)日：2009-09-17

申请号：US12089498

申请日：2006-12-15

申请人： Yosuke Kita ,  Yukishige Inaba ,  Kunihiko Mineya ,  Takeshi Yao

发明人： Yosuke Kita ,  Yukishige Inaba ,  Kunihiko Mineya ,  Takeshi Yao

IPC分类号： H01M4/58

CPC分类号： H01M4/131 ,  H01M4/364 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525

摘要： An object of the present invention is to provide a non-aqueous electrolyte secondary battery that is excellent in cycle characteristics even in a high-temperature environment and high in thermal stability. The non-aqueous electrolyte secondary battery of the present invention comprises at least one of an active material A and an active material C, and an active material B as positive electrode active materials. The active material A is LixCoO2 (0.9≦x≦1.2). The active material B is LixNiyMnzM1-y-zO2 (0.9≦x≦1.2, 0.1≦y≦0.5, 0.2≦z≦0.5, 0.2≦1−y−z≦0.5 and 0.9≦y/z≦2.5; and M is at least one selected from the group consisting of Co, Mg, Al, Ti, Sr, Ca, V, Fe, Y, Zr, Mo, Tc, Ru, Ta, W and Re). The active material C is LixCo1-aMaO2 (0.9≦x≦1.2 and 0.005≦a≦0.1; and M is at least one selected from the group consisting of Mg, Al, Ti, Sr, Mn, Ni, Ca, V, Fe, Y, Zr, Mo, Tc, Ru, Ta, W, Re, Yb, Cu, Zn and Ba).

摘要翻译： 本发明的目的在于提供即使在高温环境下也具有优异的循环特性且热稳定性高的非水电解质二次电池。 本发明的非水电解质二次电池包含活性物质A和活性物质C，作为正极活性物质的活性物质B中的至少一种。 活性物质A为LixCoO2（0.9 <= x <= 1.2）。 活性物质B为LixNiyMnzM1-y-zO2（0.9 <= x <=1.2,0.1≤y≤0.5,0.2≤z≤0.5,0.2≤1-yz≤0.5,0.9≤y/ z <= 2.5; M为选自Co，Mg，Al，Ti，Sr，Ca，V，Fe，Y，Zr，Mo，Tc，Ru，Ta，W和Re中的至少一种）。 活性物质C为LixCo1-aMaO2（0.9 <= x <= 1.2，0.005 <= a <= 0.1; M为选自Mg，Al，Ti，Sr，Mn，Ni，Ca ，V，Fe，Y，Zr，Mo，Tc，Ru，Ta，W，Re，Yb，Cu，Zn和Ba）。

公开(公告)号：US20080118833A1

公开(公告)日：2008-05-22

申请号：US11667110

申请日：2005-11-16

申请人： Atsushi Ueda ,  Shoichiro Watanabe ,  Takeshi Yao ,  Takashi Takeuchi ,  Takayuki Shirane ,  Takaya Saito ,  Hiromi Nagata

发明人： Atsushi Ueda ,  Shoichiro Watanabe ,  Takeshi Yao ,  Takashi Takeuchi ,  Takayuki Shirane ,  Takaya Saito ,  Hiromi Nagata

IPC分类号： H01M4/02 ,  H01M4/58 ,  H01M4/52 ,  H01M10/40

CPC分类号： H01M10/0566 ,  H01M4/131 ,  H01M4/133 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/587 ,  H01M10/0525 ,  H01M10/44 ,  H01M10/448 ,  H01M2010/4292

摘要： A non-aqueous electrolyte secondary battery includes a positive electrode that contains a lithium composite oxide as an active material. The cut-off voltage of charge is set to 4.25 to 4.5 V. In a region where the positive electrode and the negative electrode face each other, the Wp/Wn ratio R is in the range from 1.3 to 19 where Wp is the weight of the active material contained in the positive electrode per unit area and Wn is the weight of the active material contained in the negative electrode per unit area. This battery is excellent in safety, cycle characteristics, and storage characteristics even when the cut-off voltage of charge in a normal operating condition is set to 4.25 V or more.

摘要翻译： 非水电解质二次电池包括含有作为活性物质的锂复合氧化物的正极。 电荷截止电压设定为4.25〜4.5V。在正极和负极彼此面对的区域中，Wp / Wn比R在1.3〜19的范围内，Wp为 包含在每单位面积的正极中的活性物质，Wn是单位面积中负极中含有的活性物质的重量。 即使正常工作状态下的充电截止电压设定为4.25V以上，该电池的安全性，循环特性，存储特性也优异。

公开(公告)号：US6114063A

公开(公告)日：2000-09-05

申请号：US34910

申请日：1998-03-04

申请人： Masumi Katsumoto ,  Norikatsu Akutsu ,  Takeshi Yao ,  Yasuharu Yamamura

发明人： Masumi Katsumoto ,  Norikatsu Akutsu ,  Takeshi Yao ,  Yasuharu Yamamura

IPC分类号： C01G51/00 ,  C01G53/00 ,  H01M4/32 ,  H01M4/36 ,  H01M4/52 ,  H01M4/62 ,  H01M10/24 ,  H01M10/30

CPC分类号： H01M4/366 ,  C01G51/42 ,  C01G53/04 ,  C01G53/42 ,  H01M10/30 ,  H01M4/32 ,  H01M4/52 ,  H01M4/624 ,  C01P2002/54 ,  C01P2002/72 ,  C01P2004/62 ,  C01P2004/80 ,  C01P2004/84 ,  C01P2006/40 ,  H01M2004/021 ,  Y02E60/124

摘要： An alkaline storage battery comprises a positive electrode prepared by filling a nickel hydroxide in a porous plaque as an active material, a negative electrode, a separator and an alkaline electrolyte, the positive electrode containing the nickel hydroxide as a main component and a complex oxide of lithium and cobalt as a conductive agent. The lithium-cobalt complex oxide as a conductive agent is preferably represented by the formula Li.sub.x CoO.sub.2 (x is 0.2-0.9).

摘要翻译： 碱性蓄电池包括通过将氢氧化镍填充在作为活性材料的多孔板中的正极，负极，隔板和碱性电解质，所述正极含有氢氧化镍作为主要成分，并且复合氧化物 锂和钴作为导电剂。 作为导电剂的锂钴复合氧化物优选由式LixCoO 2（x为0.2〜0.9）表示。

公开(公告)号：US6066359A

公开(公告)日：2000-05-23

申请号：US068659

申请日：1998-05-12

申请人： Takeshi Yao ,  Koji Sato ,  Hisayoshi Toratani

发明人： Takeshi Yao ,  Koji Sato ,  Hisayoshi Toratani

IPC分类号： B01J27/12 ,  B01J35/00 ,  B05D5/00 ,  B01J23/00

CPC分类号： B01J27/12 ,  B01J35/002 ,  B01J35/004

摘要： The present invention relates to a process for producing a titanium oxide thin film, said process comprises soaking a substrate in an aqueous solution containing 10.sup.-9 to 9.times.10.sup.-2 mol/L of a titanium fluoro complex compound in the presence of a fluoride ion capturing agent to form a titanium oxide thin film on the surface of the substrate; and a photocatalyst comprising the titanium oxide thin film thus produced; and can provide a simple process for the formation of a highly homogeneous titanium oxide thin film which is fast and corrosion resistant, and has a high refractive index and a catalytic activity for the photoreaction.

摘要翻译： PCT No.PCT / JP97 / 03155 Sec。 371日期：1998年5月12日 102（e）日期1998年5月12日PCT提交1997年9月8日PCT公布。 公开号WO98 / 11020 PCT 日期：1998年3月19日本发明涉及一种氧化钛薄膜的制造方法，其特征在于，所述方法包括在含有10-9〜9×10 -2 mol / L的钛氟配合物的水溶液中浸渍基材， 的氟离子捕获剂，以在衬底的表面上形成氧化钛薄膜; 和包含由此制备的氧化钛薄膜的光催化剂; 并且可以提供用于形成耐高温和耐腐蚀的高度均匀的氧化钛薄膜的简单方法，并且具有高折射率和对于光反应的催化活性。

公开(公告)号：US5759718A

公开(公告)日：1998-06-02

申请号：US570872

申请日：1995-12-12

申请人： Takeshi Yao ,  Michio Ito ,  Tadaya Okada ,  Hajime Konishi

发明人： Takeshi Yao ,  Michio Ito ,  Tadaya Okada ,  Hajime Konishi

IPC分类号： C01G51/04 ,  C01G53/00 ,  H01M4/02 ,  H01M4/32 ,  H01M4/52 ,  H01M4/62 ,  H01M10/30 ,  H01M10/34

CPC分类号： H01M4/52 ,  C01G51/04 ,  C01G53/00 ,  C01P2004/62 ,  C01P2004/80 ,  C01P2004/84 ,  C01P2006/12 ,  C01P2006/40 ,  C01P2006/60 ,  H01M10/345 ,  H01M2004/028 ,  Y02E60/124 ,  Y02P70/54

摘要： Provided are alkaline storage batteries which are higher in active material utilization as compared with conventional batteries and which can maintain the high utilization even after long-term charge-discharge cycle. Cobalt hydroxide having a BET specific surface area of 20-30 m.sup.2 /g and obtained by neutralization reaction of a cobalt salt solution and an aqueous alkali solution in the presence of a reducing agent is added to a positive electrode active material.

摘要翻译： 提供了与常规电池相比活性材料利用率更高的碱性蓄电池，并且即使在长期充放电循环之后也可以保持高的利用率。 在还原剂的存在下，通过钴盐溶液和碱水溶液的中和反应获得的BET比表面积为20〜30m2 / g的氢氧化钴被添加到正极活性物质中。

公开(公告)号：US4744654A

公开(公告)日：1988-05-17

申请号：US63810

申请日：1987-06-17

申请人： Hiroshi Jinno ,  Takeshi Yao

发明人： Hiroshi Jinno ,  Takeshi Yao

IPC分类号： G01M11/02 ,  G01N21/41 ,  G02B6/00

CPC分类号： G01N21/412

摘要： Parallel light rays are applied to a cylinder and true exit positions of the rays from the cylinder are measured, phantom exit positions for the incident rays are calculated by using a mathematical function representing a phantom refractive index profile, and the mathematical function is modified so as to minimize the sum of the squared differences between the true and phantom exit positions.

摘要翻译： 平行光线被施加到气缸，并测量来自气缸的射线的真实出口位置，通过使用表示幻影折射率分布的数学函数来计算入射光线的幻影出射位置，并且数学函数被修改为 以最小化真实和幻影出口位置之间的平方差的总和。

公开(公告)号：US08512732B2

公开(公告)日：2013-08-20

申请号：US12305270

申请日：2007-06-19

申请人： Takeshi Yao ,  Mitsuhiro Hibino ,  Takeshi Yabutsuka

发明人： Takeshi Yao ,  Mitsuhiro Hibino ,  Takeshi Yabutsuka

IPC分类号： A61F2/00 ,  A01N59/26 ,  A61K33/42 ,  A61L27/32 ,  B05D3/00

CPC分类号： A61L27/56 ,  A61L27/32 ,  C08J9/40 ,  C08J2201/038

摘要： An object of the present invention is to provide a method for producing bioactive composites having imparted thereto bioactivity, to thereby form and grow in vivo or in vitro a coating layer containing a calcium phosphate compound as the major component with a high adhesion strength on the surface of various types of porous substrates such as a porous shaped body comprising an organic polymer. The means for solving the problem is characterized by comprising at least (1) a step of immersing a porous substrate in a solution containing at least calcium ions and hydrogenphosphate ions, thereby distributing the solution to the inside of at least a part of the pores of the substrate, and (2) a step of depositing fine particles containing a calcium phosphate compound as the major component inside the pores into which the solution is introduced.

摘要翻译： 本发明的目的是提供一种赋予生物活性的生物活性复合材料的方法，从而在体内或体外形成和生长含有磷酸钙化合物作为主要成分的涂层，在表面上具有高粘合强度 的各种类型的多孔基材，例如包含有机聚合物的多孔成形体。 解决问题的手段的特征在于至少包括（1）将多孔基材浸渍在至少含有钙离子和磷酸氢根离子的溶液中的步骤，从而将溶液分配到至少一部分孔的内部 所述基板，以及（2）将含有磷酸钙化合物的微粒子作为主要成分的细粒沉积在所述溶液引入的孔内的工序。

公开(公告)号：US20110171530A1

公开(公告)日：2011-07-14

申请号：US12985517

申请日：2011-01-06

申请人： Shogo ESAKI ,  Motoaki NISHIJIMA ,  Takeshi YAO ,  Mitsuhiro HIBINO ,  Akira FUJITA

发明人： Shogo ESAKI ,  Motoaki NISHIJIMA ,  Takeshi YAO ,  Mitsuhiro HIBINO ,  Akira FUJITA

IPC分类号： H01M4/50

CPC分类号： H01M4/505

摘要： A cathode active material (1) of the present invention includes: a main crystalline phase (2) including a lithium-containing transition metal oxide containing manganese and having a spinel structure, and in the cathode active material used in a nonaqueous secondary battery, the main crystalline phase (2) includes a layer-shaped sub crystalline phase (3) which is different in elementary composition from that of the lithium-containing transition metal oxide but having an oxygen arrangement identical to that of the lithium-containing transition metal oxide and which has a spinel structure.

摘要翻译： 本发明的正极活性物质（1）包括：含有含锰的具有尖晶石结构的含锂过渡金属氧化物的主结晶相（2），在非水系二次电池中使用的正极活性物质中， 主结晶相（2）包括与含锂过渡金属氧化物不同的层状亚结晶相（3），其具有与含锂过渡金属氧化物相同的氧排列， 其具有尖晶石结构。

公开(公告)号：US20090305143A1

公开(公告)日：2009-12-10

申请号：US12067923

申请日：2007-05-09

申请人： Hiroshi Matsuno ,  Takaharu Morikawa ,  Akihiro Maeda ,  Takeshi Yao

发明人： Hiroshi Matsuno ,  Takaharu Morikawa ,  Akihiro Maeda ,  Takeshi Yao

IPC分类号： H01M10/26 ,  H01M6/16 ,  H01M10/40

CPC分类号： H01M4/13 ,  H01M4/131 ,  H01M4/485 ,  H01M4/525 ,  H01M10/052 ,  H01M10/4235 ,  H01M2004/021 ,  H01M2004/028

摘要： This invention relates to a non-aqueous electrolyte secondary battery including a positive electrode including a positive electrode mixture, a negative electrode, a separator, and a non-aqueous electrolyte. The positive electrode mixture includes a positive electrode active material, and the positive electrode active material includes a lithium nickel composite oxide. The non-aqueous electrolyte includes a non-aqueous solvent and a lithium salt dissolved in the non-aqueous solvent. The amount of moisture contained in the positive electrode mixture is greater than 1000 ppm and equal to or less than 6000 ppm. By adjusting the amount of moisture contained in the positive electrode mixture in the above range, it is possible to improve the cycle characteristics of the non-aqueous electrolyte secondary battery including the lithium nickel composite oxide as the positive electrode active material.

摘要翻译： 本发明涉及一种非水电解质二次电池，其包括正极，其包括正极合剂，负极，隔板和非水电解质。 正极合剂包括正极活性物质，正极活性物质包含锂镍复合氧化物。 非水电解质包括溶解在非水溶剂中的非水溶剂和锂盐。 正极混合物中含有的水分量大于1000ppm且等于或小于6000ppm。 通过将正极混合物中所含的水分量调节在上述范围内，可以提高包含作为正极活性物质的锂镍复合氧化物的非水电解质二次电池的循环特性。