公开(公告)号：US08883939B2

公开(公告)日：2014-11-11

申请号：US13147238

申请日：2010-02-01

Applicant: Mohammed Abboud ,  Philippe Desbois ,  Norbert Gmähle ,  Herbert Römer ,  Thilo Krebs ,  Dennis Lösch

Inventor： Mohammed Abboud ,  Philippe Desbois ,  Norbert Gmähle ,  Herbert Römer ,  Thilo Krebs ,  Dennis Lösch

IPC: C08F2/00 ,  C08G85/00 ,  C08F26/06 ,  C08F20/00 ,  C08F20/58 ,  B01J19/24 ,  C08G69/16 ,  C08G69/04 ,  B01J14/00

CPC classification number: B01J19/2415 ,  B01J14/00 ,  B01J2219/00033 ,  C08G69/04 ,  C08G69/16

Abstract: The invention relates to a process for preparing polymers from monomers and/or oligomers by adding a liquid comprising the monomers and/or oligomers dropwise to a continuous liquid phase in a reactor, the continuous liquid phase being immiscible with the liquid comprising the monomers and/or oligomers, and the monomers and/or oligomers reacting in the continuous liquid phase to give the polymer. The liquid comprising the monomers and/or oligomers is shaped to droplets outside the continuous liquid phase, which are subsequently introduced into the continuous liquid phase. The invention further relates to a reactor for performing the process, comprising a tube through which a continuous liquid phase flows, and means of generating droplets, the means of generating droplets being arranged such that the droplets are generated outside the continuous liquid phase and then introduced into the continuous liquid phase.

Abstract translation: 本发明涉及通过将单体和/或低聚物的液体滴加到反应器中的连续液相中，从单体和/或低聚物制备聚合物的方法，所述连续液相与包含单体的液体和/ 或低聚物，并且单体和/或低聚物在连续液相中反应得到聚合物。 包含单体和/或低聚物的液体成形为连续液相外的液滴，随后将其引入连续液相中。 本发明还涉及一种用于执行该方法的反应器，其包括连续液相流经的管和产生液滴的装置，产生液滴的装置被布置成使得液滴在连续液相外产生，然后引入 进入连续液相。

公开(公告)号：US06783807B2

公开(公告)日：2004-08-31

申请号：US10239826

申请日：2002-09-26

Applicant: Stephan Hüffer ,  Thilo Krebs ,  Klaus-Dieter Hungenberg ,  Ingolf Kühn ,  Ekkehard Jahns ,  Christian Lach ,  Harald Keller ,  Andreas Pfau ,  Thomas Frechen ,  Bernd Diebold ,  Peter Dillmann

Inventor： Stephan Hüffer ,  Thilo Krebs ,  Klaus-Dieter Hungenberg ,  Ingolf Kühn ,  Ekkehard Jahns ,  Christian Lach ,  Harald Keller ,  Andreas Pfau ,  Thomas Frechen ,  Bernd Diebold ,  Peter Dillmann

IPC: B05D312

CPC classification number: C23C18/1662 ,  C23C18/36 ,  Y10T428/12146 ,  Y10T428/12944

Abstract: The surfaces of apparatuses and apparatus parts for chemical plant construction, including, for example, apparatus, container and reactor walls, discharge apparatuses, fittings, pumps, filters, compressors, centrifuges, columns, heat exchangers, dryers, comminuting machines, internals, packings and mixing elements, are coated by a process wherein protuberances having a mean height of from 100 nm to 50 &mgr;m with a mean spacing of from 100 nm to 100 &mgr;m are produced on the surface to be coated and the coating is applied thereon by currentless deposition of a metal layer or of a metal-polymer dispersion layer with the aid of a plating bath which contains a metal electrolyte, a reducing agent and optionally a polymer or polymer blend to be deposited, in dispersed form.

Abstract translation: 用于化学工厂建造的装置和装置部件的表面，包括例如装置，容器和反应器壁，排放装置，配件，泵，过滤器，压缩机，离心机，柱，热交换器，干燥器，粉碎机，内部件，填料 和混合元件通过其中在待涂覆的表面上产生平均高度为100nm至100μm的平均高度为100nm至100μm的平均高度的突起的工艺，并且通过无电沉积施加涂层 金属层或金属 - 聚合物分散层的电镀液，其中分散形式含有金属电解质，还原剂和任选的待沉积的聚合物或聚合物共混物。

公开(公告)号：US20110294968A1

公开(公告)日：2011-12-01

申请号：US13147238

申请日：2010-02-01

Applicant: Mohammed Abboud ,  Philippe Desbois ,  Norbert Gmähle ,  Herbert Römer ,  Thilo Krebs ,  Dennis Lösch

Inventor： Mohammed Abboud ,  Philippe Desbois ,  Norbert Gmähle ,  Herbert Römer ,  Thilo Krebs ,  Dennis Lösch

IPC: C08F2/01 ,  B01J19/00

CPC classification number: B01J19/2415 ,  B01J14/00 ,  B01J2219/00033 ,  C08G69/04 ,  C08G69/16

Abstract: The invention relates to a process for preparing polymers from monomers and/or oligomers by adding a liquid comprising the monomers and/or oligomers dropwise to a continuous liquid phase in a reactor, the continuous liquid phase being immiscible with the liquid comprising the monomers and/or oligomers, and the monomers and/or oligomers reacting in the continuous liquid phase to give the polymer. The liquid comprising the monomers and/or oligomers is shaped to droplets outside the continuous liquid phase, which are subsequently introduced into the continuous liquid phase. The invention further relates to a reactor for performing the process, comprising a tube through which a continuous liquid phase flows, and means of generating droplets, the means of generating droplets being arranged such that the droplets are generated outside the continuous liquid phase and then introduced into the continuous liquid phase.

Abstract translation: 本发明涉及通过将单体和/或低聚物的液体滴加到反应器中的连续液相中，从单体和/或低聚物制备聚合物的方法，所述连续液相与包含单体的液体和/ 或低聚物，并且单体和/或低聚物在连续液相中反应得到聚合物。 包含单体和/或低聚物的液体成形为连续液相外的液滴，随后将其引入连续液相中。 本发明还涉及一种用于执行该方法的反应器，其包括连续液相流经的管和产生液滴的装置，产生液滴的装置被布置成使得液滴在连续液相外产生，然后引入 进入连续液相。

公开(公告)号：US06617047B1

公开(公告)日：2003-09-09

申请号：US09869139

申请日：2001-06-26

Applicant: Stephan Hüffer ,  Thilo Krebs ,  Wolfgang Loth ,  Bernd Rumpf ,  Jürgen Sturm ,  Bernd Diebold ,  Juergen Korkhaus ,  Joachim Nilges ,  Axel Franke

Inventor： Stephan Hüffer ,  Thilo Krebs ,  Wolfgang Loth ,  Bernd Rumpf ,  Jürgen Sturm ,  Bernd Diebold ,  Juergen Korkhaus ,  Joachim Nilges ,  Axel Franke

IPC: B05D136

CPC classification number: F28F19/02 ,  C23C18/1616 ,  C23C18/1662 ,  C23C18/36 ,  Y10T428/12556 ,  Y10T428/12944 ,  Y10T428/31678

Abstract: The present invention relates to a process for coating apparatuses and apparatus parts for chemical plant construction—which are taken to mean, for example, apparatus, tank and reactor walls, discharge devices, valves, pumps, filters, compressors, centrifuges, columns, dryers, comminution machines, internals, packing elements and mixing elements—wherein a metal layer or a metal/polymer dispersion layer is deposited in an electroless manner on the apparatus(es) or apparatus part(s) to be coated by bringing the parts into contact with a metal electrolyte solution which, in addition to the metal electrolyte, comprises a reducing agent and optionally the polymer or polymer mixture to be deposited in dispersed form, where at least one polymer is halogenated.

Abstract translation: 本发明涉及一种用于化工厂建设的涂布设备和设备部件的方法，其被认为是指例如设备，罐和反应器壁，排放装置，阀，泵，过滤器，压缩机，离心机，柱，干燥器 粉碎机，内部构件，填料元件和混合元件，其中金属层或金属/聚合物分散层以无电解的方式沉积在待涂覆的设备或设备部分上，使部件接触 与除了金属电解质之外的金属电解质溶液包含还原剂和任选的待分散形式沉积的聚合物或聚合物混合物，其中至少一种聚合物被卤化。

公开(公告)号：US06683126B2

公开(公告)日：2004-01-27

申请号：US09840887

申请日：2001-04-25

Applicant: Harald Keller ,  Ingolf Kühn ,  Ekkehard Jahns ,  Christian Lach ,  Stephan Hüffer ,  Thilo Krebs ,  Yi Thomann ,  Thomas Frechen

Inventor： Harald Keller ,  Ingolf Kühn ,  Ekkehard Jahns ,  Christian Lach ,  Stephan Hüffer ,  Thilo Krebs ,  Yi Thomann ,  Thomas Frechen

IPC: C08K322

CPC classification number: C09D7/70 ,  C08K3/22 ,  C08K7/24 ,  C08K9/06 ,  C08L27/18 ,  C09D7/65 ,  C09D7/68 ,  C09D7/69 ,  Y10S526/939

Abstract: The present invention provides a coating composition for producing difficult-to-wet surfaces, comprising i) at least one finely divided powder whose particles have a hydrophobic surface and a porous structure characterized by a BET surface area (determined in accordance with DIN 66131) of at least 1 m2/g, and ii) at least one film-forming binder characterized by a surface tension

Abstract translation: 本发明提供了一种用于生产难以湿润的表面的涂料组合物，其包括：i）至少一种细颗粒具有疏水表面的细碎粉末和以BET表面积（根据DIN 66131测定）为特征的多孔结构， 至少1m 2 / g，和）至少一种成膜粘合剂，其特征在于表面张力<50mN / m，粉末与粘合剂的重量比至少为1:4。还提供了一种生产 难以湿润的表面，并且提供了用于生产具有自清洁效果的表面的涂料组合物的用途以及用于降低管道中液体的流动阻力。