Abstract:
A crystalline material substantially free of framework phosphorus and comprising a CHA framework type molecular sieve with stacking faults or at least one intergrown phase of a CHA framework type molecular sieve and an AEI framework type molecular sieve, wherein said material, in its calcined, anhydrous form, has a composition involving the molar relationship: (n)X2O3:YO2, wherein X is a trivalent element; Y is a tetravalent element; and n is from 0 to about 0.5. The material exhibits activity and selectivity in the conversion of methanol to lower olefins, especially ethylene and propylene.
Abstract:
A process for reforming a hydrocarbon feed containing precursors of ethylbenzene, e.g., C8 isoalkane and/or C8 isoalkene precursors of ethylbenzene, that results in the formation of reduced amounts of ethylbenzene. The process is carried out in a catalytic reforming unit comprised of a plurality of operatively connected reactors comprising at least one lead reforming reactor and a tail reforming reactor. The process is carried out by reforming the feed in at least one lead reactor which contains a first reforming catalyst and a catalyst effective for converting ethylbenzene and further reforming the product of the lead reactor in the tail reactor that contains a second reforming catalyst.
Abstract:
The present invention relates to a method for converting a feed including an oxygenate to a product including a light olefin. In particular, this invention relates to converting an oxygenate feedstock with a silicoaluminophosphate catalyst to a product including a light olefin in a reaction apparatus. More particularly, this invention provides a means by which an optimum level of coke can be determined and utilized to generate an optimum or near-optimum yield of light olefins such as ethylene and propylene in a oxygenates to olefins system.