摘要:
Base compositions for addition-crosslinking silicone compositions are continuously produced by, in a first stage, homogeneously mixing and kneading organopolysiloxanes and flowable prehydrophobized oxidic reinforcing fillers in a continuous kneading machine with kneading chambers arranged alongside one another. In a second, downstream, stage of the process, the compositions produced in the first stage are subjected to aftertreatment in a mixing apparatus in which the compositions have been subjected to a mixing procedure with introduction of shear force.
摘要:
Base compositions for addition-crosslinking silicone compositions are continuously produced by, in a first stage, homogeneously mixing and kneading organopolysiloxanes and flowable prehydrophobized oxidic reinforcing fillers in a continuous kneading machine with kneading chambers arranged alongside one another. In a second, downstream, stage of the process, the compositions produced in the first stage are subjected to aftertreatment in a mixing apparatus in which the compositions have been subjected to a mixing procedure with introduction of shear force.
摘要:
The invention describes novel organosilicon compounds containing oligoisobutylene or polyisobutylene groups and comprising at least one unit of the formulaA.sub.a R.sub.b SiX.sub.c O.sub.4-(a+b+c)/2, (I)where R are identical or different and are each a monovalent, divalent or trivalent unsubstituted or substituted hydrocarbon radical, X are identical or different and are each a chlorine atom or a radical of the formula --OR.sup.1, where R.sup.1 is a hydrogen atom or an alkyl radical which may be substituted by an ether oxygen atom, or a radical of the formula--R.sup.2 ([OCH(CH.sub.3)CH.sub.2 ].sub.e [OCH.sub.2 CH.sub.2 ].sub.f [O(CH.sub.2).sub.4 ].sub.g OR.sup.3).sub.y (II)where R.sup.2 is a divalent or trivalent, unsubstituted or substituted hydrocarbon radical which is substituted by one or more groups of the formulae--(C.dbd.O)--O--, --(C.dbd.O)--NR.sup.3 --, --NR.sup.3 --, --O--, --S--,R.sup.3 is a hydrogen atom or R.sup.1 or a radical of the formula--(C.dbd.O)--R.sup.1,e, f and g are each an integer of 0-200, with the proviso that the sum e+f+g.gtoreq.1 and y is 1 or 2,a is 0, 1 or 2,b is 0, 1, 2 or 3,c is 0, 1, 2 or 3 and the sum a+b+c.ltoreq.4, andA is a radical which contains an oligoisobutylene or polyisobutylene group, with the proviso that at least one radical of the formula A is present per molecule.
摘要翻译:本发明描述了含有低聚异丁烯或聚异丁烯基团的新型有机硅化合物,并且包含至少一个式A a R b Si X c O 4 - (a + b + c)/ 2,(I)的单元,其中R相同或不同,并且各自是一价,二价或三价未取代的 或取代的烃基,X相同或不同,并且各自为氯原子或式-OR1的基团,其中R 1为氢原子或可被醚氧原子取代的烷基,或 其中R 2是被一个或多个基团取代的二价或三价,未取代或取代的烃基,其中R 2是(C 1 -C 4 式(C = O)-O - , - (C = O)-NR 3 - , - NR 3 - , - O-,-S-,R 3是氢原子或R 1或式 - ( C = O)-R1,e,f和g各自为0-200的整数,条件是和e + f + g> / = 1和y为1或2,a为0,1或2 ,b为0,1,2或3,c为0,1,2或3,并且和a + b + c为4, 并且A是含有低聚异丁烯或聚异丁烯基团的基团,条件是每个分子存在至少一个式A的基团。
摘要:
Ionic organosilicon compounds comprising siloxane units of the formulaA.sub.a R.sub.b X.sub.c SiO.sub.(4-a-b-c)/2 (I),in whichR is an identical or different, optionally halogenated hydrocarbon radicals having 1 to 12 carbon atoms or radicals of the formulae--R'--((NHCH.sub.2 CH.sub.2).sub.o --(N.sup.+ H.sub.2 CH.sub.2 CH.sub.2).sub.p --N.sup.(x+q-2)+ H.sub.x R".sub.q).sub.d-1 (II)--R'--(SH).sub.d-1 (III)or--R'--(Z--C (O)--CR'"=CH.sub.2).sub.d-1 (IV)in whichR', R", Z, R'", o, p, q, x, d, X and A have the meaning given in claim 1 anda is 0 or 1,b is 0, 1, 2 or 3,c is 0, 1, 2 or 3and the sum a+b+c is.ltoreq.4,with the proviso that at least one radical A is contained in each molecule, and, optionally, non-bonding counter-ions from the group consisting of alkali metal, alkaline earth metal and ammonium ions of organic amines are present to compensate the negative charges and non-bonded counter-ions from the group consisting of organic anions, such as, for example, acetate ions, are present to compensate the positive charges,their preparation and their use.
摘要:
A process for the continuous preparation of addition-crosslinking silicone rubbers from a base composition containing at least one polyvinyl polysiloxane and at least 10% by weight, based on the liquid silicone rubber, of hydrophobicized filler, by removing the base composition from a container whose volume reduces proportionally with the amount removed, and conveying the composition by way of a pump with a positive pressure difference to two further pumps (4) which convey the base composition onward, so a component A is prepared continuously by admixing at least one metal catalyst with one stream of the base composition, and a component B is prepared continuously and simultaneously by admixing the crosslinker and inhibitor with a second stream of the base composition, where the metal catalyst, crosslinker, and inhibitor are fed by way of a feed unit which meters in each of the substances.
摘要:
Organosilicon compounds containing amino groups, their preparation and their use Organosilicon compounds containing amino groups and comprising a) siloxane units of the formula R.sub.a Si(OR.sup.1).sub.b O.sub.(4-a-b)/2 (I) and b) at least one unit per molecule selected from the group consisting of units of the formulae AR.sub.C SiO.sub.(4-c-1)/2 (II), O.sub.(4-c-1)/2 R.sub.C Si--A.sup.1 --R.sub.C SiO.sub.(4-c-1)/2 (III) or ##STR1## where R is an identical or different hydrocarbon radical which has from 1 to 18 carbon atoms, optionally substituted by halogen atoms, alkoxy groups or hydroxy groups where the hydrocarbon radical is optionally interrupted by oxygen atoms, R.sup.1 is an identical or different alkyl radical which is optionally interrupted by oxygen atoms, a is 0, 1, 2 or 3 and b is 0, 1, 2 or 3, with the proviso that the sum a+b is not greater than 3, and c is 0, 1 or 2, A is a radical of the formula --R.sup.2 R.sup.3.sub.z N(--CR.sup.4.sub.2 --R.sup.5).sub.(2-z) (V), A.sup.1 is a radical of the formula ##STR2## and A.sup.2 is a radical of the formula ##STR3## where z is 0 or 1, R.sup.2 is an identical or different alkylene radical having from 2 to 8 carbon atoms, or a radical of the formula ##STR4## R.sup.3 is a hydrogen atom or an alkyl radical having from 1 to 8 carbon atoms, R.sup.4 is a hydrogen atom or an alkyl radical having from 1 to 8 carbon atoms, R.sup.5 is a radical of the formulae --CR.sup.6 .dbd.CR.sup.6.sub.2, --C.tbd.CR.sup.6, where R.sup.6 is identical or different and is a hydrogen atom or an alkyl radical having from 1 to 8 carbon atoms, with the proviso that the organosilicon compound containing amino groups has at least one siloxane unit of formula (II) per molecule and at least one unit selected from the group consisting of units of formulae (III) and (IV) per molecule.
摘要:
The present invention relates to organosilicon compounds containing (meth)acryloxy groups which can be prepared in a simple manner with high selectivity using readily accessible starting substances. The organopolysiloxanes containing (meth)acryloxy groups rapidly crosslink in the presence of a photoinitiator and light. The compounds of the present invention may be employed in the production of coatings.