Permanent organosilicon compounds, their preparation and use
    1.
    发明授权
    Permanent organosilicon compounds, their preparation and use 失效
    永久性有机硅化合物,其制备和用途

    公开(公告)号:US5998562A

    公开(公告)日:1999-12-07

    申请号:US888934

    申请日:1997-07-07

    CPC分类号: C08G77/388 C08G77/54 Y10S8/01

    摘要: The present invention relates to triazine-containing organosilicon compounds having units of the formulaA.sub.a R.sub.b X.sub.c SiO.sub.(4-a-b-c)/2 (I),whereR is identical or different and denotes a hydrogen atom or a monovalent substituted or unsubstituted hydrocarbon radical, having 1 to 26 carbon atoms, preferably 1 to 18 per radical,X is identical or different and is a halogen atom, a chlorine atom or a radical of the formula --OR.sup.1, where R.sup.1 denotes an alkyl radical, having 1 to 18 carbon atoms, preferably 1 to 8 per radical and which may be substituted by an ether oxygen atom,a is 0 or 1, preferably 0.01-0.5b is 0, 1, 2 or 3, preferably 0.5-3.0c is 0, 1, 2 or 3, preferably 0.0-2.0 and the sum a+b+c.ltoreq.4, preferably 0.1-3.5, andA is a radical of the formula ##STR1## where R.sup.2 is an unbranched or branched, optionally substituted alkylene radical, having 1 to 18, preferably 1 to 12, carbon atoms,Y is identical or different and denotes a hydrogen atom or an unbranched or branched alkyl radical, having 1 to 12, preferably 1 to 8, carbon atoms or denotes a radical of the formula --OR.sup.1, where R.sup.1 has the meaning given above, andZ is identical or different and denotes X, --NR.sub.2, --(O)CR or --SR, where X and R have the meanings given above with the proviso that at least one radical A containing at least one halogen atom, preferably a chlorine atom, is present per polymer molecule.

    摘要翻译: 本发明涉及具有式AaRbXcSiO(4-abc)/ 2(I)单元的含三嗪的有机硅化合物,其中R相同或不同,表示氢原子或一价取代或未取代的烃基,其具有1至 26个碳原子,优选1至18个基团,X相同或不同,为卤素原子,氯原子或式-OR1基团,其中R1表示具有1至18个碳原子的烷基,优选1 至8个,并且可被醚氧原子取代,a为0或1,优选为0.01-0.5b为0,1,2或3,优选0.5-3.0c为0,1,2或3,优选为 总和a + b + c 4,优选0.1-3.5,A是下式的基团,其中R 2是无支链或支链的任选取代的亚烷基,其具有1至18,优选1至 12,碳原子,Y相同或不同,表示氢原子或无支链或支链烷基,具有1至12个, 优选为1〜8个碳原子,或表示式-OR1的基团,其中R1具有上述含义,Z相同或不同,表示X,-NR2, - (O)CR或-SR,其中X和 R具有上述含义,条件是每个聚合物分子存在至少一个含有至少一个卤素原子,优选氯原子的基团A.

    Radiation-curing or heat-curing organosiloxane compositions containing
(methyl) styrene groups
    2.
    发明授权
    Radiation-curing or heat-curing organosiloxane compositions containing (methyl) styrene groups 失效
    含有(甲基)苯乙烯基团的辐射固化或热固化有机硅氧烷组合物

    公开(公告)号:US6068929A

    公开(公告)日:2000-05-30

    申请号:US72211

    申请日:1998-05-04

    摘要: Novel organosiloxane compositions which contain (methyl)styrene groups and can be prepared on the basis ofA) oligomeric or polymeric organosilicon compounds comprising at least one unit of the formulaGR.sub.c SiO.sub.(4-c-1)/2 (I)or at least one unit of the formula (I) and at least one unit of the formulaO.sub.(4-c-1)/2) R.sub.c Si--G.sup.1 --R.sub.c SiO.sub.(4-c-1)/2(II)B) monomeric alkenyloxy compounds, maleates, fumarates, maleimides, (meth)acrylates, (methyl)styrenes, acrylamides, itaconic esters and/or oligomeric or polymeric organosilicon compounds containing on average more than one alkenyloxy, maleate, fumarate, maleimide or (meth)acrylate group, where R are identical or different hydrocarbon radicals which may be halogenated or unhalogenated or a radical of the formula--R.sup.1 --[OCH.sub.2 CH.sub.2 ].sub.o --[OCH(CH.sub.3)CH.sub.2 ].sub.p --[O(CH.sub.2).sub.4 ].sub.q --OR.sup.2,whereR.sup.1 is a linear or branched alkylene radical,R.sup.2 is a hydrogen atom, an alkyl radical or a radical of the formula --CO--R.sup.3, where R.sup.3 is an alkyl radical,G is a radical of the formula (IV) --R.sup.4 -(phenyl) which is substituted by [--Y.sub.(5-d) ] and (--R.sup.5.sub.d), with the proviso that at least one radical R.sup.5 is present andG.sup.1 is a radical of the formula (V) --(phenyl)-(R.sup.4).sub.d -- which is substituted by [--Y.sub.4-d ], whereR.sup.4 is a linear or branched, substituted or unsubstituted alkylene radical,R.sup.5 is a vinyl radical or isopropenyl radical,Y can be identical or different and each Y is a hydrogen atom or is as defined for R, or is a radical of the formula --OR.sup.6, whereR.sup.6 is a C.sub.1-8 alkyl radical optionally interrupted by an ether oxygen atom, andc is 0, 1 or 2, on average from 0.0 to 2.0,d is 1, 2 or 3,o is 0 or an integer from 1 to 100,p is 0 or an integer from 1 to 100, andq is 0 or an integer from 1 to 100, with the proviso that the sum o+p+q is >0.

    摘要翻译: 含有(甲基)苯乙烯基团的新型有机硅氧烷组合物并且可以基于A)包含至少一种式GRcO(4-c-1)/ 2(I)单元的低聚或聚合有机硅化合物或至少一个单元 (4-c-1)/ 2)RcSi-G1-RcSiO(4-c-1)/ 2(II)B)单体链烯氧基化合物,马来酸酯,富马酸酯的至少一个单元 ,马来酰亚胺,(甲基)丙烯酸酯,(甲基)苯乙烯,丙烯酰胺,衣康酸酯和/或低聚或聚合的有机硅化合物,其平均含有多于一个烯氧基,马来酸酯,富马酸酯,马来酰亚胺或(甲基)丙烯酸酯基团,其中R相同或 可以被卤化或未卤化的不同烃基或式-R1- [OCH2CH2] o- [OCH(CH3)CH2]对 - [O(CH2)4] q-OR2的基团,其中R1是直链或支链 亚烷基,R2是氢原子,烷基或式-CO-R3的基团,其中R3是烷基,G是式(IV)-R4-(苯基) h被[-Y(5-d)]和(-R5d)取代,条件是存在至少一个基团R 5,并且G 1是式(Ⅴ) - (苯基) - (R 4)d - 被[-Y4-d]取代,其中R4是直链或支链的取代或未取代的亚烷基,R5是乙烯基或异丙烯基,Y可以相同或不同,并且每个Y是氢原子或是 如R所定义,或者是式-OR 6的基团,其中R 6是任选被醚氧原子中断的C 1-8烷基,c是0,1或2,平均为0.0至2.0,d为 1,2或3,o为0或1〜100的整数,p为0或1〜100的整数,q为0或1〜100的整数,条件是+ o + p + q是> 0。

    Hydrophilic permanent organosilicon compounds
    3.
    发明授权
    Hydrophilic permanent organosilicon compounds 失效
    亲水性永久性有机硅化合物

    公开(公告)号:US6043362A

    公开(公告)日:2000-03-28

    申请号:US888557

    申请日:1997-07-07

    摘要: The invention relates to oxyalkylene-group-containing organosilicon compounds having units of the formula ##STR1## where R is identical or different, and denotes a monovalent halogenated or nonhalogenated hydrocarbon radical, X is identical or different and is a chlorine atom or a radical of the formula --OR.sup.1, where R.sup.1 denotes an alkyl radical which can be substituted by an ether oxygen atom,a is 0 or 1,b is 0, 1, 2 or 3,c is 0, 1, 2 or 3 and the total a+b+c.ltoreq.4 andA is a radical of the formula ##STR2## where R.sup.2 signifies an unbranched or branched substituted or unsubstituted divalent hydrocarbon radical, which may or may not contain ether, amine, sulfide, ester, amide, carbonate, urea and urethane groups, B is identical or different, and denotes X, --NR.sub.2.sup.1, --O--C(.dbd.O)--R.sup.1, --SR.sup.1 or a radical of the formula--NR.sup.3 R.sup.2 [O--CH(CH.sub.3)--CH.sub.2 ].sub.d [OCH.sub.2 CH.sub.2 ].sub.e [O(CH.sub.2).sub.4 ].sub.f OR.sup.4 (III),where X, R.sup.1 and R.sup.2 have the meanings given for these above, R.sup.3 is identical or different and is a hydrogen atom or has the meaning of R, R.sup.4 has the meaning of R.sup.3 or signifies a radical of the formula--C(.dbd.O)--R, --R.sup.2 NR.sub.2.sup.3, --NR.sup.3 R.sup.2 --, --R.sup.2 NR.sub.2.sup.3 H.sup.+ X.sup.-,d, e and f are an integer from 0 to 200, with the proviso that the sum d+e+f.gtoreq.1 and B contains at least one radical of the formula (III) per polymer molecule.

    摘要翻译: 本发明涉及具有下式的单元的含氧化烯基的有机硅化合物,其中R相同或不同,表示一价卤代或非卤代烃基,X相同或不同,为氯原子或式 - OR1,其中R1表示可被醚氧原子取代的烷基,a为0或1,b为0,1,2或3,c为0,1,2或3,总计a + b + C 4和A是下式的基团,其中R 2表示无支链或支链的取代或未取代的二价烃基,其可以含有或不含有醚,胺,硫醚,酯,酰胺,碳酸酯,脲和氨基甲酸酯基团, B表示相同或不同的表示X,-NR 21,-OC(= O)-R 1,-SR 1或-NR 3 R 2基团的基团[O-CH(CH 3)-CH 2] d [OCH 2 CH 2] CH 2)4] fOR 4(III),其中X,R 1和R 2具有上述含义,R 3相同或不同,为氢原子或具有R的含义,R 4具有平均 或表示式-C(= O)-R,-R2NR23,-NR3R2-,-R2NR23H + X,D,e和f的基团为0至200的整数,条件是 总和d + e + f> / = 1,B包含每个聚合物分子中至少一个式(III)的基团。

    Polysiloxanes containing heterocyclic functions, their preparation and
use
    4.
    发明授权
    Polysiloxanes containing heterocyclic functions, their preparation and use 失效
    含有杂环官能团的聚硅氧烷,其制备和用途

    公开(公告)号:US5969077A

    公开(公告)日:1999-10-19

    申请号:US163526

    申请日:1998-09-30

    摘要: Organosiloxane compounds bearing nitrogen-containing heterocycles, in which the heterocycles are bonded to a silicon atom via divalent radicals containing a unit of the general formula (I) ##STR1## in which E is one of the radicals --O--, --S--, --NR.sup.1 -- or --N.dbd., where R and R.sup.1 are each a C.sub.1 - to C.sub.20 -hydrocarbon radical which is optionally substituted by halogen, amine, ammonium or mercapto groups and may optionally be interrupted by groups chosen from --C(O)--, --C(O)--O--, --C(O)--NR.sup.3 --, --NR.sup.3 --, --O--, --S--, and--N.dbd. is a constituent of a heterocycle,can be used for the treatment of textile fibers, textile sheet materials and leather and as stabilizers in synthetic polymers.

    摘要翻译: 带有含氮杂环的有机硅氧烷化合物,其中杂环通过含有通式(I)的单元的二价基团键合到硅原子上,其中E是基团-O - , - S-,-NR1- 或-N =,其中R和R 1各自为任选被卤素,胺,铵或巯基取代的C 1 -C 20烃基,并且可以任选地被选自-C(O) - , - C (O)-O - , - C(O)-NR 3 - , - NR 3 - , - O - , - S-和-N =是杂环的成分,可用于纺织纤维,织物 片材和皮革以及合成聚合物中的稳定剂。

    Organosilicon compounds containing amino groups, their preparation and
their use
    5.
    发明授权
    Organosilicon compounds containing amino groups, their preparation and their use 失效
    含有氨基的有机硅化合物,其制备及其用途

    公开(公告)号:US5840951A

    公开(公告)日:1998-11-24

    申请号:US888405

    申请日:1997-07-07

    IPC分类号: C08G77/388 C08G77/54 C07F7/10

    CPC分类号: C08G77/54

    摘要: Organosilicon compounds containing amino groups, their preparation and their use Organosilicon compounds containing amino groups and comprising a) siloxane units of the formula R.sub.a Si(OR.sup.1).sub.b O.sub.(4-a-b)/2 (I) and b) at least one unit per molecule selected from the group consisting of units of the formulae AR.sub.C SiO.sub.(4-c-1)/2 (II), O.sub.(4-c-1)/2 R.sub.C Si--A.sup.1 --R.sub.C SiO.sub.(4-c-1)/2 (III) or ##STR1## where R is an identical or different hydrocarbon radical which has from 1 to 18 carbon atoms, optionally substituted by halogen atoms, alkoxy groups or hydroxy groups where the hydrocarbon radical is optionally interrupted by oxygen atoms, R.sup.1 is an identical or different alkyl radical which is optionally interrupted by oxygen atoms, a is 0, 1, 2 or 3 and b is 0, 1, 2 or 3, with the proviso that the sum a+b is not greater than 3, and c is 0, 1 or 2, A is a radical of the formula --R.sup.2 R.sup.3.sub.z N(--CR.sup.4.sub.2 --R.sup.5).sub.(2-z) (V), A.sup.1 is a radical of the formula ##STR2## and A.sup.2 is a radical of the formula ##STR3## where z is 0 or 1, R.sup.2 is an identical or different alkylene radical having from 2 to 8 carbon atoms, or a radical of the formula ##STR4## R.sup.3 is a hydrogen atom or an alkyl radical having from 1 to 8 carbon atoms, R.sup.4 is a hydrogen atom or an alkyl radical having from 1 to 8 carbon atoms, R.sup.5 is a radical of the formulae --CR.sup.6 .dbd.CR.sup.6.sub.2, --C.tbd.CR.sup.6, where R.sup.6 is identical or different and is a hydrogen atom or an alkyl radical having from 1 to 8 carbon atoms, with the proviso that the organosilicon compound containing amino groups has at least one siloxane unit of formula (II) per molecule and at least one unit selected from the group consisting of units of formulae (III) and (IV) per molecule.

    摘要翻译: 含有氨基的有机硅化合物及其制备及其用途含有氨基的有机硅化合物,包含a)式RaSi(OR1)bO(4-ab)/ 2(I))的硅氧烷单元,b)每分子选择至少一个单元 由式ARCSiO(4-c-1)/ 2(II),O(4-c-1)/ 2RCSi-A1-RCSiO(4-c-1)/ 2(III)或 (IV)其中R是具有1至18个碳原子的相同或不同的烃基,任选地被卤素原子,烷氧基或羟基取代,其中烃基任选被氧原子中断,R 1是相同的 或任选被氧原子间隔的不同烷基,a是0,1,2或3,b是0,1,2或3,条件是和a + b不大于3,c是 0,1或2,A是式-R 2 R 3 z N(-CR 42 -R 5)(2-z)(V)的基团,A 1是下式的基团(VI),并且A 2是 式(VII)其中z为0或1, R2是具有2至8个碳原子的相同或不同的亚烷基,或者式III的基团是氢原子或具有1至8个碳原子的烷基,R4是氢原子或烷基 具有1至8个碳原子的基团,R 5是下式的基团-CR 6 = CR 62,-C 3 CON CR 6,其中R 6相同或不同,并且是氢原子或具有1至8个碳原子的烷基, 含有氨基的有机硅化合物每分子具有至少一个式(II)的硅氧烷单元和至少一个选自每个分子式(III)和(IV)的单元的单元的单元。

    GUM BASE, CHEWING GUM PREPARATION PRODUCED THEREFROM AND METHODS FOR PRODUCTION THEREOF
    9.
    发明申请
    GUM BASE, CHEWING GUM PREPARATION PRODUCED THEREFROM AND METHODS FOR PRODUCTION THEREOF 审中-公开
    GUM基地,生产的CHEWING GUM制备物及其生产方法

    公开(公告)号:US20130309352A1

    公开(公告)日:2013-11-21

    申请号:US13863702

    申请日:2013-04-16

    IPC分类号: A23G4/08

    摘要: The invention relates to a gum base which, in comparison with known gum bases, has an improved aroma, taste and improved oxidation stability, has only low stickiness, and in addition is simple to process. It is a homogeneous composition containing 15-45% by weight of polyvinyl acetate, 10-30% by weight of vinyl laurate-vinyl acetate copolymers, 15-45% by weight of fillers, 5-30% by weight of waxes or fats, 1-10% by weight of plasticizers and 1-10% by weight of emulsifiers.

    摘要翻译: 本发明涉及一种胶基,其与已知的胶基相比具有改善的香气,味道和改善的氧化稳定性,仅具有低的粘性,并且还易于加工。 它是一种均匀的组合物,其含有15-45重量%的聚乙酸乙烯酯,10-30重量%的月桂酸乙烯酯 - 乙酸乙烯酯共聚物,15-45重量%的填料,5-30重量%的蜡或脂肪, 1-10重量%的增塑剂和1-10重量%的乳化剂。

    Thermoplastic silicone block copolymers, the production thereof and the use of the same
    10.
    发明授权
    Thermoplastic silicone block copolymers, the production thereof and the use of the same 失效
    热塑性硅酮嵌段共聚物,其生产方法及其用途

    公开(公告)号:US06824881B2

    公开(公告)日:2004-11-30

    申请号:US10451594

    申请日:2003-06-23

    IPC分类号: B32B2732

    摘要: Thermoplastic silicon block copolymers containing (A) a hard segment polymer constituent prepared from styrene, methylmethacrylate, butylacrylate, acrylonitrile, vinyl monomers, or mixtures therefore, and (B) a soft segment polymer constituent of general formula (I) G-[(SiR2O)mSiR2—X—]n(SiR2O)mSiR2-G wherein R is an optionally halogenated monovalent C1-18 hydrocarbon radical and X is a specific aryl group-containing, silicon bonded radical, and each G may be a radical (A)-Z-(Si) or Z′-(Si) wherein -Z- represents an aryl group-containing bivalent radical and Z′- represents a monovalent aryl group-containing radical, provided that there is, at most, one radical G and one radical Z′- in formula (I). In formula (I), m represents a whole number between 1 and 1000 and n represents 0 or a whole number between 1 and 20, provided that when n does not equal 0, 4≦n·m≦1000.

    摘要翻译: 含有(A)由苯乙烯,甲基丙烯酸甲酯,丙烯酸丁酯,丙烯腈,乙烯基单体或其混合物制备的硬链段聚合物组分的热塑性硅嵌段共聚物,和(B)通式(I)的软链段聚合物组分G - [(SiR 2 O )mSiR 2 -X-n(SiR 2 O)m SiR 2 -G其中R是任选卤代的一价C 1-18烃基,X是特定的含芳基的硅键合基团,并且每个G可以是基团(A) - Z-(Si)或Z' - (Si)其中-Z-表示含芳基的二价基团,Z'表示含单价芳基的基团,条件是至多存在一个基团G和一个 式(I)中的基团Z'-。 在式(I)中,m表示1与1000之间的整数,n表示0或1至20之间的整数,条件是当n不等于0时,4 <= n.m <= 1000。