公开(公告)号：US4838896A

公开(公告)日：1989-06-13

申请号：US151032

申请日：1988-02-01

Applicant: Bruno Kissling ,  Tibor Robinson

Inventor： Bruno Kissling ,  Tibor Robinson

IPC: C08L39/00 ,  D06M13/02 ,  D06M13/11 ,  D06M13/322 ,  D06M15/55 ,  D06M101/00 ,  D06M101/02 ,  D06M101/06 ,  D06M101/08 ,  D06P1/52 ,  D06P1/642 ,  D06P5/08

CPC classification number: D06P5/08 ,  C08L39/00 ,  D06P1/5242 ,  D06P1/642 ,  Y10S8/917 ,  Y10S8/918

Abstract: A mixture of a textile auxiliary (T) obtained by reacting epichlorohydrin and ammonia in defined mole ratio, and a polymeric compound (P) which is a water-soluble homopolymer of a mono- or di-allylamine, or a water-soluble copolymer consisting of mono-, di- or tri-allylamine units may be used as an aftertreatment agent for fixation of anionic and sulphur dyeings on cellulosic fibres. The treated dyeings have better fastness properties than dyeings treated with either (T) or (P) alone.

公开(公告)号：US4645511A

公开(公告)日：1987-02-24

申请号：US686135

申请日：1984-12-24

Applicant: Jurg Heller ,  Bruno Kissling ,  Tibor Robinson ,  Salvatore Valenti

Inventor： Jurg Heller ,  Bruno Kissling ,  Tibor Robinson ,  Salvatore Valenti

IPC: D06P3/60 ,  D06L3/12 ,  D06P1/30 ,  D06P1/41 ,  D06P3/62 ,  D06P5/08 ,  C09B62/00

CPC classification number: D06P3/62 ,  D06L3/1257 ,  D06P1/30 ,  D06P1/41 ,  D06P5/08 ,  Y10S8/917 ,  Y10S8/918 ,  Y10S8/924

Abstract: Aftertreatment of textile fibres which have been optically brightened or dyed or printed with certain direct dyes, or with basic or sulphur dyes, increases wet-fastness properties. The aftertreatment agent is a polymeric, polybasic amino compound, which is applied under alkaline conditions.

Abstract translation: 经过光学增白或染色或用某些直接染料或用碱性或硫色染料印花的纺织纤维的后处理提高了耐湿性。 后处理剂是在碱性条件下施用的聚合的多碱性氨基化合物。

公开(公告)号：US4599087A

公开(公告)日：1986-07-08

申请号：US686136

申请日：1984-12-24

Applicant: Jurg Heller ,  Bruno Kissling ,  Tibor Robinson ,  Salvatore Valenti

Inventor： Jurg Heller ,  Bruno Kissling ,  Tibor Robinson ,  Salvatore Valenti

IPC: C08G73/02 ,  D06L3/12 ,  D06M13/385 ,  D06P1/38 ,  D06P1/41 ,  D06P1/52 ,  D06P3/62 ,  D06P3/66 ,  D06P3/82 ,  D06P5/08

CPC classification number: D06P3/66 ,  C08G73/022 ,  D06L3/1257 ,  D06M13/385 ,  D06P1/38 ,  D06P1/41 ,  D06P1/5264 ,  D06P3/62 ,  D06P3/8252 ,  D06P5/08 ,  Y10S8/917 ,  Y10S8/918 ,  Y10S8/922 ,  Y10S8/924 ,  Y10S8/927

Abstract: Polymeric compounds (A) obtained by the reaction of epihalohydrin with a polyalkylene polyamine are useful as textile treatment agents. As pretreatment agents they improve the color yield of the subsequent dyeing, as aftertreatment agents they improve fastness properties. Certain of the products (A) are novel.

Abstract translation: 通过表卤代醇与聚亚烷基多胺反应获得的聚合物（A）可用作纺织品处理剂。 作为预处理剂，它们可以提高随后染色的颜色产率，作为后处理剂，它们可提高牢度性能。 某些产品（A）是新颖的。

公开(公告)号：US4410652A

公开(公告)日：1983-10-18

申请号：US347138

申请日：1982-02-09

Applicant: Tibor Robinson ,  Walter Knobel ,  Bruno Kissling

Inventor： Tibor Robinson ,  Walter Knobel ,  Bruno Kissling

IPC: D06P1/38 ,  C08G12/04 ,  C08G12/34 ,  C08G12/40 ,  D06M15/423 ,  D06M15/70 ,  D06P1/52 ,  D06P1/56 ,  D06P3/62 ,  D06P3/66 ,  D06P5/06 ,  D06P5/08 ,  C08L61/32

CPC classification number: C08G12/046 ,  C08G12/043 ,  C08G12/34 ,  D06M15/423 ,  D06P1/5264 ,  D06P1/56 ,  D06P3/62 ,  D06P3/66 ,  D06P5/08

Abstract: The wet fastness of direct dyes on cellulose substrates is improved by after-treatment with the reaction product of an amine with cyanamide, dicyanodiamide, guanidine or biguanidine which is further reacted with an N-methylol resin precursor, and heat curing in the presence of a catalyst. The unfixed portion of reactive dyes substantive to cellulose may also be given improved wet fastness by this treatment, so that washing to remove unfixed reactive dye may not be necessary.

Abstract translation: 直接染料在纤维素基质上的耐湿牢度通过胺与氨基氰，二氰基二酰胺，胍或双胍的反应产物进行后处理而得到改善，其与N-羟甲基树脂前体进一步反应，并在 催化剂。 通过这种处理，还可以赋予纤维素大量的活性染料的未固定部分改善的耐湿牢度，从而可能不需要洗涤去除未固定的活性染料。

公开(公告)号：US4225310A

公开(公告)日：1980-09-30

申请号：US920495

申请日：1978-06-29

Applicant: Brian Acton ,  Bruno Kissling ,  Tibor Robinson ,  Milica Urosevic

Inventor： Brian Acton ,  Bruno Kissling ,  Tibor Robinson ,  Milica Urosevic

IPC: D06M15/423 ,  D06M13/02 ,  D06M13/192 ,  D06M13/322 ,  D06M13/35 ,  D06M13/355 ,  D06M13/358 ,  D06M13/402 ,  D06M13/432 ,  D06M13/47 ,  D06M13/477 ,  D06M101/00 ,  D06M101/02 ,  D06M101/06 ,  D06M101/08 ,  D06M101/16 ,  D06M101/30 ,  D06M101/32 ,  D06P3/60 ,  D06P3/82 ,  D06P5/28

CPC classification number: D06P5/005 ,  D06P3/6033 ,  D06P3/8233

Abstract: The present invention provides a textile finishing process comprising applying to a substrate containing cellulose fibres an aqueous medium comprisingA. a water-soluble, monomeric, resin-forming precondensate consisting of one or more N-methylol derivates of melamine, urea, substituted ureas, triazones, carbamates and urones, or mixtures thereof, said derivative containing at least 3 N-methylol groups or their lower alkyl ethers,B. one or more compounds having solvent properties for disperse dyes, which also increase their substantivity to cellulose, and at the same time have affinity for polyester fibres.C. One or more reactive softeners which are capable of chemical reaction with the --OH groups of cellulose, thereby reducing their hydrophilic properties, andD. a catalyst system for the simultaneous cross-linking of components A, B and C which causes neglible yellowing of cellulose fibres up to a temperature of 220.degree. C.,subsequently drying the substrate and subjecting it to a temperature at which cross-linking takes place.The treated substrates have increased affinity for disperse dyes, as well as crease resistant properties.

Abstract translation: 本发明提供了一种纺织整理方法，其包括向含有纤维素纤维的基材施加包含A的水性介质。水溶性单体树脂形成性预缩合物，其由一种或多种三聚氰胺的N-羟甲基衍生物，尿素，取代的脲， 三唑酮，氨基甲酸酯和脲或其混合物，所述衍生物含有至少3个N-羟甲基或其低级烷基醚。B.一种或多种对分散染料具有溶剂性质的化合物，其也增加其对纤维素的亲和性， 同时对聚酯纤维有亲和力。 C.一种或多种反应性软化剂，其能够与纤维素的-OH基团发生化学反应，从而降低其亲水性质，以及D.用于同时交联组分A，B和C的催化剂体系，其导致可发黄化 的纤维素纤维，直到温度为220℃，随后干燥基材并使其处于发生交联的温度。 经处理的底物对分散染料具有增加的亲和力，以及抗皱性能。

公开(公告)号：US4200564A

公开(公告)日：1980-04-29

申请号：US952359

申请日：1978-10-18

Applicant: Paul Komminoth ,  Tibor Robinson ,  Milica Urosevic

Inventor： Paul Komminoth ,  Tibor Robinson ,  Milica Urosevic

IPC: D06M15/423 ,  D06M13/14 ,  D06M13/22 ,  D06M13/38

CPC classification number: D06M15/423

Abstract: Disclosed is a treatment process for textile substrates comprising or consisting of regenerated cellulose, which process comprises applying to the substrate an aqueous medium comprising (A) a monomeric, hydrolysis stable, hydrosoluble, resin forming cross linking agent containing at least two N-methylol or N-alkoxymethyl groups, (B) a hydrosoluble, prepolymerized, linear, filler resin forming, cross-linking agent, also containing at least two N-methylol or N-alkoxymethyl groups, (C) a reactive acetal of formula ##STR1## wherein X and Y, independently, are H or CH.sub.2 OH, (D) a first cross-linking catalyst, being an alkaline earth metal salt of a strong acid and (E) a second cross-linking catalyst, being an acidic aluminium salt, subsequently drying the substrate and subjecting same to a temperature at which cross-linking takes place, and an aqueous concentrate for use therein.

Abstract translation: 公开了一种用于包含再生纤维素或由再生纤维素组成的织物基材的处理方法，该方法包括向基材施加水性介质，该水性介质包含（A）单体，水解稳定的，可水解的树脂形成交联剂，其含有至少两个N-羟甲基或 N-烷氧基甲基，（B）还含有至少两个N-羟甲基或N-烷氧基甲基的水溶性预聚合的线性填料树脂形成交联剂，（C）式（IMA）的反应性缩醛，其中 X和Y独立地是H或CH 2 OH，（D）作为强酸的碱土金属盐的第一交联催化剂和（E）第二交联催化剂，作为酸性铝盐，随后干燥 该基底并经受相当于发生交联的温度，以及其中使用的含水浓缩物。

公开(公告)号：US4125652A

公开(公告)日：1978-11-14

申请号：US796640

申请日：1977-05-13

Applicant: Paul Komminoth ,  Tibor Robinson ,  Milica Urosevic

Inventor： Paul Komminoth ,  Tibor Robinson ,  Milica Urosevic

IPC: D06M13/02 ,  D06M13/137 ,  D06M13/322 ,  D06M13/402 ,  D06M13/432 ,  D06M15/423 ,  D06M15/427 ,  D06M15/45 ,  D06M101/00 ,  D06M101/02 ,  D06M101/06 ,  D06M101/08 ,  D06M13/14 ,  D06M13/22 ,  D06M13/38

CPC classification number: D06M15/423

Abstract: Disclosed is a treatment process for textile substrates comprising or consisting of regenerated cellulose, which process comprises applying to the substrate an aqueous medium comprising (A) a monomeric, hydrolysis stable, hydrosoluble, resin forming cross linking agent containing at least two N-methylol or N-alkoxymethyl groups, (B) a hydrosoluble, prepolymerised, linear, filler resin forming, cross-linking agent, also containing at least two N-methylol or N-alkoxymethyl groups, (C) a reactive acetal of formula ##STR1## wherein X and Y, independently, are H or CH.sub.2 OH, (D) a first cross-linking catalyst, being an alkaline earth metal salt of a strong acid and (E) a second cross-linking catalyst, being an acidic aluminium salt, subsequently drying the substrate and subjecting same to a temperature at which cross-linking takes place, and an aqueous concentrate for use therein.

Abstract translation: 公开了一种用于包含再生纤维素或由再生纤维素组成的织物基材的处理方法，该方法包括向基材施加水性介质，该水性介质包含（A）单体，水解稳定的，可水解的树脂形成交联剂，其含有至少两个N-羟甲基或 （B）还含有至少两个N-羟甲基或N-烷氧基甲基的（C）式XO（CH2）的反应性缩醛的水溶性预聚合的线性填料树脂形成交联剂， 2（CH 2）2 OCH 2 YO（CH 2）2 O（CH 2）2 OCH 2 + RF + TR＆lt; IMAGE＆gt;其中X和Y独立地是H或CH 2 OH，（D）第一交联催化剂， 强酸和（E）第二交联催化剂，其为酸性铝盐，随后将基材干燥并使其处于发生交联的温度，以及其中使用的含水浓缩物。

公开(公告)号：US4883615A

公开(公告)日：1989-11-28

申请号：US884853

申请日：1986-07-14

Applicant: Tibor Robinson ,  Rainer Wolf

Inventor： Tibor Robinson ,  Rainer Wolf

IPC: C08G12/02 ,  C08K5/521 ,  C08K5/527 ,  C08K5/5353

CPC classification number: C08G12/02 ,  C08K5/521 ,  C08K5/527 ,  C08K5/5353 ,  Y10T428/31551

Abstract: A process for flameproofing a substrate comprising applying to the substrate a compound of formula I ##STR1## in which R.sub.1.sup..sym. is a N.sup..sym. cation defined in the Specification and R.sub.2 and R.sub.3 are organic radicals.Substrates to which the compound of formula I can be applied include cellulosic substrates.

Abstract translation: 一种用于对衬底进行隔爆的方法，包括向所述衬底施加式I化合物（I），其中R 1（+）是在说明书中定义的N（+）阳离子，R2和R3是有机基团。 可以应用式I化合物的底物包括纤维素底物。

公开(公告)号：US4718918A

公开(公告)日：1988-01-12

申请号：US874984

申请日：1986-06-16

Applicant: Jurg Heller ,  Bruno Kissling ,  Tibor Robinson ,  Salvatore Valenti

Inventor： Jurg Heller ,  Bruno Kissling ,  Tibor Robinson ,  Salvatore Valenti

IPC: C08G73/02 ,  D06L3/12 ,  D06P1/38 ,  D06P1/41 ,  D06P1/52 ,  D06P3/62 ,  D06P3/66 ,  D06P3/82 ,  D06P5/08

CPC classification number: C08G73/022 ,  D06L3/1257 ,  D06P1/38 ,  D06P1/41 ,  D06P1/5264 ,  D06P3/62 ,  D06P3/66 ,  D06P3/8252 ,  D06P5/08 ,  Y10S8/917 ,  Y10S8/918 ,  Y10S8/922 ,  Y10S8/924 ,  Y10S8/927

Abstract: Polymeric compounds (A) obtained by the reaction of epihalo-hydrin with a polyalkylene polyamine are useful as textile treatment agents. As pretreatment agents they improve the color yield of the subsequent dyeing, as aftertreatment agents they improve fastness properties. Certain of the products (A) are novel.

Abstract translation: 通过表卤代醇与聚亚烷基多胺的反应获得的聚合物（A）可用作纺织品处理剂。 作为预处理剂，它们可以提高随后染色的颜色产率，作为后处理剂，它们可提高牢度性能。 某些产品（A）是新颖的。

公开(公告)号：US4443223A

公开(公告)日：1984-04-17

申请号：US413015

申请日：1982-08-30

Applicant: Bruno Kissling ,  Walter Knobel ,  Tibor Robinson

Inventor： Bruno Kissling ,  Walter Knobel ,  Tibor Robinson

IPC: C08G12/02 ,  C08G12/46 ,  C08L73/02 ,  D06P1/56 ,  D06P5/08 ,  C08G12/40 ,  D06M15/54

CPC classification number: C08L73/02 ,  C08G12/02 ,  C08G12/46 ,  D06P1/56 ,  D06P5/08 ,  Y10S8/918

Abstract: The fastness of direct dyes on cellulose substrates is improved by after-treatment with the reaction product of a quaternary polyalkylene polyamine with an N-methylol resin precursor, and heat curing in the presence of a catalyst. The unfixed portion of reactive dyes substantive to cellulose may also be given improved wet and light fastness by this treatment.

Abstract translation: 直接染料在纤维素基质上的坚牢度通过用四聚聚亚烷基多胺与N-羟甲基树脂前体的反应产物进行后处理，并在催化剂存在下加热固化而得到改善。 通过这种处理，还可以赋予纤维素大量的活性染料的未固定部分提供改善的耐湿和耐光性。