Process for preparing 2-(2-tert-butylaminoethoxy)ethanol (tert-butylaminodiglycol, TBADG)
    1.
    发明授权
    Process for preparing 2-(2-tert-butylaminoethoxy)ethanol (tert-butylaminodiglycol, TBADG) 有权
    制备2-(2-叔丁基氨基乙氧基)乙醇(叔丁基氨基二甘醇,TBADG)

    公开(公告)号:US08455693B2

    公开(公告)日:2013-06-04

    申请号:US13112161

    申请日:2011-05-20

    IPC分类号: C07C209/16

    摘要: A process for preparing 2-(2-tert-butylaminoethoxy)ethanol (tert-butylaminodiglycol, TBADG) by reacting diethylene glycol (DG) with tert-butylamine (TBA) in the presence of hydrogen and of a copper catalyst, by effecting the reaction at a temperature in the range from 160 to 220° C. in the presence of a copper- and aluminum oxide-containing catalyst, where the catalytically active material of the catalyst, before the reduction thereof with hydrogen, comprises 20 to 75% by weight of aluminum oxide (Al2O3), 20 to 75% by weight of oxygen compounds of copper, calculated as CuO, and ≦5% by weight of oxygen compounds of nickel, calculated as NiO.

    摘要翻译: 通过在氢气和铜催化剂的存在下使二甘醇(DG)与叔丁胺(TBA)反应,通过进行反应来制备2-(2-叔丁基氨基乙氧基)乙醇(叔丁基氨基二甘醇,TBADG) 在含有铜和氧化铝的催化剂的存在下,在160-220℃的温度下,催化剂的催化活性物质在用氢还原之前包含20-75重量% 的氧化铝(Al 2 O 3),20〜75重量%的作为CuO计算的铜的氧化合物,和5重量%的以NiO计的镍的氧化合物。

    PROCESS FOR PREPARING 2-(2-TERT-BUTYLAMINOETHOXY)ETHANOL (TERT-BUTYLAMINODIGLYCOL, TBADG)
    2.
    发明申请
    PROCESS FOR PREPARING 2-(2-TERT-BUTYLAMINOETHOXY)ETHANOL (TERT-BUTYLAMINODIGLYCOL, TBADG) 有权
    制备2-(2-叔丁基氨基甲酰氧基)乙醇(TERT-丁基氨基吡啶,TBADG)的方法

    公开(公告)号:US20110288337A1

    公开(公告)日:2011-11-24

    申请号:US13112161

    申请日:2011-05-20

    IPC分类号: C07C209/68

    摘要: A process for preparing 2-(2-tert-butylaminoethoxy)ethanol (tert-butylaminodiglycol, TBADG) by reacting diethylene glycol (DG) with tert-butylamine (TBA) in the presence of hydrogen and of a copper catalyst, by effecting the reaction at a temperature in the range from 160 to 220° C. in the presence of a copper- and aluminum oxide-containing catalyst, where the catalytically active material of the catalyst, before the reduction thereof with hydrogen, comprises 20 to 75% by weight of aluminum oxide (Al2O3), 20 to 75% by weight of oxygen compounds of copper, calculated as CuO, and ≦5% by weight of oxygen compounds of nickel, calculated as NiO.

    摘要翻译: 通过在氢气和铜催化剂的存在下使二甘醇(DG)与叔丁胺(TBA)反应,通过进行反应来制备2-(2-叔丁基氨基乙氧基)乙醇(叔丁基氨基二甘醇,TBADG) 在含有铜和氧化铝的催化剂的存在下,在160-220℃的温度下,催化剂的催化活性物质在用氢还原之前包含20-75重量% 的氧化铝(Al 2 O 3),20〜75重量%的作为CuO计算的铜的氧化合物和NiN计算的5重量%的镍氧化合物。

    PROCESS FOR RECOVERY OF CARBON DIOXIDE FROM A FLUID STREAM, IN PARTICULAR FROM SYNGAS
    4.
    发明申请
    PROCESS FOR RECOVERY OF CARBON DIOXIDE FROM A FLUID STREAM, IN PARTICULAR FROM SYNGAS 有权
    从流体流中回收二氧化碳的方法,特别是从SYNGAS

    公开(公告)号:US20120067059A1

    公开(公告)日:2012-03-22

    申请号:US13322125

    申请日:2010-05-25

    摘要: A process for removing carbon dioxide from a fluid comprises the steps of: (a) treating the fluid by bringing it into countercurrent contact with a liquid absorbent in a first absorption zone and thereafter in a second absorption zone to absorb at least part of the carbon dioxide contained in the fluid into the absorbent; (b) depressurizing the loaded absorbent to release a first stream of carbon dioxide and yield a partially regenerated absorbent; (c) recycling a first stream of the partially regenerated absorbent into the first absorption zone; (d) heating a second stream of the partially regenerated absorbent to release a second stream of carbon dioxide and yield a regenerated absorbent; (e) recycling the regenerated absorbent into the second absorption zone; (f) condensing water vapour entrained in the second stream of carbon dioxide by cooling the second stream of carbon dioxide and transferring at least part of the heat recovered to the partially regenerated absorbent by indirect heat exchange. The invention provides a two-stage carbon dioxide recovery process wherein the overall energy required for carbon dioxide recovery is reduced and/or wherein at least part of the carbon dioxide is recovered at a pressure higher than atmospheric pressure so as to reduce the energy required for compression of the carbon dioxide, e.g., for sequestration. Also disclosed is a plant for removing carbon dioxide from a fluid.

    摘要翻译: 从流体中除去二氧化碳的方法包括以下步骤:(a)通过使流体与第一吸收区中的液体吸收剂逆流接触,然后在第二吸收区中以吸收至少部分碳 包含在流体中的二氧化碳变成吸收剂; (b)减压负载的吸收剂以释放第一流二氧化碳并产生部分再生的吸收剂; (c)将部分再生的吸收剂的第一流再循环到第一吸收区中; (d)加热部分再生的吸收剂的第二料流以释放第二二氧化碳流并产生再生的吸收剂; (e)将再生的吸收剂再循环到第二吸收区; (f)通过冷却第二二氧化碳流将夹带在第二二氧化碳流中的水蒸汽冷凝,并通过间接热交换将至少部分回收的热量转移到部分再生的吸收剂中。 本发明提供二阶段二氧化碳回收方法,其中减少二氧化碳回收所需的总能量和/或其中至少部分二氧化碳在高于大气压的压力下回收,以便减少二氧化碳回收所需的能量 压缩二氧化碳,例如用于封存。 还公开了一种用于从流体中除去二氧化碳的设备。

    Process for recovery of carbon dioxide from a fluid stream, in particular from syngas
    6.
    发明授权
    Process for recovery of carbon dioxide from a fluid stream, in particular from syngas 有权
    从流体流,特别是合成气回收二氧化碳的方法

    公开(公告)号:US08795415B2

    公开(公告)日:2014-08-05

    申请号:US13322125

    申请日:2010-05-25

    IPC分类号: B01D53/14

    摘要: A process for removing carbon dioxide from a fluid comprises the steps of: (a) treating the fluid by bringing it into countercurrent contact with a liquid absorbent in a first absorption zone and thereafter in a second absorption zone to absorb at least part of the carbon dioxide contained in the fluid into the absorbent; (b) depressurizing the loaded absorbent to release a first stream of carbon dioxide and yield a partially regenerated absorbent; (c) recycling a first stream of the partially regenerated absorbent into the first absorption zone; (d) heating a second stream of the partially regenerated absorbent to release a second stream of carbon dioxide and yield a regenerated absorbent; (e) recycling the regenerated absorbent into the second absorption zone; (f) condensing water vapor entrained in the second stream of carbon dioxide by cooling the second stream of carbon dioxide and transferring at least part of the heat recovered to the partially regenerated absorbent by indirect heat exchange. The invention provides a two-stage carbon dioxide recovery process wherein the overall energy required for carbon dioxide recovery is reduced and/or wherein at least part of the carbon dioxide is recovered at a pressure higher than atmospheric pressure so as to reduce the energy required for compression of the carbon dioxide, e.g., for sequestration. Also disclosed is a plant for removing carbon dioxide from a fluid.

    摘要翻译: 从流体中除去二氧化碳的方法包括以下步骤:(a)通过使流体与第一吸收区中的液体吸收剂逆流接触,然后在第二吸收区中以吸收至少部分碳 包含在流体中的二氧化碳变成吸收剂; (b)减压负载的吸收剂以释放第一流二氧化碳并产生部分再生的吸收剂; (c)将部分再生的吸收剂的第一流再循环到第一吸收区中; (d)加热部分再生的吸收剂的第二料流以释放第二二氧化碳流并产生再生的吸收剂; (e)将再生的吸收剂再循环到第二吸收区; (f)通过冷却第二二氧化碳流将夹带在第二二氧化碳流中的水蒸汽冷凝,并通过间接热交换将至少部分回收的热量转移到部分再生的吸收剂中。 本发明提供二阶段二氧化碳回收方法,其中减少二氧化碳回收所需的总能量和/或其中至少部分二氧化碳在高于大气压的压力下回收,以便减少二氧化碳回收所需的能量 压缩二氧化碳,例如用于封存。 还公开了一种用于从流体中除去二氧化碳的设备。

    Method for obtaining a high pressure acid gas stream by removal of the acid gases from a fluid stream
    8.
    发明授权
    Method for obtaining a high pressure acid gas stream by removal of the acid gases from a fluid stream 有权
    通过从流体流中除去酸性气体来获得高压酸性气流的方法

    公开(公告)号:US07481988B2

    公开(公告)日:2009-01-27

    申请号:US10595749

    申请日:2004-11-05

    摘要: A method for obtaining an acid gas stream having a pressure of from 3 to 30 bar by removal of acid gases from a fluid stream containing H2S, the molar fraction of H2S based on the total amount of acid gases being at least 50 mol %, the method comprising bringing the fluid stream into intimate contact with a liquid absorption medium, thus producing a fluid stream substantially freed from acid gases and an acid-gas-loaded liquid absorption medium; separating the fluid stream and the liquid absorption medium; separating, by heating and optionally by expansion or stripping, the liquid absorption medium into an acid gas stream and a regenerated liquid absorption medium; passing the regenerated liquid absorption medium into a heat exchanger and cooling it there by using part of its thermal energy to heat up the acid-gas-loaded liquid absorption medium; and recirculating the regenerated liquid absorption medium.

    摘要翻译: 一种通过从含有H 2 S的流体流中除去酸性气体来获得压力为3至30巴的酸性气体流的方法,基于酸性气体的总量至少为50摩尔%的H 2 S的摩尔分数, 方法包括使流体流与液体吸收介质紧密接触,从而产生基本上不含酸性气体的流体流和载有酸性气体的液体吸收介质; 分离流体物流和液体吸收介质; 通过加热和任选地通过膨胀或汽提将液体吸收介质分离成酸性气体流和再生液体吸收介质; 将再生的液体吸收介质通入热交换器中并通过使用其热能的一部分来冷却其加热含有酸性气体的液体吸收介质; 并再循环再生液体吸收介质。